MX2013003932A - Proceso para preparar copolimero de (met)acrilato que contiene grupos amino terciarios por polimerizacion por radicales libres en solucion. - Google Patents
Proceso para preparar copolimero de (met)acrilato que contiene grupos amino terciarios por polimerizacion por radicales libres en solucion.Info
- Publication number
- MX2013003932A MX2013003932A MX2013003932A MX2013003932A MX2013003932A MX 2013003932 A MX2013003932 A MX 2013003932A MX 2013003932 A MX2013003932 A MX 2013003932A MX 2013003932 A MX2013003932 A MX 2013003932A MX 2013003932 A MX2013003932 A MX 2013003932A
- Authority
- MX
- Mexico
- Prior art keywords
- polymerization
- weight
- tertiary amino
- mixture
- meth
- Prior art date
Links
- 229920001577 copolymer Polymers 0.000 title abstract 5
- 125000001302 tertiary amino group Chemical group 0.000 title abstract 3
- 238000004519 manufacturing process Methods 0.000 title abstract 2
- 238000010526 radical polymerization reaction Methods 0.000 title abstract 2
- 238000006116 polymerization reaction Methods 0.000 abstract 5
- 239000000203 mixture Substances 0.000 abstract 4
- 239000000178 monomer Substances 0.000 abstract 4
- 239000006188 syrup Substances 0.000 abstract 3
- 235000020357 syrup Nutrition 0.000 abstract 3
- SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 abstract 2
- NIXOWILDQLNWCW-UHFFFAOYSA-N 2-Propenoic acid Natural products OC(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 abstract 2
- CERQOIWHTDAKMF-UHFFFAOYSA-N Methacrylic acid Chemical compound CC(=C)C(O)=O CERQOIWHTDAKMF-UHFFFAOYSA-N 0.000 abstract 2
- 238000002360 preparation method Methods 0.000 abstract 2
- 125000004178 (C1-C4) alkyl group Chemical group 0.000 abstract 1
- 125000005907 alkyl ester group Chemical group 0.000 abstract 1
- 238000006243 chemical reaction Methods 0.000 abstract 1
- 238000004821 distillation Methods 0.000 abstract 1
- 238000001125 extrusion Methods 0.000 abstract 1
- 239000008187 granular material Substances 0.000 abstract 1
- 239000003505 polymerization initiator Substances 0.000 abstract 1
- 239000000843 powder Substances 0.000 abstract 1
- 239000013557 residual solvent Substances 0.000 abstract 1
- 239000002904 solvent Substances 0.000 abstract 1
- 239000011877 solvent mixture Substances 0.000 abstract 1
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 abstract 1
- 229920002554 vinyl polymer Polymers 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F220/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
- C08F220/02—Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
- C08F220/10—Esters
- C08F220/12—Esters of monohydric alcohols or phenols
- C08F220/14—Methyl esters, e.g. methyl (meth)acrylate
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F2/00—Processes of polymerisation
- C08F2/04—Polymerisation in solution
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F2/00—Processes of polymerisation
- C08F2/38—Polymerisation using regulators, e.g. chain terminating agents, e.g. telomerisation
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F220/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
- C08F220/02—Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
- C08F220/10—Esters
- C08F220/12—Esters of monohydric alcohols or phenols
- C08F220/16—Esters of monohydric alcohols or phenols of phenols or of alcohols containing two or more carbon atoms
- C08F220/18—Esters of monohydric alcohols or phenols of phenols or of alcohols containing two or more carbon atoms with acrylic or methacrylic acids
- C08F220/1804—C4-(meth)acrylate, e.g. butyl (meth)acrylate, isobutyl (meth)acrylate or tert-butyl (meth)acrylate
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F220/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
- C08F220/02—Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
- C08F220/10—Esters
- C08F220/34—Esters containing nitrogen, e.g. N,N-dimethylaminoethyl (meth)acrylate
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
- Polymerisation Methods In General (AREA)
Abstract
La invención se relaciona con un proceso para preparar un copolímero de (met)acrilato que contiene grupos amino terciarios por polimerización por radicales libres en solución a partir de una mezcla de monómeros que se selecciona de a) 30 a 70% en peso de un éster alquílico de 1 a 4 átomos de carbono de ácido acrílico o ácido metacrílico, y b) 70 a 30% en peso de un éster alquílico de ácido acrílico o ácido metacrílico con un grupo amino terciario en el radical alquilo, y c) 0 a 10% de monómeros de vinilo copolimerizables adicionales, por lo que uno o más iniciadores de polimerización, opcionalmente uno o más reguladores de peso molecular y uno o más disolventes o de una mezcla de disolvente se agregan a la mezcla de monómeros para proporcionar una mezcla de polimerización la cual es polimerizada a temperaturas de 30 a 120°C durante un período de 2 a 24 horas, en donde la mezcla de polimerización es polimerizada finamente para proporcionar un jarabe de polimerización con una conversión de monómeros al copolímero de por lo menos 99% en peso, en donde el jarabe de polimerización subsecuentemente se desgasifica por destilación o por extrusión y el jarabe de polimerización desgasificado se tritura adicionalmente a una preparación de copolímero en la forma de un granulado o polvo, en donde la preparación de copolímero está definida por un peso molecular (Mw) de 25,000 a 75,000 g/mol, un índice de polidispersividad de 2.1 a 2.9 y una concentración de disolvente residual de menos de 1,000 ppm en peso.
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| PCT/EP2010/065328 WO2012048740A1 (en) | 2010-10-13 | 2010-10-13 | Process for preparing a (meth)acrylate copolymer containing tertiary amino groups by free-radical polymerization in solution |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| MX2013003932A true MX2013003932A (es) | 2013-07-05 |
Family
ID=43033174
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| MX2013003932A MX2013003932A (es) | 2010-10-13 | 2010-10-13 | Proceso para preparar copolimero de (met)acrilato que contiene grupos amino terciarios por polimerizacion por radicales libres en solucion. |
Country Status (14)
| Country | Link |
|---|---|
| US (1) | US8859697B2 (es) |
| EP (1) | EP2627677B1 (es) |
| JP (1) | JP5693737B2 (es) |
| KR (1) | KR101714112B1 (es) |
| CN (1) | CN103154041B9 (es) |
| AU (1) | AU2010362463B2 (es) |
| BR (1) | BR112013008614B8 (es) |
| CA (1) | CA2814555C (es) |
| ES (1) | ES2517269T3 (es) |
| MX (1) | MX2013003932A (es) |
| PL (1) | PL2627677T3 (es) |
| RU (1) | RU2554342C9 (es) |
| SI (1) | SI2627677T1 (es) |
| WO (1) | WO2012048740A1 (es) |
Families Citing this family (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2014111292A1 (en) | 2013-01-18 | 2014-07-24 | Basf Se | Acrylic dispersion-based coating compositions |
| RU2565761C1 (ru) * | 2015-02-05 | 2015-10-20 | Федеральное государственное бюджетное образовательное учреждение высшего профессионального образования "Нижегородский государственный технический университет им. Р.Е. Алексеева" (НГТУ) | Композиция для повышения эффективности низкотемпературной депарафинизации масляных фракций |
| CN110105487B (zh) * | 2018-03-09 | 2021-07-30 | 广州茂丰药业有限公司 | 含季铵基(甲基)丙烯酸酯共聚物的溶液聚合制备方法 |
| CN109851696B (zh) * | 2019-01-14 | 2021-07-02 | 英德茂丰药业有限公司 | 一种降低含叔氨基(甲基)丙烯酸酯共聚物残留单体和溶剂的方法 |
| DE102020201334A1 (de) | 2020-02-04 | 2021-08-05 | Tesa Se | Hoch Tg Acrylatcopolymere mit Stickstoff enthaltender aromatischer heterocyclischer Gruppe |
| EP3915543A1 (en) | 2020-05-28 | 2021-12-01 | Evonik Operations GmbH | Solid self-nanoemulsifying drug delivery system (s-snedds) |
| EP3916029A1 (en) | 2020-05-28 | 2021-12-01 | Evonik Operations GmbH | Novel methacrylate copolymer and compositions comprising it |
Family Cites Families (18)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4237253A (en) * | 1977-04-21 | 1980-12-02 | L'oreal | Copolymers, their process of preparation, and cosmetic compounds containing them |
| DE3581428D1 (de) | 1984-06-13 | 1991-02-28 | Roehm Gmbh | Verfahren zum ueberziehen von arzneiformen. |
| JPH0718014A (ja) * | 1993-06-30 | 1995-01-20 | Nippon Steel Chem Co Ltd | α−メチルスチレン系重合体の製造方法 |
| US5576403A (en) | 1994-07-28 | 1996-11-19 | National Starch And Chemical Investment Holding Corporation | Solution polymerization of vinyl monomers with water soluble initiators in substantially non-aqueous media |
| JPH101511A (ja) | 1996-06-18 | 1998-01-06 | Mitsubishi Gas Chem Co Inc | 重合体の製造方法 |
| JPH09100387A (ja) * | 1995-10-06 | 1997-04-15 | Mitsubishi Chem Corp | 毛髪化粧料 |
| US5980790A (en) * | 1997-03-04 | 1999-11-09 | Mitsubishi Gas Chemical Company, Inc. | Process for producing a copolymer |
| JP3962963B2 (ja) * | 1997-06-09 | 2007-08-22 | 荒川化学工業株式会社 | 四級アンモニウム塩基を有するポリマーおよびその製造方法 |
| DE19918435A1 (de) * | 1998-07-23 | 2000-01-27 | Roehm Gmbh | Überzugs- und Bindemittel für orale oder dermale Arzneiformen |
| IL154960A0 (en) * | 2000-10-10 | 2003-10-31 | Du Pont | Polymers having attached luminescent metal complexes and devices made with sych polymers |
| JP2002167316A (ja) * | 2000-11-30 | 2002-06-11 | Mitsubishi Chemicals Corp | 毛髪化粧料組成物 |
| JP2003252926A (ja) * | 2002-03-06 | 2003-09-10 | Kanegafuchi Chem Ind Co Ltd | 重合体の取り出し方法 |
| DE102005007059A1 (de) | 2005-02-15 | 2006-08-24 | Röhm GmbH & Co. KG | Teilneutralisiertes anionisches (Meth)acrylat-Copolymer |
| EP2027162A1 (de) | 2006-01-23 | 2009-02-25 | Basf Se | Verfahren zur herstellung von polymeren in wässrigen lösungsmitteln |
| RU2450024C2 (ru) | 2006-03-31 | 2012-05-10 | Басф Се | Способ получения сополимеров акрилатов |
| JP5331363B2 (ja) | 2008-03-31 | 2013-10-30 | ハリマ化成株式会社 | カチオン性表面サイズ剤の製造方法、該方法で得られたサイズ剤、および該サイズ剤を塗工した紙 |
| CN101475662A (zh) | 2009-01-19 | 2009-07-08 | 广州华博生物制药研究所 | 一种低成膜温度、中等渗透性药用聚甲丙烯酰铵酯的制备方法 |
| BR112013008767B8 (pt) | 2010-10-13 | 2022-07-05 | Evonik Roehm Gmbh | Processo para preparação de um copolimero de (met)acrilato contendo grupos amônio quaternário através de polimerização de radical livre em solução |
-
2010
- 2010-10-13 RU RU2013120391/04A patent/RU2554342C9/ru active
- 2010-10-13 CA CA2814555A patent/CA2814555C/en active Active
- 2010-10-13 US US13/876,277 patent/US8859697B2/en active Active
- 2010-10-13 AU AU2010362463A patent/AU2010362463B2/en active Active
- 2010-10-13 SI SI201030762T patent/SI2627677T1/sl unknown
- 2010-10-13 BR BR112013008614A patent/BR112013008614B8/pt active IP Right Grant
- 2010-10-13 ES ES10763383.6T patent/ES2517269T3/es active Active
- 2010-10-13 WO PCT/EP2010/065328 patent/WO2012048740A1/en not_active Ceased
- 2010-10-13 MX MX2013003932A patent/MX2013003932A/es active IP Right Grant
- 2010-10-13 KR KR1020137012102A patent/KR101714112B1/ko active Active
- 2010-10-13 CN CN201080069513.8A patent/CN103154041B9/zh active Active
- 2010-10-13 JP JP2013533096A patent/JP5693737B2/ja active Active
- 2010-10-13 EP EP10763383.6A patent/EP2627677B1/en active Active
- 2010-10-13 PL PL10763383T patent/PL2627677T3/pl unknown
Also Published As
| Publication number | Publication date |
|---|---|
| KR20130139990A (ko) | 2013-12-23 |
| BR112013008614B1 (pt) | 2019-11-05 |
| KR101714112B1 (ko) | 2017-03-08 |
| RU2554342C2 (ru) | 2015-06-27 |
| HK1185360A1 (en) | 2014-02-14 |
| CA2814555C (en) | 2017-09-19 |
| RU2554342C9 (ru) | 2016-06-20 |
| AU2010362463A1 (en) | 2013-05-30 |
| BR112013008614A2 (pt) | 2016-06-14 |
| AU2010362463B2 (en) | 2015-04-02 |
| CN103154041A (zh) | 2013-06-12 |
| ES2517269T3 (es) | 2014-11-03 |
| SI2627677T1 (sl) | 2014-11-28 |
| RU2013120391A (ru) | 2014-11-20 |
| EP2627677B1 (en) | 2014-07-16 |
| PL2627677T3 (pl) | 2014-12-31 |
| CA2814555A1 (en) | 2012-04-19 |
| CN103154041B9 (zh) | 2016-07-06 |
| EP2627677A1 (en) | 2013-08-21 |
| JP2013543026A (ja) | 2013-11-28 |
| US20130190468A1 (en) | 2013-07-25 |
| WO2012048740A1 (en) | 2012-04-19 |
| BR112013008614B8 (pt) | 2022-07-05 |
| JP5693737B2 (ja) | 2015-04-01 |
| US8859697B2 (en) | 2014-10-14 |
| CN103154041B (zh) | 2015-09-16 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| FG | Grant or registration |