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Dilworth et al., 1978 - Google Patents

Cyclopentadienyl titanium complexes with aryldiazenido-or phosphiniminato-ligands

Dilworth et al., 1978

Document ID
3232085836255712397
Author
Dilworth J
de Liefde Meijer H
Teuben J
Publication year
Publication venue
Journal of Organometallic Chemistry

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Snippet

Abstract [Ti (η 5-C 5 H 5) Cl 3] reacts with Me 3 Si N N Ph to give [Ti (η 5-C 5 H 5) Cl 2 (N 2 Ph)], and this gives [Ti (η 5-C 5 H 5) 2 Cl (N 2 Ph)] on treatment with sodium cyclopentadienide in THF at− 80° C.[Ti (η 5-C 5 H 4 R) Cl 3](R H, Me) reacts analogously …
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    • C07FACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F7/00Compounds containing elements of Groups 4 or 14 of the Periodic System
    • C07F7/02Silicon compounds
    • C07F7/08Compounds having one or more C-Si linkages
    • C07F7/10Containing nitrogen having a Si-N linkage
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    • C07F9/00Compounds containing elements of Groups 5 or 15 of the Periodic System
    • C07F9/02Phosphorus compounds
    • C07F9/547Heterocyclic compounds, e.g. containing phosphorus as a ring hetero atom
    • C07F9/553Heterocyclic compounds, e.g. containing phosphorus as a ring hetero atom having one nitrogen atom as the only ring hetero atom
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    • C07F7/02Silicon compounds
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    • C07F7/0803Compounds with Si-C or Si-Si linkages
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    • C07F7/00Compounds containing elements of Groups 4 or 14 of the Periodic System
    • C07F7/003Compounds containing elements of Groups 4 or 14 of the Periodic System without C-Metal linkages
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    • C07F15/00Compounds containing elements of Groups 8, 9, 10 or 18 of the Periodic System
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