MX2015006070A - Preparacion de alcoholes de alta calidad del proceso oxo de fuentes de materias primas no constantes. - Google Patents
Preparacion de alcoholes de alta calidad del proceso oxo de fuentes de materias primas no constantes.Info
- Publication number
- MX2015006070A MX2015006070A MX2015006070A MX2015006070A MX2015006070A MX 2015006070 A MX2015006070 A MX 2015006070A MX 2015006070 A MX2015006070 A MX 2015006070A MX 2015006070 A MX2015006070 A MX 2015006070A MX 2015006070 A MX2015006070 A MX 2015006070A
- Authority
- MX
- Mexico
- Prior art keywords
- quality
- oligomerizate
- composition
- inconstant
- raw material
- Prior art date
Links
- 238000000034 method Methods 0.000 title abstract 4
- 150000001298 alcohols Chemical class 0.000 title abstract 2
- 239000002994 raw material Substances 0.000 title abstract 2
- 239000000203 mixture Substances 0.000 abstract 7
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 abstract 2
- 150000001299 aldehydes Chemical class 0.000 abstract 2
- 150000001336 alkenes Chemical class 0.000 abstract 2
- 238000007037 hydroformylation reaction Methods 0.000 abstract 2
- JRZJOMJEPLMPRA-UHFFFAOYSA-N olefin Natural products CCCCCCCC=C JRZJOMJEPLMPRA-UHFFFAOYSA-N 0.000 abstract 2
- 238000006384 oligomerization reaction Methods 0.000 abstract 2
- UGFAIRIUMAVXCW-UHFFFAOYSA-N Carbon monoxide Chemical compound [O+]#[C-] UGFAIRIUMAVXCW-UHFFFAOYSA-N 0.000 abstract 1
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 abstract 1
- 229910002091 carbon monoxide Inorganic materials 0.000 abstract 1
- 239000003054 catalyst Substances 0.000 abstract 1
- 238000006243 chemical reaction Methods 0.000 abstract 1
- 239000002815 homogeneous catalyst Substances 0.000 abstract 1
- 229910052739 hydrogen Inorganic materials 0.000 abstract 1
- 239000001257 hydrogen Substances 0.000 abstract 1
- 238000005984 hydrogenation reaction Methods 0.000 abstract 1
- 238000004519 manufacturing process Methods 0.000 abstract 1
- 239000004014 plasticizer Substances 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C29/00—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring
- C07C29/132—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of an oxygen containing functional group
- C07C29/136—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of an oxygen containing functional group of >C=O containing groups, e.g. —COOH
- C07C29/14—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of an oxygen containing functional group of >C=O containing groups, e.g. —COOH of a —CHO group
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
- B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
- B01J31/18—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes containing nitrogen, phosphorus, arsenic or antimony as complexing atoms, e.g. in pyridine ligands, or in resonance therewith, e.g. in isocyanide ligands C=N-R or as complexed central atoms
- B01J31/1845—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes containing nitrogen, phosphorus, arsenic or antimony as complexing atoms, e.g. in pyridine ligands, or in resonance therewith, e.g. in isocyanide ligands C=N-R or as complexed central atoms the ligands containing phosphorus
- B01J31/185—Phosphites ((RO)3P), their isomeric phosphonates (R(RO)2P=O) and RO-substitution derivatives thereof
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
- B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
- B01J31/18—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes containing nitrogen, phosphorus, arsenic or antimony as complexing atoms, e.g. in pyridine ligands, or in resonance therewith, e.g. in isocyanide ligands C=N-R or as complexed central atoms
- B01J31/1845—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes containing nitrogen, phosphorus, arsenic or antimony as complexing atoms, e.g. in pyridine ligands, or in resonance therewith, e.g. in isocyanide ligands C=N-R or as complexed central atoms the ligands containing phosphorus
- B01J31/1885—Ligands comprising two different formal oxidation states of phosphorus in one at least bidentate ligand, e.g. phosphite/phosphinite
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2/00—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms
- C07C2/02—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by addition between unsaturated hydrocarbons
- C07C2/04—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by addition between unsaturated hydrocarbons by oligomerisation of well-defined unsaturated hydrocarbons without ring formation
- C07C2/06—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by addition between unsaturated hydrocarbons by oligomerisation of well-defined unsaturated hydrocarbons without ring formation of alkenes, i.e. acyclic hydrocarbons having only one carbon-to-carbon double bond
- C07C2/08—Catalytic processes
- C07C2/24—Catalytic processes with metals
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C29/00—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring
- C07C29/132—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of an oxygen containing functional group
- C07C29/136—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of an oxygen containing functional group of >C=O containing groups, e.g. —COOH
- C07C29/14—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of an oxygen containing functional group of >C=O containing groups, e.g. —COOH of a —CHO group
- C07C29/141—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of an oxygen containing functional group of >C=O containing groups, e.g. —COOH of a —CHO group with hydrogen or hydrogen-containing gases
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
- C07C45/49—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reaction with carbon monoxide
- C07C45/50—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reaction with carbon monoxide by oxo-reactions
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C67/00—Preparation of carboxylic acid esters
- C07C67/08—Preparation of carboxylic acid esters by reacting carboxylic acids or symmetrical anhydrides with the hydroxy or O-metal group of organic compounds
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C69/00—Esters of carboxylic acids; Esters of carbonic or haloformic acids
- C07C69/76—Esters of carboxylic acids having a carboxyl group bound to a carbon atom of a six-membered aromatic ring
- C07C69/80—Phthalic acid esters
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/04—Oxygen-containing compounds
- C08K5/10—Esters; Ether-esters
- C08K5/12—Esters; Ether-esters of cyclic polycarboxylic acids
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2523/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00
- C07C2523/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of the iron group metals or copper
- C07C2523/74—Iron group metals
- C07C2523/755—Nickel
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Inorganic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Health & Medical Sciences (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
Abstract
La preparación de alcoholes de alta calidad del proceso oxo, de fuentes de materias primas no constantes es el problema técnicamente demandante tratado por esta invención. Se relaciona con un proceso para preparar de manera continua una mezcla de alcoholes, en el cual, una mezcla de entrada que comprende olefinas y que tiene una composición que cambia con el tiempo, se somete a una oligomerización para obtener un oligomerizado y al menos una porción de los oligómeros de olefina presentes en el oligomerizado se hidroformila con monóxido de carbono e hidrógeno en una hidroformilación, en la presencia de un sistema de catalizador homogéneo para proporcionar aldehídos, al menos algunos de los cuales se convierten a la mezcla de alcohol mediante la hidrogenación subsiguiente. Más particularmente, el problema tratado por la invención es aquél de especificar un proceso tal, que permita que se produzca una calidad constante del plastificante durante un periodo de producción largo y, si se requiere, se habilite un rendimiento más alto con la misma calidad del producto. Esto se logra mediante el control de la temperatura y/o la conversión de la oligomerización, como una función de la composición actual del oligomerizado;.
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE102014209536.0A DE102014209536A1 (de) | 2014-05-20 | 2014-05-20 | Herstellung qualitativ hochwertiger Oxo-Alkohole aus unsteten Rohstoffquellen |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| MX2015006070A true MX2015006070A (es) | 2016-02-10 |
| MX375616B MX375616B (es) | 2025-03-06 |
Family
ID=53180610
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| MX2015006070A MX375616B (es) | 2014-05-20 | 2015-05-14 | Preparación de alcoholes de alta calidad del proceso oxo de fuentes de materias primas no constantes. |
Country Status (11)
| Country | Link |
|---|---|
| US (1) | US9914681B2 (es) |
| EP (1) | EP2947064B1 (es) |
| JP (1) | JP6509036B2 (es) |
| KR (1) | KR102294510B1 (es) |
| CN (1) | CN105198699B (es) |
| DE (1) | DE102014209536A1 (es) |
| ES (1) | ES2660843T3 (es) |
| MX (1) | MX375616B (es) |
| MY (1) | MY177747A (es) |
| PL (1) | PL2947064T3 (es) |
| TW (1) | TWI636035B (es) |
Families Citing this family (26)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE102013212481A1 (de) | 2013-06-27 | 2014-12-31 | Evonik Industries Ag | Oligomerisierung von C4-Strömen mit geringstem Gehalt an 1-Buten |
| DE102013221708A1 (de) | 2013-10-25 | 2015-04-30 | Evonik Industries Ag | Strahlschlaufenreaktor mit Nanofiltration und Gasseparator |
| DE102014201756A1 (de) | 2014-01-31 | 2015-08-06 | Evonik Degussa Gmbh | Reinigung chlorverschmutzter Organophosphorverbindungen |
| DE102014209532A1 (de) * | 2014-05-20 | 2015-11-26 | Evonik Degussa Gmbh | Neue Monophosphitliganden mit einer tert-Butyloxycarbonyl-Gruppe |
| DE102015202722A1 (de) * | 2014-05-20 | 2015-11-26 | Evonik Degussa Gmbh | Verfahren zur katalytischen Herstellung von Aldehyden aus Olefinen unter Einsatz von Monophosphit-Gemischen |
| EP3059005B1 (de) | 2015-02-18 | 2018-10-24 | Evonik Degussa GmbH | Abtrennung eines homogenkatalysators aus einem reaktionsgemisch mit hilfe organophiler nanofiltration unter besonderer berücksichtigung eines membran-leistungsindikators |
| ES2701843T3 (es) | 2015-11-19 | 2019-02-26 | Evonik Degussa Gmbh | Influencia de la viscosidad de mezclas de ésteres basadas en n-buteno mediante empleo selectivo de eteno en la obtención de productos previos de ésteres |
| IL295808B2 (en) | 2015-12-03 | 2023-10-01 | Regeneron Pharma | Methods for associating genetic variants with clinical outcome in patients suffering from age-related macular degeneration and receiving treatment against tubular endothelial growth factor |
| ZA201801183B (en) | 2017-02-27 | 2019-01-30 | Evonik Degussa Gmbh | Selective oligomerization of olefins |
| EP3466540B1 (en) * | 2017-05-29 | 2022-04-06 | LG Chem, Ltd. | Catalyst composition for hydroformylation reaction and method for preparing aldehyde using same |
| KR102131788B1 (ko) | 2017-05-29 | 2020-07-09 | 주식회사 엘지화학 | 히드로포밀화 반응용 촉매 조성물 및 이를 이용한 알데히드 제조방법 |
| ZA201808002B (en) | 2017-12-01 | 2019-08-28 | Evonik Degussa Gmbh | Method for obtaining alcohols from aldehydes |
| JP7340327B2 (ja) | 2017-12-01 | 2023-09-07 | エボニック オペレーションズ ゲーエムベーハー | アルデヒドｉｉｉからアルコールを得る方法 |
| ZA201808003B (en) | 2017-12-01 | 2019-08-28 | Evonik Degussa Gmbh | Method for obtaining alcohols from aldehydes ii |
| US11519020B2 (en) | 2018-05-25 | 2022-12-06 | Regeneron Pharmaceuticals, Inc. | Methods of associating genetic variants with a clinical outcome in patients suffering from age-related macular degeneration treated with anti-VEGF |
| CN112368258B (zh) * | 2018-07-02 | 2023-10-27 | 帝斯曼知识产权资产管理有限公司 | 在仲羟基及其催化剂的存在下选择性酰化伯羟基的方法 |
| ES2898877T3 (es) | 2019-01-07 | 2022-03-09 | Evonik Operations Gmbh | Producción de espuma dura de poliuretano |
| US12534564B2 (en) | 2019-01-07 | 2026-01-27 | Evonik Operations Gmbh | Production of rigid polyurethane foam |
| US11976017B2 (en) | 2019-12-19 | 2024-05-07 | Dow Technology Investments Llc | Processes for preparing isoprene and mono-olefins comprising at least six carbon atoms |
| PL4103571T3 (pl) | 2020-02-11 | 2024-04-29 | Basf Se | Niskociśnieniowe hydroformylowanie diizobutenu |
| US11236031B2 (en) | 2020-02-12 | 2022-02-01 | Saudi Arabian Oil Company | Integrated process for the production of isononanol and gasoline and diesel blending components |
| US11542447B2 (en) | 2021-03-09 | 2023-01-03 | Saudi Arabian Oil Company | Integrated process for the production of isononanol and stable / lubricating gasoline and diesel blending components |
| CA3257349A1 (en) | 2022-05-17 | 2025-04-07 | Evonik Operations Gmbh | POLYURETHANE FOAM PRODUCTION |
| ES3041442T3 (en) * | 2022-12-27 | 2025-11-12 | Evonik Oxeno Gmbh & Co Kg | Process for the preparation of a phosphoramidite and its further conversion to monophosphite |
| EP4455114A1 (de) * | 2023-04-26 | 2024-10-30 | Evonik Oxeno GmbH & Co. KG | C8-kohlenwasserstoffzusammensetzungen und ein verfahren zu deren herstellung |
| EP4678675A1 (de) | 2024-07-12 | 2026-01-14 | Evonik Operations GmbH | Herstellung von polyurethanschaumstoff |
Family Cites Families (20)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP3379551B2 (ja) * | 1993-09-13 | 2003-02-24 | 三菱化学株式会社 | ヒドロホルミル化反応の制御方法 |
| DE19654340A1 (de) * | 1996-12-24 | 1998-08-06 | Huels Chemische Werke Ag | Verfahren zur Herstellung von höheren Oxo-Alkoholen |
| MY129122A (en) | 1997-11-14 | 2007-03-30 | Basf Ag | Method for producing essentially unbranched octenes and dodecenes by oligomerising of unbranched butenes |
| DE19906518A1 (de) | 1999-02-17 | 2000-08-31 | Oxeno Olefinchemie Gmbh | Verfahren zur Fraktionierung von Dibuten |
| DE19954510A1 (de) * | 1999-11-12 | 2001-05-17 | Oxeno Olefinchemie Gmbh | Verfahren zur katalytischen Herstellung von Aldehyden aus Olefinen unter Einsatz von Ligandenmischungen |
| DE10015002A1 (de) | 2000-03-25 | 2001-09-27 | Basf Ag | Verfahren zur Herstellung von Oligomeren |
| DE10034360A1 (de) * | 2000-07-14 | 2002-01-24 | Oxeno Olefinchemie Gmbh | Mehrstufiges Verfahren zur Herstellung von Oxo-Aldehyden und/oder Alkoholen |
| CA2455191C (en) * | 2001-09-26 | 2011-03-15 | Oxeno Olefinchemie Gmbh | Alkyl phthalate mixtures with controlled viscosity |
| DE10201348A1 (de) * | 2001-09-26 | 2003-04-24 | Oxeno Olefinchemie Gmbh | Phtalsäurealkylestergemische mit kontrollierter Viskosität |
| EP1438275B1 (en) * | 2001-10-24 | 2016-05-18 | ExxonMobil Chemical Patents Inc. | Process for the oligomerisation of olefins |
| DE102004059293A1 (de) * | 2004-12-09 | 2006-06-14 | Oxeno Olefinchemie Gmbh | Verfahren zur Hydroformylierung von Olefinen |
| DE102007061648A1 (de) | 2007-12-20 | 2009-07-02 | Evonik Oxeno Gmbh | Mehrstufiges kontinuierliches Verfahren zur Hydroformylierung von höheren Olefinen oder Olefingemischen |
| DE102008007080A1 (de) | 2008-01-31 | 2009-08-06 | Evonik Oxeno Gmbh | Verfahren zur Herstellung von C9-Alkohol aus C8-Olefinen |
| DE102008007081B4 (de) | 2008-01-31 | 2018-12-06 | Evonik Degussa Gmbh | Verfahren zur Herstellung von n-Buten-Oligomeren und 1-Buten aus technischen Mischungen I von C4-Kohlenwasserstoffen |
| WO2010057905A1 (de) * | 2008-11-19 | 2010-05-27 | Basf Se | Oligomerisierung von olefinen |
| DE102009027408A1 (de) | 2009-07-01 | 2011-01-05 | Evonik Oxeno Gmbh | Regenerierung von Oligomerisierungskatalysatoren |
| DE102009029284A1 (de) * | 2009-09-08 | 2011-03-10 | Evonik Oxeno Gmbh | Verfahren zur Oligomerisierung von Olefinen |
| US8664451B2 (en) | 2009-12-22 | 2014-03-04 | Dow Technology Investments Llc | Controlling the normal:ISO aldehyde ratio in a mixed ligand hydroformylation process by controlling the olefin partial pressure |
| MX2015004616A (es) * | 2012-10-12 | 2015-07-17 | Evonik Degussa Gmbh | Bifosfito asimetrico. |
| DE102013212481A1 (de) | 2013-06-27 | 2014-12-31 | Evonik Industries Ag | Oligomerisierung von C4-Strömen mit geringstem Gehalt an 1-Buten |
-
2014
- 2014-05-20 DE DE102014209536.0A patent/DE102014209536A1/de not_active Withdrawn
-
2015
- 2015-05-14 MX MX2015006070A patent/MX375616B/es active IP Right Grant
- 2015-05-15 MY MYPI2015001311A patent/MY177747A/en unknown
- 2015-05-18 TW TW104115800A patent/TWI636035B/zh active
- 2015-05-19 CN CN201510492754.8A patent/CN105198699B/zh active Active
- 2015-05-19 EP EP15168100.4A patent/EP2947064B1/de active Active
- 2015-05-19 PL PL15168100T patent/PL2947064T3/pl unknown
- 2015-05-19 ES ES15168100.4T patent/ES2660843T3/es active Active
- 2015-05-20 US US14/717,183 patent/US9914681B2/en active Active
- 2015-05-20 JP JP2015103166A patent/JP6509036B2/ja active Active
- 2015-05-20 KR KR1020150070236A patent/KR102294510B1/ko active Active
Also Published As
| Publication number | Publication date |
|---|---|
| DE102014209536A1 (de) | 2015-11-26 |
| MX375616B (es) | 2025-03-06 |
| PL2947064T3 (pl) | 2018-06-29 |
| MY177747A (en) | 2020-09-23 |
| US9914681B2 (en) | 2018-03-13 |
| EP2947064A1 (de) | 2015-11-25 |
| TW201609617A (zh) | 2016-03-16 |
| US20150336861A1 (en) | 2015-11-26 |
| JP6509036B2 (ja) | 2019-05-08 |
| CN105198699A (zh) | 2015-12-30 |
| EP2947064B1 (de) | 2018-01-17 |
| KR20150133660A (ko) | 2015-11-30 |
| KR102294510B1 (ko) | 2021-08-26 |
| ES2660843T3 (es) | 2018-03-26 |
| CN105198699B (zh) | 2019-11-15 |
| TWI636035B (zh) | 2018-09-21 |
| JP2015218174A (ja) | 2015-12-07 |
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|---|---|---|---|
| HC | Change of company name or juridical status |
Owner name: COMERCIALIZADORA DE LACTEOS Y DERIVADOS S.A. DE C.V. |
|
| FG | Grant or registration |