[go: up one dir, main page]

MX2016008059A - Composicion catalizadora para polimerizacion de olefinas. - Google Patents

Composicion catalizadora para polimerizacion de olefinas.

Info

Publication number
MX2016008059A
MX2016008059A MX2016008059A MX2016008059A MX2016008059A MX 2016008059 A MX2016008059 A MX 2016008059A MX 2016008059 A MX2016008059 A MX 2016008059A MX 2016008059 A MX2016008059 A MX 2016008059A MX 2016008059 A MX2016008059 A MX 2016008059A
Authority
MX
Mexico
Prior art keywords
catalyst composition
polymerization
present
formula
carbon atoms
Prior art date
Application number
MX2016008059A
Other languages
English (en)
Inventor
Brijlal Sainani Jaiprakash
Taftaf Mansour
Aleksandrovich Zakharov Vladimir
Dimitrievich Bukatov Gennadii
Andreevich Sergeev Sergei
Alexander Zuideveld Martin
Ghalit Nourdin
Alexandra Batinas-Geurts Aurora
Mahendrabhai Patel Vimalkumar
Original Assignee
Saudi Basic Ind Corp
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Saudi Basic Ind Corp filed Critical Saudi Basic Ind Corp
Publication of MX2016008059A publication Critical patent/MX2016008059A/es

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/65—Pretreating the metal or compound covered by group C08F4/64 before the final contacting with the metal or compound covered by group C08F4/44
    • C08F4/651—Pretreating with non-metals or metal-free compounds
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C233/00—Carboxylic acid amides
    • C07C233/64—Carboxylic acid amides having carbon atoms of carboxamide groups bound to carbon atoms of six-membered aromatic rings
    • C07C233/67—Carboxylic acid amides having carbon atoms of carboxamide groups bound to carbon atoms of six-membered aromatic rings having the nitrogen atom of at least one of the carboxamide groups bound to a carbon atom of a hydrocarbon radical substituted by singly-bound oxygen atoms
    • C07C233/68—Carboxylic acid amides having carbon atoms of carboxamide groups bound to carbon atoms of six-membered aromatic rings having the nitrogen atom of at least one of the carboxamide groups bound to a carbon atom of a hydrocarbon radical substituted by singly-bound oxygen atoms with the substituted hydrocarbon radical bound to the nitrogen atom of the carboxamide group by an acyclic carbon atom
    • C07C233/69—Carboxylic acid amides having carbon atoms of carboxamide groups bound to carbon atoms of six-membered aromatic rings having the nitrogen atom of at least one of the carboxamide groups bound to a carbon atom of a hydrocarbon radical substituted by singly-bound oxygen atoms with the substituted hydrocarbon radical bound to the nitrogen atom of the carboxamide group by an acyclic carbon atom of an acyclic saturated carbon skeleton
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
    • B01J31/0201—Oxygen-containing compounds
    • B01J31/0202—Alcohols or phenols
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C233/00—Carboxylic acid amides
    • C07C233/01—Carboxylic acid amides having carbon atoms of carboxamide groups bound to hydrogen atoms or to acyclic carbon atoms
    • C07C233/16—Carboxylic acid amides having carbon atoms of carboxamide groups bound to hydrogen atoms or to acyclic carbon atoms having the nitrogen atom of at least one of the carboxamide groups bound to a carbon atom of a hydrocarbon radical substituted by singly-bound oxygen atoms
    • C07C233/17—Carboxylic acid amides having carbon atoms of carboxamide groups bound to hydrogen atoms or to acyclic carbon atoms having the nitrogen atom of at least one of the carboxamide groups bound to a carbon atom of a hydrocarbon radical substituted by singly-bound oxygen atoms with the substituted hydrocarbon radical bound to the nitrogen atom of the carboxamide group by an acyclic carbon atom
    • C07C233/18—Carboxylic acid amides having carbon atoms of carboxamide groups bound to hydrogen atoms or to acyclic carbon atoms having the nitrogen atom of at least one of the carboxamide groups bound to a carbon atom of a hydrocarbon radical substituted by singly-bound oxygen atoms with the substituted hydrocarbon radical bound to the nitrogen atom of the carboxamide group by an acyclic carbon atom having the carbon atom of the carboxamide group bound to a hydrogen atom or to a carbon atom of an acyclic saturated carbon skeleton
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C235/00—Carboxylic acid amides, the carbon skeleton of the acid part being further substituted by oxygen atoms
    • C07C235/42—Carboxylic acid amides, the carbon skeleton of the acid part being further substituted by oxygen atoms having carbon atoms of carboxamide groups bound to carbon atoms of six-membered aromatic rings and singly-bound oxygen atoms bound to the same carbon skeleton
    • C07C235/44—Carboxylic acid amides, the carbon skeleton of the acid part being further substituted by oxygen atoms having carbon atoms of carboxamide groups bound to carbon atoms of six-membered aromatic rings and singly-bound oxygen atoms bound to the same carbon skeleton with carbon atoms of carboxamide groups and singly-bound oxygen atoms bound to carbon atoms of the same non-condensed six-membered aromatic ring
    • C07C235/48—Carboxylic acid amides, the carbon skeleton of the acid part being further substituted by oxygen atoms having carbon atoms of carboxamide groups bound to carbon atoms of six-membered aromatic rings and singly-bound oxygen atoms bound to the same carbon skeleton with carbon atoms of carboxamide groups and singly-bound oxygen atoms bound to carbon atoms of the same non-condensed six-membered aromatic ring having the nitrogen atom of at least one of the carboxamide groups bound to an acyclic carbon atom of a hydrocarbon radical substituted by singly-bound oxygen atoms
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F110/00—Homopolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F110/04—Monomers containing three or four carbon atoms
    • C08F110/06—Propene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2/00—Processes of polymerisation
    • C08F2/38—Polymerisation using regulators, e.g. chain terminating agents, e.g. telomerisation
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/65—Pretreating the metal or compound covered by group C08F4/64 before the final contacting with the metal or compound covered by group C08F4/44
    • C08F4/652—Pretreating with metals or metal-containing compounds
    • C08F4/656—Pretreating with metals or metal-containing compounds with silicon or compounds thereof
    • C08F4/6565—Pretreating with metals or metal-containing compounds with silicon or compounds thereof and magnesium or compounds thereof
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2231/00—Catalytic reactions performed with catalysts classified in B01J31/00
    • B01J2231/60—Reduction reactions, e.g. hydrogenation
    • B01J2231/64—Reductions in general of organic substrates, e.g. hydride reductions or hydrogenations
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/001—General concepts, e.g. reviews, relating to catalyst systems and methods of making them, the concept being defined by a common material or method/theory
    • B01J2531/002—Materials
    • B01J2531/007—Promoter-type Additives
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2410/00—Features related to the catalyst preparation, the catalyst use or to the deactivation of the catalyst
    • C08F2410/01—Additive used together with the catalyst, excluding compounds containing Al or B
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2500/00—Characteristics or properties of obtained polyolefins; Use thereof
    • C08F2500/04—Broad molecular weight distribution, i.e. Mw/Mn > 6
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2500/00—Characteristics or properties of obtained polyolefins; Use thereof
    • C08F2500/12—Melt flow index or melt flow ratio
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2500/00—Characteristics or properties of obtained polyolefins; Use thereof
    • C08F2500/15—Isotactic

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Health & Medical Sciences (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)

Abstract

La presente invención se relaciona con una composición catalizadora que comprende el compuesto representado por la Fórmula (I) como un donante de electrones interno, Fórmula I en donde: R1, R2, R3, R4, R5 y R6 son los mismos o diferentes y se seleccionan independientemente de un grupo que consiste de hidrógeno, alquilo recto, ramificado o cíclico e hidrocarbilo sustituido o no sustituido aromático que tiene 1 a 20 átomos de carbono; R7 se selecciona de un grupo que consiste de alquilo recto, ramificado o cíclico e hidrocarbilo sustituido o no sustituido aromático que tiene 1 a 20 átomos de carbono; y R8 se selecciona de un grupo que consiste de hidrocarbilo sustituido o no sustituido aromático que tiene 6 a 20 átomos de carbono; N es átomo de nitrógeno; O es átomo de oxígeno; y C es átomo de carbono. La presente invención también se relaciona con un proceso para preparar dicha composición catalizadora de polimerización y con un sistema de catalizador de polimerización que comprende dicha composición catalizadora, un co-catalizador y opcionalmente un donante de electrones externo. Adicionalmente, la presente invención se relaciona con una poliolefina que se puede obtener por el proceso de acuerdo con la presente invención y al uso del compuesto de la fórmula I como un donante de electrones interno en catalizadores para polimerización de olefinas.
MX2016008059A 2013-12-20 2014-12-19 Composicion catalizadora para polimerizacion de olefinas. MX2016008059A (es)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
EP13199170 2013-12-20
US201461939962P 2014-02-14 2014-02-14
PCT/EP2014/078790 WO2015091978A1 (en) 2013-12-20 2014-12-19 Catalyst composition for polymerization of olefins

Publications (1)

Publication Number Publication Date
MX2016008059A true MX2016008059A (es) 2017-03-03

Family

ID=49876482

Family Applications (1)

Application Number Title Priority Date Filing Date
MX2016008059A MX2016008059A (es) 2013-12-20 2014-12-19 Composicion catalizadora para polimerizacion de olefinas.

Country Status (8)

Country Link
US (1) US10059656B2 (es)
EP (1) EP3083711B1 (es)
KR (1) KR102274225B1 (es)
CN (1) CN106062013B (es)
BR (1) BR112016013609B1 (es)
EA (1) EA029517B1 (es)
MX (1) MX2016008059A (es)
WO (1) WO2015091978A1 (es)

Families Citing this family (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US10000591B2 (en) 2013-12-20 2018-06-19 Saudi Basic Industries Corporation Catalyst system for polymerization of an olefin
WO2015091982A1 (en) 2013-12-20 2015-06-25 Saudi Basic Industries Corporation Catalyst system for polymerisation of an olefin
US9926391B2 (en) 2013-12-20 2018-03-27 Saudi Basic Industries Corporation Catalyst system for polymerization of an olefin
EA028922B1 (ru) 2013-12-20 2018-01-31 Сауди Бейсик Индастриз Корпорейшн Прокатализатор для полимеризации олефинов
MX2016008022A (es) 2013-12-20 2017-05-10 Saudi Basic Ind Corp Sistema catalizador para polimerizacion de una olefina.
US9944731B2 (en) 2013-12-20 2018-04-17 Saudi Basic Industries Corporation Catalyst system for polymerization of an olefin
EP3383925B1 (en) * 2015-12-02 2023-10-18 SABIC Global Technologies B.V. A procatalyst for polymerization of olefins
US10766854B2 (en) * 2017-10-20 2020-09-08 Sabic Global Technologies B.V. Synthesis method for the preparation of dibenzoate compounds, such as 4-[benzoyl(methyl)amino]pentane-2-yl dibenzoate

Family Cites Families (12)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4384087A (en) 1980-03-24 1983-05-17 Phillips Petroleum Company Composition of matter and method of preparing same, catalyst, method of producing the catalyst and polymerization process employing the catalyst
WO1996032426A1 (en) 1995-04-10 1996-10-17 Dsm N.V. Method for the preparation of a catalyst suitable for the polymerisation of an olefine
EP1086961A1 (en) 1999-09-27 2001-03-28 Dsm N.V. Process for the preparation of a catalyst component for the polymerisation of an olefin
EA013392B1 (ru) 2006-05-24 2010-04-30 Сауди Бейсик Индастриз Корпорейшн Способ получения каталитического компонента для полимеризации пропилена
EP1862480B1 (en) 2006-05-31 2016-07-27 Borealis Technology Oy Process for preparing an olefin polymerisation catalyst component with improved high temperature activity
JP5583973B2 (ja) 2006-12-22 2014-09-03 バーゼル・ポリオレフィン・イタリア・ソチエタ・ア・レスポンサビリタ・リミタータ オレフィン重合用の触媒成分及びそれから得られる触媒
US8344079B2 (en) * 2007-12-31 2013-01-01 Basf Corporation Molar ratio modifications to larger polyolefin catalysts
MY157180A (en) * 2010-02-26 2016-05-10 Grace W R & Co Procatalyst composition with substituted amide ester internal electron donor
US8551903B2 (en) * 2010-02-26 2013-10-08 Dow Global Technologies Llc Amide ester internal electron donor and process
US8466081B2 (en) * 2010-02-26 2013-06-18 Dow Global Technologies Llc Halogenated amide ester and internal electron donor with same
EP2867264B1 (en) * 2012-06-29 2016-04-20 Saudi Basic Industries Corporation Catalyst composition for polymerization of olefins
US9926391B2 (en) 2013-12-20 2018-03-27 Saudi Basic Industries Corporation Catalyst system for polymerization of an olefin

Also Published As

Publication number Publication date
BR112016013609A2 (pt) 2017-08-08
US20160340293A1 (en) 2016-11-24
WO2015091978A1 (en) 2015-06-25
EP3083711B1 (en) 2023-02-22
CN106062013B (zh) 2019-07-16
EP3083711A1 (en) 2016-10-26
BR112016013609B1 (pt) 2021-11-09
KR20160102016A (ko) 2016-08-26
EA029517B1 (ru) 2018-04-30
KR102274225B1 (ko) 2021-07-08
US10059656B2 (en) 2018-08-28
EA201691281A1 (ru) 2016-11-30
CN106062013A (zh) 2016-10-26

Similar Documents

Publication Publication Date Title
IN2014DN10763A (es)
MX2016008059A (es) Composicion catalizadora para polimerizacion de olefinas.
EA201500779A1 (ru) Каталитическая композиция для полимеризации олефинов
MX2016015768A (es) Procatalizador para la polimerizacion de olefinas.
EA201400935A1 (ru) Компонент катализатора для полимеризации олефинов
EA201692489A1 (ru) Прокатализатор полимеризации олефинов, содержащий сложный моноэфир и амидобензоатный внутренний донор
MY178722A (en) Catalyst component for olefin polymerization, preparation method thereof, and catalyst comprising same
SA515360595B1 (ar) المحفز المساعد زيجلر ناتا المدعم للبلمرة المتعددة للإيثيلين
EP2532687A3 (en) Bridged Metallocene Catalysts
MY167604A (en) Coupling agent for rubber/carbon black, and rubber composition containing same for use in tires
IN2014DN10723A (es)
PH12012501851A1 (en) Tetrahydrobenzothiophene compound
EA201990805A1 (ru) Прокатализатор для полимеризации олефинов
MY194796A (en) Method for preparing isoxazoline-containing uracil compound through methylation
SA520410979B1 (ar) محفز أوليجومرية أوليفين وطريقة لإنتاج أوليجومر أوليفين في وجود نفس المحفز
EA038511B9 (ru) Прокатализатор для полимеризации олефинов
PH12013502187A1 (en) Nitrogenated heterocyclic compound and agricultural or horticultural fungicide
EA201690387A1 (ru) Каталитическая система для полимеризации олефинов
MY170262A (en) Dicarboxylic acid compound
WO2012134719A3 (en) Novel catalysts and methods of use thereof to produce vinyl terminated polymers
MX2015009774A (es) Composiciones catalizadoras novedosas y metodos para su elaboracion y uso.
MX2016008036A (es) Sistema catalizador para polimerizacion de una olefina.
WO2013131912A3 (en) Catalyst components for the polymerization of olefins
BR112016012971A2 (pt) Complexo de metal-ligante, catalisador e processo para preparar uma poliolefina
MX2020002205A (es) Composicion no acuosa reticulable.