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MX2011004526A - Reduccion de eteres de hmf con un catalizador metalico. - Google Patents

Reduccion de eteres de hmf con un catalizador metalico.

Info

Publication number
MX2011004526A
MX2011004526A MX2011004526A MX2011004526A MX2011004526A MX 2011004526 A MX2011004526 A MX 2011004526A MX 2011004526 A MX2011004526 A MX 2011004526A MX 2011004526 A MX2011004526 A MX 2011004526A MX 2011004526 A MX2011004526 A MX 2011004526A
Authority
MX
Mexico
Prior art keywords
methanol
alkoxymethyl
furan
tetrahydrofuran
compounds
Prior art date
Application number
MX2011004526A
Other languages
English (en)
Inventor
Paul David Bloom
Alexandra J Sanborn
Original Assignee
Archer Daniels Midland Co
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Archer Daniels Midland Co filed Critical Archer Daniels Midland Co
Publication of MX2011004526A publication Critical patent/MX2011004526A/es

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D307/00—Heterocyclic compounds containing five-membered rings having one oxygen atom as the only ring hetero atom
    • C07D307/02—Heterocyclic compounds containing five-membered rings having one oxygen atom as the only ring hetero atom not condensed with other rings
    • C07D307/34—Heterocyclic compounds containing five-membered rings having one oxygen atom as the only ring hetero atom not condensed with other rings having two or three double bonds between ring members or between ring members and non-ring members
    • C07D307/38—Heterocyclic compounds containing five-membered rings having one oxygen atom as the only ring hetero atom not condensed with other rings having two or three double bonds between ring members or between ring members and non-ring members with substituted hydrocarbon radicals attached to ring carbon atoms
    • C07D307/54—Radicals substituted by carbon atoms having three bonds to hetero atoms with at the most one bond to halogen, e.g. ester or nitrile radicals
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C41/00—Preparation of ethers; Preparation of compounds having groups, groups or groups
    • C07C41/01—Preparation of ethers
    • C07C41/18—Preparation of ethers by reactions not forming ether-oxygen bonds
    • C07C41/26—Preparation of ethers by reactions not forming ether-oxygen bonds by introduction of hydroxy or O-metal groups
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C43/00—Ethers; Compounds having groups, groups or groups
    • C07C43/02—Ethers
    • C07C43/03—Ethers having all ether-oxygen atoms bound to acyclic carbon atoms
    • C07C43/04—Saturated ethers
    • C07C43/13—Saturated ethers containing hydroxy or O-metal groups
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D307/00—Heterocyclic compounds containing five-membered rings having one oxygen atom as the only ring hetero atom
    • C07D307/02—Heterocyclic compounds containing five-membered rings having one oxygen atom as the only ring hetero atom not condensed with other rings
    • C07D307/04—Heterocyclic compounds containing five-membered rings having one oxygen atom as the only ring hetero atom not condensed with other rings having no double bonds between ring members or between ring members and non-ring members
    • C07D307/10—Heterocyclic compounds containing five-membered rings having one oxygen atom as the only ring hetero atom not condensed with other rings having no double bonds between ring members or between ring members and non-ring members with substituted hydrocarbon radicals attached to ring carbon atoms
    • C07D307/12—Radicals substituted by oxygen atoms
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D307/00—Heterocyclic compounds containing five-membered rings having one oxygen atom as the only ring hetero atom
    • C07D307/02—Heterocyclic compounds containing five-membered rings having one oxygen atom as the only ring hetero atom not condensed with other rings
    • C07D307/04—Heterocyclic compounds containing five-membered rings having one oxygen atom as the only ring hetero atom not condensed with other rings having no double bonds between ring members or between ring members and non-ring members
    • C07D307/10—Heterocyclic compounds containing five-membered rings having one oxygen atom as the only ring hetero atom not condensed with other rings having no double bonds between ring members or between ring members and non-ring members with substituted hydrocarbon radicals attached to ring carbon atoms
    • C07D307/16—Radicals substituted by carbon atoms having three bonds to hetero atoms with at the most one bond to halogen, e.g. ester or nitrile radicals
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D307/00—Heterocyclic compounds containing five-membered rings having one oxygen atom as the only ring hetero atom
    • C07D307/02—Heterocyclic compounds containing five-membered rings having one oxygen atom as the only ring hetero atom not condensed with other rings
    • C07D307/34—Heterocyclic compounds containing five-membered rings having one oxygen atom as the only ring hetero atom not condensed with other rings having two or three double bonds between ring members or between ring members and non-ring members
    • C07D307/38—Heterocyclic compounds containing five-membered rings having one oxygen atom as the only ring hetero atom not condensed with other rings having two or three double bonds between ring members or between ring members and non-ring members with substituted hydrocarbon radicals attached to ring carbon atoms
    • C07D307/40—Radicals substituted by oxygen atoms
    • C07D307/42—Singly bound oxygen atoms
    • C07D307/44—Furfuryl alcohol
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00—Use of organic ingredients
    • C08K5/04—Oxygen-containing compounds
    • C08K5/06—Ethers; Acetals; Ketals; Ortho-esters
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
    • C09K3/00—Materials not provided for elsewhere

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Health & Medical Sciences (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
  • Furan Compounds (AREA)
  • Catalysts (AREA)

Abstract

Esta exposición describe métodos para reducir éter de hidroximetilfurfural y derivados de éster para producir, en el caso de los éteres, 5-(alcoximetil)-tetrahidrofurano-2-metanol y derivados de (5-alcoximetil)-furano-2-metanol, o en el caso de los ésteres, 5-(aciloximetil)-tetrahidrofurano-2-metanol y derivados de 5-(aciloximetil)-furano-2-metanol. Los métodos ejemplificados describen la purificación de los mismos. Además, la exposición se refiere a compuestos de n-alcoxi hexano diol, que son compuestos derivados útiles para el reemplazo de compuestos de carbitol a base de petróleo y pueden producirse mediante la reducción adicional del 5-(alcoximetil)-tetrahidrofura no-2-metanol y derivados de (5-alcoximetil)-furano-2-metanol. Los compuestos producidos por los métodos de la presente enseñanza son útiles como solventes y como materiales de inicio para producir otras composiciones que satisfacen los requerimientos de los químicos industriales de base biológica provenientes de recursos renovables.
MX2011004526A 2008-10-30 2009-10-30 Reduccion de eteres de hmf con un catalizador metalico. MX2011004526A (es)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US10963408P 2008-10-30 2008-10-30
PCT/US2009/062778 WO2010062689A2 (en) 2008-10-30 2009-10-30 Reduction of hmf ethers with metal catalyst

Publications (1)

Publication Number Publication Date
MX2011004526A true MX2011004526A (es) 2011-12-14

Family

ID=42226332

Family Applications (2)

Application Number Title Priority Date Filing Date
MX2014015367A MX362580B (es) 2008-10-30 2009-10-30 Reduccion de eteres de hmf con un catalizador metalico.
MX2011004526A MX2011004526A (es) 2008-10-30 2009-10-30 Reduccion de eteres de hmf con un catalizador metalico.

Family Applications Before (1)

Application Number Title Priority Date Filing Date
MX2014015367A MX362580B (es) 2008-10-30 2009-10-30 Reduccion de eteres de hmf con un catalizador metalico.

Country Status (9)

Country Link
US (4) US8709286B2 (es)
EP (1) EP2350035B1 (es)
CN (3) CN105801528B (es)
AU (1) AU2009319998B2 (es)
BR (1) BRPI0914384B1 (es)
ES (1) ES2566649T3 (es)
HU (1) HUE029859T2 (es)
MX (2) MX362580B (es)
WO (1) WO2010062689A2 (es)

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MX2010006504A (es) * 2007-12-12 2010-08-31 Archer Daniels Midland Co Conversion de carbohidratos a hidroxi-metilfurfural (hmf) y derivado.
BRPI0914384B1 (pt) * 2008-10-30 2017-04-18 Archer Daniels Midlan Company método para produzir pelo menos um composto desejado
WO2013101968A1 (en) 2011-12-30 2013-07-04 E. I. Du Pont De Nemours And Company Process for the production of hexanediols
CN104136424A (zh) 2011-12-30 2014-11-05 纳幕尔杜邦公司 由异山梨醇制备四氢呋喃-2,5-二甲醇
US8865940B2 (en) 2011-12-30 2014-10-21 E I Du Pont De Nemours And Company Process for preparing 1,6-hexanediol
US8884036B2 (en) 2011-12-30 2014-11-11 E I Du Pont De Nemours And Company Production of hydroxymethylfurfural from levoglucosenone
US8889912B2 (en) 2011-12-30 2014-11-18 E I Du Pont De Nemours And Company Process for preparing 1,6-hexanediol
CN104011001A (zh) 2011-12-30 2014-08-27 纳幕尔杜邦公司 制备1,6-己二醇的方法
US9018423B2 (en) 2012-04-27 2015-04-28 E I Du Pont De Nemours And Company Production of alpha, omega-diols
US8846984B2 (en) 2012-04-27 2014-09-30 E I Du Pont De Nemours And Company Production of α,ω-diols
US8859826B2 (en) 2012-04-27 2014-10-14 E I Du Pont De Nemours And Company Production of alpha, omega-diols
CN103073526B (zh) * 2012-12-26 2014-12-03 中国科学院宁波材料技术与工程研究所 一种2，5-二取代的四氢呋喃类混合物的制备方法
EP2989094A4 (en) * 2013-04-25 2016-11-02 Archer Daniels Midland Co CATALYTIC SYNTHESIS OF REDUCED FURANDERIVATES
AU2014366329A1 (en) * 2013-12-19 2016-06-02 Archer Daniels Midland Company Sulfonates of furan-2,5-dimethanol and (tetrahydrofuran-2,5-diyl)dimethanol and derivatives thereof
BR112018014278B1 (pt) 2016-01-13 2022-07-12 Stora Enso Oyj Processos para a preparação de ácido 2,5-furandicarboxílico e intermediários e derivados dos mesmos
WO2017222532A1 (en) * 2016-06-23 2017-12-28 Archer Daniels Midland Company Preparation of mono- and di-alkyl halide furanic compounds from 2,5-bis(hydroxymethyl)-tetrahydrofurans (bhmthf) and derivatives thereof
BR112020000611B1 (pt) 2017-07-12 2024-03-05 Stora Enso Oyj Produtos purificados de via de ácido 2,5-furanoodicarboxílico
WO2021261393A1 (ja) * 2020-06-22 2021-12-30 東レ・ファインケミカル株式会社 テトラヒドロフラン－２－カルボン酸の製造方法
CN117019148B (zh) * 2023-07-10 2025-11-11 昆明理工大学 一种金属单原子掺杂的铜基催化剂及其制备方法与应用

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Also Published As

Publication number Publication date
ES2566649T3 (es) 2016-04-14
WO2010062689A2 (en) 2010-06-03
CN102177146A (zh) 2011-09-07
CN103626639A (zh) 2014-03-12
US20160297788A1 (en) 2016-10-13
WO2010062689A3 (en) 2010-07-22
AU2009319998A1 (en) 2010-06-03
CN103626639B (zh) 2016-12-07
US20140239230A1 (en) 2014-08-28
CN105801528B (zh) 2019-06-21
EP2350035B1 (en) 2016-01-13
HUE029859T2 (en) 2017-04-28
US9416119B2 (en) 2016-08-16
BRPI0914384B1 (pt) 2017-04-18
EP2350035A2 (en) 2011-08-03
BRPI0914384A2 (pt) 2016-10-18
EP2350035A4 (en) 2012-07-25
CN102177146B (zh) 2016-02-10
US20120261618A1 (en) 2012-10-18
US9422258B2 (en) 2016-08-23
US9783516B2 (en) 2017-10-10
US8709286B2 (en) 2014-04-29
AU2009319998B2 (en) 2015-07-16
MX362580B (es) 2019-01-25
US20140200299A1 (en) 2014-07-17
CN105801528A (zh) 2016-07-27

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