Angerman et al., 1967 - Google Patents
Kinetic study on the alkaline hydrolysis of oxalato, fumarato, and maleoto complexes of pentaamminecobalt (III)Angerman et al., 1967
- Document ID
- 11851069218178001580
- Author
- Angerman N
- Jordan R
- Publication year
- Publication venue
- Inorganic Chemistry
External Links
Snippet
The rate for the hydrolysis of thefumarato and maleato complexes of pentaamminecobalt (III) was found to be first order in hydroxide ion and in the complex. At 25 (µ= 1.0, NaCl), for the fumarato complex k, AH~, and* are 8.00 X 10" 6 M~ l sec-1, 28.5 kcal mole-1, and 18.3 cal …
- 238000005904 alkaline hydrolysis reaction 0 title description 5
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F5/00—Compounds containing elements of Groups 3 or 13 of the Periodic System
- C07F5/02—Boron compounds
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| Zhang et al. | The aluminum chemistry and corrosion in alkaline solutions | |
| James et al. | Metal tetrahydroborates | |
| Perlmutter-Hayman | The primary kinetic salt effect in aqueous solution | |
| Ford et al. | Acid-catalyzed aquation of hexaammineruthenium (II) and pentaaminepyridineruthenium (II) complex ions | |
| Heine et al. | Charge makes a difference: molecular ionic bismuth compounds | |
| Shaw | Inorganic Hydrides: The Commonwealth and International Library: Chemistry Division | |
| Dematteis et al. | Exploring Ternary and Quaternary Mixtures in the LiBH4‐NaBH4‐KBH4‐Mg (BH4) 2‐Ca (BH4) 2 System | |
| Swift | The kinetics of structural transformation of hydrated cobalt (II) and zinc (II) ions in aqueous solution | |
| Angerman et al. | Kinetic study on the alkaline hydrolysis of oxalato, fumarato, and maleoto complexes of pentaamminecobalt (III) | |
| Murakami et al. | Solvolysis of Organic Phosphates. IV. 3-Pyridyl and 8-Quinoly Phosphates as Effected by the Presence of Metal Ions | |
| Birk | Mechanism of the bromate in oxidation of aquoiron (II) | |
| Vitiello et al. | Equilibriums and kinetics of interconversion of cis and trans octahedral and planar forms of the nickel (II) complex of 1, 4, 8, 11-tetraazaundecane | |
| Banks et al. | Reactions of nitrous oxide with some transition-metal complexes | |
| Mason III et al. | The Replacement of an Ammonia Molecule in Halopentaammineplatinum (IV) Cations by Halide Ions | |
| French et al. | Induced electron transfer. Action of one-electron oxidants on (pyridinemethanol) pentaamminecobalt (III) complexes | |
| Espenson et al. | A kinetic study of the reactions of chromium (II) and the isomeric dichlorotetraaquochromium (III) ions | |
| Ratnam et al. | Kinetic and mechanistic studies on the oxidation of hydroxylamine, semicarbazide, and thiosemicarbazide by iron (III) in the presence of triazines | |
| US3390966A (en) | Chemical products and their preparation | |
| Addison et al. | The (4+) oxidation state in simple palladium compounds | |
| Fraser | The Effect of Chelation by Nonbridging Ligands on the Rate of Reduction of Cobalt (III) Sulfato and Acetato Complexes | |
| Li et al. | Stabilities of the 2-mercaptoethylamine complexes of trivalent metal ions and divalent metal ions in aqueous solution | |
| Cain et al. | Kinetics of aquation of cis-dibromobis (ethylenediamine) cobalt (III) cation | |
| Mustofy et al. | Kinetics and mechanism of anation of hydroxopentaaquo chromium (III) ion by L-histidine in water ethanol mixtures of different dielectric constant | |
| Boyd et al. | Molybdenum (IV) compounds for mediation of electron transfer. 1. Synthesis, characterization, and reactions of compounds containing molybddenum (IV) coordinated to trihalostannate (II) ions | |
| WATTS | Solvents and their role in determining inorganic mechanisms |