MX2013006029A - Composicion tipo azeotropo de (z) - 1 - cloro - 3, 3, 3 - trifluoropropeno y acido fluorhidrico. - Google Patents
Composicion tipo azeotropo de (z) - 1 - cloro - 3, 3, 3 - trifluoropropeno y acido fluorhidrico.Info
- Publication number
- MX2013006029A MX2013006029A MX2013006029A MX2013006029A MX2013006029A MX 2013006029 A MX2013006029 A MX 2013006029A MX 2013006029 A MX2013006029 A MX 2013006029A MX 2013006029 A MX2013006029 A MX 2013006029A MX 2013006029 A MX2013006029 A MX 2013006029A
- Authority
- MX
- Mexico
- Prior art keywords
- azeotrope
- chloro
- compositions
- useful
- hydrogen fluoride
- Prior art date
Links
- 239000000203 mixture Substances 0.000 title abstract 4
- LDTMPQQAWUMPKS-UPHRSURJSA-N (z)-1-chloro-3,3,3-trifluoroprop-1-ene Chemical group FC(F)(F)\C=C/Cl LDTMPQQAWUMPKS-UPHRSURJSA-N 0.000 title abstract 2
- KRHYYFGTRYWZRS-UHFFFAOYSA-N Fluorane Chemical compound F KRHYYFGTRYWZRS-UHFFFAOYSA-N 0.000 title abstract 2
- 229910000040 hydrogen fluoride Inorganic materials 0.000 title abstract 2
- 239000004604 Blowing Agent Substances 0.000 abstract 1
- CBENFWSGALASAD-UHFFFAOYSA-N Ozone Chemical compound [O-][O+]=O CBENFWSGALASAD-UHFFFAOYSA-N 0.000 abstract 1
- 239000012459 cleaning agent Substances 0.000 abstract 1
- 150000001875 compounds Chemical class 0.000 abstract 1
- 230000000779 depleting effect Effects 0.000 abstract 1
- 239000012530 fluid Substances 0.000 abstract 1
- NBVXSUQYWXRMNV-UHFFFAOYSA-N fluoromethane Chemical compound FC NBVXSUQYWXRMNV-UHFFFAOYSA-N 0.000 abstract 1
- 238000004519 manufacturing process Methods 0.000 abstract 1
- 231100000252 nontoxic Toxicity 0.000 abstract 1
- 230000003000 nontoxic effect Effects 0.000 abstract 1
- 239000003380 propellant Substances 0.000 abstract 1
- 239000003507 refrigerant Substances 0.000 abstract 1
- 239000002904 solvent Substances 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C19/00—Acyclic saturated compounds containing halogen atoms
- C07C19/08—Acyclic saturated compounds containing halogen atoms containing fluorine
- C07C19/10—Acyclic saturated compounds containing halogen atoms containing fluorine and chlorine
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C17/00—Preparation of halogenated hydrocarbons
- C07C17/38—Separation; Purification; Stabilisation; Use of additives
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
- C09K5/00—Heat-transfer, heat-exchange or heat-storage materials, e.g. refrigerants; Materials for the production of heat or cold by chemical reactions other than by combustion
- C09K5/02—Materials undergoing a change of physical state when used
- C09K5/04—Materials undergoing a change of physical state when used the change of state being from liquid to vapour or vice versa
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N25/00—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests
- A01N25/02—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests containing liquids as carriers, diluents or solvents
- A01N25/04—Dispersions, emulsions, suspoemulsions, suspension concentrates or gels
- A01N25/06—Aerosols
-
- A—HUMAN NECESSITIES
- A62—LIFE-SAVING; FIRE-FIGHTING
- A62D—CHEMICAL MEANS FOR EXTINGUISHING FIRES OR FOR COMBATING OR PROTECTING AGAINST HARMFUL CHEMICAL AGENTS; CHEMICAL MATERIALS FOR USE IN BREATHING APPARATUS
- A62D1/00—Fire-extinguishing compositions; Use of chemical substances in extinguishing fires
- A62D1/0028—Liquid extinguishing substances
- A62D1/0057—Polyhaloalkanes
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D3/00—Distillation or related exchange processes in which liquids are contacted with gaseous media, e.g. stripping
- B01D3/34—Distillation or related exchange processes in which liquids are contacted with gaseous media, e.g. stripping with one or more auxiliary substances
- B01D3/36—Azeotropic distillation
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B7/00—Halogens; Halogen acids
- C01B7/19—Fluorine; Hydrogen fluoride
- C01B7/191—Hydrogen fluoride
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C21/00—Acyclic unsaturated compounds containing halogen atoms
- C07C21/02—Acyclic unsaturated compounds containing halogen atoms containing carbon-to-carbon double bonds
- C07C21/18—Acyclic unsaturated compounds containing halogen atoms containing carbon-to-carbon double bonds containing fluorine
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
- C09K3/00—Materials not provided for elsewhere
- C09K3/30—Materials not provided for elsewhere for aerosols
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
- C09K5/00—Heat-transfer, heat-exchange or heat-storage materials, e.g. refrigerants; Materials for the production of heat or cold by chemical reactions other than by combustion
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
- C09K5/00—Heat-transfer, heat-exchange or heat-storage materials, e.g. refrigerants; Materials for the production of heat or cold by chemical reactions other than by combustion
- C09K5/02—Materials undergoing a change of physical state when used
- C09K5/04—Materials undergoing a change of physical state when used the change of state being from liquid to vapour or vice versa
- C09K5/041—Materials undergoing a change of physical state when used the change of state being from liquid to vapour or vice versa for compression-type refrigeration systems
- C09K5/044—Materials undergoing a change of physical state when used the change of state being from liquid to vapour or vice versa for compression-type refrigeration systems comprising halogenated compounds
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D7/00—Compositions of detergents based essentially on non-surface-active compounds
- C11D7/50—Solvents
- C11D7/5036—Azeotropic mixtures containing halogenated solvents
- C11D7/504—Azeotropic mixtures containing halogenated solvents all solvents being halogenated hydrocarbons
- C11D7/5045—Mixtures of (hydro)chlorofluorocarbons
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Materials Engineering (AREA)
- Life Sciences & Earth Sciences (AREA)
- Dispersion Chemistry (AREA)
- Physics & Mathematics (AREA)
- Combustion & Propulsion (AREA)
- Thermal Sciences (AREA)
- Wood Science & Technology (AREA)
- General Chemical & Material Sciences (AREA)
- General Health & Medical Sciences (AREA)
- Business, Economics & Management (AREA)
- Emergency Management (AREA)
- Inorganic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Agronomy & Crop Science (AREA)
- Pest Control & Pesticides (AREA)
- Plant Pathology (AREA)
- Toxicology (AREA)
- Dentistry (AREA)
- Zoology (AREA)
- Environmental Sciences (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Detergent Compositions (AREA)
Abstract
Se describen mezclas azeotrópicas y de tipo azeótropo de (Z)-l-cloro-3,3,3-trifluoropropeno (1233zd(Z)) y ácido fluorhídrico. Tales composiciones son útiles como un intermediario en la producción de 1233zd (Z). El ultimo compuesto es útil como un fluorocarburo con cero agotamiento de la capa de ozono, no tóxico, útil como un solvente, un agente de soplado, un refrigerante, un agente de limpieza, un propulsor de aerosol, un medio de transferencia térmica, dieléctrico, una composición extintora y fluido que trabaja con un ciclo de energía.
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US41932210P | 2010-12-03 | 2010-12-03 | |
| US13/253,270 US8378158B2 (en) | 2010-12-03 | 2011-10-05 | Azeotrope-like compositions of (Z)-1-chloro-3,3,3-trifluoropropene and hydrogen fluoride |
| PCT/US2011/062884 WO2012075283A2 (en) | 2010-12-03 | 2011-12-01 | Azeotrope-like compositions of (z)-1-chloro-3,3,3-trifluoropropene and hydrogen fluoride |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| MX2013006029A true MX2013006029A (es) | 2013-07-15 |
| MX358760B MX358760B (es) | 2018-09-03 |
Family
ID=46161340
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| MX2013006029A MX358760B (es) | 2010-12-03 | 2011-12-01 | Composicion tipo azeotropo de (z) - 1 - cloro - 3, 3, 3 - trifluoropropeno y acido fluorhidrico. |
Country Status (7)
| Country | Link |
|---|---|
| US (2) | US8378158B2 (es) |
| EP (1) | EP2646403A4 (es) |
| JP (1) | JP5961182B2 (es) |
| KR (1) | KR101900294B1 (es) |
| CN (2) | CN107964395A (es) |
| MX (1) | MX358760B (es) |
| WO (1) | WO2012075283A2 (es) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US10815452B2 (en) | 2015-09-04 | 2020-10-27 | AGC Inc. | Solvent composition, cleaning method and method of forming a coating film |
Families Citing this family (19)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US9334206B2 (en) | 2013-03-15 | 2016-05-10 | Honeywell International Inc. | Integrated process to produce 2,3,3,3-tetrafluoropropene |
| FR3003567B1 (fr) | 2013-03-20 | 2015-03-06 | Arkema France | Composition comprenant hf et 3,3,3-trifluoropropene |
| FR3003565B1 (fr) * | 2013-03-20 | 2018-06-29 | Arkema France | Composition comprenant hf et 2,3,3,3-tetrafluoropropene |
| FR3003569B1 (fr) * | 2013-03-20 | 2015-12-25 | Arkema France | Composition comprenant hf et 1,3,3,3-tetrafluoropropene |
| FR3003566B1 (fr) * | 2013-03-20 | 2018-07-06 | Arkema France | Composition comprenant hf et e-3,3,3-trifluoro-1-chloropropene |
| WO2015048604A1 (en) * | 2013-09-30 | 2015-04-02 | E. I. Du Pont De Nemours And Company | Fire extinguishing and fire suppression compositions comprising 3-chloro-1,1,1-trifluoropropene |
| FR3015478B1 (fr) * | 2013-12-19 | 2015-12-25 | Arkema France | Compositions azeotropiques a base de fluorure d'hydrogene et de z-3,3,3-trifluoro-1-chloropropene |
| JP6503765B2 (ja) * | 2015-02-02 | 2019-04-24 | セントラル硝子株式会社 | 含フッ素オレフィンを構成成分とする共沸様組成物 |
| WO2018044787A1 (en) * | 2016-09-01 | 2018-03-08 | Honeywell International Inc. | SEPARATION OF (Z)-1-CHLORO-3,3,3-TRIFLUOROPROPENE (HCFO-1233zd(Z)) AND 1-CHLORO-1,3,3,3-TETRAFLUOROPROPANE (HCFC-244fa) BY ADDING A THIRD COMPONENT |
| FR3056222B1 (fr) | 2016-09-19 | 2020-01-10 | Arkema France | Composition a base de 1-chloro-3,3,3-trifluoropropene |
| KR102652080B1 (ko) * | 2016-12-02 | 2024-03-28 | 허니웰 인터내셔날 인코포레이티드 | Hcfo-1233zd를 건조시키는 방법 |
| WO2018118625A1 (en) * | 2016-12-21 | 2018-06-28 | Arkema Inc. | Processes and systems for recovering r1233zd in purified form |
| US20180194703A1 (en) * | 2017-01-06 | 2018-07-12 | Honeywell International Inc. | Systems and methods for separating (e)-1-chloro-3,3,3-trifluoropropene, hf, and a heavy organic and reactor purge |
| WO2019051390A1 (en) * | 2017-09-11 | 2019-03-14 | The Chemours Company, Fc, Llc | AZEOTROPIC COMPOSITIONS COMPRISING HYDROGEN FLUORIDE AND FLUOROCARBONS |
| FR3077572B1 (fr) | 2018-02-05 | 2021-10-08 | Arkema France | Composition azeotropique ou quasi-azeotropique ternaire comprenant hf, 2,3,3,3-tetrafluoropropene et 1,1,1,2,2,-pentafluoropropane. |
| WO2020014828A1 (en) * | 2018-07-16 | 2020-01-23 | Honeywell International Inc. | Methods for forming aerogels |
| JP7656166B2 (ja) * | 2020-03-27 | 2025-04-03 | セントラル硝子株式会社 | 溶剤組成物、エアゾール組成物、洗浄剤、物品の洗浄方法、塗膜形成用組成物、塗膜付き物品の製造方法、水切り剤、リンス剤及び潤滑剤溶液 |
| US20240376031A1 (en) * | 2023-05-10 | 2024-11-14 | Honeywell International Inc. | Azeotrope and azeotrope-like compositions of 1,1,2-trifluoroethane (hfc-143) and 1-chloro-1,1,2-trifluoroethane (hcfc-133b) and applications thereof |
| US20250197215A1 (en) * | 2023-12-19 | 2025-06-19 | Honeywell International Inc. | Methods for recovering hydrogen fluoride from a fluorocarbon production process |
Family Cites Families (27)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US6755942B1 (en) * | 1995-08-01 | 2004-06-29 | E. I. Du Pont De Nemours And Company | Process for the manufacture of halocarbons and selected compounds and azeotropes with HF |
| US6111150A (en) | 1996-06-20 | 2000-08-29 | Central Glass Company, Limited | Method for producing 1,1,1,3,3,-pentafluoropropane |
| US5710352A (en) | 1996-09-19 | 1998-01-20 | Alliedsignal Inc. | Vapor phase process for making 1,1,1,3,3-pentafluoropropane and 1-chloro-3,3,3-trifluoropropene |
| BE1011765A3 (fr) | 1998-02-26 | 2000-01-11 | Solvay | Procede d'hydrofluoration d'hydrocarbures. |
| US6013846A (en) * | 1998-03-05 | 2000-01-11 | Elf Atochem North America, Inc. | Azeotrope of HF and 1233zd |
| JP3518321B2 (ja) * | 1998-03-23 | 2004-04-12 | ダイキン工業株式会社 | 1,1,1,3,3−ペンタフルオロプロパンの製造方法 |
| JP4389389B2 (ja) * | 1998-11-13 | 2009-12-24 | ダイキン工業株式会社 | 1,1,1,3,3−ペンタフルオロプロパンおよび1,1,1−トリフルオロ−3−クロロ−2−プロペンから成る共沸組成物およびそれを用いる分離精製方法、ならびに1,1,1,3,3−ペンタフルオロプロパンおよび1,1,1−トリフルオロ−3−クロロ−2−プロペンの製造方法 |
| US6528691B1 (en) | 1999-05-14 | 2003-03-04 | Atofina Chemicals, Inc. | Preparation of 245fa |
| US6475971B2 (en) * | 2001-01-24 | 2002-11-05 | Honeywell International Inc. | Azeotrope-like composition of 1,2-dichloro-3,3,3-trifluoropropene and hydrogen fluoride composition |
| US7094936B1 (en) * | 2001-07-20 | 2006-08-22 | Great Lakes Chemical Corporation | Process for preparing halogenated alkanes |
| US7833433B2 (en) | 2002-10-25 | 2010-11-16 | Honeywell International Inc. | Heat transfer methods using heat transfer compositions containing trifluoromonochloropropene |
| US9796848B2 (en) | 2002-10-25 | 2017-10-24 | Honeywell International Inc. | Foaming agents and compositions containing fluorine substituted olefins and methods of foaming |
| US6759381B1 (en) | 2003-05-06 | 2004-07-06 | Honeywell International Inc. | Azeotrope-like compositions of 1-chloro-1,3,3,3-tetrafluoropropane and 1,2-dichloro-3,3,3-trifluoropropene |
| US6844475B1 (en) | 2003-08-08 | 2005-01-18 | Honeywell International Business Machines | Low temperature production of 1-chloro-3,3,3-trifluoropropene (HCFC-1233zd) |
| US8034251B2 (en) * | 2007-01-03 | 2011-10-11 | Honeywell International Inc. | Azeotropic compositions of 2-chloro-3,3,3-trifluoropropene (HCFC-1233xf), 2-chloro-1,1,1,2-tetrafluoropropane (HCFC-244bb), and hydrogen fluoride (HF) |
| US20090224207A1 (en) * | 2008-03-06 | 2009-09-10 | Pham Hang T | Azeotrope-Like Composition of 2-Chloro-3,3,3-Trifluoropropene (HCFC-1233xf) and Hydrogen Fluoride (HF) |
| EP2098499B2 (en) * | 2008-03-06 | 2017-11-22 | Honeywell International Inc. | Azeotrope-like composition of 2-chloro-3,3,3-trifluoropropene (HCFC-1233xf) and hydrogen fluoride (HF) |
| US7803283B2 (en) * | 2008-03-31 | 2010-09-28 | Honeywell Internationl Inc. | Azeotrope-like compositions of 2-chloro-3,3,3-trifluoropropene (HCFC-1233xf) and 2-chloro-1,1,1,2-tetrafluoropropane (HCFC-244bb) |
| US7829747B2 (en) | 2008-04-24 | 2010-11-09 | Honeywell International Inc. | Process for dehydrofluorination of 3-chloro-1,1,1,3-tetrafluoropropane to 1-chloro-3,3,3-trifluoropropene |
| US8168837B2 (en) * | 2008-05-15 | 2012-05-01 | Honeywell International Inc. | Process for separating hydrogen fluoride from organic feedstocks |
| US8820079B2 (en) * | 2008-12-05 | 2014-09-02 | Honeywell International Inc. | Chloro- and bromo-fluoro olefin compounds useful as organic rankine cycle working fluids |
| US8217208B2 (en) * | 2008-12-12 | 2012-07-10 | Honeywell International, Inc. | Isomerization of 1-chloro-3,3,3-trifluoropropene |
| US8075797B2 (en) | 2009-01-29 | 2011-12-13 | Honeywell International Inc. | Azeotrope-like compositions of pentafluoropropane, chlorotrifluoropropene, and hydrogen fluoride |
| JP5477011B2 (ja) * | 2009-02-03 | 2014-04-23 | セントラル硝子株式会社 | (z)−1−クロロ−3,3,3−トリフルオロプロペンの精製方法 |
| US8735636B2 (en) * | 2009-03-24 | 2014-05-27 | Arkema Inc. | Separation of R-1233 from hydrogen fluoride |
| US8648221B2 (en) * | 2011-01-19 | 2014-02-11 | Honeywell International Inc. | Integrated process to co-produce trans-1-chloro-3,3,3-trifluoropropene, trans-1,3,3,3-tetrafluoropropene, and 1,1,1,3,3-pentafluoropropane |
| US8741828B2 (en) * | 2011-02-23 | 2014-06-03 | Honeywell International Inc. | Azeotrope and azeotrope-like compositions useful for the production of haloolefins |
-
2011
- 2011-10-05 US US13/253,270 patent/US8378158B2/en not_active Expired - Fee Related
- 2011-12-01 CN CN201711360709.2A patent/CN107964395A/zh active Pending
- 2011-12-01 MX MX2013006029A patent/MX358760B/es active IP Right Grant
- 2011-12-01 CN CN2011800581682A patent/CN103313961A/zh active Pending
- 2011-12-01 EP EP11845797.7A patent/EP2646403A4/en not_active Withdrawn
- 2011-12-01 WO PCT/US2011/062884 patent/WO2012075283A2/en not_active Ceased
- 2011-12-01 JP JP2013542179A patent/JP5961182B2/ja active Active
- 2011-12-01 KR KR1020137017255A patent/KR101900294B1/ko active Active
-
2013
- 2013-01-14 US US13/740,972 patent/US8541634B2/en active Active
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US10815452B2 (en) | 2015-09-04 | 2020-10-27 | AGC Inc. | Solvent composition, cleaning method and method of forming a coating film |
| US11401486B2 (en) | 2015-09-04 | 2022-08-02 | AGC Inc. | Solvent composition, cleaning method and method of forming a coating film |
Also Published As
| Publication number | Publication date |
|---|---|
| CN107964395A (zh) | 2018-04-27 |
| US20130131404A1 (en) | 2013-05-23 |
| US20120138841A1 (en) | 2012-06-07 |
| EP2646403A4 (en) | 2014-11-12 |
| US8378158B2 (en) | 2013-02-19 |
| WO2012075283A2 (en) | 2012-06-07 |
| JP5961182B2 (ja) | 2016-08-02 |
| US8541634B2 (en) | 2013-09-24 |
| CN103313961A (zh) | 2013-09-18 |
| WO2012075283A3 (en) | 2012-08-02 |
| JP2014507486A (ja) | 2014-03-27 |
| EP2646403A2 (en) | 2013-10-09 |
| MX358760B (es) | 2018-09-03 |
| KR101900294B1 (ko) | 2018-09-20 |
| KR20130136497A (ko) | 2013-12-12 |
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