Malament et al., 1970 - Google Patents
. alpha.,. alpha.-Dichloroazoalkanes. II. Mechanism of stereospecific synthesis and substitutionMalament et al., 1970
- Document ID
- 210081743921919140
- Author
- Malament D
- McBride J
- Publication year
- Publication venue
- Journal of the American Chemical Society
External Links
Snippet
Five mechanisms are proposed to explain stereospecific 1, 4-chlorine addition to ketazines. Three of these are shown to be consistent with experimental observations on the reaction and with theory. Factors favoring nucleophilic attack trans to an emerging lone pair are …
- 230000000707 stereoselective 0 title abstract description 4
Classifications
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- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C17/00—Preparation of halogenated hydrocarbons
- C07C17/26—Preparation of halogenated hydrocarbons by reactions involving an increase in the number of carbon atoms in the skeleton
- C07C17/32—Preparation of halogenated hydrocarbons by reactions involving an increase in the number of carbon atoms in the skeleton by introduction of halogenated alkyl groups into ring compounds
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