MX2015015312A - Proceso para la sintesis de 5-hidroximetilfurfural a partir de sacaridos. - Google Patents
Proceso para la sintesis de 5-hidroximetilfurfural a partir de sacaridos.Info
- Publication number
- MX2015015312A MX2015015312A MX2015015312A MX2015015312A MX2015015312A MX 2015015312 A MX2015015312 A MX 2015015312A MX 2015015312 A MX2015015312 A MX 2015015312A MX 2015015312 A MX2015015312 A MX 2015015312A MX 2015015312 A MX2015015312 A MX 2015015312A
- Authority
- MX
- Mexico
- Prior art keywords
- synthesis
- sacaridos
- hydroximethylfurfural
- hydroxymethylfurfural
- hmf
- Prior art date
Links
- 238000000034 method Methods 0.000 title abstract 3
- 230000015572 biosynthetic process Effects 0.000 title abstract 2
- 238000003786 synthesis reaction Methods 0.000 title abstract 2
- NOEGNKMFWQHSLB-UHFFFAOYSA-N 5-hydroxymethylfurfural Chemical compound OCC1=CC=C(C=O)O1 NOEGNKMFWQHSLB-UHFFFAOYSA-N 0.000 abstract 4
- RJGBSYZFOCAGQY-UHFFFAOYSA-N hydroxymethylfurfural Natural products COC1=CC=C(C=O)O1 RJGBSYZFOCAGQY-UHFFFAOYSA-N 0.000 abstract 4
- 150000001720 carbohydrates Chemical class 0.000 abstract 1
- 125000004432 carbon atom Chemical group C* 0.000 abstract 1
- 230000018044 dehydration Effects 0.000 abstract 1
- 238000006297 dehydration reaction Methods 0.000 abstract 1
- 150000002016 disaccharides Chemical class 0.000 abstract 1
- 150000004676 glycans Chemical class 0.000 abstract 1
- 150000002402 hexoses Chemical class 0.000 abstract 1
- 150000002772 monosaccharides Chemical class 0.000 abstract 1
- 229920001542 oligosaccharide Polymers 0.000 abstract 1
- 150000002482 oligosaccharides Chemical class 0.000 abstract 1
- 229920001282 polysaccharide Polymers 0.000 abstract 1
- 239000005017 polysaccharide Substances 0.000 abstract 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J27/00—Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds
- B01J27/14—Phosphorus; Compounds thereof
- B01J27/186—Phosphorus; Compounds thereof with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
- B01J27/188—Phosphorus; Compounds thereof with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium with chromium, molybdenum, tungsten or polonium
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J35/00—Catalysts, in general, characterised by their form or physical properties
- B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
- B01J35/61—Surface area
- B01J35/615—100-500 m2/g
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D307/00—Heterocyclic compounds containing five-membered rings having one oxygen atom as the only ring hetero atom
- C07D307/02—Heterocyclic compounds containing five-membered rings having one oxygen atom as the only ring hetero atom not condensed with other rings
- C07D307/34—Heterocyclic compounds containing five-membered rings having one oxygen atom as the only ring hetero atom not condensed with other rings having two or three double bonds between ring members or between ring members and non-ring members
- C07D307/38—Heterocyclic compounds containing five-membered rings having one oxygen atom as the only ring hetero atom not condensed with other rings having two or three double bonds between ring members or between ring members and non-ring members with substituted hydrocarbon radicals attached to ring carbon atoms
- C07D307/40—Radicals substituted by oxygen atoms
- C07D307/46—Doubly bound oxygen atoms, or two oxygen atoms singly bound to the same carbon atom
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D307/00—Heterocyclic compounds containing five-membered rings having one oxygen atom as the only ring hetero atom
- C07D307/02—Heterocyclic compounds containing five-membered rings having one oxygen atom as the only ring hetero atom not condensed with other rings
- C07D307/34—Heterocyclic compounds containing five-membered rings having one oxygen atom as the only ring hetero atom not condensed with other rings having two or three double bonds between ring members or between ring members and non-ring members
- C07D307/38—Heterocyclic compounds containing five-membered rings having one oxygen atom as the only ring hetero atom not condensed with other rings having two or three double bonds between ring members or between ring members and non-ring members with substituted hydrocarbon radicals attached to ring carbon atoms
- C07D307/40—Radicals substituted by oxygen atoms
- C07D307/46—Doubly bound oxygen atoms, or two oxygen atoms singly bound to the same carbon atom
- C07D307/48—Furfural
- C07D307/50—Preparation from natural products
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Furan Compounds (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
- Saccharide Compounds (AREA)
- Catalysts (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Abstract
Esta invención se relaciona a un nuevo proceso para la síntesis de 5-hidroximetilfurfural (HMF) a partir de sacáridos. En particular esta invención se relaciona a un nuevo proceso para la deshidratación de monosacáridos que tienen 6 átomos de carbono (hexosas), disacáridos, oligosacáridos y polisacáridos que se derivan de los mismos para producir 5-hidroximetilfurfural (HMF) altamente puro en alto rendimiento.
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| IT000003A ITNO20130003A1 (it) | 2013-05-09 | 2013-05-09 | Processo di sintesi di 5-idrossimetilfurfurale da saccaridi |
| PCT/EP2014/059538 WO2014180979A1 (en) | 2013-05-09 | 2014-05-09 | Process for the synthesis of 5-hydroxymethylfurfural from saccharides |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| MX2015015312A true MX2015015312A (es) | 2016-07-26 |
| MX376575B MX376575B (es) | 2025-03-07 |
Family
ID=48748412
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| MX2015015312A MX376575B (es) | 2013-05-09 | 2014-05-09 | Proceso para la síntesis de 5-hidroximetilfurfural a partir de sacáridos. |
Country Status (11)
| Country | Link |
|---|---|
| US (1) | US9409877B2 (es) |
| EP (1) | EP2994458B1 (es) |
| JP (1) | JP2016521281A (es) |
| KR (1) | KR20160005358A (es) |
| CN (1) | CN105377825B (es) |
| BR (1) | BR112015028117B1 (es) |
| CA (1) | CA2909881C (es) |
| ES (1) | ES2624487T3 (es) |
| IT (1) | ITNO20130003A1 (es) |
| MX (1) | MX376575B (es) |
| WO (1) | WO2014180979A1 (es) |
Families Citing this family (21)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| BR112016011539A2 (pt) | 2013-11-21 | 2017-08-08 | Mallinath Lali Arvind | Processo para a preparação de um derivado de furano e processo para a preparação de um catalisador ácido sólido heterogêneo |
| CN107001305B (zh) * | 2014-10-16 | 2019-10-11 | 诺瓦蒙特股份公司 | 生产和分离5-羟甲基糠醛的方法 |
| CN104923315B (zh) * | 2015-05-29 | 2018-11-16 | 盐城工学院 | 一种固体酸催化剂TiP/ATP及其制备方法和应用 |
| JP6293333B2 (ja) * | 2016-06-27 | 2018-03-14 | 日本食品化工株式会社 | 5−ヒドロキシメチル−2−フルフラールの製造方法 |
| US11274089B2 (en) | 2016-06-27 | 2022-03-15 | Nihon Shokuhin Kako Co., Ltd. | 5-hydroxymethyl-2-furfural production method |
| CN106279077B (zh) * | 2016-07-27 | 2019-01-04 | 邵阳学院 | 一种复合掺杂磷钨酸盐催化合成5-羟甲基糠醛的方法 |
| KR102146094B1 (ko) | 2016-08-24 | 2020-08-19 | 주식회사 엘지화학 | N-치환 말레이미드 제조용 탈수 반응 촉매, 이의 제조 방법, 및 n-치환 말레이미드의 제조 방법 |
| CN106699703B (zh) * | 2017-01-06 | 2020-09-29 | 吉林大学 | 磷酸锆负载二氧化钛催化生物质糖制备5-羟甲基糠醛的方法 |
| FR3071497B1 (fr) * | 2017-09-28 | 2021-06-11 | Ifp Energies Now | Procede de production de 5-hydroxymethylfurfural en presence d'un catalyseur inorganique de deshydratation et d'une source de chlorure |
| CN108190905A (zh) * | 2017-12-04 | 2018-06-22 | 中国科学院宁波材料技术与工程研究所 | Kl分子筛催化剂的制备方法及其应用 |
| IT201800007204A1 (it) | 2018-07-13 | 2020-01-13 | Processo per la produzione e la separazione di 5-idrossimetilfurfurale con sali ammonici quaternari” | |
| CA3142306A1 (en) * | 2019-06-06 | 2020-12-10 | Purac Biochem B.V. | Process for manufacturing hydroxymethylfurfural |
| IT201900025096A1 (it) | 2019-12-20 | 2021-06-20 | Novamont Spa | Processo per la sintesi di acido 2,5-furandicarbossilico |
| IT202000025960A1 (it) * | 2020-10-30 | 2022-04-30 | Chemicle Ltd | Processo per l’isomerizzazione di glucidi in idrossimetilfurfurale |
| CN112354563B (zh) * | 2020-11-27 | 2023-04-18 | 广东省科学院生物工程研究所 | 一种负载磷钨酸的碳催化剂、其制备方法和应用 |
| CN114805253B (zh) * | 2021-01-28 | 2024-07-09 | 中国石油化工股份有限公司 | 一种制备5-羟甲基糠醛的方法 |
| JP7677008B2 (ja) * | 2021-07-12 | 2025-05-15 | 三菱ケミカル株式会社 | 5-ヒドロキシメチルフルフラール製造用触媒及び5-ヒドロキシメチルフルフラールの製造方法 |
| CN116063258B (zh) * | 2021-10-29 | 2025-03-11 | 中国石油化工股份有限公司 | 一种连续生产5-羟甲基糠醛和2,5-呋喃二甲酸的方法 |
| CN116139900B (zh) * | 2021-11-19 | 2024-10-15 | 中国科学院宁波材料技术与工程研究所 | 一种生物基多孔酸性催化剂及其制备方法与应用 |
| CN114805256B (zh) * | 2022-05-17 | 2023-12-05 | 广东石油化工学院 | 两性离子内盐催化果糖基碳水化合物脱水制备5-羟甲基糠醛的方法 |
| WO2026013041A1 (en) | 2024-07-08 | 2026-01-15 | Novamont S.P.A. | Improved process for the synthesis and purification of hmf |
Family Cites Families (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP5101821B2 (ja) * | 2006-01-28 | 2012-12-19 | 公立大学法人大阪府立大学 | 不均一系リン酸ジルコニウム触媒、脱水反応方法、5−ヒドロキシメチルフルフラール製造方法、セルロース分解方法、及び不均一系リン酸ジルコニウム触媒の再生方法 |
| CN101811066A (zh) | 2010-05-14 | 2010-08-25 | 天津大学 | 一种用于六碳糖脱水合成5-羟甲基糠醛的催化剂及合成5-羟甲基糠醛的方法 |
| CN101906088B (zh) | 2010-08-24 | 2013-01-02 | 中国科学院青岛生物能源与过程研究所 | 一种制备5-羟甲基糠醛的方法 |
| CN102212046A (zh) * | 2011-04-19 | 2011-10-12 | 天津理工大学 | 一种用于蔗糖或多糖脱水合成5-羟甲基糠醛的催化体系 |
| CN102814189A (zh) * | 2012-09-13 | 2012-12-12 | 中国科学技术大学 | 一种固体酸催化剂的制备方法及其用途 |
-
2013
- 2013-05-09 IT IT000003A patent/ITNO20130003A1/it unknown
-
2014
- 2014-05-09 CN CN201480026361.1A patent/CN105377825B/zh active Active
- 2014-05-09 KR KR1020157034833A patent/KR20160005358A/ko not_active Ceased
- 2014-05-09 WO PCT/EP2014/059538 patent/WO2014180979A1/en not_active Ceased
- 2014-05-09 ES ES14725400.7T patent/ES2624487T3/es active Active
- 2014-05-09 EP EP14725400.7A patent/EP2994458B1/en active Active
- 2014-05-09 JP JP2016512388A patent/JP2016521281A/ja active Pending
- 2014-05-09 BR BR112015028117A patent/BR112015028117B1/pt active IP Right Grant
- 2014-05-09 US US14/889,526 patent/US9409877B2/en active Active
- 2014-05-09 MX MX2015015312A patent/MX376575B/es active IP Right Grant
- 2014-05-09 CA CA2909881A patent/CA2909881C/en active Active
Also Published As
| Publication number | Publication date |
|---|---|
| MX376575B (es) | 2025-03-07 |
| ITNO20130003A1 (it) | 2014-11-10 |
| US9409877B2 (en) | 2016-08-09 |
| CN105377825B (zh) | 2017-09-05 |
| KR20160005358A (ko) | 2016-01-14 |
| JP2016521281A (ja) | 2016-07-21 |
| WO2014180979A1 (en) | 2014-11-13 |
| ES2624487T3 (es) | 2017-07-14 |
| EP2994458B1 (en) | 2017-02-08 |
| BR112015028117B1 (pt) | 2020-04-14 |
| BR112015028117A2 (pt) | 2017-07-25 |
| CA2909881C (en) | 2021-01-26 |
| WO2014180979A9 (en) | 2015-02-19 |
| EP2994458A1 (en) | 2016-03-16 |
| CA2909881A1 (en) | 2014-11-13 |
| US20160115142A1 (en) | 2016-04-28 |
| CN105377825A (zh) | 2016-03-02 |
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Legal Events
| Date | Code | Title | Description |
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| FG | Grant or registration |