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MX2013014563A - Composicion desemulsionante de poliorganosiloxano biodegradable y procedimiento para formar el mismo. - Google Patents

Composicion desemulsionante de poliorganosiloxano biodegradable y procedimiento para formar el mismo.

Info

Publication number
MX2013014563A
MX2013014563A MX2013014563A MX2013014563A MX2013014563A MX 2013014563 A MX2013014563 A MX 2013014563A MX 2013014563 A MX2013014563 A MX 2013014563A MX 2013014563 A MX2013014563 A MX 2013014563A MX 2013014563 A MX2013014563 A MX 2013014563A
Authority
MX
Mexico
Prior art keywords
subscript
carbon atoms
radical
monovalent
general formula
Prior art date
Application number
MX2013014563A
Other languages
English (en)
Inventor
Monjit Phukan
Anubhav Saxena
Majyank Kumar Dubey
Antonio Palumbo
Kalman Koczo
Original Assignee
Momentive Performance Mat Inc
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Momentive Performance Mat Inc filed Critical Momentive Performance Mat Inc
Publication of MX2013014563A publication Critical patent/MX2013014563A/es

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L83/00Compositions of macromolecular compounds obtained by reactions forming in the main chain of the macromolecule a linkage containing silicon with or without sulfur, nitrogen, oxygen or carbon only; Compositions of derivatives of such polymers
    • C08L83/10Block- or graft-copolymers containing polysiloxane sequences
    • C08L83/12Block- or graft-copolymers containing polysiloxane sequences containing polyether sequences
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D17/00Separation of liquids, not provided for elsewhere, e.g. by thermal diffusion
    • B01D17/02Separation of non-miscible liquids
    • B01D17/04Breaking emulsions
    • B01D17/047Breaking emulsions with separation aids
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10GCRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G33/00Dewatering or demulsification of hydrocarbon oils
    • C10G33/04Dewatering or demulsification of hydrocarbon oils with chemical means
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08GMACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G77/00Macromolecular compounds obtained by reactions forming a linkage containing silicon with or without sulfur, nitrogen, oxygen or carbon in the main chain of the macromolecule
    • C08G77/42Block-or graft-polymers containing polysiloxane sequences
    • C08G77/46Block-or graft-polymers containing polysiloxane sequences containing polyether sequences

Landscapes

  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Organic Chemistry (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Polymers & Plastics (AREA)
  • Health & Medical Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • General Chemical & Material Sciences (AREA)
  • Medicinal Chemistry (AREA)
  • Physics & Mathematics (AREA)
  • Thermal Sciences (AREA)
  • Silicon Polymers (AREA)
  • Emulsifying, Dispersing, Foam-Producing Or Wetting Agents (AREA)
  • Compositions Of Macromolecular Compounds (AREA)
  • Colloid Chemistry (AREA)
  • Medicinal Preparation (AREA)

Abstract

Sn i a presen te se provee una composición desemulsionante que comprende (a) una emulsión; y (b) una cantidad desemulsionante efectiva de por lo menos un compuesto poliorganosiloxano que tiene la fórmula general (I) : M1aM2bD1cD2dT1eT2fQg (I) en donde: R1R2R3Si01/2, M2 R4R5RLSi01/2, D1 = R6R7Si02/2, D2 = R8RLSi02/2, T1 = R9Si03/2, T2 = RLSi03/2, Q = Si04/2, en donde R1, R2, R3, R4, R5, R6, R7, R8 y R9 son cada uno independientemente seleccionados entre radicales hidrocarburo de alquilo, arilo o aralquilo monovalentes que contienen de 1 a 60 átomos de carbono, que contienen opcionalmente al menos un heteroátomo, o al menos un radical de poliéter monovalente que tiene la fórmula general Rp ; Rp es un radical de la fórmula general (II) poliéter monovalente: - (CnH2n) 0 (C2H40)o- (C3H60) p (C4H80) q-R10 (II) en donde R10 es hidrógeno o un radical alquilo monovalente que contiene de 1 a aproximadamente 20 átomos de carbono o un grupo acilo; los subíndices a, b, e, d, e, f y q son cero o números enteros positivos, sujeto a las limitaciones: 2 = a 1- b + e 4 d 1 e -1- f + q = 500, b - d 1 f = 1 y a -1 b r 2 + e 1- f+2g; el subíndice n es de 2 a aproximadamente 10; el subíndice o es de 0 a alrededor de 200; el subíndice p es de 0 a aproximadamente 200; el subíndice q es de 0 a aproximadamente 200, y, sujeto a la limitación o + p + q = 1; RL es radical monovalente independientemente elegido de la fórmula general (III): - X-O-(C2H4O)r(C3H6O)s-(C4H8O) t -{C(O)CuI42uO}v-R11 (III) en donde R1' es hidrógeno o alquilo radical monovalente que contiene de 1 a aproximadamente 20 átomos de carbono o un grupo acilo, y en donde X es un radical hidrocarburo o aralquilo divalente lineal, ramiftcado o cíclico que contiene de aproximadamente 2 a aproximadamente 20 átomos de carbono, que contiene opcionalmente al menos un heteroátomo; el subíndice r es de 0 a aproximadamente 200; el subíndice s es de 0 a 200; el subíndice t es de 0 a aproximadamente 200; el subíndice u es de 1 a aproximadamente 20; el subíndice y es de 1 a aproximadamente 200, y sujeto a la limitación de si r + s + t es igual a cero, entonces el poliorganosiloxano contiene al menos un radical Rp. También se provee en la presente un método para separar emulsiones que comprenden combinar los componentes de composición desemulsionante en una mezcla; permitiendo que la mezcla se separe en por lo menos dos fases y separe por lo menos las dos fases entre ellas.
MX2013014563A 2011-06-21 2012-06-21 Composicion desemulsionante de poliorganosiloxano biodegradable y procedimiento para formar el mismo. MX2013014563A (es)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US13/165,085 US8779012B2 (en) 2011-06-21 2011-06-21 Biodegradable polyorganosiloxane demulsifier composition and method for making the same
PCT/US2012/043486 WO2012177836A1 (en) 2011-06-21 2012-06-21 Biodegradable polyorganosiloxane demulsifier composition and method for making the same

Publications (1)

Publication Number Publication Date
MX2013014563A true MX2013014563A (es) 2014-03-21

Family

ID=46551851

Family Applications (1)

Application Number Title Priority Date Filing Date
MX2013014563A MX2013014563A (es) 2011-06-21 2012-06-21 Composicion desemulsionante de poliorganosiloxano biodegradable y procedimiento para formar el mismo.

Country Status (7)

Country Link
US (1) US8779012B2 (es)
EP (1) EP2723817B1 (es)
CN (1) CN103781853A (es)
BR (1) BR112013032372A2 (es)
CA (1) CA2838343A1 (es)
MX (1) MX2013014563A (es)
WO (1) WO2012177836A1 (es)

Families Citing this family (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US9683163B2 (en) 2012-12-31 2017-06-20 Baker Hughes Incorporated Functionalized silicate nanoparticle composition, removing and exfoliating asphaltenes with same
US9012377B2 (en) 2012-12-31 2015-04-21 Baker Hughes Incorporated Functionalized silicate nanoparticle composition, removing and exfoliating asphaltenes with same
EP3065839A1 (en) 2013-11-04 2016-09-14 Dow Corning Do Brasil Limitada Reduced foam petroleum composition field of the disclosure
CA2982344A1 (en) * 2015-03-17 2016-09-22 Baker Hughes, A Ge Company, Llc Functionalized silicate nanoparticle composition, removing and exfoliating asphaltenes with same
FR3048975B1 (fr) 2016-03-18 2019-11-29 Oleon Nv Desemulsifiant pour petrole
US20190111360A1 (en) * 2017-10-18 2019-04-18 Baker Hughes, A Ge Company, Llc Environmentally friendly demulsifiers
DE102022118294A1 (de) 2022-07-21 2024-02-01 Fraunhofer-Gesellschaft zur Förderung der angewandten Forschung eingetragener Verein Biodegradierbare Polysiloxane

Family Cites Families (12)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB8328233D0 (en) * 1983-10-21 1983-11-23 British Petroleum Co Plc Demulsifying process
FR2565233B1 (fr) 1984-05-30 1986-09-12 Rhone Poulenc Rech Copolymere greffe de silicone et de polylactone lie par une liaison urethanne
US4663413A (en) 1985-01-04 1987-05-05 Thoratec Laboratories Corp. Polysiloxane-polylactone block copolymers
DE3535283A1 (de) 1985-10-03 1987-04-09 Byk Chemie Gmbh Polyestergruppenhaltige polysiloxane fuer lacke und formmassen und die verwendung hierfuer
DE3622571A1 (de) 1986-07-04 1988-01-21 Goldschmidt Ag Th Verwendung von polyoxyalkylen-polysiloxan-blockmischpolymerisaten als demulgatoren fuer wasser enthaltendes erdoel
DE68920476T2 (de) 1988-05-17 1995-06-01 Dow Corning Ltd Organosiliziumverbindungen.
JPH0692481B2 (ja) 1989-06-02 1994-11-16 信越化学工業株式会社 ポリラクトン変性オルガノポリシロキサン化合物
JP3500477B2 (ja) 1994-12-21 2004-02-23 関西ペイント株式会社 ラクトン変性オルガノポリシロキサン化合物及びその製造法
US6001140A (en) 1996-04-04 1999-12-14 Witco Corporation Diesel fuel and lubricating oil antifoams and methods of use
US7745501B2 (en) * 2006-06-22 2010-06-29 Momentive Performance Materials Inc. Method for demulsifying
US8030363B2 (en) 2008-01-25 2011-10-04 Momentive Performance Materials Inc. Polyorganosiloxane demulsifier compositions and methods of making the same
EP2504381B1 (en) 2009-11-24 2018-03-07 Momentive Performance Materials GmbH Hydrophilic/lipophilic modified polysiloxanes as emulsifiers

Also Published As

Publication number Publication date
CA2838343A1 (en) 2012-12-27
CN103781853A (zh) 2014-05-07
EP2723817B1 (en) 2016-11-16
US8779012B2 (en) 2014-07-15
EP2723817A1 (en) 2014-04-30
BR112013032372A2 (pt) 2017-01-03
WO2012177836A1 (en) 2012-12-27
US20120329887A1 (en) 2012-12-27

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