MX2011009030A - Espumas de poliuretano que comprenden polioles basados en lipido. - Google Patents
Espumas de poliuretano que comprenden polioles basados en lipido.Info
- Publication number
- MX2011009030A MX2011009030A MX2011009030A MX2011009030A MX2011009030A MX 2011009030 A MX2011009030 A MX 2011009030A MX 2011009030 A MX2011009030 A MX 2011009030A MX 2011009030 A MX2011009030 A MX 2011009030A MX 2011009030 A MX2011009030 A MX 2011009030A
- Authority
- MX
- Mexico
- Prior art keywords
- polyol
- isocyanate
- lipid
- isocyanate modified
- modified polyol
- Prior art date
Links
- 229920005862 polyol Polymers 0.000 title abstract 11
- 150000003077 polyols Chemical class 0.000 title abstract 11
- 150000002632 lipids Chemical class 0.000 title abstract 3
- 229920005830 Polyurethane Foam Polymers 0.000 title abstract 2
- 239000011496 polyurethane foam Substances 0.000 title abstract 2
- 239000012948 isocyanate Substances 0.000 abstract 8
- 150000002513 isocyanates Chemical class 0.000 abstract 8
- 239000004615 ingredient Substances 0.000 abstract 2
- 239000003054 catalyst Substances 0.000 abstract 1
- 239000006260 foam Substances 0.000 abstract 1
- 238000005187 foaming Methods 0.000 abstract 1
- 239000004088 foaming agent Substances 0.000 abstract 1
- 238000001879 gelation Methods 0.000 abstract 1
- 125000002887 hydroxy group Chemical group [H]O* 0.000 abstract 1
- 238000004519 manufacturing process Methods 0.000 abstract 1
- 239000000203 mixture Substances 0.000 abstract 1
- 229920000642 polymer Polymers 0.000 abstract 1
- 239000004814 polyurethane Substances 0.000 abstract 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/08—Processes
- C08G18/16—Catalysts
- C08G18/22—Catalysts containing metal compounds
- C08G18/24—Catalysts containing metal compounds of tin
- C08G18/244—Catalysts containing metal compounds of tin tin salts of carboxylic acids
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/08—Processes
- C08G18/14—Manufacture of cellular products
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/08—Processes
- C08G18/16—Catalysts
- C08G18/22—Catalysts containing metal compounds
- C08G18/222—Catalysts containing metal compounds metal compounds not provided for in groups C08G18/225 - C08G18/26
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
- C08G18/2805—Compounds having only one group containing active hydrogen
- C08G18/2815—Monohydroxy compounds
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
- C08G18/30—Low-molecular-weight compounds
- C08G18/32—Polyhydroxy compounds; Polyamines; Hydroxyamines
- C08G18/3203—Polyhydroxy compounds
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
- C08G18/40—High-molecular-weight compounds
- C08G18/48—Polyethers
- C08G18/4891—Polyethers modified with higher fatty oils or their acids or by resin acids
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/70—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the isocyanates or isothiocyanates used
- C08G18/72—Polyisocyanates or polyisothiocyanates
- C08G18/74—Polyisocyanates or polyisothiocyanates cyclic
- C08G18/76—Polyisocyanates or polyisothiocyanates cyclic aromatic
- C08G18/7614—Polyisocyanates or polyisothiocyanates cyclic aromatic containing only one aromatic ring
- C08G18/7621—Polyisocyanates or polyisothiocyanates cyclic aromatic containing only one aromatic ring being toluene diisocyanate including isomer mixtures
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/70—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the isocyanates or isothiocyanates used
- C08G18/72—Polyisocyanates or polyisothiocyanates
- C08G18/74—Polyisocyanates or polyisothiocyanates cyclic
- C08G18/76—Polyisocyanates or polyisothiocyanates cyclic aromatic
- C08G18/7657—Polyisocyanates or polyisothiocyanates cyclic aromatic containing two or more aromatic rings
- C08G18/7664—Polyisocyanates or polyisothiocyanates cyclic aromatic containing two or more aromatic rings containing alkylene polyphenyl groups
- C08G18/7671—Polyisocyanates or polyisothiocyanates cyclic aromatic containing two or more aromatic rings containing alkylene polyphenyl groups containing only one alkylene bisphenyl group
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G2110/00—Foam properties
- C08G2110/0008—Foam properties flexible
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G2110/00—Foam properties
- C08G2110/0025—Foam properties rigid
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G2110/00—Foam properties
- C08G2110/0041—Foam properties having specified density
- C08G2110/005—< 50kg/m3
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G2110/00—Foam properties
- C08G2110/0083—Foam properties prepared using water as the sole blowing agent
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/249921—Web or sheet containing structurally defined element or component
- Y10T428/249953—Composite having voids in a component [e.g., porous, cellular, etc.]
- Y10T428/249978—Voids specified as micro
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Engineering & Computer Science (AREA)
- Manufacturing & Machinery (AREA)
- Polyurethanes Or Polyureas (AREA)
Abstract
Se describe un método de elaboración de una espuma de poliuretano a partir de una mezcla de poliol modificado con isocianato e ingredientes formadores de espuma, en donde el poliol modificado con isocianato es elaborado mediante la reacción de al menos un poliol con al menos un isocianato multifuncional, en donde el poliol modificado con isocianato es un polímero de poliol no convertido en espuma que tiene grupos OH disponibles, en donde los ingredientes formadores de espuma comprenden al menos un isocianato multifuncional y un agente de formación de espuma, preferentemente agua, y caracterizado porque (i) al menos un poliol del cual es elaborado el poliol modificado con isocianato, comprende al menos un poliol basado en lípido que ha sufrido reacción con el isocianato en presencia de un catalizador de gelificación de PU, y/o (ii) el poliol modificado con isocianato es mezclado con un poliol basado en lípido antes de, o al mismo tiempo que la conversión en espuma.
Applications Claiming Priority (7)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| GB0903717A GB0903717D0 (en) | 2009-03-04 | 2009-03-04 | Flexible polyurethane foam |
| GB0905948A GB0905948D0 (en) | 2009-03-04 | 2009-04-06 | Flexible polyurethane foam |
| GB0909563A GB0909563D0 (en) | 2009-03-04 | 2009-06-03 | Flexible polyurethane foam |
| GB0910063A GB0910063D0 (en) | 2009-03-04 | 2009-06-11 | Polyurethane foam |
| GB0912558A GB0912558D0 (en) | 2009-03-04 | 2009-07-20 | Polyurethane foam |
| GB0917550A GB0917550D0 (en) | 2009-03-04 | 2009-10-07 | Polyurethane foam |
| PCT/GB2010/000381 WO2010100421A2 (en) | 2009-03-04 | 2010-03-03 | Polyurethane foam |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| MX2011009030A true MX2011009030A (es) | 2011-12-14 |
Family
ID=40580612
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| MX2011009030A MX2011009030A (es) | 2009-03-04 | 2010-03-03 | Espumas de poliuretano que comprenden polioles basados en lipido. |
Country Status (15)
| Country | Link |
|---|---|
| US (3) | US8815968B2 (es) |
| EP (1) | EP2403890B1 (es) |
| JP (2) | JP5829918B2 (es) |
| CN (1) | CN102341421A (es) |
| BR (1) | BRPI1009559A2 (es) |
| CA (1) | CA2753346C (es) |
| DK (1) | DK2403890T3 (es) |
| ES (1) | ES2604002T3 (es) |
| GB (6) | GB0903717D0 (es) |
| HU (1) | HUE030202T2 (es) |
| MX (1) | MX2011009030A (es) |
| PL (1) | PL2403890T3 (es) |
| PT (1) | PT2403890T (es) |
| RU (1) | RU2529469C2 (es) |
| WO (1) | WO2010100421A2 (es) |
Families Citing this family (24)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| GB0705685D0 (en) * | 2007-03-24 | 2007-05-02 | Nauer Fritz Ag | Polyurethane foam |
| ES2399170T3 (es) * | 2008-02-01 | 2013-03-26 | Dow Global Technologies Llc | Polialcoholes copoliméricos basados en aceite natural y productos de poliuretano obtenidos a partir de los mismos |
| CN102428115A (zh) * | 2009-04-16 | 2012-04-25 | 3M创新有限公司 | 适用于涂布饮用水管道的方法和组合物 |
| MX2010005069A (es) * | 2009-05-27 | 2010-11-26 | Bayer Materialscience Ag | Procedimiento para la fabricacion de espumas blandas de poliuretano con emision reducida. |
| EP2545091A1 (en) * | 2010-03-12 | 2013-01-16 | Dow Global Technologies LLC | Gels and soft polyurethane elastomers made with natural oil based polyols |
| CN103827307A (zh) | 2011-02-02 | 2014-05-28 | 索拉兹米公司 | 产自重组产油微生物的定制油 |
| MY163707A (en) | 2011-03-30 | 2017-10-13 | 3M Innovative Properties Co | Composition comprising cyclic secondary amine and methods of coating drinking water pipelines |
| DE102011110016A1 (de) * | 2011-08-11 | 2013-02-14 | Evonik Goldschmidt Gmbh | Zusammensetzung enthaltend Zinn- und/oder Zink-Salze der Ricinolsäure sowie mindestens ein weiteres Zinncarboxylat und Verwendung der Zusammensetzung bei der Herstellung von Polyurethansystemen |
| DE102011110020A1 (de) * | 2011-08-11 | 2013-02-14 | Evonik Goldschmidt Gmbh | Formulierung enthaltend Zinn-und/oder Zink-Salze der Ricinolsäure,Harnstoff,Polyethylenglykol und Zuckeralkohol und Verwendung der Formulierung bei der Herstellung von Polyurethansystemen |
| US20130289150A1 (en) * | 2012-04-26 | 2013-10-31 | Bayer Materialscience Ag | Viscoelastic polyurethane foams |
| KR20140102821A (ko) * | 2013-02-15 | 2014-08-25 | 엘지전자 주식회사 | 반응성 기포개방제 조성물, 폴리올 조성물 및 개방기포형 폴리우레탄폼 |
| JP2014201603A (ja) * | 2013-04-01 | 2014-10-27 | 株式会社ブリヂストン | 電極材製造用ポリウレタンフォーム及びその製造方法 |
| WO2015021541A1 (en) | 2013-08-13 | 2015-02-19 | Enerlab 2000 Inc. | Process for the preparation of lignin based polyurethane products |
| MY203264A (en) * | 2014-05-26 | 2024-06-20 | Univ Kebangsaan Malaysia | Method to produce natural oil-based polyurethane prepolymer |
| EP3294786A4 (en) * | 2015-05-15 | 2019-02-27 | Stepan Company | ETHOXYLATED PLANT OILS IN LOW-DENSITY SPRAY FORMULATIONS |
| WO2018015245A1 (de) * | 2016-07-21 | 2018-01-25 | Covestro Deutschland Ag | Hochtemperaturstabile polyisocyanuratschaumstoffe |
| CN108623771B (zh) * | 2017-03-15 | 2022-10-25 | 科思创德国股份有限公司 | 羟基封端的聚氨酯预聚体及其制备方法 |
| CN111565929B (zh) | 2017-12-25 | 2022-06-10 | 井上株式会社 | 层叠体和车辆用内饰材料的表皮材料 |
| JP7112298B2 (ja) * | 2018-09-19 | 2022-08-03 | 株式会社イノアックコーポレーション | 積層体と車両用内装材の表皮材 |
| KR102308560B1 (ko) * | 2020-07-01 | 2021-10-06 | 주식회사 케이씨씨 | 접착제용 우레탄 수지 및 그 제조방법 |
| CN111825827A (zh) * | 2020-07-22 | 2020-10-27 | 江苏君晟家居科技有限公司 | 植物油基改性异氰酸酯的合成工艺以及其应用 |
| US11613604B2 (en) | 2021-06-28 | 2023-03-28 | Covestro Llc | Isocyanate-reactive compositions, polyurethane foams formed therefrom, multi-layer composite articles that include such foams, and methods for their preparation |
| PL448801A1 (pl) * | 2024-06-12 | 2025-12-15 | Politechnika Krakowska im. Tadeusza Kościuszki | Sposób wytwarzania wiskoelastycznej pianki poliuretanowej |
| WO2026005000A1 (ja) * | 2024-06-28 | 2026-01-02 | 株式会社イノアックコーポレーション | ポリウレタンフォーム及びシートパッド |
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| AU2008296317A1 (en) * | 2007-09-07 | 2009-03-12 | Dow Global Technologies Inc. | Use of natural oil based compounds of low functionality to enhance foams |
| EP2062927B1 (de) * | 2007-11-20 | 2016-06-29 | Henkel AG & Co. KGaA | 2K-PU-Klebstoff für Tieftemperaturanwendungen |
| ES2399170T3 (es) * | 2008-02-01 | 2013-03-26 | Dow Global Technologies Llc | Polialcoholes copoliméricos basados en aceite natural y productos de poliuretano obtenidos a partir de los mismos |
| EP2274357A2 (en) * | 2008-03-20 | 2011-01-19 | Dow Global Technologies Inc. | Prepolymers made from natural oil based polyols |
| ES2401058T3 (es) * | 2008-06-12 | 2013-04-16 | Dow Global Technologies Llc | Prepolímeros de poliol de polioles basados en aceite natural y espumas de poliuretano flexibles correspondientes |
-
2009
- 2009-03-04 GB GB0903717A patent/GB0903717D0/en not_active Ceased
- 2009-04-06 GB GB0905948A patent/GB0905948D0/en not_active Ceased
- 2009-06-03 GB GB0909563A patent/GB0909563D0/en not_active Ceased
- 2009-06-11 GB GB0910063A patent/GB0910063D0/en not_active Ceased
- 2009-07-20 GB GB0912558A patent/GB0912558D0/en not_active Ceased
- 2009-10-07 GB GB0917550A patent/GB0917550D0/en not_active Ceased
-
2010
- 2010-03-03 HU HUE10711917A patent/HUE030202T2/en unknown
- 2010-03-03 BR BRPI1009559A patent/BRPI1009559A2/pt not_active IP Right Cessation
- 2010-03-03 CN CN2010800105431A patent/CN102341421A/zh active Pending
- 2010-03-03 WO PCT/GB2010/000381 patent/WO2010100421A2/en not_active Ceased
- 2010-03-03 CA CA2753346A patent/CA2753346C/en not_active Expired - Fee Related
- 2010-03-03 PL PL10711917T patent/PL2403890T3/pl unknown
- 2010-03-03 ES ES10711917.4T patent/ES2604002T3/es active Active
- 2010-03-03 JP JP2011552504A patent/JP5829918B2/ja not_active Expired - Fee Related
- 2010-03-03 PT PT107119174T patent/PT2403890T/pt unknown
- 2010-03-03 US US12/716,684 patent/US8815968B2/en not_active Expired - Fee Related
- 2010-03-03 DK DK10711917.4T patent/DK2403890T3/en active
- 2010-03-03 EP EP10711917.4A patent/EP2403890B1/en not_active Not-in-force
- 2010-03-03 RU RU2011140163/04A patent/RU2529469C2/ru not_active IP Right Cessation
- 2010-03-03 MX MX2011009030A patent/MX2011009030A/es active IP Right Grant
-
2014
- 2014-07-19 US US14/335,882 patent/US20140329923A1/en not_active Abandoned
- 2014-07-24 US US14/339,939 patent/US20140336347A1/en not_active Abandoned
-
2015
- 2015-07-31 JP JP2015152125A patent/JP2015193854A/ja not_active Withdrawn
Also Published As
| Publication number | Publication date |
|---|---|
| ES2604002T3 (es) | 2017-03-02 |
| DK2403890T3 (en) | 2016-12-12 |
| WO2010100421A2 (en) | 2010-09-10 |
| JP5829918B2 (ja) | 2015-12-09 |
| HUE030202T2 (en) | 2017-04-28 |
| PL2403890T3 (pl) | 2017-08-31 |
| RU2529469C2 (ru) | 2014-09-27 |
| GB0909563D0 (en) | 2009-07-15 |
| GB0912558D0 (en) | 2009-08-26 |
| US20100227151A1 (en) | 2010-09-09 |
| JP2012519743A (ja) | 2012-08-30 |
| US8815968B2 (en) | 2014-08-26 |
| CA2753346C (en) | 2017-08-29 |
| CN102341421A (zh) | 2012-02-01 |
| WO2010100421A4 (en) | 2010-12-16 |
| WO2010100421A3 (en) | 2010-10-28 |
| US20140336347A1 (en) | 2014-11-13 |
| US20140329923A1 (en) | 2014-11-06 |
| EP2403890B1 (en) | 2016-08-17 |
| BRPI1009559A2 (pt) | 2016-03-22 |
| GB0903717D0 (en) | 2009-04-15 |
| GB0905948D0 (en) | 2009-05-20 |
| EP2403890A2 (en) | 2012-01-11 |
| PT2403890T (pt) | 2016-11-14 |
| RU2011140163A (ru) | 2013-04-10 |
| JP2015193854A (ja) | 2015-11-05 |
| CA2753346A1 (en) | 2010-09-10 |
| GB0917550D0 (en) | 2009-11-25 |
| GB0910063D0 (en) | 2009-07-22 |
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