MX2007016309A - Organic catalyst with enhanced enzyme compatibility. - Google Patents

Abstract

This invention relates to cleaning compositions comprising organic catalysts having enhanced enzyme compatibility and processes for making and using such cleaning compositions. The catalysts are zwitterionic sulfate derivatives of 3,4-dihydroisoquinoline.

Description

CATALIZ \ ADOR QRGANiCO WITH COMPATIB. ILID. A.D EMZiMATnC -A ME FIELD OF THE FLNVENCBON This invention relates to cleaning compositions comprising organic catalysts and methods for making and using said cleaning products.

ANTECEDENTS OF THE BNVENCDOM Oxygen-based bleaching agents, for example, hydrogen peroxide, are generally used to facilitate the removal of stains and dirt from clothing and various surfaces. Unfortunately, these agents depend a lot on the temperature index. As a result, when these agents are used in colder solutions, the cleaning action of the solutions decreases markedly. In an effort to solve the aforementioned performance problem, the industry has developed a class of materials known as "bleach activators". However, since these materials rapidly lose their effectiveness when the temperature of the solution is 40 ° C, other organic catalysts have been developed, such as the inferna salt 3,4-dihydro-2- [2- (sulfoxy) decyl] isoquinolinio . In general, since the catalysts of the current art are effective under lower water temperature conditions, they can inactivate certain enzymes. Since most cleaning and laundry compositions are formulated with enzymes, it can be problematic to formulate cleaning products with such catalysts. Accordingly, there is a need to achieve a low-priced cleaning composition comprising an organic catalyst that can provide the combined benefits of formulation flexibility, bleaching performance with low water temperature and enzyme compatibility.

BRIEF DESCRIPTION OF THE DNVEN The present invention relates to cleaning compositions comprising organic cayalizers which, in turn, have enzymatic compatibility and methods to make and use them.

DETAILED DESCRIPTION OF THE DNVENCCQN Definitions As used herein, the term "cleaning composition" includes, unless otherwise indicated, granular washing agents or in the form of a multipurpose or "high performance" powder, especially laundry detergents; cleaning agents liquid, in gel, or in the form of paste mullipropósiío, especially so-called high performance liquids; liquid detergents for fine fabrics; agents for the manual washing of dishes, or agents of low performance for the washing of crockery, especially those of great volume of foam; agents for washing in the dishwasher, including various types of iables, granules, aids and rinsing liquids, for domestic and institutional use; liquid disinfectant and cleaning agents, including those of the antibacterial agent for hand washing, laundry bars, mouth rinses, aftermarket cleansers, shampoos for carpets or trolleys, cleaners for bathrooms; shampoos and hair rinses; gels for shower and bath foams and melal cleaners; as well as cleaning aids such as bleach detergent builders and "bar wipers" or pretreatment type. As used herein, the phrase "is independently selected from the group comprising ..." means that the entities or elements of the said Markush group that are selected may be the same, or different, or any mixture of elements. . The test methods set out in the Test Methods Section of the present application should be used to determine the respective values of the parameters of the applicants' inventions. Unless otherwise specified, all levels of the component or composition are expressed in reference to the active level of that component or composition, and are exclusive of impurities, for example, residual solvents or by-products, which may be present. in the sources distributed in the market. All percentages and proportions are calculated by weight, unless otherwise indicated. All percentages and proportions are calculated based on the composition, unless otherwise specified. It shall be understood that the maximum numerical limit given in this specification shall include any lower numerical limit, as if the lower numerical limits had been explicitly annotated herein. Any minimum numerical limit given in this specification shall include the largest numerical limit, as if the larger numerical limits had been explicitly annotated herein. Any numerical range given in this specification shall include any smaller numerical range that falls within the larger numerical range, as if all minor numerical intervals had been explicitly annotated herein. All documents cited herein are considered incorporated in their relevant part as reference. The mention of any document should not be construed as an admission that it corresponds to a prior industry with respect to the present invention.

Cleaning compositions comprising an organic calyser The request has shown that the careful choice of the R1 content of the organic catalyst of the present invention results in improved enzymatic compatability. Without being resisted by the theory, the applicants consider that this is due to the favorable partition of the caíalizador in aqueous environments, as a result of the aforementioned successful choice of the entity R1. In one aspect of the applicants' invention, the cleaning compositions are composed of organic caulks that have a value of 70 or more, or even 80 or more. In one aspect of the applicants' invention, the cleaning compositions are compounds of organic caulisters that follow Formula 1 or Formula 2 below or mixtures thereof.

Formula 1 Formula 2 wherein R is a branched alkyl group containing 9 to 24 carbons, or a linear alkyl group containing 11 to 24 carbons; a branched alkyl group containing 9 to 18 carbons, or a linear alkyl group containing 11 to 18 carbons; is selected from the group comprising 2-propylheptyl, 2-butyloctyl, 2-pentylnonyl, 2-hexyldecyl, n-dodecyl, n-tetradecyl, n-hexadecyl, n-octadecyl, isononyl, isodecyl, isotridecyl and isopentadecyl; it is selected from the group comprising 2-builoyl, 2-penynylnonyl, 2-hexyldecyl, isolideid, and sopenladecyl. The remainder of any of the aspects of the aforementioned cleaning compositions is comprised of one or more auxiliary materials.

Processes for making suitable organic caulisers Suitable organic caulisers can be produced by using a variety of reaction vessels and procedures that include batch, semilole, and continuous processes. In one aspect of the invention of the quislakiids, the method of making said calycator comprises passing the reaction of the sulfur dioxide complex 3,4-dihydroisoquinoline with an epoxide to form said organic calychator. In another aspect of the invention of the applicants, the process of making said catalyst comprises the reaction steps of 3,4-dihydroisoquinoline with a material selected from the group comprising sulfur dioxide, a material providing sulfur dioxide and mixtures of these to form a complex of sulfur dioxide 3,4-dihydroisoquinoline and to cause the reaction of the sulfur dioxide complex 3,4-dihydroisoquinoline with an epoxide to form said organic catalyst. In another aspect of the applicants' invention, the method of making said catalyst comprises the passage of the reaction of 3,4-dihydroisoquinoline with a sulfur trioxide epoxide complex to form said organic catalyst. In another aspect of the applicants' invention, the method of making said catalyst comprises the reaction steps of an epoxide with a material selected from the group comprising sulfur trioxide, a material that provides sulfur trioxide and mixtures thereof to form a complex of epoxide sulfur trioxide and of causing the reaction of such epoxide sulfur trioxide complex with 3,4-dihydroisoquinoline to form said organic calychator. The version of the mentioned calycator which contains the o-aziridinium ring can be produced by contacting the said catalyst version containing an iminium ring with an oxygen transfer agent such as a peroxycarboxylic acid or a peroxymonosulfuric acid, for example, Oxone ®. Such species can be prepared on site and used without purification.

Although the skilled technician who processes the teachings of the present specification will be able to easily determine the desired reaction conditions and the reaction concentrations, the general reaction parameters of the aforementioned aspects of the invention of the applicants include reaction molarities of approximately 0 ° C to about 150 ° C, or from about 0 ° C to about 125 ° C; Reaction pressures of about 0.01 MPa (0.1 Aim) to about 10.1 MPa (100 Aim), from about 0.03 MPa (0.3 atm) to about 1.01 MPa (10 atm) or approximatively 0.1 MPa (1 aim) to about 1.01 MPa (10 aim); reaction times from 0.1 hour to about 96 hours, from about 1 hour to about 72 hours, or from about 1 hour to about 24 hours. The reaction can also be carried out in an inert atmosphere or in any other anhydrous condition including, when a solvent is employed, the use of an anhydrous solvent. The materials that are used in the practice of the applicants process include 3,4-dihydroisoquinoline; epoxies and mixtures thereof; sulfur dioxide, sulfur dioxide fuens and mixtures of these; and solvents. When 3,4-dihydroisoquinoline is used, the initial reaction mixture generally comprises from about 0.5% by weight to about 70% by weight, from about 5% by weight to about 70% by weight or about 10% by weight to about 50% by weight of said material. The 3,4-dihydroisoquinoline can be made in accordance with the protocol described in the Example. When using epoxides, the initial reaction mixture generally comprises from about 0.5 wt% to about 70 wt%, from about 5 wt% to about 70 wt% or from about 10 wt% to about 50% by weight of said material. Useful epoxides include, but are not limited to, epoxide such as 2-propylheptyl glycidyl ether; 2-butyloctyl glycidyl ether; 2-pentynyl glycidyl ether; 2-hexyldecyl glycidyl ether; n-dodecyl glycidyl ether; n-telradecyl glycidyl ether; n-hexadecyl glycidyl ether; n-ocydecyl glycidyl ether; isononyl glycidyl ether; isodecyl glycidyl ether; iso-iridecyl glycidyl ether, and mixtures thereof. Such materials can contain oligomeric forms of glycidyl ether that can be removed optionally before being used as a reactant. The 2-propylheptyl glycidyl ether can be prepared as described in Example 2 of the present specification. All other glycidyl ethers mentioned above can be prepared according to the following generic protocol of Example 2 by replacing the appropriate alcohol in place of 2-propylheptanol. Suitable alcohols include 2-propylheplanol, 2-butyloctanol, 2-penlylononanol, 2-hexyldecanol, n-dodecanol, n-tetradecanol, n-hexadecanol, n-octadecanol, iso-nonanol, iso-decanol and iso-tridecanol. When sulfur trioxide, sulfur dioxide sources and mixtures thereof are used, the initial reaction mixture generally comprises from about 0.5 wt% to about 70 wt%, about 5 wt% about 70% by weight, or about 10% by weight to about 50% by weight, of such material. Suitable materials include sulfur dioxide, and sulfur trioxide complexes such as sulfur trioxide trimethylamine, sulfur trioxide dioxane, sulfur dioxide pyridine, sulfur trioxide N, N-dimethylformamide, sulfur dioxide sulfolane, sulfur dioxide and hydrofuran , sulfur dioxide diethyl ether, sulfur trioxide 3,4-dihydroisoquinoline, and mixtures thereof. The rest of any reaction mixture, in general, is solvent. When a solvent is used, the initial reaction mixture generally comprises 99% by weight of solvent, from about 10% by weight to about 90% by weight of solvent, or from about 20% by weight to about 80% by weight. % by weight solvenie. Suitable Solvenids include the apolar, polar, and apolar solvenides such as acceloniila, dioxane, tert-butyl methylether, ureahydrofuran, N, N-dimethylformamide, sulfolane, chlorobenzene, toluene, 1,2-dichloroeben, methylene chloride, chloroform, diethyl ether. , hexanes, pennanos, benzene,? ilenes, and mixtures of these. Suitable Solvenis can be obtained from Aldrich, P.O. Bo? 2060, Milwaukee, Wl 53201, USA Cleaning compositions and detergency detergents of cleaning compositions comprising the organic calyzers of the applicants The cleaning composition of the present invention can be used occasionally, for example, in laundry applications, hard surface cleaning, auimomaic ware washing applications, as well as as in cosmetic applications, such as teeth, hair, and skin. However, due to the unique advantages of improved effecivity in lower imaging solutions and superior enzymatic compability, the organic calyzers of the present invention are particularly suitable for laundry applications such as bleaching of fabrics by the use of detergents that conine bleaches or delergent enhancers of laundry bleach. In addition, the organic cayalizers of the present invention can be used in liquid and granular compositions. The organic catalysts of the present invention can also be used in a cleaning detergent cleaning product. A cleaning builder product including the organic caulisers of the present invention is ideal for being included in a washing process when it is desired to obtain additional bleaching efficiency. Such instances may include, but are not limited to, the application for low temperature cleaning solution. In its simplest form, the builder product may be the organic catalyst of the applicants. Preferably, the builder can be packaged dosed for addition in a cleaning process in which a source of peroxide compound is used and it is desired to obtain a higher bleaching efficiency. This single dosage may consist of a pill, lablet, soft gelatin capsule or other dosage unit such as powders or liquids previously measured. To increase the volume of this composition, a filler or carrier material can be included. Suitable fillers or carriers include, but are not limited to, various salts of sulfate, carbonate and silicate and also talc, clay and the like. In liquid compositions, the fillers or carriers can be water or low molecular weight primary and secondary alcohols, including polyols and diols. Examples of such alcohols include, but are not limited to, methanol, ethanol, propanol and isopropanol. The compositions may contain from approximately 5% to approximately 90% of these materials. Acid charges can be used to reduce the pH. Alternatively, the cleansing detergency enhancer may include a source of activated peroxide compound defined below or the accessory ingredients that are fully defined below. Dei-ergency enhancers and applicants' cleaning compositions require a caIIitically effective standardization of organic applicants. The necessary concentration of this caíalizador can be obtained by adding one or more species of the organic cauliflower of the request. As a practical matter, and not in a limiting manner, the cleaning compositions and methods herein can be adapted to provide in the order of at least 0.001 ppm, from approximately 0.001 ppm to approximately 500 ppm, of appro priately 0.005 ppm to approximately 150 ppm, or even approximately 0.05 ppm to approximately 50 ppm of the organic catalyst from the request in the washing solution. In order to obtain such levels in the washing liquid, typical compositions herein may comprise from approximately 0.0002% to approximately 5% or even from approximately 0.001% to approximately 1.5% organic catalyst by weight of the cleaning compositions. When the organic catalyst of the applicants is used in a granular composition, preferably, it is included as an encapsulated particle to protect the catalyst against moisture and other components of the granular composition during storage. In addition, the encapsulation is also useful to control the availability of the organic caulizer from those requested during the cleaning procedure and can improve the cleaning performance of the catalyst. In this regard, to encapsulate the organic catalyst of the applicants, any encapsulated metal known in the industry can be used. The encapsulating material typically encapsulates a part, but preferably all the organic catalyst of the applicants. In general, the encapsulated material is soluble or dispersible in water. The encapsulating material can have a glass transition temperature (Tg) of 0 ° C or more. Preferably, the encapsulating material is selected from the group comprising carbohydrates, natural or synthetic gums, chitin and chitosan, cellulose and cellulose derivatives, silicates, phosphates, borates, polyvinyl alcohol, polyethylene glycol, paraffin waxes and combinations thereof. Preferably, the encapsulant material is a carbohydrate, generally selected from the group comprising monosaccharides, oligosaccharides, polysaccharides, and combinations thereof. Most preferably, the encapsulating material is a starch. Preferred starches are described in EP 0 922 499 and U.S. Pat. num. 4,977,252, 5,354,559 and 5,935,826. The encapsulating material may be a microsphere made of plastic, such as lemoplastics, acrylonitrile, melacrylonitrile, polyacrylonitrile, polymethylacrylonitrile, and mixtures thereof.; Commercially available microspheres that can be used are those provided by Expancel of Stockviksverken, Sweden, under the trademark Expancel®, and those provided by PQ Corp. of Valley Forge, Pennsylvania USA. under the trade name of PM 6545, PM 6550, PM 7220, PM 7228, Extendospheres®, Luxsil®, Q-cel® and Sphericel®. The cleaning compositions described herein are preferably formulated so that, during use in aqueous cleaning operations, the wash water will have a pH of between approximately 6.5 and approximately 11, or even approve. imadamente 7.5 and 10.5. Liquid product formulations for dishwashing generally have a pH of approximately 6.8 and approximately 9.0. Laundry products usually have a pH of about 9 to approximately 11. The techniques for conirol pH at recommended levels of use include the use of buffers, alkalis, acids, etc. and they are known to those with experience in the industry.

Attached Materials Although not essential for the purposes of the present, the lisia not limited to additional components included below is suitable for use in the insular compositions herein and may conveniently be incorporated into certain preferred embodiments of the invention, for example, to facilitate or improve the cleaning performance, to bring the substrate to be cleaned or to modify the aesthetics of the cleaning composition, as in the case of perfumes, dyes, dyes or the like. The precise nature of these additional components and the levels of their incorporation will depend on the physical form of the composition and the type of cleaning operation in which they will be used. Suitable adjunct materials include, but are not limited to, surfactants, builders, chelating agents, dye transfer inhibitors, dispersants, enzymes and enzyme scavengers, calynelyl materials, bleaching agents, hydrogen peroxide, sources hydrogen peroxide, preformed peracids, polymeric dispersing agents, clay slurry removal agents, clay fillers, foam suppressors, perfumes, perfumes, cleaning agents, softeners, carriers, hydrotropes, processing aids , solvents or pigments. In addition to the following disclosure, suitable examples of such additional components and levels of use are found in U.S. Pat. num. 5,576,282, 6,306,812 B1 and 6,326,348 B1 which are incorporated by reference. As mentioned above, the additional ingredients are not essential for the applicants' compositions. Thus, certain embodiments of the applicant's compositions do not contain one or more of the following adjunct materials: surfactants, builders, chelating agents, ion transfer inhibitors, dispersants, enzymes, and enzyme stabilizers, materials catalysts, bleaching agents, hydrogen peroxide, hydrogen peroxide sources, preformed peracids, polymeric dispersing agents, anti-redeposition agents / removal of clay soiling, polishes, foam suppressors, dyes, perfumes, structure elasticizing agents, fabric softeners fabrics, carriers, hydrotropes, processing aids, solvents or pigments. However, when the composition contains one or more additional components, that or those components must be present as specified below: Bleaching agents: the cleaning compositions of the present invention may comprise one or more bleaching agents. - Suitable bleaching agents disíiníos to whitening caíalizadores include foioblanqueadores, acclivadores of bleach, peroxide of hydrogen, sources of peroxide of hydrogen, perácidos preformed and mixtures of these. Generally, when a bleaching agent is used, the compositions of the present invention may comprise from 0.1% to approximately 50% or even from approximately 0.1% to approximately 25% of the bleaching agent by weight. of the cleaning composition. Examples of suitable bleaching agents include: (1) photobleaching agents such as, for example, zinc sulphonate phthalocyanine; (2) preformed peracids: Suitable prefortified peracids include, but are not limited to, compounds selected from the group comprising salts and percarboxylic acids, percarbonic salts and acids, perimidic salts and acids, salts and butyrosulfuric acids, for example. , O? Zone ®, and mixtures of these. Suitable percarboxylic acids include hydrophobic and hydrophilic peracids having the formula R- (C = 0) 0-0-M, wherein R is an alkyl group, optionally branched, which, when the peracid is hydrophobic, is 6 to 14 carbon atoms, or 8 to 12 carbon atoms and, when the peracid is hydrophilic, less than 6 carbon atoms or even less than 4 carbon atoms; and M is a counter ion, for example, sodium, potassium or hydrogen; (3) sources of hydrogen peroxide, for example, inorganic salts of perhydrate, including alkali metal salts such as sodium salts of perbora (generally mono- or hydrohydric), percarbonate, persulfalo, perfosfalo, salts of persilicalo and mixtures of those In one aspect of the invention, the inorganic perhydrate salts are selected from the group comprising perboradic, percarbonated sodium salts and mixtures of these. When inorganic perhydrate salts are used, their concentration, generally, ranges from 0.05 to 40% by weight, or from 1 to 30% by weight of the ionic composition and, in general, they are incorporated in those compositions as a solid. crisíalino that can be coated. Suitable coatings include inorganic salts, such as alkali metal silicate, carbonate or borate salts or mixtures thereof, or organic materials, such as water soluble or dispersible polymers, waxes, oils or fatty soaps; and (4) bleach activators having R- (C = 0) -L, wherein R is an alkyl group, optionally branched, having, when the bleach activator is hydrophobic, from 6 to 14 carbon atoms, or from 8 to 12 carbon atoms and, when the bleach activator is hydrophilic, less than 6 carbon atoms or even less than 4 carbon atoms; and L is the outgoing group. Examples of suitable leaving groups are benzoic acid and derivatives thereof, especially benzene sulfonate. Suitable bleach activators include dodecanoil or? Ibenone sulfonation, decanoyl oxybenzene sulphonation, decanoyl oxybenzoic acid or salts thereof, 3,5,5-arymethylheneoyl? Ibenosulfonazole, teraceacetylelylenediamine (TAED) and nonanoyl? Ibenzenesulphone (NOBS). Suitable bleach acclimatizers are also described in WO 98/17767. Whilst any bleach activator may be used, in one aspect of the invention the cleaning composition may comprise NOBS, TAED or mixtures thereof. When present, the peracid or bleach activator is generally present in the composition in amounts of approximately 0.1% by weight to approximately 60% by weight, from approximately 0.5% by weight to approximately 40% by weight. by weight or even approximately 0.6% by weight to approximately 10% by weight depending on the composition. One or more hydrophobic peracids or precursors thereof can be used in combination with one or more hydrophilic peracids or precursors thereof. The amounts of hydrogen peroxide and peracid sources or bleach activator can be selected such that the molar ratio of the available oxygen (from the peroxide source) to the peracid is from 1: 1 to 35: 1, or even from 2: 1 to 10: 1. Lensioactive Agents: The cleaning compositions according to the present invention may contain a surfactant or a surfactant agent system, wherein said surfactant agent is selected from nonionic surfactants, anionic anionic agents, cationic surfactants, ampholytic surfactants, zwitterionic surfactants, semipolar nonionic non-ionic agents and mixtures of these. In general, when a surfactant is used, its concentration varies from approximately 0.1% to approximately 60%, from approximately 1% to approximately 50% or even approximately 5% to approximately 40% in weight of the composition. Detergency builders: cleaning compositions of the present invention may comprise one or more detergency builders or detergent builders. Generally, when using a detergent builder, the composition will comprise at least about 1%, from about 5% to about 60%, or even from about 10% to about 40% of the builder, by weight of the composition. Detergency builders include, but are not limited to, alkali metal, ammonium and alkanolammonium salts of polyphosphates, alkali metal silicates, alkaline earth metal and alkali metal carbonates, aluminosilicate detergency builders and polycarboxylate compounds, ether hydroxypolycarboxylates, maleic anhydride copolymers with ethylene or vinyl methyl ether, 1,3,5-dihydroxybenzene-2,4,6-bisulphonic acid, and carboxymethyloxysuccinic acid, the various alkali metal, ammonium and ammonium salts of polyarylene acids, such as eilendiaminoteiracetic acid and nitrilotriacetic acid, and also polycarboxylates, such as mellitic acid, succinic acid, citric acid, oxy disuccinic acid, polymaleic acid, benzene 1, 3,5-tricarboxylic acid, carboxymethyl isuccinic acid, and soluble salts thereof. Chelating agents: the cleaning compositions of the presence can confer a chelating agent. Suitable chelating agents include copper, iron or manganese chelating agents and mixtures thereof. When a chelating agent is used, the composition may comprise from about 0.005% to about 15% or even from about 3.0% to about 10% of the chelating agent by weight of the composition. Inferential transfer inhibiting agents: the cleaning compositions of the present invention may also include one or more dye transfer inhibiting agents. Suitable polymeric dye transfer inhibiting agents include, but are not limited to, polymers of polyvinylpyrrolidone, polymers of N-oxide polyamine, copolymers of N-vinylpyrrolidone and N-vinylimidazole, polyvinyl-azolidones and polyvinylimidazoles or mixtures thereof. When a dye transfer inhibiting agent is used, its concentration may vary from approximately 0.0001% to approximately 10%, from approximately 0.01% to approximately 5%, or even from approximately 0.1% to approx. 3% by weight of the composition. Polishes: the cleaning compositions of the present invention may also contain additional components that can color the articles being cleaned, such as fluorescent brighteners. Suitable concentrations of the fluorescent brighteners can be from about 0.01, about 0.05, about 0.1 or even about 0.2% by weight to 0.5 or even 0.75% by weight. Dispersants: The compositions of the present invention may also contain dispersants. Suitable water-soluble organic materials include the homo or copolymeric acids or their salts, in which the polycarboxylic acid comprises at least two carboxyl radicals separated therefrom by no more than two carbon atoms. Enzymes: cleaning compositions may comprise one or more enzymes that provide cleansing performance or fabric care benefits. Examples of suitable enzymes include, but are not limited to, hemicellulases, peroxidases, proleases, cellulases, xylanases, lipases, phospholpasses, esleases, culinases, pecinases, mannanases, petioles lyases, keratinases, reductases, oxidases, phenoloxidases, lipo? ligninases, pullulanases, tanases, penlosanases, malanases, ß-glucanases, arabinosidases, hyaluronidase, chondroilinase, laccase and amylases, or mixtures of these. A typical combination is a mixture of enzymes comprising, for example, a protease and lipase together with amylase. When the aforementioned enzymes are included in a cleaning composition, their concentration may vary from approximately 0.00001% to approximately 2%, from approximately 0.0001% to approximately 1% or even approximately 0.001% by weight. Approximately 0.5% enzyme protein by weight of the composition.

Enzyme cleaners: enzymes for detergents can be distinguished by various techniques. The enzymes employed herein can be destabilized by the presence of water-soluble magnesium or calcium ion sources in the finished compositions that provide the ions to the enzymes. When the aqueous compositions comprise proiease, a reversible inhibitor of the prolease can be added, such as a boron compound, to further improve stability. Catalytic metal complexes: applicants' compositions can include catalytic complexes of metals. A melamine-based bleach calender lipo is a caulking system comprising a transition metal cation of defined bleach catalyst activity such as copper, iron, titanium, ruthenium, tungsten, molybdenum or manganese cations, an au cation cation. of low activity metal or no catalytic bleaching activity such as zinc or aluminum cations, and a sequestrant with defined constants of stability for the calalitic and auxilliary metal grades, especially ethylenediaminetetraacetic acid, eilendiamineleira (methylene) phosphonic acid and salts soluble in water thereof. These catalysts are described in U.S. Pat. 4,430,243. If desired, the compositions herein can be catalyzed by means of a manganese compound. These compounds and the concentrations of use are well known in the industry and include, for example, the manganese-based catalysts described in U.S. Pat. no. 5,576,282.

Cobalt bleaching co-catalysts useful herein are known and described, for example, in U.S. Pat. no. 5,597,936; 5,595,967. These cobalt-based catalysts are prepared rapidly by known methods such as those described, for example, in U.S. Pat. num. 5,597,936 and 5,595,967. The compositions herein may also suitably include a ligand-binding meanal complex, such as bispidones (WO 05/042532 A1) or macropolycyclic rigid ligands - abbreviated as "MRL". By a practical consideration and not by way of limitation, the compositions and methods of the present may be adjusted to provide at least one part per one hundred million of the MRL-active species in the aqueous washing medium, and will generally provide Approximately 0.005 ppm to approximately 25 ppm, from approximately 0.05 ppm to approximately 10 ppm, or even from approximately 0.1 ppm to approximately 5 ppm of the MRL in the washing liquid. Suitable transition metals in the transition metal bleach cauliflower include, for example, manganese, iron and chromium. Suitable MRLs include 5,12-diethyl-1, 5,8,12-tetraazobicyclo [6.6.2] he? Adecano. Suitable MRLs of transition metals are readily prepared by known methods, such as are described, for example, in WO 00/32601, and in U.S. Pat. no. 6,225,464.

Solvents: Suitable solvents include water and other solvents such as lipophilic fluids. Examples of suitable lipophilic fluids include siloxanes, other silicones, hydrocarbons, glycol ethers, glycerin derivatives such as glycerin ethers, perfluorinated amines, perfluorinated and hydrofluoroether solvents, non-volatile, non-fluorinated organic solvents, diol-based solvents, other solvents compatible with the environment and mixtures of these.

Processing processes for cleaning or treatment compositions. The cleansing compositions of the present invention can be formulated in any of the suitable forms and prepared by any of the methods selected by the formulator; non-limiting examples thereof are described in the applicants' examples and in U.S. Pat. num. 5,879,584; 5,691, 297; 5,574,005; 5,569,645; 5,565,422; 5,516,448; 5,489,392; 5,486,303, which are incorporated herein by reference.

Method of use The present invention includes a method for cleaning a silium, among others, a surface or fabric. These methods include the steps of putting in a vacuum a form of the cleaning composition of the applicants, in pure form or diluted in a washing liquid, with at least a portion of a surface or cloth for then, optionally, rinsing the surface or íela The surface or sheet can be washed before the rinsing step. For the purposes of the present invention, washing includes but is not limited to scrubbing and mechanical agitation. As one skilled in the art will appreciate, the cleaning compositions of the present invention are ideal for washing garments. Accordingly, the present invention includes a method for washing lelas. The method comprises the contact between the fabric to be washed and the cleaning solution which contains at least one embodiment of the cleaning composition or cleaning detergent of the applicants or a mixture thereof. Any fabric that the consumer usually launders under normal conditions can be used. The solution preferably has a pH of about 8 to about 10.5. The compositions can be employed in concentrations of about 500 ppm to about 15,000 ppm in solution. The temperature of the water, in general, varies from approximately 5 ° C to approximately 90 ° C. The approximate proportion of water to the water, in general, varies between 1: 1 and 30: 1.

Compatibility test between the organic catalyst and the enzyme The test described below uses an alpha amylase activity assay to measure the impact of the organic catalysts on the enzyme. Equipment. The UV / V spectrophotometer is capable of measuring at 4 5 nm, heated magnetic stirrer of 40 ° C, 5 ml Luer-lock syringe and filters (Acrodisc 0.45 μm), pH meter, and esp (analytical, 4 places). Reactive. Merck amylase group (Merck Eurolab, catalog number 1.19718.0001); Trizma Base (Sigma, catalog number T-1503, or equivalent); calcium chloride dihydrate (Sigma, catalog number C-5080, or equivalent); sodium thiosulfate pentahydrate (Sigma, catalog number S-6672 or equivalent); hydrochloric acid (VWR, No. JT9535-0, or equivalent); hardness solution (CTC Group, 3.00 g / cc or equivalent); percarbonated sodium peraleic acid (Aldrich, catalog number 26933-6 or equivalent); Amylase enzymes: Termamyl, Natalase, and Duramyl (Novozymes, Denmark); granular detergent matrix that does not contain enzymes, organic catalysts or bleaching agents. 1.) Preparation of the solution: make the following preparation: a.) Iris test cushion Prepare 1 liter of 0.1 M Tris buffer, 0.5% sodium thiosulphate (W / V), 0.11% calcium chloride (w / v) with a pH of 8.3. b.) Preform detergent solution Prepare one liter of granulated detergent product free of bleaches and enzymes at 0.5% in deionized water (W / V) which is 250 ppm H202 (0.77 g percarbonate) and 2.65 g / l (10 gpg) of Hardness (880 Ul of hardness). o) Termamyl, Duramyl and Natalase raw material. Prepare 100 ml solutions, each with 0.1633 mg of active Termamyl per ml of Iris buffer, with 0.1159 mg of active Natalase per ml of tris buffer, and 0.1596 mg of active Duramyl per ml of tris buffer. d.) Raw material of organic catalysts. Prepare a solution of 500 ppm in methanol of μm. e.) Peracetic acid raw material. Prepare a peracetic acid solution of 3955 ppm in deionized water. f.) Amylase reagent. Follow the instructions of the Merck kit for the preparation of vials (containers) 1 and 2 using vial 3 and the subsequent mixture of vials 1 and 2 to produce the final reagent used in the amylase activity assay. 2.) Sample analysis a.) Sample analysis with enzymes only: Add 100 ml of detergent preform solution to a 150 ml beaker. Place the beaker on a heated stirring plate and raise the lemperairy at 40 ° C with stirring. Add Y μl of enzyme raw material to the beaker, where Y = 612 μl for Duramyl, 306 μl for Termamyl, or 918 μl for Nalalase. Dilute only the enzyme of interest. Agilar the sample lasts a minute. The timer is started. At 7 minutes, 45 seconds, remove a sample and filter it using a 0.45 μm syringe filter (5 ml syringe). Mix 6 μl of the filtered sample with 250 μl of amylase reagent in a cuvela and place the cuvela in a UV / VIS spectrophotometer to monitor the change in absorbance at 415 nm. Determine the time period (tE) to the nearest second needed to obtain the absorbance reading of 1.0 for each enzyme. Use the time period lE of each enzyme in steps 2.) b.) And 2.) c.) Later. b.) Analysis of the sample only with enzymes and peraleic acid. Follow step 2.) a.) Only after adding the enzyme, allow the solution to shake for 1 minute and then add 127 μl of peracetic acid starting material and start the timer. Take the sample at 7 minutes 45 seconds as in step 2.) a.). When the sample and the reactive have been mixed, record the absorbance in lE for the respective enzyme. Name said absorbance Ab. o) Analysis of the sample with enzymes, peraceic acid and organic cayalizer. Follow step 2.) a.) Only after adding the enzyme, allow the solution to stir for 1 minute and then add 127 μl of peraceic acid raw material and 100 μl of organic calyser raw material; start the lemporizador. Remove the sample at 7 minutes 45 seconds as in step 2.) a.). When the sample and the reactive have been mixed, record the absorbance in lE for the respective enzyme. Name said absorbance Ac. 3.) Calculate the value of the enzyme compatibility (ECV) a.) Calculate the ECV for each specific enzyme: Termamyl (ECVter), Duramyl (ECVdur) and Naialese (ECVnat). The ECV of each specific enzyme is (? JAb)? 100, where Ab and Ac are the demined values in steps 2.) b.) And 2.) o), respectively, for that enzyme. b.) The CVD for a given organic signal is the average of the individual ECV values for the enzymes. Therefore, ECV = (ECVter + ECVdur + ECVnat) / 3.

EXAMPLES Unless indicated otherwise, the materials can be obtained from Aldrich, P.O. Box 2060, Milwaukee, Wl 53201, USA In Examples 1-12, acetonitrile as a solvent can be replaced by other solvents including, but not limited to, 1,2-dichloroethane.

EXAMPLE 1 Preparation of sulfuric acid bicarbonate of morao ester 2 ° (3,4 ° d5 gdroisoquin? Oll? Na-2 ° a¡) 1 ° (2 ° prophept58ox8inr? EfiB)) - e1iillI inteles Preparation of 2-propylheplyl glycidyl ether: 2-propylheplanol (Pfaltz &Bauer, Inc.) is added in a 500 ml flask with rounded bottom and flame dried, equipped with an addition funnel loaded with epichlorohydrin (15.62 g, 0.17 mol). ., 172 E. Aurora Streei, Waterbury CT, 06708, USA) (20 g, 0.127 moles) and stannic chloride (0.20 g, 0.001 mole). The reaction is maintained in an argon atmosphere and heated at 90 ° C using an oil bath. Epichlorohydrin is applied by dripping in the stirred solution for 60 minutes and then it is stirred at 90 ° C for 18 hours. The reaction is provided with a vacuum distillation head and 1-chloro-3- (2-propyl-heptyloxy) -propan-2-ol is distilled at an emperature ranging from 90 ° C-> 0. 95 ° C under 26.7 Pa (0.2 mm Hg). Weight = 22.1 g. The 1-chloro-3- (2-propyl-hepliloxí) -propan-2-ol (5.0 g, 0.020 mol) is dissolved in leirahydrofuran (50 ml) and stirred at RT to an argon aosphere. To stir the solution, poisonous organoxide (2.52 g, 0.022 mol) was added and the suspension was stirred at RT for 18 hours. The reaction then evaporates until it dries; the residue is dissolved in hexanes and washed with water (100 ml). The hexanes phase is separated, dried with Na 2 SO 4, filtered and evaporated until it is dried to obtain the crude 2-propylheptyl glycidyl ether, which can then be purified by vacuum desilylation. Preparation of sulfuric acid of mono- [2- (3,4-dihydroisoquinoline-2-yl) -1- (2-propylheptyl-imeryl) -y-yl ester), internal salts. To a maíraz of 250 ml, of rounded bottom, of fres peaks, dried on flame, and provided with a condenser, enigid of argon dry, magnetic bar of agilación, lermómeíro and bath of heat they add 3,4-dihidroisoquinolina (0.38 mol , prepared as described in Example 1 of US Patent No. 5,576,282), 2-propylheptyl glycidyl ether (0.38 mol, prepared as described above), S03-dimethylarformamide complex (0.38 mol) and acetylilyl (500 ml). The reaction is heated to 80 ° C and stirred at the end of 72 hours. The reaction is cooled to ambient temperature, evaporated until it dries and the residue is recrystallized from the elyel or olive oil to obtain the desired product.

EXAMPLE 2 Preparation of Sulfuric Acid mopo ° 22 ° 33.4 ° dih5 lroisoq i oiSna ° 2 ° B) ° 'l (2 ° butiB-octiBoxi? Pp? Et? L) -etiB1 ester, internal salt The desired product is prepared according to Example 1, substituting 2-butyl octanol for 2-propylheptanol.

EXAMPLE 3 Preparation of suBfuric acid mo? Po ° [2 ° (3.4 ° dólh? 5droñsoqyá? P? OB8? P? A ° 2 ° flB) ° 1 ° (2 ° pentñB ° noniBoxBrnetiB) ° etñB1, saB internal The desired product is prepared according to Example 1, substituting 2-pentylnonyl (obtained from Pfalíz &Bauer, Inc., Wayerbury, CT 06708) for 2-propylheplanol.

EXAMPLE 4 Preparation of sulfuric acid? Rponoi2 °? 3.4 ° dilt? Idroñsoei] u5nolñna ° 2 ° D) ° 'il ° (2 ° hex5B-deciBoxi? PraetiS) -ethyl ester, internal saB The desired product is prepared according to Example 1, substituting 2-hexyldecanol for 2-propylheptanol.

EXAMPLE 5 Preparation of suifuric acid mon monof2 ° (3,4 ° dilhydrogsoquinoline 2 2 ° and B) ° 1 ° (dodecyloxymethyl) etil ethyl ester, internal saB The desired product is prepared according to Example 1, substituting n-dodecanol for 2-propylheptanol.

EXAMPLE 6 Preparation of suBfuric acid? Ppionof2- | 3,4 ° dglh5droisoqy5noBina ° 2 ° 5B) ° il ° ftetracioxox? Rrtietll) ° etii1 ester, internal sai The desired product is prepared according to Example 1, substituting n-telradecanol for 2-propylhepianol.

EXAMPLE 7 Preparation of suifuric acid monof2 ° (3.4 ° di idroiso? YinoB5na ° 2 ° iB) ° 1- (exacyoxymethyl) -etiBI ester, saB The desired product is prepared according to Example 1, suspending n-hentanedol by 2-propylheptanol.

EXAMPLE 8 Preparation of suBfuric acid monof2 ° (3.4 ° dchidroisoci? A? R8? 5n ° 2 ° 5fl) ° 1l ° (octac5BoximetiB) ° eti81 ester, internal saB The desired product is prepared according to Example 1, substituting n-octodecanol for 2-propylheptanol.

EXAMPLE 9 Preparation of Sulfuric Acid of Internal Mono-ester SaB [f2- (3,4- dihydroisoquinoneBina ° 2 ° ifl) ° 1 ° (iso ° nonifloxi? Pp? Et5B) ° etii1, internal saB The desired product is prepared according to Example 1, substituting iso-nonanol (E al 9 obtained from E? On Mobile Chemical, Houston, Te? As, USA) for 2-propylheptanol.

EXAMPLE 10 Preparation of suBfuric acid mon? O2 ° (3.4 ° di? H? Idro5soqyñnoB5? P? A? 2 °? B) ° 1l. { 5th decilox5m? Eti8) ° etiB1 ester, internal saB The desired product is prepared according to Example 1, by iso-decanol (obtained from City Chemicals LLC, West Haven, Connecic, USA) by 2-propylhephenol.

EXAMPLE 11 Preparation of suBfuric acid mon? Or2"(3.4 ° dih5dro5soqyñnoBina ° 2 ° ñll ° 1- (iso-tridec5Boxi? PnetB8) -eftiB1 ester.

The desired production is prepared according to Example 1, suspending iso-lidecanol (obtained from BASF Corporalion, Mount Olive, New Jersey, USA) by 2-propylheptanol.

EXAMPLE 12 Simultaneous preparation of suBfuric acid pmono 2 ° (3.4 ° dihydroisoquinone Bina ° 2 °) 1 ° (iso ° trideciBox ™ m etiB) -eftiB | ester, internal salts, ¥ mono sulfuric acid [2 ° (3,4 ° dih? 5droisoqy5noBñna ° 2 ° 5B) ° 1] ° f? so ° pentadeciBoxim? etiB) ° et581 ester, internal salt The desired products are prepared according to Example 1, by substituting a mixture of isomeric tridecanols with pentadecanols (obtained from BASF Corporation, Mount Olive, New Jersey, USA) by 2-propylheptanol.

EXAMPLE 13 The bleaching detergent compositions in the form of granular laundry detergents are illustrated by the following formulations. A B c D E F Linear alkylbenzenesulfonate 20 22 20 15 20 20 Dimethylhydroxyethyl ammonium chloride of C12 0.7 1 1 0.6 0.0 0.7 AE3S 0.9 0.0 0.9 0.0 0.0 0.9 AE7 0.0 0.5 0.0 1 3 1 Sodium tripolyphosphate 23 30 23 17 12 23 Zeolite A 0.0 0.0 0.0 0.0 10 0.0 Silicate (1.6R) 7 7 7 7 7 7 Sodium carbonate 15 14 15 18 15 15 Polyacrylate PM 4500 1 0.0 1 1 1.5 1 Carboxymethylcellulose 1 1 1 1 1 1 Savinase 32.89 mg / g 0.1 0.07 0.1 0.1 0.1 0.1 Natalase 8.65 mg / g 0.1 0.1 0.1 0.0 0.1 0.1 Polisher 15 0.06 0.0 0.06 0.18 0.06 0.06 Rinse aid 49 0.1 0.06 0.1 0.0 0.1 0.1 Diethylenetriamine pentaacetic acid 0.6 0.3 0.6 0.25 0.6 0.6 MgS04 1 1 1 0.5 1 1 Sodium percarbonate 0.0 5.2 0.1 0.0 0.0 0.0 Photoblank 0.0030 0.0015 0.0015 0.0020 0.0045 0.0010 Sodium perborate monohydrate 4.4 0.0 3.85 2.09 0.78 3.63 NOBS 1.9 0.0 1.66 1.77 0.33 0.75 TAED 0.58 1.2 0.51 0.0 0.015 0.28 Organic catalyst * 0.0185 0.0185 0.0162 0.0162 0.0111 0.0074 Sulfate / moisture 100% esp 100% esp 100% esp 100% esp 100% esp 100% * Organic catalyst prepared according to Examples 1 to 12, or mixtures of these.

Any of the above compositions is used to wash ilales at a concentration of 3500 ppm in water, 25 ° C and a water: ile ratio of 25: 1. The typical pH is 10, but it can be adjusted by altering the acid to the sodium salt form of the alkylbenzenesulphone.

EXAMPLE 14 Bleaching delergen compositions in the form of granular laundry detergents are illustrated by the following formulations.

Linear alkyl benzene sulfonate 8 7.1 7 6.5 AE3S 0 4.8 0 5.2 Alkylsulfate 1 0 1 0 AE7 2.2 0 3.2 0.1 Chloride dimethyl hydroxyethylammonium of C10.12 0.75 0.94 0.98 0.98 Crystalline layered silicate (d-Na2Si205) 4.1 0 4.8 0 A B C D Zeolite A 20 0 17 0 Citric acid 3 5 3 4 Sodium carbonate 15 20 14 20 Silicate 2R (Si02: Na20 in a 2: 1 ratio) 0.08 0 0.11 0 Agent for spotting 0.75 0.72 0.71 0.72 Acrylic acid / maleic acid copolymer 1.1 3.7 1.0 3.7 Carboxymethylcellulose 0.15 1.4 0.2 1.4 Protease (56.00 mg active / g) 0.37 0.4 0.4 0.4 Amylase (21.55 mg active / g) 0.3 0.3 0.3 0.3 Lipase (11.00 mg active / g) 0 0.7 0 0.7 Tetraacetylethylenediamine (TAED) 3.6 4.0 3.6 4.0 Percarbonate 13 13.2 13 13.2 Organic catalyst * 0.04 0.02 0.01 0.06 Na salt of ethylenediamine-NN'-disuccinic acid, (S, S) isomer (EDDS) 0.2 0.2 0.2 0.2 Hydro-ietane diphosphonate (HEDP) 0.2 0.2 0.2 0.2 MgSOa, 0.42 0.42 0.42 0.42 Perfume 0.5 0.6 0.5 0.6 Bumper foam suppressor 0.05 0.1 0.05 0.1 Soap 0.45 0.45 0.45 0.45 Sodium sulfate 22 33 24 30 Phthalocyanine sulfonated zinc 0.07 0.12 0.07 0.12 Photo whitening 0.0014 0.002 0.0014 0.001 Colored motes 0.03 0.05 0.03 0.05 Water and miscellaneous esp 100% esp 100% esp 100% esp 100% Organic catalyst prepared in accordance with Examples 1 to 12, or mixtures thereof.

Any of the above compositions is used to wash ices at a concentration of 10,000 ppm in water, 20-90 ° C, and a water: ≤ 5: 1 ratio. Approximate pH is 10, but can be adjusted by altering the ratio of acid to the sodium salt form of the alkylbenzene sulfonate.

EXAMPLE 15 The following formulations exemplify bleaching detergent compositions that come in the form of granular laundry detergents.

Linear alkylbenzenesulfonate 19.0 15.0 20.0 19.0 18.0 17.5 Alkylsulfate 1.1 1.0 0.8 1.0 1.1 1.2 AE3S 0.3 0.2 0.0 0.1 0.3 0.5 Polyacrylic acid, partially 6.0 5.5 7.5 7.0 5.8 6.0 neutralized Sodium xylene sulphonate * 1.5 1.9 2.0 1.7 1.5 1.0 PEG 4000 0.3 0.25 0.35 0.15 0.2 0.10 Polishing 49 0 0 0.32 0.04 0.04 0.16 Rinse aid 15 0 0 0.68 0.08 0.08 0.32 Humidity 2.50 2.00 2.90 2.20 2.40 1.80 Sodium carbonate 20.0 17.5 21.0 20.2 19.0 18.0 Sodium sulfate 0.20 0.30 0.50 0.30 0.45 0.10 Sodium silicate 0.25 0.25 0.55 0.30 0.25 0.10 Detergent builder of 2.7 3.0 2.2 3.7 1.5 1.0 silicate stratified Zeolite A 11.0 11.0 12.5 10.2 9.5 8.0 Protease 0.20 0.50 1.0 0.15 0.40 0.0 Silicone foam suppressor 0.40 0.35 1.00 0.60 0.50 0.00 Coarse sulfate 21.5 23.0 21.0 21.0 20.0 18.5 Reaction product of 0.40 0.25 0.10 0.35 0.60 0.00 amine comprising d- Damascona **** Perfume 0.10 0.30 0.20 0.20 0.40 0.50 Sodium percarbonate 2.8 4.5 2.00 4.7 7.4 10.0 Conventional activator (NOBS) 2.10 3.7 1.00 3.0 5.0 10.0 Organic Catalyst "0.005 0.10 1.00 0.25 0.05 0.05 Bluing agent * 0.50 0.20 1.00 0.30 0.10 0.00 esp esp esp esp esp esp Load 100% 100% 100% 100% 100% * Other hydrotropes, such as sodium toluenesulfonate, can be used. * Organic catalyst prepared in accordance with Examples 1 to 12, or mixtures thereof.

*** Such as Ultramarine Blue or Azo-CM-cellulose (Megazyme, Bray, Co. Wicklow, Ireland) **** Prepared according to WO 00/02991. Any of the above compositions is used to wash ilales at a concentration of 500-1500 ppm in water, 5-25 ° C and a water: ial ratio of 15: 1 - 25: 1. The typical pH is approximately 9.5-10, but can be adjusted by modifying the proportion of acid in Na salt to form alkylbenzene sulfonate.

EXAMPLE 16 The organic catalysts described below are tested according to Applicant's Organic Catalyst / Compatibility Test, using [peracetic acid] = 5.0 ppm; [organic caíalizador] = 0.5 ppm, and obíienen the following results. 4 8,, are comprised by the Formula 1 of the applicants.

While particular embodiments of the present invention have been illustrated and described, it will be apparent to those skilled in the art that various changes and modifications may be made without departing from the spirit and scope of the invention. It has been intended, therefore, to cover changes and modifications in the appended claims. deniro of the scope of the invention.

Claims (8)

1. - A cleaning composition comprising: a.) An organic cauliflower selected from the group composed of organic catalysts having the following formulas: (!)

(OR) (iii) and mixtures thereof; wherein each R1 is, independently, a branched alkyl group containing from 9 to 24 carbons or a linear alkyl group containing from 11 to 24 carbons; preferably, each R1 is, independently, a branched alkyl group containing 9 to 18 carbons or a linear alkyl group containing 11 to 18 carbons; more preferably, each R is independently selected from the group comprising 2-propylheptyl, 2-butyloctyl, 2-pentylnonyl, 2-heydodecyl, n-dodecyl, n-tetradecyl, n-heydecyl, n-octadecyl, isononyl , isodecyl, iso-iridecyl and iso-penladecyl; and b.) one or more au? ilial ingredients. 2. The cleaning composition according to claim 1, further characterized in that it comprises an organic catalyst having the following formula: wherein each R1 is independently a branched alkyl group containing from 9 to 24 carbons or a linear alkyl group containing from 11 to 24 carbons; preferably each R1 is independently a branched alkyl group containing 9 to 18 carbons or a linear alkyl group containing 11 to 18 carbons; more preferably, R1 is independently selected from the group comprising 2-propylheptyl, 2-butyloxy, 2-pentynyl, 2-heydecyl, n-dodecyl, n-tetradecyl, n-heydecyl, n-octadecyl, isononyl, isodecyl, iso-tridecyl and iso-pentadecyl.

3. The cleaning composition according to claim 1, further characterized in that it comprises an organic catalyst having the following formula: wherein each R1 is independently a branched alkyl group containing from 9 to 24 carbons or a linear alkyl group containing from 1 to 24 carbons; preferably each R1 is independently a branched alkyl group containing 9 to 18 carbons or a linear alkyl group containing 11 to 18 carbons; more preferably, R1 is independently selected from the group comprising 2-propylheptyl, 2-bulyloctyl, 2-pentyinonyl, 2-heydodecyl, n-dodecyl, n-ioradecyl, n-heydecyl, n-ociacdecyl, isononyl, isodecyl, iso-lridecyl and iso-penladecyl.

4. A cleaning composition comprising an organic cauliflower having an enzyme compatibility value of 70 or greater, and one or more additional ingredients.

5. The cleaning composition according to claim 4, further characterized in that it comprises an organic catalyst that has a value of enzymatic compability of 80 or greater.

6. The cleaning composition according to any of the preceding claims, further characterized in that at least one of the ingredients or more additional ingredients is selected from a source of peroxide, an enzyme, a lensioactive agent and mixtures of these .

7. The cleaning composition according to any of the preceding claims, further characterized in that the composition comprises the following additional ingredients: a source of activated peroxide, an enzyme and an insensitive agent.

8. A method for cleaning a surface or fabric comprising the steps of bringing said surface or tile into contact with a cleaning composition as claimed in any of the preceding claims and then, optionally, washing or rinsing said surface or layer. .