MX2012001510A - Proceso y sistema para la produccion de isopreno. - Google Patents
Proceso y sistema para la produccion de isopreno.Info
- Publication number
- MX2012001510A MX2012001510A MX2012001510A MX2012001510A MX2012001510A MX 2012001510 A MX2012001510 A MX 2012001510A MX 2012001510 A MX2012001510 A MX 2012001510A MX 2012001510 A MX2012001510 A MX 2012001510A MX 2012001510 A MX2012001510 A MX 2012001510A
- Authority
- MX
- Mexico
- Prior art keywords
- isoprene
- pentene
- methyl
- product stream
- metathesis
- Prior art date
Links
- RRHGJUQNOFWUDK-UHFFFAOYSA-N Isoprene Chemical compound CC(=C)C=C RRHGJUQNOFWUDK-UHFFFAOYSA-N 0.000 title abstract 12
- 238000000034 method Methods 0.000 title abstract 2
- JMMZCWZIJXAGKW-UHFFFAOYSA-N 2-methylpent-2-ene Chemical compound CCC=C(C)C JMMZCWZIJXAGKW-UHFFFAOYSA-N 0.000 abstract 6
- 238000005649 metathesis reaction Methods 0.000 abstract 3
- VXNZUUAINFGPBY-UHFFFAOYSA-N 1-Butene Chemical compound CCC=C VXNZUUAINFGPBY-UHFFFAOYSA-N 0.000 abstract 2
- QMMOXUPEWRXHJS-UHFFFAOYSA-N pentene-2 Natural products CCC=CC QMMOXUPEWRXHJS-UHFFFAOYSA-N 0.000 abstract 2
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 abstract 1
- 239000005977 Ethylene Substances 0.000 abstract 1
- VQTUBCCKSQIDNK-UHFFFAOYSA-N Isobutene Chemical group CC(C)=C VQTUBCCKSQIDNK-UHFFFAOYSA-N 0.000 abstract 1
- 150000001336 alkenes Chemical class 0.000 abstract 1
- 239000003054 catalyst Substances 0.000 abstract 1
- 239000007795 chemical reaction product Substances 0.000 abstract 1
- 238000005194 fractionation Methods 0.000 abstract 1
- 239000013067 intermediate product Substances 0.000 abstract 1
- JRZJOMJEPLMPRA-UHFFFAOYSA-N olefin Natural products CCCCCCCC=C JRZJOMJEPLMPRA-UHFFFAOYSA-N 0.000 abstract 1
- 239000000047 product Substances 0.000 abstract 1
- QQONPFPTGQHPMA-UHFFFAOYSA-N propylene Natural products CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 abstract 1
- 125000004805 propylene group Chemical group [H]C([H])([H])C([H])([*:1])C([H])([H])[*:2] 0.000 abstract 1
- 238000000197 pyrolysis Methods 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C11/00—Aliphatic unsaturated hydrocarbons
- C07C11/12—Alkadienes
- C07C11/173—Alkadienes with five carbon atoms
- C07C11/18—Isoprene
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C4/00—Preparation of hydrocarbons from hydrocarbons containing a larger number of carbon atoms
- C07C4/02—Preparation of hydrocarbons from hydrocarbons containing a larger number of carbon atoms by cracking a single hydrocarbon or a mixture of individually defined hydrocarbons or a normally gaseous hydrocarbon fraction
- C07C4/04—Thermal processes
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Physics & Mathematics (AREA)
- Thermal Sciences (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
Abstract
Aquí se describe un proceso para producir isopreno que incluye reaccionar una corriente de alimentación C4 de metátesis mezclada que comprende isobutileno y por lo menos uno de 1-buteno y 2-penteno en un primer reactor de metátesis en la presencia de un primer catalizador de metátesis, bajo condiciones suficientes para producir una corriente intermedia de producto que comprende por lo menos 30 % en peso de 2 metil-2-penteno basado en el contenido de olefina de la alimentación fresca en la corriente de alimentación C4 mezclada, y por lo menos uno de etileno y propileno, separar el 2 metil-2-penteno, someter a pirólisis el 2-metil-2-penteno separado para producir una corriente de producto de reacción que comprende isopreno, y separar el isopreno en una corriente de producto de isopreno utilizando fraccionación. También se describe un sistema para producir isopreno.
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US12/462,688 US8178736B2 (en) | 2009-08-07 | 2009-08-07 | Process and system for the production of isoprene |
| PCT/US2010/002115 WO2011016842A2 (en) | 2009-08-07 | 2010-07-29 | Process and system for the production of isoprene |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| MX2012001510A true MX2012001510A (es) | 2012-03-29 |
Family
ID=43432216
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| MX2012001510A MX2012001510A (es) | 2009-08-07 | 2010-07-29 | Proceso y sistema para la produccion de isopreno. |
Country Status (15)
| Country | Link |
|---|---|
| US (2) | US8178736B2 (es) |
| EP (1) | EP2462095B1 (es) |
| JP (1) | JP5870028B2 (es) |
| KR (1) | KR101808499B1 (es) |
| CN (1) | CN102695690B (es) |
| AR (1) | AR079593A1 (es) |
| BR (1) | BR112012002673B1 (es) |
| CA (1) | CA2769265C (es) |
| CL (1) | CL2012000260A1 (es) |
| MX (1) | MX2012001510A (es) |
| MY (2) | MY156329A (es) |
| SG (2) | SG178253A1 (es) |
| TW (1) | TWI474995B (es) |
| WO (1) | WO2011016842A2 (es) |
| ZA (1) | ZA201201624B (es) |
Families Citing this family (11)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2011075534A2 (en) * | 2009-12-18 | 2011-06-23 | Danisco Us Inc. | Purification of isoprene from renewable resources |
| WO2014077997A1 (en) * | 2012-11-19 | 2014-05-22 | Lummus Technology Inc. | Process to produce linear pentenes and metathesis thereof |
| US20140378726A1 (en) * | 2013-06-20 | 2014-12-25 | Uop Llc | Catalytic conversion processes using ionic liquids |
| US9981889B2 (en) | 2013-08-22 | 2018-05-29 | General Electric Company | Use of diethylenetriamine as a CS2 scavenger in isoprene production |
| US20150073183A1 (en) * | 2013-09-10 | 2015-03-12 | Uop Llc | Production of olefins from a methane conversion process |
| WO2015077343A1 (en) * | 2013-11-20 | 2015-05-28 | Lummus Technology Inc. | Olefin conversion process |
| CN105764875B (zh) | 2013-11-20 | 2018-05-22 | 鲁姆斯科技公司 | 烯烃转化方法 |
| EP3233772B1 (en) * | 2014-12-18 | 2021-04-21 | SABIC Global Technologies B.V. | Isoprene extraction with preserved c5 feedstock |
| CN112955420B (zh) * | 2018-09-07 | 2025-05-27 | 沙特基础全球技术有限公司 | 由c4进料料流生产mtbe和1-丁烯的方法 |
| US12473244B2 (en) * | 2019-05-09 | 2025-11-18 | Massachusetts Institute Of Technology | Promoters for heterogeneous olefin metathesis |
| US20250002428A1 (en) * | 2021-08-20 | 2025-01-02 | Exxonmobil Chemical Patents Inc. | Metathesis of C4/C5 to Propylene and 1-Hexene |
Family Cites Families (26)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| GB832475A (en) | 1958-05-02 | 1960-04-13 | Goodyear Tire & Rubber | Preparation of isoprene |
| GB934450A (en) | 1960-05-31 | 1963-08-21 | British Petroleum Co | Improvements in or relating to the isomerisation of hydrocarbons |
| US3327000A (en) | 1961-03-14 | 1967-06-20 | Sinclair Research Inc | Production of isoprene |
| US3382289A (en) | 1963-04-01 | 1968-05-07 | Exxon Research Engineering Co | Preparation of isoprene feedstock |
| US3284532A (en) | 1963-09-18 | 1966-11-08 | Goodyear Tire & Rubber | Promoted pyrolysis process |
| JPS4724523B1 (es) * | 1966-11-12 | 1972-07-06 | ||
| JPS4738402B1 (es) * | 1966-11-26 | 1972-09-28 | ||
| US3595280A (en) | 1969-08-01 | 1971-07-27 | Chisholm Ryder Co Inc | Automatic filling valve |
| BE755254A (fr) | 1969-08-25 | 1971-02-01 | Gulf Research & Dev Cy | Procede pour transformer une olefine metathese |
| US3686352A (en) | 1970-02-18 | 1972-08-22 | Arthur H Neal | Dimerization process |
| JPS5519959B2 (es) * | 1972-12-05 | 1980-05-29 | ||
| JPS5037163B1 (es) * | 1973-10-05 | 1975-12-01 | ||
| US4049616A (en) | 1974-11-18 | 1977-09-20 | The Goodyear Tire & Rubber Company | Preparation of graft, block and crosslinked unsaturated polymers and copolymers by olefin metathesis |
| JPS56128724A (en) * | 1980-03-15 | 1981-10-08 | Japan Synthetic Rubber Co Ltd | Purification of butadiene or isoprene |
| DE3338269A1 (de) * | 1983-10-21 | 1985-05-02 | Basf Ag, 6700 Ludwigshafen | Verfahren zur gewinnung von isopren aus einem c(pfeil abwaerts)5(pfeil abwaerts)-kohlenwasserstoffgemisch |
| US5057638A (en) | 1990-06-22 | 1991-10-15 | Chevron Research And Technology Company | Process for making 1-hexene from 1-butene |
| US5057644A (en) | 1990-10-31 | 1991-10-15 | Shell Oil Company | Process for the purification of alpha olefins |
| JPH05103995A (ja) | 1991-10-17 | 1993-04-27 | Maruzen Petrochem Co Ltd | オレフインの不均化触媒およびその触媒を用いたオレフインの不均化方法 |
| DE19746040A1 (de) * | 1997-10-17 | 1999-04-22 | Basf Ag | Verfahren zur Herstellung von Propen |
| FR2773558B1 (fr) * | 1998-01-14 | 2000-02-18 | Inst Francais Du Petrole | Procede pour l'obtention de 1-butene |
| DE19813720A1 (de) | 1998-03-27 | 1999-09-30 | Basf Ag | Verfahren zur Herstellung von Olefinen |
| DE19932060A1 (de) * | 1999-07-12 | 2001-01-18 | Basf Ag | Verfahren zur Herstellung von C¶5¶-/C¶6¶-Olefinen |
| US6875901B2 (en) | 2001-05-23 | 2005-04-05 | Abb Lummus Global Inc. | Olefin isomerization process |
| US7169953B2 (en) | 2001-11-09 | 2007-01-30 | The Penn State Research Foundation | P-chiral phospholanes and phosphocyclic compounds and their use in asymmetric catalytic reactions |
| US7214841B2 (en) * | 2003-07-15 | 2007-05-08 | Abb Lummus Global Inc. | Processing C4 olefin streams for the maximum production of propylene |
| US20060047176A1 (en) * | 2004-08-25 | 2006-03-02 | Gartside Robert J | Butane removal in C4 upgrading processes |
-
2009
- 2009-08-07 US US12/462,688 patent/US8178736B2/en active Active
-
2010
- 2010-07-29 MY MYPI2014002551A patent/MY156329A/en unknown
- 2010-07-29 MY MYPI2012000492A patent/MY156328A/en unknown
- 2010-07-29 WO PCT/US2010/002115 patent/WO2011016842A2/en not_active Ceased
- 2010-07-29 EP EP10745027.2A patent/EP2462095B1/en not_active Not-in-force
- 2010-07-29 MX MX2012001510A patent/MX2012001510A/es active IP Right Grant
- 2010-07-29 JP JP2012523600A patent/JP5870028B2/ja active Active
- 2010-07-29 SG SG2012007837A patent/SG178253A1/en unknown
- 2010-07-29 BR BR112012002673-9A patent/BR112012002673B1/pt not_active IP Right Cessation
- 2010-07-29 CA CA2769265A patent/CA2769265C/en not_active Expired - Fee Related
- 2010-07-29 KR KR1020127006001A patent/KR101808499B1/ko active Active
- 2010-07-29 SG SG2013013917A patent/SG188807A1/en unknown
- 2010-07-29 CN CN201080045682.8A patent/CN102695690B/zh active Active
- 2010-08-03 TW TW099125782A patent/TWI474995B/zh active
- 2010-08-06 AR ARP100102897A patent/AR079593A1/es not_active Application Discontinuation
-
2012
- 2012-01-31 CL CL2012000260A patent/CL2012000260A1/es unknown
- 2012-03-05 ZA ZA2012/01624A patent/ZA201201624B/en unknown
- 2012-05-08 US US13/466,704 patent/US8314278B2/en active Active
Also Published As
| Publication number | Publication date |
|---|---|
| AR079593A1 (es) | 2012-02-08 |
| US20110034747A1 (en) | 2011-02-10 |
| EP2462095A2 (en) | 2012-06-13 |
| KR101808499B1 (ko) | 2017-12-13 |
| BR112012002673B1 (pt) | 2019-01-22 |
| US8178736B2 (en) | 2012-05-15 |
| JP2013501712A (ja) | 2013-01-17 |
| MY156329A (en) | 2016-02-15 |
| SG178253A1 (en) | 2012-03-29 |
| EP2462095B1 (en) | 2019-02-13 |
| US20120232319A1 (en) | 2012-09-13 |
| SG188807A1 (en) | 2013-04-30 |
| CA2769265A1 (en) | 2011-02-10 |
| WO2011016842A2 (en) | 2011-02-10 |
| JP5870028B2 (ja) | 2016-02-24 |
| WO2011016842A3 (en) | 2011-06-16 |
| CA2769265C (en) | 2017-12-12 |
| KR20120060839A (ko) | 2012-06-12 |
| ZA201201624B (en) | 2012-11-28 |
| TW201109293A (en) | 2011-03-16 |
| MY156328A (en) | 2016-02-15 |
| CN102695690B (zh) | 2015-05-06 |
| BR112012002673A2 (pt) | 2016-04-12 |
| CL2012000260A1 (es) | 2012-08-03 |
| CN102695690A (zh) | 2012-09-26 |
| US8314278B2 (en) | 2012-11-20 |
| TWI474995B (zh) | 2015-03-01 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| FG | Grant or registration |