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MX2016008702A - Catalizadores soportados en polimeros naturales para la obtencion de carbonatos a partir de co2. - Google Patents

Catalizadores soportados en polimeros naturales para la obtencion de carbonatos a partir de co2.

Info

Publication number
MX2016008702A
MX2016008702A MX2016008702A MX2016008702A MX2016008702A MX 2016008702 A MX2016008702 A MX 2016008702A MX 2016008702 A MX2016008702 A MX 2016008702A MX 2016008702 A MX2016008702 A MX 2016008702A MX 2016008702 A MX2016008702 A MX 2016008702A
Authority
MX
Mexico
Prior art keywords
natural polymers
catalytic
catalysts supported
polymers
carbonates
Prior art date
Application number
MX2016008702A
Other languages
English (en)
Inventor
Martínez Palou Rafael
García De León Roberto
Guzmán Pantoja Javier
DÍAZ VELÁZQUEZ Heriberto
Original Assignee
Mexicano Inst Petrol
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Mexicano Inst Petrol filed Critical Mexicano Inst Petrol
Priority to MX2016008702A priority Critical patent/MX2016008702A/es
Priority to US15/631,089 priority patent/US20190193063A1/en
Publication of MX2016008702A publication Critical patent/MX2016008702A/es

Links

Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
    • B01J31/0234—Nitrogen-, phosphorus-, arsenic- or antimony-containing compounds
    • B01J31/0235—Nitrogen containing compounds
    • B01J31/0237—Amines
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
    • B01J31/0234—Nitrogen-, phosphorus-, arsenic- or antimony-containing compounds
    • B01J31/0235—Nitrogen containing compounds
    • B01J31/0241—Imines or enamines
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
    • B01J31/0234—Nitrogen-, phosphorus-, arsenic- or antimony-containing compounds
    • B01J31/0235—Nitrogen containing compounds
    • B01J31/0244—Nitrogen containing compounds with nitrogen contained as ring member in aromatic compounds or moieties, e.g. pyridine
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
    • B01J31/0234—Nitrogen-, phosphorus-, arsenic- or antimony-containing compounds
    • B01J31/0235—Nitrogen containing compounds
    • B01J31/0245—Nitrogen containing compounds being derivatives of carboxylic or carbonic acids
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
    • B01J31/06—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing polymers
    • B01J31/061—Chiral polymers
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/26—Catalysts comprising hydrides, coordination complexes or organic compounds containing in addition, inorganic metal compounds not provided for in groups B01J31/02 - B01J31/24
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/02—Impregnation, coating or precipitation
    • B01J37/0236—Drying, e.g. preparing a suspension, adding a soluble salt and drying
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/04—Mixing
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D317/00—Heterocyclic compounds containing five-membered rings having two oxygen atoms as the only ring hetero atoms
    • C07D317/08—Heterocyclic compounds containing five-membered rings having two oxygen atoms as the only ring hetero atoms having the hetero atoms in positions 1 and 3
    • C07D317/10—Heterocyclic compounds containing five-membered rings having two oxygen atoms as the only ring hetero atoms having the hetero atoms in positions 1 and 3 not condensed with other rings
    • C07D317/32—Heterocyclic compounds containing five-membered rings having two oxygen atoms as the only ring hetero atoms having the hetero atoms in positions 1 and 3 not condensed with other rings with hetero atoms or with carbon atoms having three bonds to hetero atoms with at the most one bond to halogen, e.g. ester or nitrile radicals, directly attached to ring carbon atoms
    • C07D317/34—Oxygen atoms
    • C07D317/36—Alkylene carbonates; Substituted alkylene carbonates
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2231/00—Catalytic reactions performed with catalysts classified in B01J31/00
    • B01J2231/30—Addition reactions at carbon centres, i.e. to either C-C or C-X multiple bonds
    • B01J2231/34—Other additions, e.g. Monsanto-type carbonylations, addition to 1,2-C=X or 1,2-C-X triplebonds, additions to 1,4-C=C-C=X or 1,4-C=-C-X triple bonds with X, e.g. O, S, NH/N
    • B01J2231/341—1,2-additions, e.g. aldol or Knoevenagel condensations
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2231/00—Catalytic reactions performed with catalysts classified in B01J31/00
    • B01J2231/40—Substitution reactions at carbon centres, e.g. C-C or C-X, i.e. carbon-hetero atom, cross-coupling, C-H activation or ring-opening reactions
    • B01J2231/48—Ring-opening reactions
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/001—General concepts, e.g. reviews, relating to catalyst systems and methods of making them, the concept being defined by a common material or method/theory
    • B01J2531/002—Materials
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J27/00—Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds
    • B01J27/06—Halogens; Compounds thereof
    • B01J27/08—Halides

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Inorganic Chemistry (AREA)
  • Catalysts (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
  • Polyesters Or Polycarbonates (AREA)

Abstract

La presente invención describe un procedimiento para preparar sistemas catalíticos basados en sales metálicas, soportadas en polímeros naturales y co-auxilidadas por bases orgánicas, para la transformación catalítica de Dióxido de carbono en carbonatos orgánicos por medio de reacciones de cicloadición a epóxidos. Las ventajas del sistema presentado se pueden resumir en el uso de materias primas de bajo costo para la preparación del sistema catalítico, reducido impacto ambiental por tratarse de materiales de muy baja toxicidad y/o biodegradables tales como los polímeros de origen natural, así como una alta eficiencia catalítica al lograr selectividades del 100% y en algunos casos rendimientos cuantitativos.
MX2016008702A 2016-06-30 2016-06-30 Catalizadores soportados en polimeros naturales para la obtencion de carbonatos a partir de co2. MX2016008702A (es)

Priority Applications (2)

Application Number Priority Date Filing Date Title
MX2016008702A MX2016008702A (es) 2016-06-30 2016-06-30 Catalizadores soportados en polimeros naturales para la obtencion de carbonatos a partir de co2.
US15/631,089 US20190193063A1 (en) 2016-06-30 2017-06-23 Catalysts supported on natural polymers for the production of carbonates from co2

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
MX2016008702A MX2016008702A (es) 2016-06-30 2016-06-30 Catalizadores soportados en polimeros naturales para la obtencion de carbonatos a partir de co2.

Publications (1)

Publication Number Publication Date
MX2016008702A true MX2016008702A (es) 2018-01-01

Family

ID=61437348

Family Applications (1)

Application Number Title Priority Date Filing Date
MX2016008702A MX2016008702A (es) 2016-06-30 2016-06-30 Catalizadores soportados en polimeros naturales para la obtencion de carbonatos a partir de co2.

Country Status (2)

Country Link
US (1) US20190193063A1 (es)
MX (1) MX2016008702A (es)

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN113522336A (zh) * 2021-07-12 2021-10-22 宁波杭州湾新材料研究院 负载铝单原子的氮掺杂碳材料、其制备方法及应用
CN115404696A (zh) * 2021-05-26 2022-11-29 天津大学 一种多巴胺醌纤维及其制备方法、应用、应用方法

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* Cited by examiner, † Cited by third party
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CN115582149B (zh) * 2021-07-05 2023-10-31 中国石油化工股份有限公司 一种用于合成碳酸亚烷基酯的催化剂及其制备和应用
CN114082442B (zh) * 2021-11-18 2024-01-19 河南大学 丁二酰亚胺基离子液体及用其催化合成喹唑啉-2,4(1h,3h)-二酮的方法
CN114044893B (zh) * 2021-11-22 2023-04-28 常州大学 一种用于二氧化碳和环氧化合物共聚的催化剂及其制备方法
CN116408119B (zh) * 2021-12-29 2024-11-01 中国石油天然气股份有限公司 一种用于co2和环氧化物合成环碳酸酯的非金属催化剂、制备方法及应用
CN114437364B (zh) * 2022-01-26 2023-02-28 青岛科技大学 金属耦合三嗪多孔有机框架及其构筑方法和催化co2与环氧化物耦合制备环状碳酸酯应用
CN114887658B (zh) * 2022-05-12 2024-03-05 合肥工业大学 树枝状介孔二氧化硅微球负载卡宾催化剂及其在催化二氧化碳合成环状碳酸酯中的应用
CN115677928B (zh) * 2022-10-28 2023-10-20 浙江理工大学 一种双功能咪唑基离子液体交联共聚物及其制备方法和催化应用
CN119613406A (zh) * 2024-09-11 2025-03-14 沈阳工业大学 一种碱性离子液体催化剂、制备方法及其应用

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN115404696A (zh) * 2021-05-26 2022-11-29 天津大学 一种多巴胺醌纤维及其制备方法、应用、应用方法
CN115404696B (zh) * 2021-05-26 2023-12-12 天津大学 一种多巴胺醌纤维及其制备方法、应用、应用方法
CN113522336A (zh) * 2021-07-12 2021-10-22 宁波杭州湾新材料研究院 负载铝单原子的氮掺杂碳材料、其制备方法及应用
CN113522336B (zh) * 2021-07-12 2023-06-23 宁波杭州湾新材料研究院 负载铝单原子的氮掺杂碳材料、其制备方法及应用

Also Published As

Publication number Publication date
US20190193063A1 (en) 2019-06-27

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