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MX2009002359A - Catalizador soportado en carbon para la desmetalizacion de crudos pesados y residuos. - Google Patents

Catalizador soportado en carbon para la desmetalizacion de crudos pesados y residuos.

Info

Publication number
MX2009002359A
MX2009002359A MX2009002359A MX2009002359A MX2009002359A MX 2009002359 A MX2009002359 A MX 2009002359A MX 2009002359 A MX2009002359 A MX 2009002359A MX 2009002359 A MX2009002359 A MX 2009002359A MX 2009002359 A MX2009002359 A MX 2009002359A
Authority
MX
Mexico
Prior art keywords
residue
crude oil
heavy crude
catalyst
demetallation
Prior art date
Application number
MX2009002359A
Other languages
English (en)
Inventor
Satoshi Terai
Jorge Ancheyta Juarez
Dres Samir Kumar Maity
M En C Fernando Alonso Martinez
Dres Hidetsugu Fukuyama
Masayuki Uchida
Original Assignee
Mexicano Inst Petrol
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Mexicano Inst Petrol filed Critical Mexicano Inst Petrol
Priority to MX2009002359A priority Critical patent/MX2009002359A/es
Priority to US12/716,776 priority patent/US8431018B2/en
Publication of MX2009002359A publication Critical patent/MX2009002359A/es

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G45/00—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds
    • C10G45/02—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds to eliminate hetero atoms without changing the skeleton of the hydrocarbon involved and without cracking into lower boiling hydrocarbons; Hydrofinishing
    • C10G45/04—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds to eliminate hetero atoms without changing the skeleton of the hydrocarbon involved and without cracking into lower boiling hydrocarbons; Hydrofinishing characterised by the catalyst used
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J21/00—Catalysts comprising the elements, oxides, or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium, or hafnium
    • B01J21/18—Carbon
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/84—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J23/85—Chromium, molybdenum or tungsten
    • B01J23/88—Molybdenum
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J27/00—Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds
    • B01J27/14—Phosphorus; Compounds thereof
    • B01J27/186—Phosphorus; Compounds thereof with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J27/188—Phosphorus; Compounds thereof with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium with chromium, molybdenum, tungsten or polonium
    • B01J27/19—Molybdenum
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J35/63—Pore volume
    • B01J35/635—0.5-1.0 ml/g
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J35/63—Pore volume
    • B01J35/638—Pore volume more than 1.0 ml/g
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J35/66—Pore distribution
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/0009—Use of binding agents; Moulding; Pressing; Powdering; Granulating; Addition of materials ameliorating the mechanical properties of the product catalyst
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/08—Heat treatment
    • B01J37/10—Heat treatment in the presence of water, e.g. steam
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G45/00—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds
    • C10G45/02—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds to eliminate hetero atoms without changing the skeleton of the hydrocarbon involved and without cracking into lower boiling hydrocarbons; Hydrofinishing
    • C10G45/04—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds to eliminate hetero atoms without changing the skeleton of the hydrocarbon involved and without cracking into lower boiling hydrocarbons; Hydrofinishing characterised by the catalyst used
    • C10G45/06—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds to eliminate hetero atoms without changing the skeleton of the hydrocarbon involved and without cracking into lower boiling hydrocarbons; Hydrofinishing characterised by the catalyst used containing nickel or cobalt metal, or compounds thereof
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/20—Sulfiding

Landscapes

  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Materials Engineering (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • General Chemical & Material Sciences (AREA)
  • Physics & Mathematics (AREA)
  • Thermal Sciences (AREA)
  • Catalysts (AREA)

Abstract

En la presente invención se empleó un soporte de carbón que contiene alta área superficial específica alta, volumen de poro grande y (i) un metal de transición del Grupo VIB, (ii) un metal no noble del Grupo VIII, (iii) fósforo, para la hidrodesmetalización e hidrodesulfuración de crudos pesados y residuos. Asimismo, el catalizador es preparado mediante el uso de un agente quelante y posee una actividad hacia la hidrodesulfuración más alta, asumiendo que están presentes metales activos más dispersados sobre este catalizador. Los estudios de la actividad en una corrida de larga duración mostraron que el catalizador que posee solamente molibdeno soportado en carbón activado posee buena estabilidad conforme avanza el tiempo de corrida y una capacidad de retención de metales alta.
MX2009002359A 2009-03-03 2009-03-03 Catalizador soportado en carbon para la desmetalizacion de crudos pesados y residuos. MX2009002359A (es)

Priority Applications (2)

Application Number Priority Date Filing Date Title
MX2009002359A MX2009002359A (es) 2009-03-03 2009-03-03 Catalizador soportado en carbon para la desmetalizacion de crudos pesados y residuos.
US12/716,776 US8431018B2 (en) 2009-03-03 2010-03-03 Carbon supported catalyst for demetallation of heavy crude oil and residue

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
MX2009002359A MX2009002359A (es) 2009-03-03 2009-03-03 Catalizador soportado en carbon para la desmetalizacion de crudos pesados y residuos.

Publications (1)

Publication Number Publication Date
MX2009002359A true MX2009002359A (es) 2010-10-01

Family

ID=42677275

Family Applications (1)

Application Number Title Priority Date Filing Date
MX2009002359A MX2009002359A (es) 2009-03-03 2009-03-03 Catalizador soportado en carbon para la desmetalizacion de crudos pesados y residuos.

Country Status (2)

Country Link
US (1) US8431018B2 (es)
MX (1) MX2009002359A (es)

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CN102091651A (zh) * 2010-12-10 2011-06-15 中国石油天然气股份有限公司 一种选择性加氢脱硫催化剂的制备方法
CN102091652B (zh) * 2010-12-10 2013-04-24 中国石油天然气股份有限公司 一种选择性加氢脱硫催化剂和应用
CN103717305B (zh) * 2011-06-22 2016-02-17 国际壳牌研究有限公司 加氢处理催化剂以及制备和使用该催化剂的方法
CN102861589A (zh) * 2011-07-07 2013-01-09 中国石油化工股份有限公司 一种高活性加氢脱金属催化剂及其制备方法
CN102861590A (zh) * 2011-07-07 2013-01-09 中国石油化工股份有限公司 一种加氢脱金属催化剂及其制备方法
RU2495717C1 (ru) * 2012-09-24 2013-10-20 Федеральное государственное бюджетное учреждение науки Институт проблем переработки углеводородов Сибирского отделения Российской академии наук (ИППУ СО РАН) Способ получения нанесенного катализатора гидропереработки тяжелых нефтяных фракций
WO2014176197A1 (en) * 2013-04-24 2014-10-30 Shell Oil Company Activation of a hydroprocessing catalyst with steam
CN105273746B (zh) * 2014-07-18 2017-05-24 中国石油化工股份有限公司 一种加氢脱氧方法
CN106268848A (zh) * 2016-07-22 2017-01-04 西安向阳航天材料股份有限公司 一种焦炉煤气加氢脱硫催化剂及其制备方法
CN107961795B (zh) * 2016-10-20 2020-12-04 中国石油化工股份有限公司 一种加氢脱硫催化剂及其制备方法和硫化态加氢脱硫催化剂的制备方法
CN107961773B (zh) * 2016-10-20 2020-12-04 中国石油化工股份有限公司 一种加氢脱硫催化剂及其制备方法和硫化态加氢脱硫催化剂的制备方法
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CN111195525A (zh) * 2018-11-19 2020-05-26 中国石油天然气股份有限公司 一种渣油加氢脱硫催化剂及其制备方法
CN111375415B (zh) * 2018-12-29 2022-10-11 中国石油化工股份有限公司 一种低碳烷烃脱氢制烯烃催化剂及其制备方法
CN111375436B (zh) * 2018-12-29 2022-06-07 中国石油化工股份有限公司 重油加氢处理催化剂及其制法
CN111375422B (zh) * 2018-12-29 2022-10-11 中国石油化工股份有限公司 一种用于催化氧化甲醛的催化剂及其制备方法
CN111375430B (zh) * 2018-12-29 2022-04-08 中国石油化工股份有限公司 一种硫化型加氢催化剂及其制备方法
CN111375406B (zh) * 2018-12-29 2022-06-07 中国石油化工股份有限公司 一种臭氧催化氧化催化剂及其制备方法
US11325107B2 (en) 2019-02-13 2022-05-10 King Fahd University Of Petroleum And Minerals Method for producing activated carbon supported Ni/Mo catalyst for hydrodesulfurization
CN116060033B (zh) * 2021-10-29 2024-05-10 中国石油化工股份有限公司 一种石蜡加氢精制催化剂及其制备方法和应用
CN114029046B (zh) * 2021-12-20 2022-08-19 黑龙江大学 一种以生物质制备的片层碳为载体的复合加氢脱硫催化剂的制备方法

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Also Published As

Publication number Publication date
US8431018B2 (en) 2013-04-30
US20100224535A1 (en) 2010-09-09

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