[go: up one dir, main page]

Roscoe et al., 1970 - Google Patents

Icosahedral carboranes. XIV. Preparation of boron-substituted carboranes by boron-insertion reaction

Roscoe et al., 1970

Document ID
482184980360881687
Author
Roscoe J
Kongpricha S
Papetti S
Publication year
Publication venue
Inorganic Chemistry

External Links

Snippet

[(CH3) 3NH][0-B9C2H12], prepared according to the Hawthorne method, 10 was converted to the dilithio derivative, Lisjo-BgCsHn], by treatment with butyl-lithium. This is advantageous over the treatment with sodium hydride11 in that butyllithium is easier to handle than sodium …
Continue reading at pubs.acs.org (other versions)

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F5/00—Compounds containing elements of Groups 3 or 13 of the Periodic System
    • C07F5/02—Boron compounds
    • C07F5/04—Esters of boric acids
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F7/00—Compounds containing elements of Groups 4 or 14 of the Periodic System
    • C07F7/02—Silicon compounds
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B35/00—Boron; Compounds thereof
    • C01B35/08—Compounds containing boron and nitrogen, phosphorus, oxygen, sulfur, selenium or tellurium
    • C01B35/10—Compounds containing boron and oxygen
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
    • C07C45/45—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by condensation
    • C07C45/46—Friedel-Crafts reactions
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F3/00—Compounds containing elements of Groups 2 or 12 of the Periodic System
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F9/00—Compounds containing elements of Groups 5 or 15 of the Periodic System
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F17/00—Metallocenes
    • C07F17/02—Metallocenes of metals of Groups 8, 9 or 10 of the Periodic System
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D213/00—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members
    • C07D213/02—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members having three double bonds between ring members or between ring members and non-ring members
    • C07D213/04—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members having three double bonds between ring members or between ring members and non-ring members having no bond between the ring nitrogen atom and a non-ring member or having only hydrogen or carbon atoms directly attached to the ring nitrogen atom
    • C07D213/06—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members having three double bonds between ring members or between ring members and non-ring members having no bond between the ring nitrogen atom and a non-ring member or having only hydrogen or carbon atoms directly attached to the ring nitrogen atom containing only hydrogen and carbon atoms in addition to the ring nitrogen atom
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B21/00—Nitrogen; Compounds thereof
    • C01B21/082—Compounds containing nitrogen and non-metals and optionally metals

Similar Documents

Publication Publication Date Title
Roscoe et al. Icosahedral carboranes. XIV. Preparation of boron-substituted carboranes by boron-insertion reaction
Haaf et al. Synthesis and reactivity of the stable silylene N, N'-di-tert-butyl-1, 3-diaza-2-sila-2-ylidene
Lee et al. Trivalent lanthanide chalcogenolates: synthesis, structure, and thermolysis chemistry
Graybill et al. The Preparation and Reactions of B9H13 (Ligand) Anions
Nöth et al. Hexakis (dimethylamino) cyclohexaborane, a boron (I) compound without electron deficiency
Smith et al. Synthesis of nido-and closo-arsacarboranes
Baudry et al. Pentadienyluranium borohydride complexes and their cyclopentadienyl analogues; crystal structures of (η-2, 4-Me2C5H5) U (BH4) 3 and (η-C5H5) U (BH4) 3
Razuvaev et al. Tricarbonylchromiumphenylboric acid
Beak et al. Dominance of the proximity effect of complexation over resonance and inductive effects in directing a metalation: regiospecific. beta. lithiation of N, N-diisopropylcyclohex-3-enecarboxamide and of N, N-diisopropyl-2-methylpent-3-enecarboxamide
Lawrence et al. Pentaborane (9) as a source for higher boron hydride systems. A new synthesis of nido-5, 6-dimethyl-5, 6-dicarbaoctaborane (10)
Landro et al. Synthesis of lithiomethanes (CH4− nLin) and characterization of the vapor species of lithiomethanes by flash vaporization mass spectroscopy
US3826820A (en) Preparation of non-solvated crystalline alpha-aluminum hydride
Wynne et al. Adducts of sulfur nitride with boron trihalides and antimony pentachloride
Melcher et al. Preparation and spectral characterization of unsymmetrically substituted borazines
Barabás et al. Heterocyclic organoboron compounds—VII: Chelated bis-(1, 3-diketonato) boronium salts with acetylacetone, benzoylacetone and dibenzoylmethane
US2822247A (en) Process for the synthesis of manganese carbonyl
US2992885A (en) Adducts of diborane with metal salts
US3098864A (en) Arylferrocenes and a process for preparing them
Keith et al. Ammonium perbromate
Gul'mamed et al. Metallocyclopentadienyl derivatives of bivalent samarium, europium and ytterbium
Rausch et al. SIGMA-BONDED ORGANIC DERIVATIVES OF HAFNIUM
Wochner et al. Molecular structure and chemical properties of a binuclear cyclopentadienylcobalt nitrosyl cation
Tiitta et al. Thermoanalytical studies on volatile complexes containing alkali metals
Woods et al. Triethylborane from Triethylaluminum and Borazines
Nesmeyanov et al. A Comparative 19F NMR study of electronic effects in some fluoroaryl compounds of antimony and bismuth and in their carbon and nitrogen analogues