MD842G2 - Procedeu de obţinere a 4-aminodifenilaminei - Google Patents
Procedeu de obţinere a 4-aminodifenilamineiInfo
- Publication number
- MD842G2 MD842G2 MD94-0303A MD940303A MD842G2 MD 842 G2 MD842 G2 MD 842G2 MD 940303 A MD940303 A MD 940303A MD 842 G2 MD842 G2 MD 842G2
- Authority
- MD
- Moldova
- Prior art keywords
- adpa
- produce
- substituted derivatives
- aminodiphenylamine
- preparing
- Prior art date
Links
- ATGUVEKSASEFFO-UHFFFAOYSA-N p-aminodiphenylamine Chemical compound C1=CC(N)=CC=C1NC1=CC=CC=C1 ATGUVEKSASEFFO-UHFFFAOYSA-N 0.000 title abstract 5
- 238000000034 method Methods 0.000 title abstract 3
- CBCKQZAAMUWICA-UHFFFAOYSA-N 1,4-phenylenediamine Chemical compound NC1=CC=C(N)C=C1 CBCKQZAAMUWICA-UHFFFAOYSA-N 0.000 abstract 2
- PAYRUJLWNCNPSJ-UHFFFAOYSA-N Aniline Chemical compound NC1=CC=CC=C1 PAYRUJLWNCNPSJ-UHFFFAOYSA-N 0.000 abstract 2
- LQNUZADURLCDLV-UHFFFAOYSA-N nitrobenzene Chemical class [O-][N+](=O)C1=CC=CC=C1 LQNUZADURLCDLV-UHFFFAOYSA-N 0.000 abstract 2
- 230000029936 alkylation Effects 0.000 abstract 1
- 238000005804 alkylation reaction Methods 0.000 abstract 1
- 150000001448 anilines Chemical class 0.000 abstract 1
- 239000003963 antioxidant agent Substances 0.000 abstract 1
- 150000001875 compounds Chemical class 0.000 abstract 1
- 150000003839 salts Chemical class 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C209/00—Preparation of compounds containing amino groups bound to a carbon skeleton
- C07C209/02—Preparation of compounds containing amino groups bound to a carbon skeleton by substitution of hydrogen atoms by amino groups
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C209/00—Preparation of compounds containing amino groups bound to a carbon skeleton
- C07C209/30—Preparation of compounds containing amino groups bound to a carbon skeleton by reduction of nitrogen-to-oxygen or nitrogen-to-nitrogen bonds
- C07C209/32—Preparation of compounds containing amino groups bound to a carbon skeleton by reduction of nitrogen-to-oxygen or nitrogen-to-nitrogen bonds by reduction of nitro groups
- C07C209/36—Preparation of compounds containing amino groups bound to a carbon skeleton by reduction of nitrogen-to-oxygen or nitrogen-to-nitrogen bonds by reduction of nitro groups by reduction of nitro groups bound to carbon atoms of six-membered aromatic rings in presence of hydrogen-containing gases and a catalyst
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C209/00—Preparation of compounds containing amino groups bound to a carbon skeleton
- C07C209/30—Preparation of compounds containing amino groups bound to a carbon skeleton by reduction of nitrogen-to-oxygen or nitrogen-to-nitrogen bonds
- C07C209/38—Preparation of compounds containing amino groups bound to a carbon skeleton by reduction of nitrogen-to-oxygen or nitrogen-to-nitrogen bonds by reduction of nitroso groups
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
- Measurement Of The Respiration, Hearing Ability, Form, And Blood Characteristics Of Living Organisms (AREA)
- User Interface Of Digital Computer (AREA)
- Input From Keyboards Or The Like (AREA)
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US07/719,876 US5117063A (en) | 1991-06-21 | 1991-06-21 | Method of preparing 4-aminodiphenylamine |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| MD842F2 MD842F2 (en) | 1997-09-30 |
| MD842G2 true MD842G2 (ro) | 1998-12-31 |
Family
ID=24891732
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| MD94-0303A MD842G2 (ro) | 1991-06-21 | 1994-07-29 | Procedeu de obţinere a 4-aminodifenilaminei |
Country Status (19)
| Country | Link |
|---|---|
| US (4) | US5117063A (de) |
| EP (1) | EP0590053B2 (de) |
| JP (1) | JP3167029B2 (de) |
| KR (1) | KR0132514B1 (de) |
| AT (1) | ATE158567T1 (de) |
| AU (1) | AU653249B2 (de) |
| BR (1) | BR9206180A (de) |
| CA (1) | CA2065056A1 (de) |
| CZ (1) | CZ281972B6 (de) |
| DE (1) | DE69222417T3 (de) |
| EE (1) | EE03043B1 (de) |
| ES (1) | ES2110001T5 (de) |
| HU (1) | HU214296B (de) |
| MD (1) | MD842G2 (de) |
| PL (3) | PL168393B1 (de) |
| RU (1) | RU2102381C1 (de) |
| SK (1) | SK283999B6 (de) |
| UA (1) | UA26851C2 (de) |
| WO (1) | WO1993000324A1 (de) |
Families Citing this family (102)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5117063A (en) * | 1991-06-21 | 1992-05-26 | Monsanto Company | Method of preparing 4-aminodiphenylamine |
| EP0566783A1 (de) * | 1992-04-21 | 1993-10-27 | Akzo N.V. | Verfahren zur Herstellung von Nitrodiarylaminen |
| US5331099A (en) * | 1992-05-22 | 1994-07-19 | Monsanto Company | Process for preparing p-nitroaromatic amides and products thereof |
| US5552531A (en) * | 1992-05-22 | 1996-09-03 | Monsanto Company | Process for preparing substituted aromatic azo compounds |
| US5252737A (en) * | 1992-05-22 | 1993-10-12 | Monsanto Company | Process for preparing N-aliphatic substituted p-phenylenediamines |
| US5233010A (en) * | 1992-10-15 | 1993-08-03 | Monsanto Company | Process for preparing isocyanate and carbamate ester products |
| EP0803496B1 (de) * | 1992-10-28 | 2000-03-08 | Mitsui Chemicals, Inc. | Verfahren zur Herstellung von Diphenylamin oder kernsubstituierten Derivaten |
| US5451702A (en) * | 1993-04-26 | 1995-09-19 | Monsanto Company | Process for preparing substituted aromatic amines |
| US5380946A (en) * | 1993-07-30 | 1995-01-10 | Monsanto Company | Process for preparing p-nitroaromatic amides and products thereof |
| JPH07149695A (ja) * | 1993-09-30 | 1995-06-13 | Seiko Kagaku Kk | 4−アミノジフェニルアミン類の製造方法 |
| US5382691A (en) * | 1993-11-05 | 1995-01-17 | Monsanto Company | Process for preparing substituted aromatic amines |
| DE4427249A1 (de) * | 1994-08-02 | 1996-02-08 | Bayer Ag | Verfahren zur Herstellung nitrosubstituierter Arylamine |
| DE4427248A1 (de) * | 1994-08-02 | 1996-02-08 | Bayer Ag | Verfahren zur Herstellung nitrosubstituierter Arylamide und Arylamine |
| DE4432556A1 (de) * | 1994-09-13 | 1996-03-14 | Bayer Ag | Verfahren zur Herstellung nitrosubstituierter Arylamine |
| DE19600722A1 (de) * | 1996-01-11 | 1997-07-17 | Bayer Ag | Verfahren zur Herstellung von gegebenenfalls substituierten 4-Aminodiphenylaminen |
| US5728882A (en) * | 1996-04-04 | 1998-03-17 | Uniroyal Chemical Company, Inc. | Preparation of substituted aromatic amines |
| DE19709124A1 (de) * | 1997-03-06 | 1998-09-10 | Bayer Ag | Verfahren zur Herstellung von 4-Aminodiphenylamin |
| US5925790A (en) * | 1997-03-13 | 1999-07-20 | Uniroyal Chemical Company, Inc. | Preparation of substituted aromatic amines |
| US5977411A (en) * | 1997-06-10 | 1999-11-02 | Flexsys America L.P. | Catalytic hydrogeneration of nitrobenzene to 4-aminodiphenylamine in the presence of a hydroxyl compound and a solvent |
| TW500712B (en) * | 1997-08-06 | 2002-09-01 | Bayer Ag | Process for the preparation of 4-aminodiphenylamine |
| DE19810929A1 (de) * | 1998-03-13 | 1999-09-16 | Bayer Ag | Verfahren zur Herstellung von 4-Aminodiphenylamin |
| US6140538A (en) | 1998-05-18 | 2000-10-31 | Flexsys America L.P. | Process for preparing 4-aminodiphenylamines |
| US5840982A (en) * | 1998-06-04 | 1998-11-24 | Uniroyal Chemical Company, Inc. | Process for preparing para-phenylenediamine derivatives |
| SK283209B6 (sk) * | 1998-12-11 | 2003-03-04 | Duslo, A. S. | Spôsob prípravy 4-aminodifenylamínu |
| RU2225387C2 (ru) * | 1999-02-03 | 2004-03-10 | Флекссис Америка Л.П. | Способ получения 4-аминодифениламинов |
| US6069279A (en) * | 1999-06-14 | 2000-05-30 | Simon; Mark W. | Preparation of substituted aromatic amines |
| US6229035B1 (en) | 1999-06-16 | 2001-05-08 | Uniroyal Chemical Company, Inc. | Preparation of substituted aromatic amines |
| KR100302862B1 (ko) * | 1999-07-08 | 2001-09-13 | 박찬구 | 페닐유레아로부터 4-니트로디페닐아민 및 4-니트로아닐린을 제조하는 방법 |
| KR100298572B1 (ko) | 1999-08-19 | 2001-09-22 | 박찬구 | 카바아닐라이드로부터 4-니트로디페닐아민과 4-니트로소디페닐아민의 제조방법 |
| KR100331490B1 (ko) | 1999-12-03 | 2002-04-09 | 박찬구 | 요소와 니트로벤젠으로 부터 4,4'-디니트로디페닐아민을제조하는 방법 |
| US6156932A (en) * | 2000-02-23 | 2000-12-05 | Korea Kumho Petrochemical Co., Ltd. | Preparation of 4,4'-dinitrodiphenylamine from urea and nitrobenzene |
| US6495723B1 (en) * | 2000-06-21 | 2002-12-17 | Flexsys America | Zeolite support loaded with a base material for use in the coupling of aniline and nitrobenzene |
| US7045647B2 (en) | 2000-10-16 | 2006-05-16 | Uniroyal Chemical Company, Inc. | Blends of quinone alkide and nitroxyl compounds and polymerization inhibitors |
| US6685823B2 (en) * | 2000-10-16 | 2004-02-03 | Uniroyal Chemical Company, Inc. | C-nitrosoaniline compounds and their blends as polymerization inhibitors |
| US6395933B1 (en) | 2001-07-23 | 2002-05-28 | Flexsys America, L.P. | Process for preparing 4-aminodiphenylamine intermediates |
| CN100546972C (zh) * | 2001-07-23 | 2009-10-07 | 弗莱克塞斯美国公司 | 制备4-氨基二苯基胺的方法 |
| DE60214220T2 (de) * | 2001-10-12 | 2007-10-11 | Flexsys B.V. | Verfahren zur verbesserung der reinheit von quaternären ammoniumhydroxiden durch elektrolyse in einer zelle mit zwei kammern |
| KR20030035343A (ko) * | 2001-10-31 | 2003-05-09 | 금호석유화학 주식회사 | 4-니트로소 치환 방향족아민 화합물의 제조방법 |
| RU2223259C2 (ru) * | 2002-03-29 | 2004-02-10 | Мартынов Николай Васильевич | Способ получения 4-аминодифениламина |
| RU2278108C2 (ru) * | 2002-04-12 | 2006-06-20 | Татьяна Валентиновна Рудакова | Способ получения 4-аминодифениламина |
| US20040039181A1 (en) * | 2002-07-29 | 2004-02-26 | Rains Roger Keranen | Process for preparing aromatic azo and hydrazo compounds, aromatic amides and aromatic amines |
| US7183439B2 (en) * | 2002-12-10 | 2007-02-27 | Flexsys America L.P. | Process for preparing 4-aminodiphenylamine intermediates |
| RU2289569C2 (ru) * | 2002-12-10 | 2006-12-20 | Флекссис Америка Л.П. | Способ получения 4-аминодифениламина и его промежуточных соединений |
| US8686188B2 (en) | 2003-07-04 | 2014-04-01 | Jiangsu Sinorgchem Technology Co., Ltd. | Process for preparing 4-aminodiphenylamine |
| MXPA05013788A (es) * | 2003-07-04 | 2006-06-27 | Nongyue Wang | Proceso para preparar 4-aminodifenilamina. |
| ES2373720T3 (es) * | 2003-07-04 | 2012-02-08 | Jiangsu Sinorgchem Technology Co., Ltd | Método para la producción de 4-aminodifenilamina. |
| US8486223B2 (en) * | 2003-07-04 | 2013-07-16 | Jiangsu Sinorgchem Technology Co., Ltd. | Falling film evaporator |
| RU2247712C1 (ru) * | 2003-09-08 | 2005-03-10 | Мартынов Николай Васильевич | Способ получения 4-аминодифениламина |
| AU2005269780A1 (en) * | 2004-07-23 | 2006-02-09 | Polnox Corporation | Anti-oxidant macromonomers and polymers and methods of making and using the same |
| RU2265590C1 (ru) * | 2004-08-17 | 2005-12-10 | Мартынов Николай Васильевич | Способ получения 4-аминодифениламина |
| RU2276132C1 (ru) * | 2004-09-08 | 2006-05-10 | Николай Васильевич Мартынов | Раствор для синтеза 4-аминодифениламина, способ его получения и способ получения 4-аминодифениламина |
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| US7902317B2 (en) | 2004-12-03 | 2011-03-08 | Polnox Corporation | Synthesis of aniline and phenol-based antioxidant macromonomers and corresponding polymers |
| US7799948B2 (en) * | 2005-02-22 | 2010-09-21 | Polnox Corporation | Nitrogen and hindered phenol containing dual functional macromolecular antioxidants: synthesis, performances and applications |
| EP1866279A2 (de) * | 2005-03-25 | 2007-12-19 | Polnox Corporation | Alkylierte und polymere makromolekulare antioxidationsmittel sowie verfahren zu ihrer herstellung und verwendung |
| KR100621310B1 (ko) * | 2005-05-16 | 2006-09-06 | 금호석유화학 주식회사 | 4-아미노디페닐아민의 제조방법 |
| CN100363330C (zh) * | 2005-05-20 | 2008-01-23 | 中国石油天然气集团公司 | 一种提高4-氨基二苯胺产率的方法 |
| JP4626428B2 (ja) * | 2005-07-19 | 2011-02-09 | ソニー株式会社 | Ofdm復調装置及び方法 |
| EP1966293A1 (de) * | 2005-10-27 | 2008-09-10 | Polnox Corporation | Stabilisierte polyolefinzusammensetzungen |
| US7705176B2 (en) * | 2005-10-27 | 2010-04-27 | Polnox Corporation | Macromolecular antioxidants based on sterically hindered phenols and phosphites |
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| US9329486B2 (en) | 2005-10-28 | 2016-05-03 | Dynaloy, Llc | Dynamic multi-purpose composition for the removal of photoresists and method for its use |
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| US20070161522A1 (en) | 2005-12-02 | 2007-07-12 | Cholli Ashok L | Lubricant oil compositions |
| RU2293723C1 (ru) * | 2005-12-05 | 2007-02-20 | Открытое акционерное общество "Химпром" | Способ получения 4-аминодифениламина |
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| US7767853B2 (en) | 2006-10-20 | 2010-08-03 | Polnox Corporation | Antioxidants and methods of making and using the same |
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| CN101830811B (zh) * | 2010-02-23 | 2013-04-03 | 江苏扬农化工集团有限公司 | 4-氨基二苯胺的制备方法 |
| CN102259029B (zh) | 2010-05-24 | 2014-12-10 | 江苏圣奥化学科技有限公司 | 固体碱催化剂 |
| CN102093231A (zh) * | 2010-06-25 | 2011-06-15 | 天津市有机化工一厂 | 用Co-B非晶态合金催化剂催化生产4-氨基二苯胺的方法 |
| CN102372639A (zh) * | 2010-08-20 | 2012-03-14 | 中国石油化工集团公司 | 一种制备4-氨基二苯胺的方法 |
| KR101358605B1 (ko) | 2010-12-21 | 2014-02-04 | 금호석유화학 주식회사 | 4-니트로아닐린을 이용한 4,4'-디니트로디페닐아민 및 4,4'-비스(알킬아미노)디페닐아민의 제조방법 |
| KR101358519B1 (ko) | 2010-12-21 | 2014-02-05 | 금호석유화학 주식회사 | 복합염기촉매를 이용한 4,4'-디니트로디페닐아민 및 4,4'-비스(알킬아미노)디페닐아민의 제조방법 |
| RU2447058C1 (ru) * | 2010-12-24 | 2012-04-10 | Федеральное государственное унитарное предприятие "Научно-исследовательский институт полимерных материалов" | Способ получения 2-нитродифениламина |
| CN102344376B (zh) * | 2011-08-17 | 2014-04-02 | 中国石油化工股份有限公司 | 一种制备对氨基二苯胺的方法 |
| US8987181B2 (en) | 2011-11-08 | 2015-03-24 | Dynaloy, Llc | Photoresist and post etch residue cleaning solution |
| US9708243B2 (en) | 2012-03-07 | 2017-07-18 | Nocil Limited | Process for preparing 4-aminodiphenylamine |
| WO2013153419A1 (en) * | 2012-04-13 | 2013-10-17 | Nocil Limited | An efficient continuous process for manufacturing of 4-aminodiphenylamine from aniline and nitrobenzene |
| RU2502725C1 (ru) * | 2012-10-22 | 2013-12-27 | Российская Федерация, От Имени Которой Выступает Министерство Промышленности И Торговли Российской Федерации | Способ получения n-алкил-n'-фенил-пара-фенилендиаминов |
| US9158202B2 (en) | 2012-11-21 | 2015-10-13 | Dynaloy, Llc | Process and composition for removing substances from substrates |
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| WO2014098775A1 (en) | 2012-12-19 | 2014-06-26 | Slovenská Technická Univerzita V Bratislave, Strojnícka Fakulta | Automobile bodies and their manufacturing processes |
| RU2553984C2 (ru) * | 2013-02-28 | 2015-06-20 | Олег Александрович ГОДЗОЕВ | Способ получения 4-аминодифениламина и его алкилированных производных |
| WO2015077635A2 (en) | 2013-11-22 | 2015-05-28 | Polnox Corporation | Macromolecular antioxidants based on dual type moiety per molecule: structures methods of making and using the same |
| EP3154923A1 (de) * | 2013-12-16 | 2017-04-19 | Duslo, A.S. | Verfahren zur herstellung von 4-aminodiphenylamin-vorläufern |
| CN103864626B (zh) * | 2014-03-17 | 2016-04-06 | 山东尚舜化工有限公司 | 一种4-氨基二苯胺的催化加氢的生产设备及工艺 |
| CN103819346B (zh) * | 2014-03-17 | 2015-11-04 | 山东尚舜化工有限公司 | 一种4-氨基二苯胺的前体的生产设备及生产工艺 |
| CN103992229B (zh) * | 2014-05-19 | 2016-01-27 | 浙江永合化工有限公司 | 一种3,5-二甲基苯胺的制备方法 |
| CN104529916B (zh) * | 2014-12-25 | 2017-01-25 | 天津大学 | 从化工产品生产废料中分离高纯度吩嗪的方法 |
| WO2018160879A2 (en) | 2017-03-01 | 2018-09-07 | Polnox Corporation | Macromolecular corrosion (mcin) inhibitors: structures, methods of making and using the same |
| CN108558675A (zh) * | 2018-04-25 | 2018-09-21 | 南通理工学院 | 一种4-氨基二苯胺的合成方法 |
| CN110496613B (zh) * | 2019-09-11 | 2022-04-22 | 万华化学集团股份有限公司 | 一种加氢催化剂、其制备方法以及制备邻二氨基甲基环己烷的方法 |
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| WO2023028524A1 (en) | 2021-08-24 | 2023-03-02 | Flexsys America L.P. | New antidegradants based on fatty acids or derivatives functionalized with phenylenediamines |
| US20240124683A1 (en) | 2022-09-28 | 2024-04-18 | The Goodyear Tire & Rubber Company | Rubber - forming additives from biomass through syngas production |
| US20240117149A1 (en) | 2022-09-28 | 2024-04-11 | The Goodyear Tire & Rubber Company | Rubber - forming additives from end of life tires through syngas production |
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Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3847990A (en) * | 1971-09-28 | 1974-11-12 | Bayer Ag | Process for the production of nitrodiphenyl amine derivatives |
| US4404401A (en) * | 1979-02-23 | 1983-09-13 | Akzona Incorporated | Process for the preparation of para-amino-diphenylamine |
| US4479008A (en) * | 1982-09-30 | 1984-10-23 | Uniroyal, Inc. | Preparation of p-nitrosodiphenylamine |
| DE3501698A1 (de) * | 1985-01-19 | 1986-07-24 | Bayer Ag, 5090 Leverkusen | Verfahren zur herstellung von 4-nitrodiphenylaminen |
| US4683332A (en) * | 1985-05-20 | 1987-07-28 | The Goodyear Tire & Rubber Company | Para-nitrodiphenylamine synthesis |
| US4760186A (en) * | 1986-09-15 | 1988-07-26 | Monsanto Company | Preparation of substituted aromatic amines |
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| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| GB935303A (en) † | 1961-01-03 | 1963-08-28 | Ici Ltd | Improved process for the manufacture of 4-aminodiphenylamine |
| GB1440767A (en) * | 1972-11-24 | 1976-06-23 | Ici Ltd | Oxidation process for the manufacture of 4-aminodiphenylamine and related higher amines |
| GB1528057A (en) * | 1976-01-20 | 1978-10-11 | Westland Aircraft Ltd | Vibration absorbers |
| DE2633811C2 (de) * | 1976-07-28 | 1983-11-10 | Bayer Ag, 5090 Leverkusen | Verfahren zur Herstellung von Nitrodiphenylaminen |
| ZA774380B (en) † | 1976-08-13 | 1978-06-28 | Uniroyal Inc | Reduction and reductive alkylation of p-nitrosoarylamines with platinum metal sulfide catalysts |
| DE2713602C3 (de) * | 1977-03-28 | 1980-03-20 | Akzo Gmbh, 5600 Wuppertal | Verfahren zur Herstellung von Nitrosobenzol |
| US4187248A (en) * | 1977-11-23 | 1980-02-05 | Monsanto Company | Making a nitrodiarylamine by reacting an alkali metal salt of a formamide with a nitrohaloarene |
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| US4140716A (en) * | 1978-01-05 | 1979-02-20 | Monsanto Company | Process for making an amide of formic acid and forming nitrodiarylamine therefrom |
| US4196146A (en) * | 1978-03-13 | 1980-04-01 | Monsanto Company | Making nitrodiarylamines from formyl derivatives of aromatic amines and nitrohaloarenes by admixing with certain aqueous salt solutions |
| US4404402A (en) * | 1980-08-18 | 1983-09-13 | American Cyanamid Company | Aniline intermediates |
| US4313002A (en) † | 1980-10-29 | 1982-01-26 | Uop Inc. | Preparation of p-aminodiphenylamines |
| US4518803A (en) * | 1982-09-30 | 1985-05-21 | Uniroyal, Inc. | Process for the preparation of p-nitrosodiphenylamine |
| US4614817A (en) * | 1983-12-19 | 1986-09-30 | Monsanto Company | Making nitrodiarylamines |
| EP0184914A1 (de) † | 1984-12-05 | 1986-06-18 | UNIROYAL CHEMICAL COMPANY, Inc. | Verfahren zur Herstellung von 4-Aminodiphenylaminen |
| DE3504479A1 (de) * | 1985-02-09 | 1986-08-14 | Bayer Ag, 5090 Leverkusen | Verfahren zur herstellung von 4-nitrodiphenylaminen |
| US5117063A (en) † | 1991-06-21 | 1992-05-26 | Monsanto Company | Method of preparing 4-aminodiphenylamine |
| DE19600722A1 (de) † | 1996-01-11 | 1997-07-17 | Bayer Ag | Verfahren zur Herstellung von gegebenenfalls substituierten 4-Aminodiphenylaminen |
| SK283209B6 (sk) † | 1998-12-11 | 2003-03-04 | Duslo, A. S. | Spôsob prípravy 4-aminodifenylamínu |
-
1991
- 1991-06-21 US US07/719,876 patent/US5117063A/en not_active Expired - Lifetime
-
1992
- 1992-03-27 EP EP92914179A patent/EP0590053B2/de not_active Expired - Lifetime
- 1992-03-27 KR KR1019930703471A patent/KR0132514B1/ko not_active Expired - Lifetime
- 1992-03-27 JP JP50144693A patent/JP3167029B2/ja not_active Expired - Lifetime
- 1992-03-27 PL PL92301799A patent/PL168393B1/pl unknown
- 1992-03-27 DE DE69222417T patent/DE69222417T3/de not_active Expired - Lifetime
- 1992-03-27 BR BR9206180A patent/BR9206180A/pt not_active IP Right Cessation
- 1992-03-27 AT AT92914179T patent/ATE158567T1/de not_active IP Right Cessation
- 1992-03-27 PL PL92307117A patent/PL168917B1/pl unknown
- 1992-03-27 WO PCT/US1992/002232 patent/WO1993000324A1/en not_active Ceased
- 1992-03-27 ES ES92914179T patent/ES2110001T5/es not_active Expired - Lifetime
- 1992-03-27 US US08/157,120 patent/US5453541A/en not_active Expired - Lifetime
- 1992-03-27 PL PL92307116A patent/PL168938B1/pl unknown
- 1992-03-27 AU AU22245/92A patent/AU653249B2/en not_active Expired
- 1992-03-27 RU RU93058557A patent/RU2102381C1/ru active
- 1992-03-27 UA UA93003978A patent/UA26851C2/uk unknown
- 1992-03-27 SK SK1452-93A patent/SK283999B6/sk not_active IP Right Cessation
- 1992-03-27 HU HU9303686A patent/HU214296B/hu not_active IP Right Cessation
- 1992-03-27 CZ CS932484A patent/CZ281972B6/cs not_active IP Right Cessation
- 1992-04-03 CA CA002065056A patent/CA2065056A1/en not_active Abandoned
-
1994
- 1994-07-29 MD MD94-0303A patent/MD842G2/ro active IP Right Grant
- 1994-11-23 EE EE9400390A patent/EE03043B1/xx unknown
-
1995
- 1995-05-05 US US08/435,607 patent/US5608111A/en not_active Expired - Lifetime
- 1995-05-10 US US08/438,603 patent/US5623088A/en not_active Expired - Lifetime
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| US3847990A (en) * | 1971-09-28 | 1974-11-12 | Bayer Ag | Process for the production of nitrodiphenyl amine derivatives |
| US4404401A (en) * | 1979-02-23 | 1983-09-13 | Akzona Incorporated | Process for the preparation of para-amino-diphenylamine |
| US4479008A (en) * | 1982-09-30 | 1984-10-23 | Uniroyal, Inc. | Preparation of p-nitrosodiphenylamine |
| DE3501698A1 (de) * | 1985-01-19 | 1986-07-24 | Bayer Ag, 5090 Leverkusen | Verfahren zur herstellung von 4-nitrodiphenylaminen |
| US4683332A (en) * | 1985-05-20 | 1987-07-28 | The Goodyear Tire & Rubber Company | Para-nitrodiphenylamine synthesis |
| US4760186A (en) * | 1986-09-15 | 1988-07-26 | Monsanto Company | Preparation of substituted aromatic amines |
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| Title |
|---|
| Tetrahedron Letters, vol.31, no.22, 1990 ( Oxford, GB. N.R. Ayyangar et al., p. 3217-3220). * |
Also Published As
| Publication number | Publication date |
|---|---|
| ES2110001T5 (es) | 2006-11-16 |
| US5623088A (en) | 1997-04-22 |
| ATE158567T1 (de) | 1997-10-15 |
| BR9206180A (pt) | 1995-04-25 |
| AU2224592A (en) | 1993-01-25 |
| CA2065056A1 (en) | 1992-12-22 |
| AU653249B2 (en) | 1994-09-22 |
| RU2102381C1 (ru) | 1998-01-20 |
| PL168917B1 (pl) | 1996-05-31 |
| EE03043B1 (et) | 1997-10-15 |
| PL168393B1 (pl) | 1996-02-29 |
| US5117063A (en) | 1992-05-26 |
| US5453541A (en) | 1995-09-26 |
| WO1993000324A1 (en) | 1993-01-07 |
| HU9303686D0 (en) | 1994-04-28 |
| SK283999B6 (sk) | 2004-07-07 |
| UA26851C2 (uk) | 1999-12-29 |
| PL168938B1 (pl) | 1996-05-31 |
| EP0590053B1 (de) | 1997-09-24 |
| HU214296B (hu) | 1998-03-02 |
| JP3167029B2 (ja) | 2001-05-14 |
| CZ248493A3 (en) | 1994-03-16 |
| DE69222417T2 (de) | 1998-04-16 |
| CZ281972B6 (cs) | 1997-04-16 |
| EP0590053A1 (de) | 1994-04-06 |
| EP0590053B2 (de) | 2006-04-12 |
| MD842F2 (en) | 1997-09-30 |
| DE69222417T3 (de) | 2006-11-16 |
| HUT66362A (en) | 1994-11-28 |
| ES2110001T3 (es) | 1998-02-01 |
| JPH06508630A (ja) | 1994-09-29 |
| US5608111A (en) | 1997-03-04 |
| DE69222417D1 (de) | 1997-10-30 |
| SK145293A3 (en) | 1994-07-06 |
| KR0132514B1 (ko) | 1998-04-13 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| FG3A | Granted patent for invention | ||
| IF99 | Valid patent on 19990615 |
Free format text: EXPIRES: 20140729 |