MX2010001462A - Compuestos de pirazol para controlar plagas de invertebrados. - Google Patents
Compuestos de pirazol para controlar plagas de invertebrados.Info
- Publication number
- MX2010001462A MX2010001462A MX2010001462A MX2010001462A MX2010001462A MX 2010001462 A MX2010001462 A MX 2010001462A MX 2010001462 A MX2010001462 A MX 2010001462A MX 2010001462 A MX2010001462 A MX 2010001462A MX 2010001462 A MX2010001462 A MX 2010001462A
- Authority
- MX
- Mexico
- Prior art keywords
- invertebrate pests
- controlling invertebrate
- compounds
- formulae
- relates
- Prior art date
Links
- 241000607479 Yersinia pestis Species 0.000 title abstract 4
- 150000003217 pyrazoles Chemical class 0.000 title abstract 2
- 150000001875 compounds Chemical class 0.000 abstract 2
- 229910052760 oxygen Inorganic materials 0.000 abstract 2
- 241000238421 Arthropoda Species 0.000 abstract 1
- 150000001204 N-oxides Chemical class 0.000 abstract 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 abstract 1
- 229910052739 hydrogen Inorganic materials 0.000 abstract 1
- 239000001257 hydrogen Substances 0.000 abstract 1
- 125000004435 hydrogen atom Chemical class [H]* 0.000 abstract 1
- 239000001301 oxygen Substances 0.000 abstract 1
- 150000003839 salts Chemical class 0.000 abstract 1
Classifications
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- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
- A01N43/64—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with three nitrogen atoms as the only ring hetero atoms
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
- A01N43/48—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with two nitrogen atoms as the only ring hetero atoms
- A01N43/56—1,2-Diazoles; Hydrogenated 1,2-diazoles
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
- A01N43/64—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with three nitrogen atoms as the only ring hetero atoms
- A01N43/707—1,2,3- or 1,2,4-triazines; Hydrogenated 1,2,3- or 1,2,4-triazines
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
- A01N43/72—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with nitrogen atoms and oxygen or sulfur atoms as ring hetero atoms
- A01N43/74—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with nitrogen atoms and oxygen or sulfur atoms as ring hetero atoms five-membered rings with one nitrogen atom and either one oxygen atom or one sulfur atom in positions 1,3
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N47/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid
- A01N47/08—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid the carbon atom having one or more single bonds to nitrogen atoms
- A01N47/10—Carbamic acid derivatives, i.e. containing the group —O—CO—N<; Thio analogues thereof
- A01N47/18—Carbamic acid derivatives, i.e. containing the group —O—CO—N<; Thio analogues thereof containing a —O—CO—N< group, or a thio analogue thereof, directly attached to a heterocyclic or cycloaliphatic ring
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61P—SPECIFIC THERAPEUTIC ACTIVITY OF CHEMICAL COMPOUNDS OR MEDICINAL PREPARATIONS
- A61P31/00—Antiinfectives, i.e. antibiotics, antiseptics, chemotherapeutics
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61P—SPECIFIC THERAPEUTIC ACTIVITY OF CHEMICAL COMPOUNDS OR MEDICINAL PREPARATIONS
- A61P33/00—Antiparasitic agents
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61P—SPECIFIC THERAPEUTIC ACTIVITY OF CHEMICAL COMPOUNDS OR MEDICINAL PREPARATIONS
- A61P33/00—Antiparasitic agents
- A61P33/14—Ectoparasiticides, e.g. scabicides
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D401/00—Heterocyclic compounds containing two or more hetero rings, having nitrogen atoms as the only ring hetero atoms, at least one ring being a six-membered ring with only one nitrogen atom
- C07D401/02—Heterocyclic compounds containing two or more hetero rings, having nitrogen atoms as the only ring hetero atoms, at least one ring being a six-membered ring with only one nitrogen atom containing two hetero rings
- C07D401/12—Heterocyclic compounds containing two or more hetero rings, having nitrogen atoms as the only ring hetero atoms, at least one ring being a six-membered ring with only one nitrogen atom containing two hetero rings linked by a chain containing hetero atoms as chain links
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D401/00—Heterocyclic compounds containing two or more hetero rings, having nitrogen atoms as the only ring hetero atoms, at least one ring being a six-membered ring with only one nitrogen atom
- C07D401/14—Heterocyclic compounds containing two or more hetero rings, having nitrogen atoms as the only ring hetero atoms, at least one ring being a six-membered ring with only one nitrogen atom containing three or more hetero rings
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D417/00—Heterocyclic compounds containing two or more hetero rings, at least one ring having nitrogen and sulfur atoms as the only ring hetero atoms, not provided for by group C07D415/00
- C07D417/14—Heterocyclic compounds containing two or more hetero rings, at least one ring having nitrogen and sulfur atoms as the only ring hetero atoms, not provided for by group C07D415/00 containing three or more hetero rings
Landscapes
- Life Sciences & Earth Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- General Health & Medical Sciences (AREA)
- Plant Pathology (AREA)
- Wood Science & Technology (AREA)
- Environmental Sciences (AREA)
- Zoology (AREA)
- Dentistry (AREA)
- Engineering & Computer Science (AREA)
- Pest Control & Pesticides (AREA)
- Agronomy & Crop Science (AREA)
- Veterinary Medicine (AREA)
- General Chemical & Material Sciences (AREA)
- Animal Behavior & Ethology (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Pharmacology & Pharmacy (AREA)
- Medicinal Chemistry (AREA)
- Public Health (AREA)
- Nuclear Medicine, Radiotherapy & Molecular Imaging (AREA)
- Tropical Medicine & Parasitology (AREA)
- Oncology (AREA)
- Communicable Diseases (AREA)
- Agricultural Chemicals And Associated Chemicals (AREA)
- Plural Heterocyclic Compounds (AREA)
- Pharmaceuticals Containing Other Organic And Inorganic Compounds (AREA)
Abstract
Nuevos compuestos de pirazol de las fórmulas I y II, a sus sales y sus N-óxidos que se pueden usar para combatir o controlar plagas de invertebrados, en particular plagas de artrópodos. También, un método para controlar plagas de invertebrados usando estos compuestos. Además, semillas y a una composición agrícola y veterinaria que comprende dichos compuestos (ver fórmulas I, II) en donde A es un radical pirazol de las fórmulas A1, A2 o A3 (ver fórmulas A1, A2, A3) # denota el sitio de unión con el resto de las fórmulas I o II X1 es S, O o NR1a X2 es OR2a, NR2bR2C, S(O)mR2d; X3 es un solo par u oxígeno; R1, R2 y R3 son, inter alia, hidrógeno, y en donde R41, R42, R43, R51, R52, R53, R61, R62, R63, son como se definen en la reivindicación 1.
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US96810907P | 2007-08-27 | 2007-08-27 | |
| PCT/EP2008/061136 WO2009027393A2 (en) | 2007-08-27 | 2008-08-26 | Pyrazole compounds for controlling invertebrate pests |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| MX2010001462A true MX2010001462A (es) | 2010-03-01 |
Family
ID=40090302
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| MX2010001462A MX2010001462A (es) | 2007-08-27 | 2008-08-26 | Compuestos de pirazol para controlar plagas de invertebrados. |
Country Status (24)
| Country | Link |
|---|---|
| US (2) | US8642597B2 (es) |
| EP (1) | EP2197280B1 (es) |
| JP (1) | JP2010536926A (es) |
| KR (1) | KR20100065340A (es) |
| CN (1) | CN101835377B (es) |
| AR (1) | AR068063A1 (es) |
| AU (1) | AU2008292238B2 (es) |
| BR (1) | BRPI0816132B1 (es) |
| CA (1) | CA2695733A1 (es) |
| CL (1) | CL2008002530A1 (es) |
| CO (1) | CO6170408A2 (es) |
| CR (1) | CR11297A (es) |
| EC (1) | ECSP109992A (es) |
| ES (1) | ES2423932T3 (es) |
| MA (1) | MA31709B1 (es) |
| MX (1) | MX2010001462A (es) |
| PE (1) | PE20090609A1 (es) |
| PL (1) | PL2197280T3 (es) |
| RU (1) | RU2516290C2 (es) |
| TW (1) | TW200917962A (es) |
| UA (1) | UA103006C2 (es) |
| UY (1) | UY31308A1 (es) |
| WO (1) | WO2009027393A2 (es) |
| ZA (1) | ZA201002109B (es) |
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| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US8642597B2 (en) | 2007-08-27 | 2014-02-04 | Basf Se | Pyrazole compounds for controlling invertebrate pests |
| EP2725023A1 (de) * | 2008-06-13 | 2014-04-30 | Bayer CropScience AG | Neue heteroaromatische Amide als Schädlingsbekämpfungsmittel |
| US8853125B2 (en) | 2008-09-24 | 2014-10-07 | Basf Se | Pyrazole compounds for controlling invertebrate pests |
| EA020661B1 (ru) | 2008-09-24 | 2014-12-30 | Басф Се | Пиразольные соединения для борьбы с беспозвоночными вредителями |
| US8946231B2 (en) * | 2009-03-23 | 2015-02-03 | Merck Sharp & Dohme Corp. | P2X3, receptor antagonists for treatment of pain |
| EP2236505A1 (de) | 2009-04-03 | 2010-10-06 | Bayer CropScience AG | Acylierte Aminopyridine und - pyridazine als Insektizide |
| WO2011003796A1 (en) * | 2009-07-06 | 2011-01-13 | Basf Se | Pyridazine compounds for controlling invertebrate pests |
| WO2011003793A1 (en) * | 2009-07-06 | 2011-01-13 | Basf Se | Pyridazine compounds for controlling invertebrate pests |
| CN102469785A (zh) * | 2009-07-24 | 2012-05-23 | 巴斯夫欧洲公司 | 防治无脊椎动物害虫的吡啶衍生物 |
| WO2011117198A2 (en) | 2010-03-23 | 2011-09-29 | Basf Se | Pyridazine compounds for controlling invertebrate pests |
| WO2011117286A1 (en) | 2010-03-23 | 2011-09-29 | Basf Se | Pyridazine compounds for controlling invertebrate pests |
| US8966814B2 (en) | 2010-04-01 | 2015-03-03 | Ball Horticultural Company | Cast pellets for planting seeds |
| WO2011123602A1 (en) * | 2010-04-01 | 2011-10-06 | Ball Horticultural Company | Cast pellets for planting seeds |
| WO2012034960A1 (en) | 2010-09-13 | 2012-03-22 | Basf Se | Pyridine compounds for controlling invertebrate pests ii |
| WO2012034959A2 (en) * | 2010-09-13 | 2012-03-22 | Basf Se | Pyridine compounds for controlling invertebrate pests iii |
| US8609700B2 (en) | 2010-09-13 | 2013-12-17 | Basf Se | Pyridine compounds for controlling invertebrate pests I |
| BR112013013623A2 (pt) | 2010-12-10 | 2016-07-12 | Basf Se | métodos para controlar pragas invertebradas e para proteger material de propagagação de planta e/ou as plantas, material de propagação de planta, uso de um composto da fórmula i e composto de pirazol da fórmula i |
| US20130267476A1 (en) * | 2010-12-20 | 2013-10-10 | Basf Se | Pesticidal Active Mixtures Comprising Pyrazole Compounds |
| PH12013501934A1 (en) | 2011-03-18 | 2022-04-08 | Bayer Ip Gmbh | N-(3-carbamoylphenyl)-1h-pyrazole-5-carboxamide derivatives and the use thereof for controlling animal pests |
| DK2699563T6 (da) * | 2011-04-21 | 2024-08-19 | Basf Se | Hidtil ukendte pesticide parazolforbindelser |
| WO2013156318A1 (en) | 2012-04-16 | 2013-10-24 | Basf Se | Substituted pesticidal pyrazole compounds |
| PT3300602T (pt) | 2012-06-20 | 2020-06-17 | Basf Se | Misturas pesticidas que compreendem um composto de pirazol |
| EP2700634A1 (en) * | 2012-08-20 | 2014-02-26 | Basf Se | 5-difluoromethylpyrazole amides having herbicidal activity |
| EP2700635A1 (en) * | 2012-08-20 | 2014-02-26 | Basf Se | 5-Trifluoromethylpyrazole amides having herbicidal activity |
| WO2014063942A1 (en) | 2012-10-23 | 2014-05-01 | Basf Se | Substituted pesticidal pyrazole compounds |
| WO2014064129A1 (en) * | 2012-10-24 | 2014-05-01 | Basf Se | Pyrazole compounds for controlling invertebrate pests |
| CA2880326A1 (en) * | 2012-10-26 | 2014-05-01 | F. Hoffmann-La Roche Ag | 3,4-disubstituted 1 h-pyrazole and 4,5-disubstituted thiazole inhibitors of syk cap |
| CN102993097A (zh) * | 2012-11-09 | 2013-03-27 | 贵州大学 | 吡唑酰胺类化合物及其应用 |
| BR112015016394A2 (pt) | 2013-01-10 | 2017-07-11 | Gruenenthal Gmbh | carboxamidas ii baseadas em pirazolil como inibidoras do canal crac |
| US9206136B2 (en) | 2013-01-10 | 2015-12-08 | Grünenthal GmbH | Pyrazolyl-based carboxamides I |
| MX2015013740A (es) | 2013-03-25 | 2016-02-29 | Sanofi Sa | Derivados de pirazolnaftridinona, preparacion y uso terapautico de los mismos. |
| US9750253B2 (en) * | 2013-04-10 | 2017-09-05 | Syngenta Participations Ag | Pesticidally active substituted pyridyl carboxamides |
| CA2935662A1 (en) * | 2014-01-31 | 2015-08-06 | Basf Se | Pyrazoles for controlling invertebrate pests |
| US9751862B2 (en) | 2014-03-20 | 2017-09-05 | Syngenta Participations Ag | Pesticidally active substituted pyridyl carboxamides |
| WO2015162133A1 (en) * | 2014-04-22 | 2015-10-29 | Basf Se | C3-c4-cycloalkenyl-comprising pyrazoles for controlling invertebrate pests |
| WO2015169734A1 (en) * | 2014-05-05 | 2015-11-12 | Basf Se | Pyrazoles for controlling invertebrate pests |
| WO2015197187A1 (en) | 2014-06-24 | 2015-12-30 | Grünenthal GmbH | Pyrazolyl-based carboxamides v |
| US10414733B2 (en) | 2014-07-31 | 2019-09-17 | Basf Se | Process for preparing pyrazoles |
| SI3240785T1 (sl) | 2014-12-29 | 2021-11-30 | THE UNITED STATES OF AMERICA, as represented by THE SECRETARY, DEPARTMENT OF HEALTH AND HUMAN SERVICES, OFFICE OF TECHNOLOGY TRANSFER, NATIONAL INSTITUTES OF HEALTH | Malomolekulski zaviralci laktat dehidrogenaze in postopki za uporabo le-teh |
| WO2016180833A1 (en) | 2015-05-11 | 2016-11-17 | Basf Se | Process for preparing 4-amino-pyridazines |
| US10537558B2 (en) | 2015-06-01 | 2020-01-21 | Bantam Pharmaceutical, Llc | Substituted pyrazole and pyrrole compounds and methods for using them for inhibition of initiation of translation and treatment of diseases and disorders relating thereto |
| WO2016202935A1 (en) | 2015-06-19 | 2016-12-22 | Bayer Pharma Aktiengesellschaft | Glucose transport inhibitors |
| EP3411360B1 (en) | 2016-02-02 | 2020-03-11 | Basf Se | Catalytic hydrogenation process for preparing pyrazoles |
| NZ754827A (en) | 2016-11-30 | 2025-10-31 | Bantam Pharmaceutical Llc | Substituted pyrazole compounds and methods of using them for treatment of hyperproliferative diseases |
| MX2019006296A (es) | 2016-11-30 | 2019-11-12 | Bantam Pharmaceutical Llc | Métodos de uso de compuestos de pirazol y pirazol sustituido y para el tratamiento de enfermedades hiperproliferativas. |
| WO2019016069A1 (de) * | 2017-07-18 | 2019-01-24 | Bayer Cropscience Aktiengesellschaft | Substituierte 5-(het-)arylpyrazolamide sowie deren salze und ihre verwendung als herbizide wirkstoffe |
| WO2019137995A1 (en) | 2018-01-11 | 2019-07-18 | Basf Se | Novel pyridazine compounds for controlling invertebrate pests |
| JPWO2019168112A1 (ja) * | 2018-02-28 | 2021-02-25 | 北興化学工業株式会社 | イミド誘導体およびそれらを有効成分として含有する殺菌剤 |
| EP3643705A1 (en) * | 2018-10-24 | 2020-04-29 | Basf Se | Pesticidal compounds |
| US20240132475A1 (en) * | 2021-02-04 | 2024-04-25 | Aurigene Oncology Limited | Substituted pyrazolyl compounds as malt-1 inhibitors |
| TW202440540A (zh) * | 2022-12-20 | 2024-10-16 | 美商富曼西公司 | 用於防治和對抗無脊椎有害生物的唑類化合物 |
| CN119101038B (zh) * | 2023-10-16 | 2025-10-28 | 山东智荟检测科技有限公司 | 哒嗪类化合物及其制备方法与用途 |
| WO2025167527A1 (zh) * | 2024-02-06 | 2025-08-14 | 青岛清原化合物有限公司 | 一种吡唑酰胺类化合物及其应用 |
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- 2008-08-26 PL PL08787484T patent/PL2197280T3/pl unknown
- 2008-08-26 CN CN200880112508.3A patent/CN101835377B/zh active Active
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- 2008-08-26 CA CA2695733A patent/CA2695733A1/en not_active Abandoned
- 2008-08-26 AR ARP080103703A patent/AR068063A1/es not_active Application Discontinuation
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- 2008-08-26 RU RU2010111359/13A patent/RU2516290C2/ru not_active IP Right Cessation
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| CA2695733A1 (en) | 2009-03-05 |
| AR068063A1 (es) | 2009-11-04 |
| AU2008292238A1 (en) | 2009-03-05 |
| CN101835377A (zh) | 2010-09-15 |
| PE20090609A1 (es) | 2009-06-14 |
| UY31308A1 (es) | 2009-03-02 |
| UA103006C2 (ru) | 2013-09-10 |
| WO2009027393A3 (en) | 2009-09-24 |
| US20110059973A1 (en) | 2011-03-10 |
| EP2197280B1 (en) | 2013-06-19 |
| WO2009027393A2 (en) | 2009-03-05 |
| CR11297A (es) | 2010-05-19 |
| BRPI0816132A8 (pt) | 2019-01-15 |
| ZA201002109B (en) | 2013-06-26 |
| US20140068820A1 (en) | 2014-03-06 |
| CO6170408A2 (es) | 2010-06-18 |
| ECSP109992A (es) | 2010-03-31 |
| JP2010536926A (ja) | 2010-12-02 |
| ES2423932T3 (es) | 2013-09-25 |
| KR20100065340A (ko) | 2010-06-16 |
| CL2008002530A1 (es) | 2009-10-23 |
| TW200917962A (en) | 2009-05-01 |
| US8642597B2 (en) | 2014-02-04 |
| US9204647B2 (en) | 2015-12-08 |
| BRPI0816132A2 (pt) | 2014-10-07 |
| RU2010111359A (ru) | 2011-10-10 |
| CN101835377B (zh) | 2014-12-10 |
| PL2197280T3 (pl) | 2013-11-29 |
| MA31709B1 (fr) | 2010-09-01 |
| AU2008292238B2 (en) | 2014-06-12 |
| EP2197280A2 (en) | 2010-06-23 |
| BRPI0816132B1 (pt) | 2019-06-18 |
| RU2516290C2 (ru) | 2014-05-20 |
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