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MX2012010927A - Catalizadores de amoxidacion de oxido de metal mezclado mejorados. - Google Patents

Catalizadores de amoxidacion de oxido de metal mezclado mejorados.

Info

Publication number
MX2012010927A
MX2012010927A MX2012010927A MX2012010927A MX2012010927A MX 2012010927 A MX2012010927 A MX 2012010927A MX 2012010927 A MX2012010927 A MX 2012010927A MX 2012010927 A MX2012010927 A MX 2012010927A MX 2012010927 A MX2012010927 A MX 2012010927A
Authority
MX
Mexico
Prior art keywords
degrees
angle
ray diffraction
metal oxide
mixed metal
Prior art date
Application number
MX2012010927A
Other languages
English (en)
Inventor
Charles J Besecker
Michael J Seely
Robert A Gustaferro
Mark A Toft
James F Brazdil
Original Assignee
Ineos Usa Llc
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Ineos Usa Llc filed Critical Ineos Usa Llc
Publication of MX2012010927A publication Critical patent/MX2012010927A/es

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    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/84—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J23/85—Chromium, molybdenum or tungsten
    • B01J23/88—Molybdenum
    • B01J23/887—Molybdenum containing in addition other metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/8878—Chromium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/002—Mixed oxides other than spinels, e.g. perovskite
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/84—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J23/85—Chromium, molybdenum or tungsten
    • B01J23/88—Molybdenum
    • B01J23/881—Molybdenum and iron
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/84—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J23/85—Chromium, molybdenum or tungsten
    • B01J23/88—Molybdenum
    • B01J23/887—Molybdenum containing in addition other metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/8871—Rare earth metals or actinides
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/84—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J23/85—Chromium, molybdenum or tungsten
    • B01J23/88—Molybdenum
    • B01J23/887—Molybdenum containing in addition other metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/8876—Arsenic, antimony or bismuth
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/30—Catalysts, in general, characterised by their form or physical properties characterised by their physical properties
    • B01J35/34—Mechanical properties
    • B01J35/38—Abrasion or attrition resistance
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/02—Impregnation, coating or precipitation
    • B01J37/03—Precipitation; Co-precipitation
    • B01J37/031—Precipitation
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C253/00—Preparation of carboxylic acid nitriles
    • C07C253/24—Preparation of carboxylic acid nitriles by ammoxidation of hydrocarbons or substituted hydrocarbons
    • C07C253/26—Preparation of carboxylic acid nitriles by ammoxidation of hydrocarbons or substituted hydrocarbons containing carbon-to-carbon multiple bonds, e.g. unsaturated aldehydes
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C255/00—Carboxylic acid nitriles
    • C07C255/01—Carboxylic acid nitriles having cyano groups bound to acyclic carbon atoms
    • C07C255/06—Carboxylic acid nitriles having cyano groups bound to acyclic carbon atoms of an acyclic and unsaturated carbon skeleton
    • C07C255/07—Mononitriles
    • C07C255/08—Acrylonitrile; Methacrylonitrile
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2235/00—Indexing scheme associated with group B01J35/00, related to the analysis techniques used to determine the catalysts form or properties
    • B01J2235/15—X-ray diffraction
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2523/00—Constitutive chemical elements of heterogeneous catalysts
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2523/00—Constitutive chemical elements of heterogeneous catalysts
    • B01J2523/10—Constitutive chemical elements of heterogeneous catalysts of Group I (IA or IB) of the Periodic Table
    • B01J2523/12—Sodium
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00—Technologies relating to chemical industry
    • Y02P20/50—Improvements relating to the production of bulk chemicals
    • Y02P20/52—Improvements relating to the production of bulk chemicals using catalysts, e.g. selective catalysts

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Catalysts (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)

Abstract

La presente invención se refiere a una composición catalítica útil para la conversión de una olefina seleccionada del grupo que consiste de propileno, isobutileno o mezclas de los mismos, a acrilonitrilo, metacrilonitrilo, y mezclas de los mismos. La composición catalítica comprende un complejo de óxidos de metal que comprende bismuto, molibdeno, hierro, cerio y otros elementos promotores, en donde el patrón de difracción de rayos X de la composición catalítica tiene picos de difracción de rayos X a ángulo 2? 28 -0.3 grados y ángulo 2? 26.5 +0.3 grados, y en donde la relación de la intensidad del pico de difracción de rayos X más intenso dentro del ángulo 2? 28 -0.3 grados a la intensidad del pico de difracción de rayos X más intenso dentro del ángulo 2? 26.5 +0.3 grados se define como X/Y, y en donde X/Y es mayor que o igual a 0.7.
MX2012010927A 2010-03-23 2011-03-21 Catalizadores de amoxidacion de oxido de metal mezclado mejorados. MX2012010927A (es)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US12/661,705 US8153546B2 (en) 2010-03-23 2010-03-23 Mixed metal oxide ammoxidation catalysts
PCT/US2011/000510 WO2011119208A1 (en) 2010-03-23 2011-03-21 Improved mixed metal oxide ammoxidation catalysts

Publications (1)

Publication Number Publication Date
MX2012010927A true MX2012010927A (es) 2012-12-17

Family

ID=44059062

Family Applications (1)

Application Number Title Priority Date Filing Date
MX2012010927A MX2012010927A (es) 2010-03-23 2011-03-21 Catalizadores de amoxidacion de oxido de metal mezclado mejorados.

Country Status (11)

Country Link
US (2) US8153546B2 (es)
EP (1) EP2550100B1 (es)
JP (1) JP5940053B2 (es)
KR (1) KR101772247B1 (es)
CN (1) CN102892498B (es)
BR (1) BR112012023960B1 (es)
MX (1) MX2012010927A (es)
MY (1) MY169991A (es)
RU (1) RU2561084C2 (es)
TW (1) TWI508777B (es)
WO (1) WO2011119208A1 (es)

Families Citing this family (20)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US9433929B2 (en) 2011-09-21 2016-09-06 Ineos Europe Ag Mixed metal oxide catalysts
CN104136412B (zh) 2012-02-29 2016-12-28 三菱丽阳株式会社 丙烯腈的制造方法
EP2821390A4 (en) * 2012-02-29 2015-02-25 Mitsubishi Rayon Co Method for producing acrylonitrile
US8722940B2 (en) * 2012-03-01 2014-05-13 Saudi Basic Industries Corporation High molybdenum mixed metal oxide catalysts for the production of unsaturated aldehydes from olefins
US8835666B2 (en) 2012-11-26 2014-09-16 Ineos Usa Llc Pre calcination additives for mixed metal oxide ammoxidation catalysts
US9435043B2 (en) * 2014-04-14 2016-09-06 California Institute Of Technology Oxygen evolution reaction catalysis
BR112016027658B1 (pt) 2014-05-29 2021-09-28 Ineos Europe Ag Composições catalíticas
WO2015183284A1 (en) * 2014-05-29 2015-12-03 Ineos Usa, Llc Improved selective ammoxidation catalysts
CN105413701B (zh) * 2014-09-17 2018-01-09 中国石油化工股份有限公司 用于生产双醋酸亚乙酯的催化剂
US9844769B2 (en) * 2014-12-17 2017-12-19 Ineos Europe Ag Mixed metal oxide ammoxidation catalysts
KR101960919B1 (ko) * 2015-08-11 2019-03-22 주식회사 엘지화학 고성능 폴리옥소메탈레이트 촉매 및 이의 제조 방법
US20190001309A1 (en) * 2016-01-25 2019-01-03 Asahi Kasei Kabushiki Kaisha Catalyst for fluidized bed ammoxidation reaction, and method for producing acrylonitrile
MY186963A (en) * 2016-01-25 2021-08-26 Asahi Chemical Ind Catalyst for fluidized bed ammoxidation reaction, and method for producing acrylonitrile
CN107913596B (zh) * 2016-10-09 2020-05-05 中国石油化工股份有限公司 含氰废气催化氧化脱氰方法
US10626082B2 (en) 2016-10-11 2020-04-21 Ineos Europe Ag Ammoxidation catalyst with selective co-product HCN production
KR102290739B1 (ko) * 2018-03-30 2021-08-19 아사히 가세이 가부시키가이샤 촉매, 촉매의 제조 방법, 아크릴로니트릴의 제조 방법
JP7174846B2 (ja) 2019-09-30 2022-11-17 エルジー・ケム・リミテッド プロピレンのアンモ酸化用触媒、その製造方法、およびこれを利用したプロピレンのアンモ酸化方法
CN113164928B (zh) 2019-09-30 2024-09-17 株式会社Lg化学 用于丙烯的氨氧化催化剂、该催化剂的制造方法、使用所述催化剂的氨氧化方法
KR102519507B1 (ko) * 2019-09-30 2023-04-07 주식회사 엘지화학 프로필렌의 암모산화용 촉매, 이의 제조 방법, 및 이를 이용한 프로필렌의 암모산화 방법
CN116078396B (zh) * 2021-11-05 2025-09-19 中国石油化工股份有限公司 氨氧化催化剂及其制备方法和生产腈类化合物的方法

Family Cites Families (62)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
IT708871A (es) 1962-11-28
US4503001A (en) 1970-10-30 1985-03-05 Standard Oil Company (Indiana) Process for the manufacture of acrylonitrile and methacrylonitrile
US4863891A (en) 1971-02-04 1989-09-05 The Standard Oil Company Catalyst for the manufacture of acrylonitrile and methacrylonitrile
US4767878A (en) 1971-02-04 1988-08-30 The Standard Oil Company Process for the manufacture of acrylonitrile and methacrylonitrile
US4766232A (en) 1973-06-04 1988-08-23 The Standard Oil Company Production of unsaturated nitriles using catalysts containing boron, gallium or indium
US4139552A (en) 1974-01-04 1979-02-13 The Standard Oil Company Production of unsaturated nitriles
JPS5245692B2 (es) 1973-10-16 1977-11-17
US4192776A (en) * 1973-12-19 1980-03-11 The Standard Oil Company Catalysts and process for the ammoxidation of olefins
US4168246A (en) 1975-11-28 1979-09-18 Monsanto Company Production of (amm)oxidation catalyst
US4040978A (en) 1975-11-28 1977-08-09 Monsanto Company Production of (amm)oxidation catalyst
US4148757A (en) 1977-08-10 1979-04-10 The Standard Oil Company Process for forming multi-component oxide complex catalysts
SU738658A1 (ru) * 1978-02-20 1980-06-05 Ордена Ленина Институт Химической Физики Ан Ссср Катализатор дл окислени олефинов
US4377534A (en) 1978-02-27 1983-03-22 The Standard Oil Co. Production of unsaturated nitriles
US4212766A (en) * 1978-04-21 1980-07-15 Standard Oil Company Process for forming multi-component oxide complex catalysts
JPS57130548A (en) 1981-02-05 1982-08-13 Mitsubishi Chem Ind Ltd Catalyst composition
US4746753A (en) 1981-04-29 1988-05-24 The Standard Oil Company Preparation of acrylonitrile from propylene, oxygen and ammonia in the presence of an alkali metal promoted bismuth, cerium, molybdenum, tungsten catalyst
JPS61234943A (ja) * 1985-04-11 1986-10-20 Nippon Shokubai Kagaku Kogyo Co Ltd 共役ジオレフィン製造用触媒の製造方法
US4939286A (en) 1985-09-10 1990-07-03 The Standard Oil Company Promoted bismuth cerium molybdate catalysts
US5093299A (en) 1990-01-09 1992-03-03 The Standard Oil Company Catalyst for process for the manufacture of acrylonitrile and methacrylonitrile
US5175334A (en) 1990-01-09 1992-12-29 The Standard Oil Company Process for the manufacture of acrylonitrile and methacrylonitrile
US5212137A (en) 1990-01-09 1993-05-18 Standard Oil Company Catalyst for the manufacture of acrylonitrile and methacrylonitrile
US5235088A (en) 1990-03-19 1993-08-10 The Standard Oil Company Process and catalyst for propylene ammoxidation to acrylonitrile
US5134105A (en) 1990-03-19 1992-07-28 The Standard Oil Company Catalyst for propylene ammoxidation to acrylonitrile
CN1021638C (zh) 1990-11-05 1993-07-21 中国石油化工总公司 丙烯腈流化床催化剂
DE4220859A1 (de) 1992-06-25 1994-01-05 Basf Ag Multimetalloxidmassen
US5583086A (en) 1993-03-09 1996-12-10 Basf Aktiengesellschaft Cesium containing multimetal oxide catalyst compositions for the preparation of methacrolein by gas-phase-catalytic oxidation
JP3534431B2 (ja) 1993-08-06 2004-06-07 旭化成ケミカルズ株式会社 不飽和ニトリルの製法
US5658842A (en) 1993-08-10 1997-08-19 Asahi Kasei Kogyo Kabushiki Kaisha Ammoxidation catalyst composition, and process for producing acrylonitrile or methacrylonitrile using the same
US5780664A (en) 1993-08-17 1998-07-14 Asahi Kasei Kogyo Kabushi Kaisha Ammoxidation catalyst composition
DE4332542A1 (de) 1993-09-24 1995-03-30 Basf Ag Katalysator auf der Basis von Fe-, Co-, Bi- und Mo-Oxiden
DE4405059A1 (de) 1994-02-17 1995-08-24 Basf Ag Multimetalloxidmassen
JP3214975B2 (ja) * 1994-04-25 2001-10-02 旭化成株式会社 アンモ酸化触媒組成物および製造方法
CN1114915A (zh) 1994-07-13 1996-01-17 中国石油化工总公司 生产丙烯腈的流化床催化剂
JP3982852B2 (ja) 1995-06-30 2007-09-26 三菱レイヨン株式会社 流動層プロセス
US5834394A (en) 1996-08-06 1998-11-10 China-Petro-Chemical Corporation Fluidized-bed catalyst for propylene ammoxidation to acrylonitrile
ID20670A (id) * 1997-08-05 1999-02-11 Asahi Chemical Ind Katalis amoksidasi untuk digunakan dalam memproduksi akrilonitril atau metakrilonitril dari propana atau isobutana dengan amoksidasi
US5840648A (en) 1997-09-02 1998-11-24 The Standard Oil Company Catalyst for the manufacture of acrylonitrile and hydrogen cyanide
JP4212154B2 (ja) * 1997-12-24 2009-01-21 旭化成ケミカルズ株式会社 触媒およびこれを用いた不飽和ニトリルの製造法
CN1086154C (zh) 1998-03-30 2002-06-12 中国石油化工总公司 丙烯氨氧化催化剂
EP1075871B1 (en) * 1998-04-23 2004-09-22 Mitsubishi Rayon Co., Ltd. Catalyst for producing unsaturated nitrile
US6143690A (en) 1998-05-07 2000-11-07 Asahi Kasei Kogyo Kabushiki Kaisha Ammoxidation catalyst for use in producing acrylonitrile or methacrylonitrile from propane or isobutane
CN1092540C (zh) 1999-06-24 2002-10-16 中国石油化工集团公司 丙烯氨氧化流化床催化剂
WO2001014057A1 (en) 1999-08-19 2001-03-01 China Petro-Chemical Corporation Fluid bed catalyst for ammoxidation of propylene to acrylonitrile
ES2265984T3 (es) * 1999-10-18 2007-03-01 Mitsubishi Rayon Co., Ltd. Metodo para producir acrilonitrilo, catalizador para uso en el metodo, y metodo para producir el catalizador.
KR100681222B1 (ko) 1999-10-18 2007-02-09 미쯔비시 레이온 가부시끼가이샤 아크릴로니트릴의 제조방법, 여기에 사용되는 촉매, 및 그촉매의 제조방법
CN1104282C (zh) 1999-10-28 2003-04-02 中国石化上海石油化工股份有限公司 丙烯、异丁烯氨氧化流化床催化剂
CN1136980C (zh) 2000-02-24 2004-02-04 中国石油化工集团公司 丙烯氨氧化生产丙烯腈的流化床催化剂
CN1102576C (zh) 2000-02-24 2003-03-05 中国石油化工集团公司 丙烯氨氧化制丙烯腈的流化床催化剂
US6458742B1 (en) 2000-08-17 2002-10-01 The Standard Oil Company Catalyst for the manufacture of acrylonitrile
JP4530595B2 (ja) * 2000-12-13 2010-08-25 旭化成ケミカルズ株式会社 酸化またはアンモ酸化用酸化物触媒
JP4030740B2 (ja) 2001-10-11 2008-01-09 ダイヤニトリックス株式会社 アンモ酸化用触媒の製造方法
FR2840420B1 (fr) 2002-05-31 2005-05-27 Sepro Robotique Dispositif et produit-programme de commande, notamment de manipulateurs ou de robots
US7038082B2 (en) * 2002-10-17 2006-05-02 Basf Aktiengesellschaft Preparation of a multimetal oxide material
US7071140B2 (en) * 2002-12-02 2006-07-04 The Standard Oil Company Catalyst for the manufacture of acrylonitrile
US7348291B2 (en) * 2002-12-02 2008-03-25 Ineos Usa Llc Catalyst for the manufacture of acrylonitrile
CN100342969C (zh) * 2002-12-02 2007-10-17 标准石油公司 用于制造丙烯腈的Rb、Ce、Cr、Ni、Fe、Bi及Mo的混合氧化物催化剂
CN100438981C (zh) * 2002-12-02 2008-12-03 伊内奥斯美国公司 用于制造丙烯腈的K、Cs、Ce、Cr、Co、Ni、Fe、Bi和Mo的混合氧化物催化剂
KR100687671B1 (ko) 2003-03-05 2007-03-02 아사히 가세이 케미칼즈 가부시키가이샤 입상 다공성 암모산화 촉매
JP4242197B2 (ja) 2003-04-18 2009-03-18 ダイヤニトリックス株式会社 アクリロニトリル合成用触媒
US7902112B2 (en) * 2006-10-26 2011-03-08 Dia-Nitrix Co., Ltd. Fluidized bed catalyst for producing acrylonitrile and process for producing acrylonitrile
US8420566B2 (en) * 2010-03-23 2013-04-16 Ineos Usa Llc High efficiency ammoxidation process and mixed metal oxide catalysts
BR112012023838B1 (pt) * 2010-03-23 2023-10-31 Ineos Europe Ag Composição catalítica e processo para produzir acrilonitrila,acetonitrila e ácido cianídrico

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WO2011119208A1 (en) 2011-09-29
TW201138965A (en) 2011-11-16
EP2550100A1 (en) 2013-01-30
KR20130007625A (ko) 2013-01-18
US8350075B2 (en) 2013-01-08
US8153546B2 (en) 2012-04-10
BR112012023960B1 (pt) 2019-02-05
US20120130112A1 (en) 2012-05-24
RU2012143840A (ru) 2014-04-27
BR112012023960A2 (pt) 2017-10-03
CN102892498A (zh) 2013-01-23
KR101772247B1 (ko) 2017-08-29
RU2561084C2 (ru) 2015-08-20
US20110237753A1 (en) 2011-09-29
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