MX2010008383A - Method for coating metal surfaces with a phosphate layer and then with a polymer lubricant layer. - Google Patents
Method for coating metal surfaces with a phosphate layer and then with a polymer lubricant layer.Info
- Publication number
- MX2010008383A MX2010008383A MX2010008383A MX2010008383A MX2010008383A MX 2010008383 A MX2010008383 A MX 2010008383A MX 2010008383 A MX2010008383 A MX 2010008383A MX 2010008383 A MX2010008383 A MX 2010008383A MX 2010008383 A MX2010008383 A MX 2010008383A
- Authority
- MX
- Mexico
- Prior art keywords
- layer
- phosphate
- ionomer
- polymer material
- organic polymer
- Prior art date
Links
- 239000000314 lubricant Substances 0.000 title abstract 6
- 229910019142 PO4 Inorganic materials 0.000 title abstract 4
- NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 title abstract 4
- 239000010452 phosphate Substances 0.000 title abstract 4
- 229910052751 metal Inorganic materials 0.000 title abstract 2
- 239000002184 metal Substances 0.000 title abstract 2
- 238000000034 method Methods 0.000 title abstract 2
- 229920000642 polymer Polymers 0.000 title abstract 2
- 239000011248 coating agent Substances 0.000 title 1
- 238000000576 coating method Methods 0.000 title 1
- 229920000554 ionomer Polymers 0.000 abstract 3
- 229920000620 organic polymer Polymers 0.000 abstract 3
- 239000002861 polymer material Substances 0.000 abstract 3
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 abstract 2
- SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 abstract 1
- NIXOWILDQLNWCW-UHFFFAOYSA-N 2-Propenoic acid Natural products OC(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 abstract 1
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 abstract 1
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 abstract 1
- JOYRKODLDBILNP-UHFFFAOYSA-N Ethyl urethane Chemical compound CCOC(N)=O JOYRKODLDBILNP-UHFFFAOYSA-N 0.000 abstract 1
- 239000005977 Ethylene Substances 0.000 abstract 1
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 abstract 1
- PWHULOQIROXLJO-UHFFFAOYSA-N Manganese Chemical compound [Mn] PWHULOQIROXLJO-UHFFFAOYSA-N 0.000 abstract 1
- CERQOIWHTDAKMF-UHFFFAOYSA-N Methacrylic acid Chemical compound CC(=C)C(O)=O CERQOIWHTDAKMF-UHFFFAOYSA-N 0.000 abstract 1
- 239000004952 Polyamide Substances 0.000 abstract 1
- 230000002378 acidificating effect Effects 0.000 abstract 1
- 229910052791 calcium Inorganic materials 0.000 abstract 1
- 239000011575 calcium Substances 0.000 abstract 1
- 229920001577 copolymer Polymers 0.000 abstract 1
- 150000002118 epoxides Chemical class 0.000 abstract 1
- 150000002148 esters Chemical class 0.000 abstract 1
- 229910052749 magnesium Inorganic materials 0.000 abstract 1
- 239000011777 magnesium Substances 0.000 abstract 1
- 229910052748 manganese Inorganic materials 0.000 abstract 1
- 239000011572 manganese Substances 0.000 abstract 1
- 239000000178 monomer Substances 0.000 abstract 1
- 229920002647 polyamide Polymers 0.000 abstract 1
- QQONPFPTGQHPMA-UHFFFAOYSA-N propylene Natural products CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 abstract 1
- 125000004805 propylene group Chemical group [H]C([H])([H])C([H])([*:1])C([H])([H])[*:2] 0.000 abstract 1
- 150000003839 salts Chemical class 0.000 abstract 1
Classifications
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M173/00—Lubricating compositions containing more than 10% water
- C10M173/02—Lubricating compositions containing more than 10% water not containing mineral or fatty oils
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M111/00—Lubrication compositions characterised by the base-material being a mixture of two or more compounds covered by more than one of the main groups C10M101/00 - C10M109/00, each of these compounds being essential
- C10M111/04—Lubrication compositions characterised by the base-material being a mixture of two or more compounds covered by more than one of the main groups C10M101/00 - C10M109/00, each of these compounds being essential at least one of them being a macromolecular organic compound
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- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2201/00—Inorganic compounds or elements as ingredients in lubricant compositions
- C10M2201/04—Elements
- C10M2201/041—Carbon; Graphite; Carbon black
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- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2201/00—Inorganic compounds or elements as ingredients in lubricant compositions
- C10M2201/06—Metal compounds
- C10M2201/062—Oxides; Hydroxides; Carbonates or bicarbonates
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- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2201/00—Inorganic compounds or elements as ingredients in lubricant compositions
- C10M2201/06—Metal compounds
- C10M2201/065—Sulfides; Selenides; Tellurides
- C10M2201/066—Molybdenum sulfide
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- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2201/00—Inorganic compounds or elements as ingredients in lubricant compositions
- C10M2201/085—Phosphorus oxides, acids or salts
- C10M2201/0853—Phosphorus oxides, acids or salts used as base material
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- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2201/00—Inorganic compounds or elements as ingredients in lubricant compositions
- C10M2201/10—Compounds containing silicon
- C10M2201/102—Silicates
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- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2205/00—Organic macromolecular hydrocarbon compounds or fractions, whether or not modified by oxidation as ingredients in lubricant compositions
- C10M2205/02—Organic macromolecular hydrocarbon compounds or fractions, whether or not modified by oxidation as ingredients in lubricant compositions containing acyclic monomers
- C10M2205/022—Ethene
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- C10M2205/00—Organic macromolecular hydrocarbon compounds or fractions, whether or not modified by oxidation as ingredients in lubricant compositions
- C10M2205/02—Organic macromolecular hydrocarbon compounds or fractions, whether or not modified by oxidation as ingredients in lubricant compositions containing acyclic monomers
- C10M2205/024—Propene
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- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2205/00—Organic macromolecular hydrocarbon compounds or fractions, whether or not modified by oxidation as ingredients in lubricant compositions
- C10M2205/04—Organic macromolecular hydrocarbon compounds or fractions, whether or not modified by oxidation as ingredients in lubricant compositions containing aromatic monomers, e.g. styrene
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- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2205/00—Organic macromolecular hydrocarbon compounds or fractions, whether or not modified by oxidation as ingredients in lubricant compositions
- C10M2205/16—Paraffin waxes; Petrolatum, e.g. slack wax
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- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2205/00—Organic macromolecular hydrocarbon compounds or fractions, whether or not modified by oxidation as ingredients in lubricant compositions
- C10M2205/18—Natural waxes, e.g. ceresin, ozocerite, bees wax, carnauba; Degras
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- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2209/00—Organic macromolecular compounds containing oxygen as ingredients in lubricant compositions
- C10M2209/02—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
- C10M2209/08—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds containing monomers having an unsaturated radical bound to a carboxyl radical, e.g. acrylate type
- C10M2209/084—Acrylate; Methacrylate
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- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2209/00—Organic macromolecular compounds containing oxygen as ingredients in lubricant compositions
- C10M2209/02—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
- C10M2209/08—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds containing monomers having an unsaturated radical bound to a carboxyl radical, e.g. acrylate type
- C10M2209/084—Acrylate; Methacrylate
- C10M2209/0845—Acrylate; Methacrylate used as base material
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- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2209/00—Organic macromolecular compounds containing oxygen as ingredients in lubricant compositions
- C10M2209/10—Macromolecular compoundss obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- C10M2209/103—Polyethers, i.e. containing di- or higher polyoxyalkylene groups
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- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2215/00—Organic non-macromolecular compounds containing nitrogen as ingredients in lubricant Compositions
- C10M2215/02—Amines, e.g. polyalkylene polyamines; Quaternary amines
- C10M2215/04—Amines, e.g. polyalkylene polyamines; Quaternary amines having amino groups bound to acyclic or cycloaliphatic carbon atoms
- C10M2215/042—Amines, e.g. polyalkylene polyamines; Quaternary amines having amino groups bound to acyclic or cycloaliphatic carbon atoms containing hydroxy groups; Alkoxylated derivatives thereof
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- C10M2217/00—Organic macromolecular compounds containing nitrogen as ingredients in lubricant compositions
- C10M2217/04—Macromolecular compounds from nitrogen-containing monomers obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- C10M2217/044—Polyamides
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- C10M2217/00—Organic macromolecular compounds containing nitrogen as ingredients in lubricant compositions
- C10M2217/04—Macromolecular compounds from nitrogen-containing monomers obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- C10M2217/045—Polyureas; Polyurethanes
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- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2217/00—Organic macromolecular compounds containing nitrogen as ingredients in lubricant compositions
- C10M2217/04—Macromolecular compounds from nitrogen-containing monomers obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- C10M2217/046—Polyamines, i.e. macromoleculars obtained by condensation of more than eleven amine monomers
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- C10M2227/00—Organic non-macromolecular compounds containing atoms of elements not provided for in groups C10M2203/00, C10M2207/00, C10M2211/00, C10M2215/00, C10M2219/00 or C10M2223/00 as ingredients in lubricant compositions
- C10M2227/02—Esters of silicic acids
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- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2227/00—Organic non-macromolecular compounds containing atoms of elements not provided for in groups C10M2203/00, C10M2207/00, C10M2211/00, C10M2215/00, C10M2219/00 or C10M2223/00 as ingredients in lubricant compositions
- C10M2227/04—Organic non-macromolecular compounds containing atoms of elements not provided for in groups C10M2203/00, C10M2207/00, C10M2211/00, C10M2215/00, C10M2219/00 or C10M2223/00 as ingredients in lubricant compositions having a silicon-to-carbon bond, e.g. organo-silanes
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- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2229/00—Organic macromolecular compounds containing atoms of elements not provided for in groups C10M2205/00, C10M2209/00, C10M2213/00, C10M2217/00, C10M2221/00 or C10M2225/00 as ingredients in lubricant compositions
- C10M2229/02—Unspecified siloxanes; Silicones
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- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
- C10N2020/00—Specified physical or chemical properties or characteristics, i.e. function, of component of lubricating compositions
- C10N2020/01—Physico-chemical properties
- C10N2020/04—Molecular weight; Molecular weight distribution
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- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
- C10N2030/00—Specified physical or chemical properties which is improved by the additive characterising the lubricating composition, e.g. multifunctional additives
- C10N2030/06—Oiliness; Film-strength; Anti-wear; Resistance to extreme pressure
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- C10N2030/00—Specified physical or chemical properties which is improved by the additive characterising the lubricating composition, e.g. multifunctional additives
- C10N2030/12—Inhibition of corrosion, e.g. anti-rust agents or anti-corrosives
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- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
- C10N2040/00—Specified use or application for which the lubricating composition is intended
- C10N2040/20—Metal working
- C10N2040/24—Metal working without essential removal of material, e.g. forming, gorging, drawing, pressing, stamping, rolling or extruding; Punching metal
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- C10N2040/00—Specified use or application for which the lubricating composition is intended
- C10N2040/20—Metal working
- C10N2040/243—Cold working
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- C10N2040/00—Specified use or application for which the lubricating composition is intended
- C10N2040/20—Metal working
- C10N2040/244—Metal working of specific metals
- C10N2040/245—Soft metals, e.g. aluminum
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- C10N2040/20—Metal working
- C10N2040/244—Metal working of specific metals
- C10N2040/246—Iron or steel
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- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
- C10N2040/00—Specified use or application for which the lubricating composition is intended
- C10N2040/20—Metal working
- C10N2040/244—Metal working of specific metals
- C10N2040/247—Stainless steel
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- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
- C10N2050/00—Form in which the lubricant is applied to the material being lubricated
- C10N2050/015—Dispersions of solid lubricants
- C10N2050/02—Dispersions of solid lubricants dissolved or suspended in a carrier which subsequently evaporates to leave a lubricant coating
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- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
- C10N2050/00—Form in which the lubricant is applied to the material being lubricated
- C10N2050/023—Multi-layer lubricant coatings
- C10N2050/025—Multi-layer lubricant coatings in the form of films or sheets
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- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
- C10N2080/00—Special pretreatment of the material to be lubricated, e.g. phosphatising or chromatising of a metal
Landscapes
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Organic Chemistry (AREA)
- Lubricants (AREA)
- Application Of Or Painting With Fluid Materials (AREA)
- Laminated Bodies (AREA)
Abstract
The invention relates to a method for preparing metal workpieces for cold forming by first applying a phosphate layer and then applying a lubricant layer which has a major content in organic polymer material. The phosphate layer is formed by an aqueous acidic phosphating solution having a major content in calcium, magnesium or/and manganese and phosphate. The lubricant layer is formed by contacting the phosphated surface with an aqueous lubricant composition which has a content in organic polymer material based on ionomer and optionally also non-ionomer, the organic polymer material used predominantly being monomers, oligomers, co-oligomers, polymers or/and copolymers based on ionomer, acrylic acid/methacrylic acid, epoxide, ethylene, polyamide, propylene, styrene, urethane, the ester(s) or/and salt(s) thereof. The invention also relates to the corresponding lubricant composition, to the lubricant layer produced thereof and to its use.
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE102008000187 | 2008-01-30 | ||
| PCT/EP2009/050851 WO2009095373A1 (en) | 2008-01-30 | 2009-01-26 | Method for coating metal surfaces with a phosphate layer and then with a polymer lubricant layer |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| MX2010008383A true MX2010008383A (en) | 2010-08-11 |
Family
ID=40547997
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| MX2010008383A MX2010008383A (en) | 2008-01-30 | 2009-01-26 | Method for coating metal surfaces with a phosphate layer and then with a polymer lubricant layer. |
Country Status (20)
| Country | Link |
|---|---|
| US (1) | US9422503B2 (en) |
| EP (1) | EP2238227B1 (en) |
| KR (1) | KR101633005B1 (en) |
| CN (1) | CN101983232B (en) |
| AR (1) | AR070687A1 (en) |
| AU (1) | AU2009209697B2 (en) |
| BR (1) | BRPI0906356A2 (en) |
| CA (1) | CA2713541C (en) |
| CL (1) | CL2009000227A1 (en) |
| DK (1) | DK2238227T3 (en) |
| ES (1) | ES2523702T3 (en) |
| HU (1) | HUE026555T2 (en) |
| MX (1) | MX2010008383A (en) |
| PL (1) | PL2238227T3 (en) |
| PT (1) | PT2238227E (en) |
| RU (1) | RU2501848C2 (en) |
| TW (1) | TWI457433B (en) |
| UA (1) | UA102838C2 (en) |
| WO (1) | WO2009095373A1 (en) |
| ZA (1) | ZA201005731B (en) |
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| TR201101163A2 (en) * | 2011-02-08 | 2011-10-21 | Bortek Bor Teknoloji̇leri̇ Ve Mekatroni̇k Sanayi̇ Ve Ti̇caret Li̇mi̇ted Şi̇rketi̇ | Method of improving the properties of phosphate coating. |
| KR101324260B1 (en) * | 2011-12-28 | 2013-11-01 | 주식회사 포스코 | Insulation coating material for non-oriented electrical steel sheet and method for manufacturing the same |
| WO2015055756A1 (en) * | 2013-10-17 | 2015-04-23 | Chemetall Gmbh | Method for preparing shaped metal bodies for cold working |
| KR101815412B1 (en) * | 2014-02-21 | 2018-01-04 | 니혼 파커라이징 가부시키가이샤 | Composition for direct-current cathodic electrolysis, lubrication-film-equipped metal material, and production method therefor |
| CN103952226B (en) * | 2014-03-28 | 2016-03-02 | 安徽联硕实业有限公司 | The environment-friendly high-efficiency wire drawing liquid that a kind of viscosity is controlled |
| JP6405216B2 (en) * | 2014-12-09 | 2018-10-17 | シェルルブリカンツジャパン株式会社 | Lubricating oil composition for sliding guide surfaces |
| CN104388914A (en) * | 2014-12-16 | 2015-03-04 | 常熟市东方特种金属材料厂 | Method for preparing phosphating liquid of carbon steel material |
| DE102017207591A1 (en) * | 2017-05-05 | 2018-11-08 | Federal-Mogul Nürnberg GmbH | Steel piston with a phosphate layer |
| US10876217B2 (en) | 2018-04-13 | 2020-12-29 | Molecular Surface Technologies, Llc | Electrochemical attachment of phosphonic acids to metallic substrates and osteoconductive medical devices containing same |
| EP3569680A1 (en) * | 2018-05-17 | 2019-11-20 | Biotronik Ag | Lubricant, particularly for use in a direct or indirect tubular impact extrusion process, particularly for manufacturing of magnesium alloy tubes |
| CN108949315B (en) * | 2018-06-25 | 2021-11-12 | 杰锡工业技术(上海)有限公司 | Environment-friendly energy-saving novel metal cold forming processing method |
| EP3599072A1 (en) * | 2018-07-05 | 2020-01-29 | Tipper Tie technopack GmbH | Method and device for applying varnish coatings to an item to be coated |
| US12303936B2 (en) | 2018-12-26 | 2025-05-20 | Quatssant, Llc | Method of photografting organic molecules to metallic substrates and devices having photografted organic molecules |
| WO2020225877A1 (en) * | 2019-05-08 | 2020-11-12 | 三菱電機株式会社 | Scroll component, manufacturing method thereof, and scroll compressor |
| US11540514B2 (en) | 2019-06-25 | 2023-01-03 | Molecular Surface Technologies, Llc | Electrochemical attachment of phosphonic acids to metallic substrates and antimicrobial medical devices containing same |
| CN111014326B (en) * | 2019-12-25 | 2021-06-15 | 南京派诺金属表面处理技术有限公司 | Wire drawing powder for steel cord and preparation method thereof |
| CA3168959A1 (en) | 2020-02-25 | 2021-09-02 | Yinfeng SHI | One-step pretreatment method of metallic substrates for metal cold forming |
| CA3168965A1 (en) | 2020-02-25 | 2021-09-02 | Yinfeng SHI | One-step pretreatment method of metallic substrates for metal cold forming |
| CN113930096A (en) * | 2020-06-29 | 2022-01-14 | Agc株式会社 | Composite materials, methods for their manufacture and uses |
| MX2023011416A (en) | 2021-04-01 | 2023-10-17 | Chemetall Gmbh | One-step pretreatment method of metallic substrates at non-neutral ph values for metal cold forming. |
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-
2008
- 2008-04-29 TW TW097115637A patent/TWI457433B/en not_active IP Right Cessation
-
2009
- 2009-01-26 AU AU2009209697A patent/AU2009209697B2/en not_active Ceased
- 2009-01-26 CA CA2713541A patent/CA2713541C/en not_active Expired - Fee Related
- 2009-01-26 US US12/863,805 patent/US9422503B2/en not_active Expired - Fee Related
- 2009-01-26 PT PT97052260T patent/PT2238227E/en unknown
- 2009-01-26 HU HUE09705226A patent/HUE026555T2/en unknown
- 2009-01-26 WO PCT/EP2009/050851 patent/WO2009095373A1/en not_active Ceased
- 2009-01-26 KR KR1020107019234A patent/KR101633005B1/en not_active Expired - Fee Related
- 2009-01-26 ES ES09705226.0T patent/ES2523702T3/en active Active
- 2009-01-26 MX MX2010008383A patent/MX2010008383A/en active IP Right Grant
- 2009-01-26 RU RU2010135780/04A patent/RU2501848C2/en not_active IP Right Cessation
- 2009-01-26 DK DK09705226.0T patent/DK2238227T3/en active
- 2009-01-26 BR BRPI0906356-0A patent/BRPI0906356A2/en active Search and Examination
- 2009-01-26 CN CN200980111860.XA patent/CN101983232B/en not_active Expired - Fee Related
- 2009-01-26 UA UAA201010442A patent/UA102838C2/en unknown
- 2009-01-26 EP EP09705226.0A patent/EP2238227B1/en not_active Not-in-force
- 2009-01-26 PL PL09705226T patent/PL2238227T3/en unknown
- 2009-01-27 AR ARP090100243A patent/AR070687A1/en not_active Application Discontinuation
- 2009-01-30 CL CL2009000227A patent/CL2009000227A1/en unknown
-
2010
- 2010-08-11 ZA ZA2010/05731A patent/ZA201005731B/en unknown
Also Published As
| Publication number | Publication date |
|---|---|
| PT2238227E (en) | 2014-10-13 |
| BRPI0906356A2 (en) | 2015-07-07 |
| EP2238227B1 (en) | 2014-06-18 |
| KR101633005B1 (en) | 2016-06-23 |
| ZA201005731B (en) | 2011-10-26 |
| PL2238227T3 (en) | 2015-02-27 |
| CN101983232B (en) | 2015-02-04 |
| CA2713541A1 (en) | 2009-08-06 |
| CN101983232A (en) | 2011-03-02 |
| CL2009000227A1 (en) | 2010-08-20 |
| AR070687A1 (en) | 2010-04-28 |
| US9422503B2 (en) | 2016-08-23 |
| AU2009209697A1 (en) | 2009-08-06 |
| DK2238227T3 (en) | 2014-09-29 |
| RU2501848C2 (en) | 2013-12-20 |
| RU2010135780A (en) | 2012-03-10 |
| AU2009209697B2 (en) | 2013-02-07 |
| WO2009095373A1 (en) | 2009-08-06 |
| CA2713541C (en) | 2017-01-10 |
| US20110100081A1 (en) | 2011-05-05 |
| ES2523702T3 (en) | 2014-11-28 |
| HUE026555T2 (en) | 2016-06-28 |
| TWI457433B (en) | 2014-10-21 |
| UA102838C2 (en) | 2013-08-27 |
| KR20100111309A (en) | 2010-10-14 |
| EP2238227A1 (en) | 2010-10-13 |
| TW200932896A (en) | 2009-08-01 |
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