WO2018010067A1 - Field-effect transistor and manufacturing method thereof - Google Patents
Field-effect transistor and manufacturing method thereof Download PDFInfo
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- WO2018010067A1 WO2018010067A1 PCT/CN2016/089644 CN2016089644W WO2018010067A1 WO 2018010067 A1 WO2018010067 A1 WO 2018010067A1 CN 2016089644 W CN2016089644 W CN 2016089644W WO 2018010067 A1 WO2018010067 A1 WO 2018010067A1
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- H01L21/02—Manufacture or treatment of semiconductor devices or of parts thereof
- H01L21/04—Manufacture or treatment of semiconductor devices or of parts thereof the devices having potential barriers, e.g. a PN junction, depletion layer or carrier concentration layer
- H01L21/18—Manufacture or treatment of semiconductor devices or of parts thereof the devices having potential barriers, e.g. a PN junction, depletion layer or carrier concentration layer the devices having semiconductor bodies comprising elements of Group IV of the Periodic Table or AIIIBV compounds with or without impurities, e.g. doping materials
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- the invention relates to the technical field of electronic components, in particular to a field effect transistor and a manufacturing method thereof.
- FETs Field Effect Transistors
- main structure includes a substrate, a channel layer disposed on the substrate, and disposed on both sides of the channel layer.
- the FET is usually fabricated by photolithography.
- a large gap (usually a few microns) is usually left between the gate and the source electrode (drain electrode).
- the uncovered channel layer between the gate and the source electrode (drain electrode) cannot be gate-modulated, and a parasitic resistance is formed on the unmodulated channel layer, so when the gap is large, the channel layer is formed.
- the parasitic resistance is also large, resulting in a decrease in the transconductance of the field effect transistor, a slower switching speed, and a reduced gain, which is extremely disadvantageous for the radio frequency application of the field effect transistor.
- a gap is usually left between the gate and the source electrode (drain electrode) in the existing field effect transistor, and the present invention provides the problem that the parasitic resistance is formed.
- a field effect transistor comprising: a substrate, a channel layer disposed on the substrate, and source electrodes disposed on the channel layer and respectively located on both sides of the channel layer And a drain electrode, an insulating layer disposed on the source electrode, the drain electrode, and the channel layer, and a gate disposed on the insulating layer, the gate being disposed at the source electrode and the drain Between the poles, the field effect transistor further includes a conductive thin film layer, the conductive thin film layer being located between the source electrode and the drain electrode, and the conductive thin film layer covering the gate electrode and at the source electrode and The insulating layer between the drain electrodes extends.
- a conductive thin film layer is formed on the insulating layer of the top surface of the gate, the side of the gate, and the source electrode and the drain electrode, and the conductive film is connected to the gate and at the source. Electrode and Extending on the insulating layer between the drain electrodes corresponds to increasing the gate length, reducing the gap between the gate and the source electrode (drain electrode), making it easier for the gate to modulate the channel layer, thereby reducing The parasitic resistance increases the transconductance of the device and improves the switching speed and gain of the field effect transistor.
- the channel layer is a two-dimensional crystalline material layer.
- the channel layer is implemented using a two-dimensional crystalline material layer, which improves the performance of the field effect transistor.
- the two-dimensional crystalline material layer is a transition metal sulfide layer, a graphene layer, or a black phosphorus layer.
- the conductive thin film layer is a graphene conductive thin film layer or a transition metal sulfide Conductive film layer.
- a gap exists between the conductive thin film layer and the source electrode, There is a gap between the conductive film layer and the drain electrode.
- a method of fabricating a field effect transistor comprising:
- a source electrode and a drain electrode on the channel layer, the source electrode and the drain electrode being respectively located on both sides of the channel layer;
- the conductive thin film layer is located between the source electrode and the drain electrode, and the conductive thin film layer covers the gate electrode and is between the source electrode and the drain electrode Extending on the insulating layer.
- a conductive thin film layer is formed on the insulating layer of the top surface of the gate, the side of the gate, and the source electrode and the drain electrode, and the conductive film is connected to the gate and at the source. Extending on the insulating layer between the electrode and the drain electrode, corresponding to increasing the gate length, reducing the gap between the gate and the source electrode (drain electrode), making it easier for the gate to modulate the channel layer, thereby The parasitic resistance is reduced, the transconductance of the device is increased, and the switching speed and gain of the field effect transistor are improved.
- the channel layer is a two-dimensional crystal material Material layer.
- the two-dimensional crystalline material layer is a transition metal sulfide layer, a graphene layer, or a black phosphorus layer.
- the substrate includes, but is not limited to, silicon, silicon oxide, boron nitride, etc., which can withstand high temperatures.
- the insulating layer includes, but is not limited to, a layer of a gate dielectric material that can withstand high temperatures, such as aluminum oxide or tantalum oxide.
- the source electrode, the drain electrode, and the gate electrode are electrodes formed of any one of the following metal materials or an alloy of any two or more kinds of metal materials: Pt, Ni, Au, and Cu.
- the forming the conductive thin film layer on the gate includes:
- a source gas is introduced during annealing, and the source gas is used to react under the catalytic action of the gate electrode to form the conductive thin film layer.
- the conductive thin film layer is a graphene conductive thin film layer or a transition metal sulfide conductive thin film layer.
- the annealing temperature is 900-1100 ° C, and the annealing time is 5-60 minutes.
- the source gas is argon gas, hydrogen gas, and methane, or argon gas, hydrogen gas, and Acetylene.
- the annealing temperature is 800-1050 ° C
- the annealing time is 10- 90 minutes.
- the source gas is argon gas, hydrogen sulfide, and transition group Metal oxides, or argon, hydrogen sulfide, and transition metal chlorides.
- forming a channel layer on the substrate comprises:
- a two-dimensional crystalline material layer is formed on the substrate using a micromechanical lift-off method.
- the forming the source electrode and the drain electrode on the channel layer comprises:
- the source electrode Forming the source electrode on the channel layer by an electron beam evaporation process and a lift-off Lift-off process And a drain electrode; or, the source electrode and the drain electrode are formed on the channel layer by a sputtering process and a Lift-off process.
- forming an insulating layer on the channel layer on which the source electrode and the drain electrode are formed comprises:
- the insulating layer is deposited on the channel layer on which the source and drain electrodes are formed using an atomic layer deposition ALD process.
- forming a gate on the insulating layer comprises:
- the gate is formed on the channel layer by an electron beam evaporation process and a lift-off Lift-off process; or the gate is formed on the channel layer by a sputtering process and a Lift-off process.
- FIG. 1 is a schematic structural diagram of a field effect transistor according to an embodiment of the present invention.
- FIG. 2 is a flow chart of a method for fabricating a field effect transistor according to an embodiment of the present invention
- 2a is a schematic structural diagram of a field effect transistor according to an embodiment of the present invention.
- 2b is a schematic structural view of a field effect transistor according to an embodiment of the present invention.
- 2c is a schematic structural diagram of a field effect transistor according to an embodiment of the present invention.
- 2d is a schematic structural diagram of a field effect transistor according to an embodiment of the present invention.
- 2e is a transfer characteristic diagram of a graphene field effect transistor according to an embodiment of the present invention.
- 2f is a transfer characteristic diagram of a graphene field effect transistor according to an embodiment of the present invention.
- FIG. 3 is a flow chart of another method for fabricating a field effect transistor according to an embodiment of the present invention.
- FIG. 4 is a flow chart of another method for fabricating a field effect transistor according to an embodiment of the present invention.
- the field effect transistor includes a substrate 101, a channel layer 102 disposed on the substrate 101, and is disposed in the trench.
- the source electrode 103 and the drain electrode 104 on the track layer 102 and on both sides of the channel layer 102, the insulating layer 105 disposed on the source electrode 103, the drain electrode 104, and the channel layer 102, and the insulating layer 105 are disposed on the insulating layer 105.
- the gate electrode 106 is disposed between the source electrode 103 and the drain electrode 104.
- the field effect transistor further includes a conductive thin film layer 107 between the source electrode 103 and the drain electrode 104, and the conductive thin film layer 107 simultaneously covers the gate electrode 106 and the insulating layer 105 between the source electrode 103 and the drain electrode 104. Extend.
- a conductive thin film layer 107 is formed on the top surface of the gate electrode 106, the side surface of the gate electrode 106, and the insulating layer 105 between the source electrode 103 and the drain electrode 104, and the conductive film is connected to the gate electrode 106. And extending over the insulating layer 105 between the source electrode 103 and the drain electrode 104, corresponding to increasing the length of the gate electrode 106, reducing the gap between the gate electrode 106 and the source electrode 103 (drain electrode 104), so that the gate 106 makes it easier to modulate the channel layer 102, thereby reducing parasitic resistance, increasing the transconductance of the device, and increasing the switching speed and gain of the field effect transistor.
- the substrate 101 includes, but is not limited to, silicon, silicon oxide, boron nitride, or the like which can withstand high temperatures. Since the field effect transistor structure to be formed needs to be annealed when the conductive thin film layer 107 is grown, the use of the high temperature resistant substrate 101 ensures the growth of the conductive thin film layer 107.
- a buffer layer may be disposed between the substrate 101 and the channel layer 102.
- the buffer layer is used to reduce the structural difference between the substrate 101 and the channel layer 102, so that the channel layer 102 can be formed.
- the buffer layer may be a silicon dioxide layer or the like.
- the channel layer 102 may be a two-dimensional crystalline material layer.
- the channel layer 102 is implemented by a two-dimensional crystalline material layer. Since the thickness of the two-dimensional crystalline material layer is small and the performance is stable, the two-dimensional crystalline material layer is used as the channel layer, thereby improving the performance of the field effect transistor.
- the two-dimensional crystalline material layer may be a transition metal sulfide layer (such as a molybdenum disulfide layer), a graphene layer or a black phosphorus layer, and the two-dimensional crystalline material layer has good electrical conductivity.
- a transition metal sulfide layer such as a molybdenum disulfide layer
- a graphene layer or a black phosphorus layer and the two-dimensional crystalline material layer has good electrical conductivity.
- the source electrode 103, the drain electrode 104, and the gate electrode 106 are electrodes formed of any one of the following metal materials or an alloy of two or more kinds of metal materials: platinum Pt, nickel Ni, gold Au, and copper Cu.
- the insulating layer 105 includes, but is not limited to, a layer of a gate dielectric material that can withstand high temperatures such as aluminum oxide, yttrium oxide, or the like. Since the field effect transistor structure to be formed needs to be annealed when the conductive thin film layer 107 is grown, the selection of the high temperature resistant insulating layer 105 ensures the growth of the conductive thin film layer 107.
- the conductive thin film layer 107 may be a graphene conductive thin film layer 107 or a transition metal sulfide conductive thin film layer 107.
- a gap between the conductive thin film layer 107 and the source electrode 103, and a gap exists between the conductive thin film layer 107 and the drain electrode 104.
- a gap is provided between the conductive thin film layer 107 and the source electrode 103 (drain electrode 104), so that leakage due to the quality of the insulating layer 105 is difficult to ensure.
- the gap between the conductive thin film layer 107 and the source electrode 103 (drain electrode 104) may be 2 to 10 nm.
- the field effect transistor provided by the embodiment of the present invention may include more or less film layers as long as the function of the field effect transistor can be realized.
- FIG. 2 is a flow chart of a method for fabricating a field effect transistor according to an embodiment of the present invention. The method is used to fabricate the field effect transistor shown in FIG. 1. Referring to FIG. 2, the method includes:
- Step 201 Providing a substrate.
- the substrate includes, but is not limited to, silicon, silicon oxide, boron nitride, etc., which can withstand high temperatures. Since the field effect transistor structure to be formed needs to be annealed when the conductive thin film layer is grown, the high temperature resistant substrate can be used to ensure the growth of the conductive thin film layer.
- Step 202 Form a channel layer on the substrate.
- the channel layer may be a two-dimensional crystalline material layer.
- Step 202 can include forming a two-dimensional crystalline material layer on the substrate using a micromechanical lift-off method.
- the two-dimensional crystalline material layer may be a transition metal sulfide layer (such as a molybdenum disulfide layer), a graphene layer or a black phosphorus layer, and the two-dimensional crystalline material layer has good electrical conductivity.
- a transition metal sulfide layer such as a molybdenum disulfide layer
- a graphene layer or a black phosphorus layer and the two-dimensional crystalline material layer has good electrical conductivity.
- the two-dimensional crystalline material layer can also be grown on the substrate by a gas phase process.
- a channel layer 102 is formed on the substrate 101.
- Step 203 forming a source electrode and a drain electrode on the channel layer, and the source electrode and the drain electrode are respectively located on both sides of the channel layer.
- Step 203 may include: forming a source electrode and a drain electrode on the channel layer by an electron beam evaporation process and a lift-off process; or forming a source electrode on the channel layer by a sputtering process and a Lift-off process; Leakage electrode.
- the source electrode and the drain electrode are electrodes formed of any one of the following metal materials or an alloy of two or more kinds of metal materials: Pt, Ni, Au, and Cu.
- a source electrode 103 and a drain electrode 104 are formed on the channel layer 102.
- Step 204 Form an insulating layer on the channel layer on which the active electrode and the drain electrode are formed.
- Step 204 may include: using Atomic Layer Deposition (ALD) The process deposits an insulating layer on the channel layer on which the active and drain electrodes are formed.
- ALD Atomic Layer Deposition
- the insulating layer includes, but is not limited to, a layer of a gate dielectric material that can withstand high temperatures such as aluminum oxide or tantalum oxide. Since the field effect transistor structure to be formed needs to be annealed when the conductive thin film layer is grown, the selection of the high temperature resistant insulating layer ensures the growth of the conductive thin film layer.
- the insulating layer 105 covers the source electrode 103, the drain electrode 104, and the channel layer 102.
- Step 205 forming a gate on the insulating layer, and the gate is disposed between the source electrode and the drain electrode.
- Step 205 may include forming a gate on the channel layer using an electron beam evaporation process and a lift-off Lift-off process; or forming a gate on the channel layer using a sputtering process and a Lift-off process.
- the gate is an electrode formed of any one of the following metal materials or an alloy of any two or more kinds of metal materials: Pt, Ni, Au, and Cu.
- a gate electrode 106 is formed on the insulating layer 105.
- Step 206 Form a conductive thin film layer on the gate electrode, the conductive thin film layer is located between the source electrode and the drain electrode, and the conductive thin film layer covers the gate electrode and extends on the insulating layer between the source electrode and the drain electrode.
- Step 206 may include annealing the field effect transistor structure formed with the gate electrode, introducing a source gas during annealing, forming a conductive thin film layer on the gate electrode, and the source gas is used for reacting under the catalytic action of the gate electrode to form a conductive layer. Film layer.
- the annealing temperature is 800-1200 ° C
- the annealing time is 5-90 minutes.
- the gate serves as a catalyst for the growth of the conductive thin film layer to form a conductive thin film layer under annealing.
- the length of the conductive film layer is related to the material, the annealing temperature and the time; for the conductive film layer of different materials, the relationship between the extension length and the annealing temperature and time can be obtained by prior testing. Thereby achieving precise control of the extension length of the conductive film layer.
- the length of extension of the conductive film is controlled by controlling the annealing time given the material and temperature.
- the conductive thin film layer may be a graphene conductive thin film layer or a transition metal sulfide conductive thin film layer.
- the gap between the conductive thin film layer and the source electrode (drain electrode) may be 2 to 10 nm.
- the conductive thin film layer 107 simultaneously covers the top surface of the gate electrode 106, the side surface of the gate electrode 106, and the insulating layer 105 between the source electrode 103 and the drain electrode 104.
- the field effect transistor fabricated in the embodiment of the present invention can increase the gate length to enable more regions of the channel layer to be modulated by the gate, thereby increasing the transconductance of the device, thereby improving the switching speed and gain of the field effect transistor. This effect can be verified by simulation, and the simulation results are shown in Figures 2e and 2f.
- a graphene field effect transistor (using a graphene layer as a channel layer) is used as a simulation object, and the graphene field effect is obtained when the length of the gate modulatable region (the length marked by a in FIG. 1) is 1 ⁇ m and 2 ⁇ m, respectively.
- the transfer characteristics of the transistor are shown in Figures 2e and 2f. It can be seen from FIG. 2e that the curve corresponding to the broken line is located above the curve corresponding to the solid line, that is, the working current Id of the graphene field effect transistor having the gate-modulable region of 2 ⁇ m is larger under the action of the same gate voltage VG; It can be seen from Fig.
- a conductive thin film layer is formed on the insulating layer of the top surface of the gate, the side of the gate, and the source electrode and the drain electrode, and the conductive film is connected to the gate electrode at the source electrode and the drain electrode.
- the extension between the insulating layers is equivalent to increasing the gate length, reducing the gap between the gate and the source electrode (drain electrode), making it easier for the gate to modulate the channel layer, thereby reducing parasitics.
- the resistor increases the transconductance of the device and increases the switching speed and gain of the field effect transistor.
- the field effect transistor only adds one step of annealing process to metal catalyzed to form a conductive thin film layer, does not introduce too many complicated processes, and has a simple manufacturing process.
- the channel layer of the field effect transistor prepared by the method is a transition metal sulfide layer, and the conductive film layer is a graphene conductive film layer.
- the method includes:
- Step 301 Providing a substrate.
- the substrate may be a Si substrate.
- the method further comprises: performing surface cleaning and heat treatment on the substrate.
- Step 302 deposit a buffer layer on the substrate.
- the buffer layer may be a silicon oxide layer or the like, and the silicon oxide layer may have a thickness of 300 nm.
- Step 303 Forming a transition metal sulfide layer by a micromechanical stripping method and transferring the transition metal sulfide layer to the buffer layer.
- Step 304 using an electron beam evaporation process on a buffer layer formed with a transition metal sulfide layer Plating Pt film.
- Step 305 The Pt film is processed by a Lift-off process to form a source electrode and a drain electrode.
- Step 306 depositing a layer of aluminum oxide as an insulating layer on the transition metal sulfide layer forming the active electrode and the drain electrode using an ALD process.
- Step 307 plating a Pt film on the insulating layer by an electron beam evaporation process.
- Step 308 The Pt film is processed by a Lift-off process to form a gate, and the gate is disposed between the source electrode and the drain electrode.
- Step 309 annealing the gate-forming field effect transistor structure, and introducing a source gas during annealing, and the source gas is used for reacting under the catalytic action of the gate electrode to form a graphene conductive film layer.
- the source gas may be argon, hydrogen and methane, or argon, hydrogen and acetylene.
- the annealing temperature may be from 900 to 1100 ° C, and the annealing time may be from 5 to 60 minutes. Preferably, the annealing temperature is 1000 ° C and the annealing time is 30 minutes.
- argon is a carrier gas
- hydrogen is a reducing gas
- methane or acetylene is a carbon source gas
- methane or acetylene cleaves carbon atoms to form graphene and epitaxy.
- the gate acts as a catalyst for graphene growth, and forms a graphene conductive thin film layer under annealing. Therefore, when the graphene grows, the gate surface and the vicinity region extend to the periphery, and the extension length and the annealing temperature are Time-dependent; during the growth of the graphene conductive film layer, the graphene conductive film extends slowly to the periphery, and the length of the graphene conductive film extension can be controlled by controlling the annealing time.
- the channel layer of the field effect transistor prepared by the method is a black phosphorus layer
- the conductive film layer is a transition metal oxide conductive film layer. Referring to Figure 4, the method includes:
- Step 401 Providing a substrate.
- the substrate may be a Si substrate.
- the method further comprises: performing surface cleaning and heat treatment on the substrate.
- Step 402 deposit a buffer layer on the substrate.
- the buffer layer may be a silicon oxide layer or the like, and the silicon oxide layer may have a thickness of 100 nm.
- Step 403 Forming a black phosphorus layer by a micromechanical stripping method and transferring the black phosphorus layer onto the buffer layer.
- Step 404 Au film is plated on the buffer layer on which the black phosphorus layer is formed by a sputtering process.
- Step 405 The Au film is processed by a Lift-off process to form a source electrode and a drain electrode.
- Step 406 depositing a layer of germanium dioxide as an insulating layer on the black phosphor layer forming the active electrode and the drain electrode using an ALD process.
- Step 407 Au film is plated on the insulating layer by a sputtering process.
- Step 408 The Au film is processed by a Lift-off process to form a gate, and the gate is disposed between the source electrode and the drain electrode.
- Step 409 annealing the gate-forming field effect transistor structure, and introducing a source gas during annealing, and the source gas is used for reacting under the catalytic action of the gate electrode to form a transition metal oxide conductive film layer.
- the source gas may be argon, hydrogen sulfide, and a transition metal oxide (such as MoO 3 ), or argon, hydrogen sulfide, and a transition metal chloride (such as MoCl 5 ).
- the annealing temperature may be 800-1050 ° C, and the annealing time may be 10-90 minutes. Preferably, the annealing temperature is 9000 ° C and the annealing time is 60 minutes.
- argon is a carrier gas, and under high temperature metal catalysis, hydrogen sulfide reacts with a transition metal oxide or a transition metal chloride to form a transition metal sulfide attached to the surface of the field effect transistor structure forming the gate and epitaxially grown.
- the gate acts as a catalyst for the growth of the transition metal oxide, forming a transition metal oxide conductive thin film layer under annealing, and thus the transition metal oxide grows from the gate surface and the vicinity to the periphery.
- the extension length is related to the annealing temperature and time; during the growth process of the transition metal oxide conductive film layer, the transition metal oxide conductive film extends slowly to the periphery, and the transition metal oxide can be controlled by controlling the annealing time. The length of the film extension.
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Abstract
Description
本发明涉及电子元器件技术领域,特别涉及一种场效应晶体管及其制作方法。The invention relates to the technical field of electronic components, in particular to a field effect transistor and a manufacturing method thereof.
场效应晶体管(Field Effect Transistors,简称FET)简称场效应管,是一种常见的电子元器件,其主要结构包括衬底,设置在衬底上的沟道层,设置在沟道层两侧的源电极和漏电极,设置在源电极、漏电极和沟道层上的绝缘层,以及设置在绝缘层上且位于源电极和漏电极之间的栅极。Field Effect Transistors (FETs), abbreviated as field effect transistors, are a common electronic component whose main structure includes a substrate, a channel layer disposed on the substrate, and disposed on both sides of the channel layer. A source electrode and a drain electrode, an insulating layer disposed on the source electrode, the drain electrode, and the channel layer, and a gate electrode disposed on the insulating layer between the source electrode and the drain electrode.
场效应管通常采用光刻工艺制作,在制作过程中,由于制作工艺的精度限制,栅极与源电极(漏电极)之间通常会留有较大的间隙(通常为几微米),由于处于栅极与源电极(漏电极)之间未被覆盖的沟道层不能被栅极调制,未被调制的沟道层上会形成寄生电阻,因此当上述间隙较大时,沟道层上形成的寄生电阻也较大,导致场效应晶体管的跨导减小、开关速度变慢、增益减小,对于场效应晶体管的射频应用极为不利。The FET is usually fabricated by photolithography. During the fabrication process, due to the precision of the fabrication process, a large gap (usually a few microns) is usually left between the gate and the source electrode (drain electrode). The uncovered channel layer between the gate and the source electrode (drain electrode) cannot be gate-modulated, and a parasitic resistance is formed on the unmodulated channel layer, so when the gap is large, the channel layer is formed. The parasitic resistance is also large, resulting in a decrease in the transconductance of the field effect transistor, a slower switching speed, and a reduced gain, which is extremely disadvantageous for the radio frequency application of the field effect transistor.
发明内容Summary of the invention
为了解决现有场效应晶体管中栅极与源电极(漏电极)之间通常会留有一定的间隙,处于该间隙下方的沟道层没有被栅极调制,形成寄生电阻的问题,本发明提供了一种场效应晶体管及其制作方法。In order to solve the problem that the channel layer under the gap is not modulated by the gate and the parasitic resistance is formed, a gap is usually left between the gate and the source electrode (drain electrode) in the existing field effect transistor, and the present invention provides the problem that the parasitic resistance is formed. A field effect transistor and a method of fabricating the same.
第一方面,提供了一种场效应晶体管,包括:衬底,设置在所述衬底上的沟道层,设置在所述沟道层上且分别位于所述沟道层两侧的源电极和漏电极,设置在所述源电极、所述漏电极和所述沟道层上的绝缘层,以及设置在所述绝缘层上的栅极,所述栅极设置在所述源电极和漏电极之间,所述场效应晶体管还包括导电薄膜层,所述导电薄膜层位于在所述源电极和漏电极之间,且所述导电薄膜层覆盖所述栅极并在所述源电极和漏电极之间的绝缘层上延伸。In a first aspect, a field effect transistor is provided, comprising: a substrate, a channel layer disposed on the substrate, and source electrodes disposed on the channel layer and respectively located on both sides of the channel layer And a drain electrode, an insulating layer disposed on the source electrode, the drain electrode, and the channel layer, and a gate disposed on the insulating layer, the gate being disposed at the source electrode and the drain Between the poles, the field effect transistor further includes a conductive thin film layer, the conductive thin film layer being located between the source electrode and the drain electrode, and the conductive thin film layer covering the gate electrode and at the source electrode and The insulating layer between the drain electrodes extends.
在本实施例中,通过在栅极的顶面、所述栅极的侧面以及所述源电极和漏电极之间的绝缘层上形成一导电薄膜层,该导电薄膜与栅极相连且在源电极和 漏电极之间的绝缘层上延伸,相当于增加了栅极长度,减小了栅极与源电极(漏电极)之间的间隙,使栅极更容易对沟道层进行调制,从而减小了寄生电阻,增加了器件的跨导,提升了场效应晶体管的开关速度与增益。In this embodiment, a conductive thin film layer is formed on the insulating layer of the top surface of the gate, the side of the gate, and the source electrode and the drain electrode, and the conductive film is connected to the gate and at the source. Electrode and Extending on the insulating layer between the drain electrodes corresponds to increasing the gate length, reducing the gap between the gate and the source electrode (drain electrode), making it easier for the gate to modulate the channel layer, thereby reducing The parasitic resistance increases the transconductance of the device and improves the switching speed and gain of the field effect transistor.
结合第一方面,在第一方面的第一实现方式中,所述沟道层为二维晶体材料层。In conjunction with the first aspect, in a first implementation of the first aspect, the channel layer is a two-dimensional crystalline material layer.
在该实现方式中,沟道层采用二维晶体材料层实现,提高了场效应晶体管的性能。In this implementation, the channel layer is implemented using a two-dimensional crystalline material layer, which improves the performance of the field effect transistor.
结合第一方面的第一实现方式,在第一方面的第二实现方式中,所述二维晶体材料层为过渡族金属硫化物层、石墨烯层或黑磷层。In conjunction with the first implementation of the first aspect, in the second implementation of the first aspect, the two-dimensional crystalline material layer is a transition metal sulfide layer, a graphene layer, or a black phosphorus layer.
结合第一方面或第一方面的第一实现方式或第一方面的第二实现方式,在第一方面的第三实现方式中,所述导电薄膜层为石墨烯导电薄膜层或过渡族金属硫化物导电薄膜层。In combination with the first aspect or the first implementation manner of the first aspect or the second implementation manner of the first aspect, in the third implementation manner of the first aspect, the conductive thin film layer is a graphene conductive thin film layer or a transition metal sulfide Conductive film layer.
结合第一方面或第一方面的第一实现方式至第三实现方式中的任一项,在第一方面的第四实现方式中,所述导电薄膜层与所述源电极之间存在间隙,所述导电薄膜层与所述漏电极之间存在间隙。In combination with the first aspect or the first implementation to the third implementation of the first aspect, in a fourth implementation manner of the first aspect, a gap exists between the conductive thin film layer and the source electrode, There is a gap between the conductive film layer and the drain electrode.
第二方面,提供了一种场效应晶体管制作方法,所述方法包括:In a second aspect, a method of fabricating a field effect transistor is provided, the method comprising:
提供一衬底;Providing a substrate;
在所述衬底上形成沟道层;Forming a channel layer on the substrate;
在所述沟道层上形成源电极和漏电极,所述源电极和漏电极分别位于所述沟道层两侧;Forming a source electrode and a drain electrode on the channel layer, the source electrode and the drain electrode being respectively located on both sides of the channel layer;
在形成有所述源电极和漏电极的所述沟道层上形成绝缘层;Forming an insulating layer on the channel layer on which the source electrode and the drain electrode are formed;
在所述绝缘层上形成栅极,所述栅极设置在所述源电极和漏电极之间;Forming a gate on the insulating layer, the gate being disposed between the source electrode and the drain electrode;
在所述栅极上形成导电薄膜层,所述导电薄膜层位于所述源电极和漏电极之间,且所述导电薄膜层覆盖所述栅极并在所述源电极和漏电极之间的绝缘层上延伸。Forming a conductive thin film layer on the gate, the conductive thin film layer is located between the source electrode and the drain electrode, and the conductive thin film layer covers the gate electrode and is between the source electrode and the drain electrode Extending on the insulating layer.
在本实施例中,通过在栅极的顶面、所述栅极的侧面以及所述源电极和漏电极之间的绝缘层上形成一导电薄膜层,该导电薄膜与栅极相连且在源电极和漏电极之间的绝缘层上延伸,相当于增加了栅极长度,减小了栅极与源电极(漏电极)之间的间隙,使栅极更容易对沟道层进行调制,从而减小了寄生电阻,增加了器件的跨导,提升了场效应晶体管的开关速度与增益。In this embodiment, a conductive thin film layer is formed on the insulating layer of the top surface of the gate, the side of the gate, and the source electrode and the drain electrode, and the conductive film is connected to the gate and at the source. Extending on the insulating layer between the electrode and the drain electrode, corresponding to increasing the gate length, reducing the gap between the gate and the source electrode (drain electrode), making it easier for the gate to modulate the channel layer, thereby The parasitic resistance is reduced, the transconductance of the device is increased, and the switching speed and gain of the field effect transistor are improved.
结合第二方面,在第二方面的第一实现方式中,所述沟道层为二维晶体材 料层。In conjunction with the second aspect, in the first implementation of the second aspect, the channel layer is a two-dimensional crystal material Material layer.
结合第二方面的第一实现方式,在第二方面的第二实现方式中,所述二维晶体材料层为过渡族金属硫化物层、石墨烯层或黑磷层。In conjunction with the first implementation of the second aspect, in the second implementation of the second aspect, the two-dimensional crystalline material layer is a transition metal sulfide layer, a graphene layer, or a black phosphorus layer.
其中,所述衬底包括但不限于硅、氧化硅、氮化硼等可以承受高温的衬底。Wherein, the substrate includes, but is not limited to, silicon, silicon oxide, boron nitride, etc., which can withstand high temperatures.
其中,所述绝缘层包括但不限于氧化铝、氧化铪等可以承受高温的栅介质材料层。The insulating layer includes, but is not limited to, a layer of a gate dielectric material that can withstand high temperatures, such as aluminum oxide or tantalum oxide.
其中,所述源电极、漏电极和栅极为下述任一金属材料或任意两种以上金属材料的合金形成的电极:Pt、Ni、Au、Cu。The source electrode, the drain electrode, and the gate electrode are electrodes formed of any one of the following metal materials or an alloy of any two or more kinds of metal materials: Pt, Ni, Au, and Cu.
结合第二方面或第二方面的第一实现方式或第二方面的第二实现方式,在第二方面的第三实现方式中,所述在所述栅极上形成导电薄膜层,包括:With the second aspect or the second implementation of the second aspect or the second implementation of the second aspect, in the third implementation of the second aspect, the forming the conductive thin film layer on the gate includes:
对形成所述栅极的场效应晶体管结构进行退火;Annealing the field effect transistor structure forming the gate;
退火时通入源气体,所述源气体用于在所述栅极的催化作用下反应,从而形成所述导电薄膜层。A source gas is introduced during annealing, and the source gas is used to react under the catalytic action of the gate electrode to form the conductive thin film layer.
结合第二方面的第三实现方式,在第二方面的第四实现方式中,所述导电薄膜层为石墨烯导电薄膜层或过渡族金属硫化物导电薄膜层。In conjunction with the third implementation of the second aspect, in the fourth implementation of the second aspect, the conductive thin film layer is a graphene conductive thin film layer or a transition metal sulfide conductive thin film layer.
结合第二方面的第四实现方式,在第二方面的第五实现方式中,所述导电薄膜层为石墨烯导电薄膜层时,退火温度为900-1100℃,退火时间为5-60分钟。In conjunction with the fourth implementation of the second aspect, in the fifth implementation manner of the second aspect, when the conductive thin film layer is a graphene conductive thin film layer, the annealing temperature is 900-1100 ° C, and the annealing time is 5-60 minutes.
结合第二方面的第四实现方式,在第二方面的第六实现方式中,所述导电薄膜层为石墨烯导电薄膜层时,源气体为氩气、氢气和甲烷,或者氩气、氢气和乙炔。With reference to the fourth implementation manner of the second aspect, in the sixth implementation manner of the second aspect, when the conductive thin film layer is a graphene conductive thin film layer, the source gas is argon gas, hydrogen gas, and methane, or argon gas, hydrogen gas, and Acetylene.
结合第二方面的第四实现方式,在第二方面的第七实现方式中,所述导电薄膜层为过渡族金属氧化物导电薄膜层时,退火温度为800-1050℃,退火时间为10-90分钟。With reference to the fourth implementation manner of the second aspect, in the seventh implementation manner of the second aspect, when the conductive thin film layer is a transition metal oxide conductive thin film layer, the annealing temperature is 800-1050 ° C, and the annealing time is 10- 90 minutes.
结合第二方面的第四实现方式,在第二方面的第八实现方式中,所述导电薄膜层为过渡族金属硫化物导电薄膜层时,所述源气体为氩气、硫化氢和过渡族金属氧化物,或者氩气、硫化氢和过渡族金属氯化物。With reference to the fourth implementation manner of the second aspect, in the eighth implementation manner of the second aspect, when the conductive thin film layer is a transition metal sulfide conductive thin film layer, the source gas is argon gas, hydrogen sulfide, and transition group Metal oxides, or argon, hydrogen sulfide, and transition metal chlorides.
其中,所述在所述衬底上形成沟道层,包括:Wherein the forming a channel layer on the substrate comprises:
采用微机械剥离方法在所述衬底上形成二维晶体材料层。A two-dimensional crystalline material layer is formed on the substrate using a micromechanical lift-off method.
其中,所述在所述沟道层上形成源电极和漏电极,包括:Wherein the forming the source electrode and the drain electrode on the channel layer comprises:
利用电子束蒸发工艺和剥离Lift-off工艺在所述沟道层上形成所述源电极 和漏电极;或者,利用溅射工艺和Lift-off工艺在所述沟道层上形成所述源电极和漏电极。Forming the source electrode on the channel layer by an electron beam evaporation process and a lift-off Lift-off process And a drain electrode; or, the source electrode and the drain electrode are formed on the channel layer by a sputtering process and a Lift-off process.
其中,所述在形成有所述源电极和漏电极的所述沟道层上形成绝缘层,包括:Wherein the forming an insulating layer on the channel layer on which the source electrode and the drain electrode are formed comprises:
使用原子层沉积ALD工艺在形成有所述源电极和漏电极的所述沟道层上沉积所述绝缘层。The insulating layer is deposited on the channel layer on which the source and drain electrodes are formed using an atomic layer deposition ALD process.
其中,所述在所述绝缘层上形成栅极,包括:Wherein the forming a gate on the insulating layer comprises:
利用电子束蒸发工艺和剥离Lift-off工艺在所述沟道层上形成所述栅极;或者,利用溅射工艺和Lift-off工艺在所述沟道层上形成所述栅极。The gate is formed on the channel layer by an electron beam evaporation process and a lift-off Lift-off process; or the gate is formed on the channel layer by a sputtering process and a Lift-off process.
为了更清楚地说明本发明实施例中的技术方案,下面将对实施例描述中所需要使用的附图作简单地介绍,显而易见地,下面描述中的附图仅仅是本发明的一些实施例,对于本领域普通技术人员来讲,在不付出创造性劳动的前提下,还可以根据这些附图获得其他的附图。In order to more clearly illustrate the technical solutions in the embodiments of the present invention, the drawings used in the description of the embodiments will be briefly described below. It is obvious that the drawings in the following description are only some embodiments of the present invention. Other drawings may also be obtained from those of ordinary skill in the art in light of the inventive work.
图1是本发明实施例提供的一种场效应晶体管的结构示意图;1 is a schematic structural diagram of a field effect transistor according to an embodiment of the present invention;
图2是本发明实施例提供的一种场效应晶体管制作方法的流程图;2 is a flow chart of a method for fabricating a field effect transistor according to an embodiment of the present invention;
图2a是本发明实施例提供的场效应晶体管制作过程中的结构示意图;2a is a schematic structural diagram of a field effect transistor according to an embodiment of the present invention;
图2b是本发明实施例提供的场效应晶体管制作过程中的结构示意图;2b is a schematic structural view of a field effect transistor according to an embodiment of the present invention;
图2c是本发明实施例提供的场效应晶体管制作过程中的结构示意图;2c is a schematic structural diagram of a field effect transistor according to an embodiment of the present invention;
图2d是本发明实施例提供的场效应晶体管制作过程中的结构示意图;2d is a schematic structural diagram of a field effect transistor according to an embodiment of the present invention;
图2e是本发明实施例提供的一种石墨烯场效应晶体管的转移特性曲线图;2e is a transfer characteristic diagram of a graphene field effect transistor according to an embodiment of the present invention;
图2f是本发明实施例提供的一种石墨烯场效应晶体管的转移特性曲线图;2f is a transfer characteristic diagram of a graphene field effect transistor according to an embodiment of the present invention;
图3是本发明实施例提供的另一种场效应晶体管制作方法的流程图;3 is a flow chart of another method for fabricating a field effect transistor according to an embodiment of the present invention;
图4是本发明实施例提供的另一种场效应晶体管制作方法的流程图。4 is a flow chart of another method for fabricating a field effect transistor according to an embodiment of the present invention.
为使本发明的目的、技术方案和优点更加清楚,下面将结合附图对本发明实施方式作进一步地详细描述。The embodiments of the present invention will be further described in detail below with reference to the accompanying drawings.
图1是本发明实施例提供的一种场效应晶体管的结构示意图,参见图1,该场效应晶体管包括:衬底101,设置在衬底101上的沟道层102,设置在沟
道层102上且分别位于沟道层102两侧的源电极103和漏电极104,设置在源电极103、漏电极104和沟道层102上的绝缘层105,以及设置在绝缘层105上的栅极106,栅极106设置在源电极103和漏电极104之间。场效应晶体管还包括导电薄膜层107,导电薄膜层107位于源电极103和漏电极104之间,且导电薄膜层107同时覆盖栅极106并在源电极103和漏电极104之间的绝缘层105上延伸。1 is a schematic structural diagram of a field effect transistor according to an embodiment of the present invention. Referring to FIG. 1, the field effect transistor includes a
在本实施例中,通过在栅极106的顶面、栅极106的侧面以及源电极103和漏电极104之间的绝缘层105上形成一导电薄膜层107,该导电薄膜与栅极106相连且在源电极103和漏电极104之间的绝缘层105上延伸,相当于增加了栅极106长度,减小了栅极106与源电极103(漏电极104)之间的间隙,使栅极106更容易对沟道层102进行调制,从而减小了寄生电阻,增加了器件的跨导,提升了场效应晶体管的开关速度与增益。In the present embodiment, a conductive
在本发明实施例中,衬底101包括但不限于硅、氧化硅、氮化硼等可以承受高温的衬底。由于导电薄膜层107生长时,需要对以形成的场效应晶体管结构进行退火,因此选用耐高温的衬底101可以保证导电薄膜层107生长。In the embodiment of the present invention, the
可选地,当衬底101和沟道层102之间还可以设置一层缓冲层,缓冲层用于减小衬底101和沟道层102之间的结构差异,使沟道层102能够形成在衬底101上,该缓冲层可以为二氧化硅层等。Optionally, a buffer layer may be disposed between the
在本发明实施例中,沟道层102可以为二维晶体材料层。在该实现方式中,沟道层102采用二维晶体材料层实现,由于二维晶体材料层厚度小,性能稳定,因此采用二维晶体材料层作为沟道层,提高了场效应晶体管的性能。In an embodiment of the invention, the
具体地,二维晶体材料层可以为过渡族金属硫化物层(如二硫化钼层)、石墨烯层或黑磷层,上述二维晶体材料层具有良好的导电性。Specifically, the two-dimensional crystalline material layer may be a transition metal sulfide layer (such as a molybdenum disulfide layer), a graphene layer or a black phosphorus layer, and the two-dimensional crystalline material layer has good electrical conductivity.
在本发明实施例中,源电极103、漏电极104、栅极106为下述任一金属材料或任意两种以上金属材料的合金形成的电极:铂Pt、镍Ni、金Au、铜Cu。In the embodiment of the present invention, the
在本发明实施例中,绝缘层105包括但不限于氧化铝、氧化铪等可以承受高温的栅介质材料层。由于导电薄膜层107生长时,需要对以形成的场效应晶体管结构进行退火,因此选用耐高温的绝缘层105可以保证导电薄膜层107生长。In the embodiment of the present invention, the insulating
在本发明实施例中,导电薄膜层107可以为石墨烯导电薄膜层107或过渡族金属硫化物导电薄膜层107。
In the embodiment of the present invention, the conductive
可选地,导电薄膜层107与源电极103之间存在间隙,导电薄膜层107与漏电极104之间存在间隙。在导电薄膜层107与源电极103(漏电极104)之间设置间隙,可以避免由于绝缘层105质量难以保证,造成的漏电现象。Optionally, there is a gap between the conductive
具体地,导电薄膜层107与源电极103(漏电极104)之间的间隙可以为2至10nm。Specifically, the gap between the conductive
本发明实施例提供的场效应晶体管可以包括更多或更少的膜层,只要能够实现场效应晶体管的功能即可。The field effect transistor provided by the embodiment of the present invention may include more or less film layers as long as the function of the field effect transistor can be realized.
图2是本发明实施例提供的一种场效应晶体管制作方法的流程图,该方法用于制作图1所示的场效应晶体管,参见图2,方法包括:2 is a flow chart of a method for fabricating a field effect transistor according to an embodiment of the present invention. The method is used to fabricate the field effect transistor shown in FIG. 1. Referring to FIG. 2, the method includes:
步骤201:提供一衬底。Step 201: Providing a substrate.
其中,衬底包括但不限于硅、氧化硅、氮化硼等可以承受高温的衬底。由于导电薄膜层生长时,需要对以形成的场效应晶体管结构进行退火,因此选用耐高温的衬底可以保证导电薄膜层生长。The substrate includes, but is not limited to, silicon, silicon oxide, boron nitride, etc., which can withstand high temperatures. Since the field effect transistor structure to be formed needs to be annealed when the conductive thin film layer is grown, the high temperature resistant substrate can be used to ensure the growth of the conductive thin film layer.
步骤202:在衬底上形成沟道层。Step 202: Form a channel layer on the substrate.
其中,沟道层可以为二维晶体材料层。则步骤202可以包括:采用微机械剥离方法在衬底上形成二维晶体材料层。Wherein, the channel layer may be a two-dimensional crystalline material layer. Step 202 can include forming a two-dimensional crystalline material layer on the substrate using a micromechanical lift-off method.
具体地,二维晶体材料层可以为过渡族金属硫化物层(如二硫化钼层)、石墨烯层或黑磷层,上述二维晶体材料层具有良好的导电性。Specifically, the two-dimensional crystalline material layer may be a transition metal sulfide layer (such as a molybdenum disulfide layer), a graphene layer or a black phosphorus layer, and the two-dimensional crystalline material layer has good electrical conductivity.
在其他实施例中,二维晶体材料层还可以通过气相方法在衬底上生长。In other embodiments, the two-dimensional crystalline material layer can also be grown on the substrate by a gas phase process.
如图2a所示,衬底101上形成有沟道层102。As shown in FIG. 2a, a
步骤203:在沟道层上形成源电极和漏电极,源电极和漏电极分别位于沟道层两侧。Step 203: forming a source electrode and a drain electrode on the channel layer, and the source electrode and the drain electrode are respectively located on both sides of the channel layer.
步骤203可以包括:利用电子束蒸发工艺和剥离(Lift-off)工艺在沟道层上形成源电极和漏电极;或者,利用溅射工艺和Lift-off工艺在沟道层上形成源电极和漏电极。Step 203 may include: forming a source electrode and a drain electrode on the channel layer by an electron beam evaporation process and a lift-off process; or forming a source electrode on the channel layer by a sputtering process and a Lift-off process; Leakage electrode.
其中,源电极、漏电极为下述任一金属材料或任意两种以上金属材料的合金形成的电极:Pt、Ni、Au、Cu。The source electrode and the drain electrode are electrodes formed of any one of the following metal materials or an alloy of two or more kinds of metal materials: Pt, Ni, Au, and Cu.
如图2b所示,沟道层102上形成有源电极103和漏电极104。As shown in FIG. 2b, a
步骤204:在形成有源电极和漏电极的沟道层上形成绝缘层。Step 204: Form an insulating layer on the channel layer on which the active electrode and the drain electrode are formed.
步骤204可以包括:使用原子层沉积(Atomic Layer Deposition,简称ALD) 工艺在形成有源电极和漏电极的沟道层上沉积绝缘层。Step 204 may include: using Atomic Layer Deposition (ALD) The process deposits an insulating layer on the channel layer on which the active and drain electrodes are formed.
其中,绝缘层包括但不限于氧化铝、氧化铪等可以承受高温的栅介质材料层。由于导电薄膜层生长时,需要对以形成的场效应晶体管结构进行退火,因此选用耐高温的绝缘层可以保证导电薄膜层生长。The insulating layer includes, but is not limited to, a layer of a gate dielectric material that can withstand high temperatures such as aluminum oxide or tantalum oxide. Since the field effect transistor structure to be formed needs to be annealed when the conductive thin film layer is grown, the selection of the high temperature resistant insulating layer ensures the growth of the conductive thin film layer.
如图2c所示,绝缘层105覆盖源电极103、漏电极104和沟道层102。As shown in FIG. 2c, the insulating
步骤205:在绝缘层上形成栅极,栅极设置在源电极和漏电极之间。Step 205: forming a gate on the insulating layer, and the gate is disposed between the source electrode and the drain electrode.
步骤205可以包括:利用电子束蒸发工艺和剥离Lift-off工艺在沟道层上形成栅极;或者,利用溅射工艺和Lift-off工艺在沟道层上形成栅极。Step 205 may include forming a gate on the channel layer using an electron beam evaporation process and a lift-off Lift-off process; or forming a gate on the channel layer using a sputtering process and a Lift-off process.
其中,栅极为下述任一金属材料或任意两种以上金属材料的合金形成的电极:Pt、Ni、Au、Cu。The gate is an electrode formed of any one of the following metal materials or an alloy of any two or more kinds of metal materials: Pt, Ni, Au, and Cu.
如图2d所示,绝缘层105上形成有栅极106。As shown in FIG. 2d, a
步骤206:在栅极上形成导电薄膜层,导电薄膜层位于源电极和漏电极之间,且导电薄膜层覆盖栅极并在源电极和漏电极之间的绝缘层上延伸。Step 206: Form a conductive thin film layer on the gate electrode, the conductive thin film layer is located between the source electrode and the drain electrode, and the conductive thin film layer covers the gate electrode and extends on the insulating layer between the source electrode and the drain electrode.
步骤206可以包括:对形成有栅极的场效应晶体管结构进行退火,退火时通入源气体,在栅极上形成导电薄膜层,源气体用于在栅极的催化作用下反应,从而形成导电薄膜层。在上述过程中,退火温度为800-1200℃,退火时间为5-90分钟。在该过程中,栅极作为导电薄膜层生长的催化剂,在退火作用下形成导电薄膜层。由于栅极表面及附近区域向周围延伸,且导电薄膜层的延伸长度与材料、退火温度和时间相关;因此对于不同材料的导电薄膜层,可以通过事先测试得到延伸长度与退火温度和时间的关系,从而实现导电薄膜层的延伸长度的精确控制。例如,在给定材料和温度的情况下,通过控制退火时间来控制导电薄膜延伸的长度。Step 206 may include annealing the field effect transistor structure formed with the gate electrode, introducing a source gas during annealing, forming a conductive thin film layer on the gate electrode, and the source gas is used for reacting under the catalytic action of the gate electrode to form a conductive layer. Film layer. In the above process, the annealing temperature is 800-1200 ° C, and the annealing time is 5-90 minutes. In this process, the gate serves as a catalyst for the growth of the conductive thin film layer to form a conductive thin film layer under annealing. Since the surface of the gate and the vicinity of the gate extend to the periphery, and the length of the conductive film layer is related to the material, the annealing temperature and the time; for the conductive film layer of different materials, the relationship between the extension length and the annealing temperature and time can be obtained by prior testing. Thereby achieving precise control of the extension length of the conductive film layer. For example, the length of extension of the conductive film is controlled by controlling the annealing time given the material and temperature.
在退火过程中,也会减少源电极和漏电极表面缺陷和杂质,降低其与沟道之间的接触电阻。During the annealing process, surface and drain electrode defects and impurities are also reduced, and the contact resistance between the source and the drain is reduced.
其中,导电薄膜层可以为石墨烯导电薄膜层或过渡族金属硫化物导电薄膜层。The conductive thin film layer may be a graphene conductive thin film layer or a transition metal sulfide conductive thin film layer.
可选地,导电薄膜层与源电极之间存在间隙,导电薄膜层与漏电极之间存在间隙。Optionally, there is a gap between the conductive film layer and the source electrode, and a gap exists between the conductive film layer and the drain electrode.
具体地,导电薄膜层与源电极(漏电极)之间的间隙可以为2至10nm。Specifically, the gap between the conductive thin film layer and the source electrode (drain electrode) may be 2 to 10 nm.
如图1所示,导电薄膜层107同时覆盖在栅极106的顶面、栅极106的侧面以及源电极103和漏电极104之间的绝缘层105上。
As shown in FIG. 1, the conductive
本发明实施例制作的场效应晶体管,在增加了栅极长度后,使沟道层更多的区域能够被栅极调制,增加器件的跨导,从而提升了场效应晶体管的开关速度与增益,该效果可以通过仿真进行验证,仿真结果如图2e和2f所示。The field effect transistor fabricated in the embodiment of the present invention can increase the gate length to enable more regions of the channel layer to be modulated by the gate, thereby increasing the transconductance of the device, thereby improving the switching speed and gain of the field effect transistor. This effect can be verified by simulation, and the simulation results are shown in Figures 2e and 2f.
具体以石墨烯场效应晶体管(采用石墨烯层作为沟道层)作为仿真对象,在栅极可调制区域长度(如图1中a所标记的长度)分别为1μm和2μm时,石墨烯场效应晶体管的转移特性曲线如图2e和2f所示。根据图2e可以看出,虚线对应的曲线位于实线对应的曲线的上方,即在相同栅极电压VG作用下,具有2μm栅极可调制区域的石墨烯场效应晶体管的工作电流Id更大;根据图2f可以看出,在栅极电压VG相同时,虚线对应的曲线的绝对值大于实线对应的曲线的绝对值,即在相同栅极电压VG作用下,具有2μm栅极可调制区域的石墨烯场效应晶体管的跨导更大。因此,栅极长度较大时,石墨烯场效应晶体管的工作电流和跨导也都较大,性能好。Specifically, a graphene field effect transistor (using a graphene layer as a channel layer) is used as a simulation object, and the graphene field effect is obtained when the length of the gate modulatable region (the length marked by a in FIG. 1) is 1 μm and 2 μm, respectively. The transfer characteristics of the transistor are shown in Figures 2e and 2f. It can be seen from FIG. 2e that the curve corresponding to the broken line is located above the curve corresponding to the solid line, that is, the working current Id of the graphene field effect transistor having the gate-modulable region of 2 μm is larger under the action of the same gate voltage VG; It can be seen from Fig. 2f that, when the gate voltage VG is the same, the absolute value of the curve corresponding to the broken line is larger than the absolute value of the curve corresponding to the solid line, that is, with the gate-modulable region of 2 μm under the action of the same gate voltage VG. The transconductance of graphene field effect transistors is larger. Therefore, when the gate length is large, the working current and the transconductance of the graphene field effect transistor are also large, and the performance is good.
在本实施例中,通过在栅极的顶面、栅极的侧面以及源电极和漏电极之间的绝缘层上形成一导电薄膜层,该导电薄膜与栅极相连且在源电极和漏电极之间的绝缘层上延伸,相当于增加了栅极长度,减小了栅极与源电极(漏电极)之间的间隙,使栅极更容易对沟道层进行调制,从而减小了寄生电阻,增加了器件的跨导,提升了场效应晶体管的开关速度与增益。另外,该场效应晶体管相比传统的场效应晶体管制备流程,只增加一步退火过程来进行金属催化形成导电薄膜层,不引入过多的复杂工艺,制作工艺简单。In this embodiment, a conductive thin film layer is formed on the insulating layer of the top surface of the gate, the side of the gate, and the source electrode and the drain electrode, and the conductive film is connected to the gate electrode at the source electrode and the drain electrode. The extension between the insulating layers is equivalent to increasing the gate length, reducing the gap between the gate and the source electrode (drain electrode), making it easier for the gate to modulate the channel layer, thereby reducing parasitics. The resistor increases the transconductance of the device and increases the switching speed and gain of the field effect transistor. In addition, compared with the conventional field effect transistor fabrication process, the field effect transistor only adds one step of annealing process to metal catalyzed to form a conductive thin film layer, does not introduce too many complicated processes, and has a simple manufacturing process.
图3是本发明实施例提供的另一种场效应晶体管制作方法的流程图,该方法制备的场效应晶体管的沟道层为过渡族金属硫化物层,导电薄膜层为石墨烯导电薄膜层,参见图3,方法包括:3 is a flow chart of another method for fabricating a field effect transistor according to an embodiment of the present invention. The channel layer of the field effect transistor prepared by the method is a transition metal sulfide layer, and the conductive film layer is a graphene conductive film layer. Referring to Figure 3, the method includes:
步骤301:提供一衬底。Step 301: Providing a substrate.
其中,衬底可以为Si衬底。Wherein, the substrate may be a Si substrate.
在步骤301之前,该方法还包括:对衬底进行表面清洁及热处理。Before the
步骤302:在衬底上沉积一层缓冲层。Step 302: deposit a buffer layer on the substrate.
其中,该缓冲层可以为氧化硅层等,氧化硅层厚度可以为300nm。The buffer layer may be a silicon oxide layer or the like, and the silicon oxide layer may have a thickness of 300 nm.
步骤303:采用微机械剥离方法形成过渡族金属硫化物层,并将过渡族金属硫化物层转移至缓冲层上。Step 303: Forming a transition metal sulfide layer by a micromechanical stripping method and transferring the transition metal sulfide layer to the buffer layer.
步骤304:利用电子束蒸发工艺在形成有过渡族金属硫化物层的缓冲层上 镀Pt膜。Step 304: using an electron beam evaporation process on a buffer layer formed with a transition metal sulfide layer Plating Pt film.
步骤305:采用Lift-off工艺处理Pt膜形成源电极和漏电极。Step 305: The Pt film is processed by a Lift-off process to form a source electrode and a drain electrode.
步骤306:使用ALD工艺在形成有源电极和漏电极的过渡族金属硫化物层上沉积一层氧化铝作为绝缘层。Step 306: depositing a layer of aluminum oxide as an insulating layer on the transition metal sulfide layer forming the active electrode and the drain electrode using an ALD process.
步骤307:利用电子束蒸发工艺在绝缘层上镀Pt膜。Step 307: plating a Pt film on the insulating layer by an electron beam evaporation process.
步骤308:采用Lift-off工艺处理Pt膜形成栅极,栅极设置在源电极和漏电极之间。Step 308: The Pt film is processed by a Lift-off process to form a gate, and the gate is disposed between the source electrode and the drain electrode.
步骤309:对形成栅极的场效应晶体管结构进行退火,退火时通入源气体,源气体用于在栅极的催化作用下反应,从而形成石墨烯导电薄膜层。Step 309: annealing the gate-forming field effect transistor structure, and introducing a source gas during annealing, and the source gas is used for reacting under the catalytic action of the gate electrode to form a graphene conductive film layer.
其中,源气体可以为氩气、氢气和甲烷,或者氩气、氢气和乙炔。退火温度可以为900-1100℃,退火时间可以为5-60分钟。优选地,退火温度为1000℃,退火时间为30分钟。反应中,氩气为载气,氢气为还原气体,甲烷或乙炔为碳源气体,高温金属催化下,甲烷或乙炔裂解出碳原子,从而形成石墨烯并外延。Wherein, the source gas may be argon, hydrogen and methane, or argon, hydrogen and acetylene. The annealing temperature may be from 900 to 1100 ° C, and the annealing time may be from 5 to 60 minutes. Preferably, the annealing temperature is 1000 ° C and the annealing time is 30 minutes. In the reaction, argon is a carrier gas, hydrogen is a reducing gas, methane or acetylene is a carbon source gas, and under high temperature metal catalysis, methane or acetylene cleaves carbon atoms to form graphene and epitaxy.
在该过程中,栅极作为石墨烯生长的催化剂,在退火作用下形成石墨烯导电薄膜层,因而石墨烯生长时,由栅极表面及附近区域向周围延伸,且延伸长度与与退火温度和时间相关;在石墨烯导电薄膜层生长的过程,石墨烯导电薄膜向周围延伸速度缓慢,可以通过控制退火时间来控制石墨烯导电薄膜延伸的长度。In this process, the gate acts as a catalyst for graphene growth, and forms a graphene conductive thin film layer under annealing. Therefore, when the graphene grows, the gate surface and the vicinity region extend to the periphery, and the extension length and the annealing temperature are Time-dependent; during the growth of the graphene conductive film layer, the graphene conductive film extends slowly to the periphery, and the length of the graphene conductive film extension can be controlled by controlling the annealing time.
图4是本发明实施例提供的另一种场效应晶体管制作方法的流程图,该方法制备的场效应晶体管的沟道层为黑磷层,导电薄膜层为过渡族金属氧化物导电薄膜层,参见图4,方法包括:4 is a flow chart of another method for fabricating a field effect transistor according to an embodiment of the present invention. The channel layer of the field effect transistor prepared by the method is a black phosphorus layer, and the conductive film layer is a transition metal oxide conductive film layer. Referring to Figure 4, the method includes:
步骤401:提供一衬底。Step 401: Providing a substrate.
其中,衬底可以为Si衬底。Wherein, the substrate may be a Si substrate.
在步骤401之前,该方法还包括:对衬底进行表面清洁及热处理。Before the
步骤402:在衬底上沉积一层缓冲层。Step 402: deposit a buffer layer on the substrate.
其中,该缓冲层可以为氧化硅层等,氧化硅层厚度可以为100nm。The buffer layer may be a silicon oxide layer or the like, and the silicon oxide layer may have a thickness of 100 nm.
步骤403:采用微机械剥离方法形成黑磷层,并将黑磷层转移至缓冲层上。Step 403: Forming a black phosphorus layer by a micromechanical stripping method and transferring the black phosphorus layer onto the buffer layer.
步骤404:利用溅射工艺在形成有黑磷层的缓冲层上镀Au膜。Step 404: Au film is plated on the buffer layer on which the black phosphorus layer is formed by a sputtering process.
步骤405:采用Lift-off工艺处理Au膜形成源电极和漏电极。 Step 405: The Au film is processed by a Lift-off process to form a source electrode and a drain electrode.
步骤406:使用ALD工艺在形成有源电极和漏电极的黑磷层上沉积一层二氧化铪作为绝缘层。Step 406: depositing a layer of germanium dioxide as an insulating layer on the black phosphor layer forming the active electrode and the drain electrode using an ALD process.
步骤407:利用溅射工艺在绝缘层上镀Au膜。Step 407: Au film is plated on the insulating layer by a sputtering process.
步骤408:采用Lift-off工艺处理Au膜形成栅极,栅极设置在源电极和漏电极之间。Step 408: The Au film is processed by a Lift-off process to form a gate, and the gate is disposed between the source electrode and the drain electrode.
步骤409:对形成栅极的场效应晶体管结构进行退火,退火时通入源气体,源气体用于在栅极的催化作用下反应,从而形成过渡族金属氧化物导电薄膜层。Step 409: annealing the gate-forming field effect transistor structure, and introducing a source gas during annealing, and the source gas is used for reacting under the catalytic action of the gate electrode to form a transition metal oxide conductive film layer.
其中,源气体可以为氩气、硫化氢和过渡族金属氧化物(如MoO3),或者氩气、硫化氢和过渡族金属氯化物(如MoCl5)。退火温度可以为800-1050℃,退火时间可以为10-90分钟。优选地,退火温度为9000℃,退火时间为60分钟。反应中,氩气为载气,高温金属催化下,硫化氢与过渡族金属氧化物或过渡族金属氯化物反应生成过渡族金属硫化物附着于形成栅极的场效应晶体管结构表面并外延生长。The source gas may be argon, hydrogen sulfide, and a transition metal oxide (such as MoO 3 ), or argon, hydrogen sulfide, and a transition metal chloride (such as MoCl 5 ). The annealing temperature may be 800-1050 ° C, and the annealing time may be 10-90 minutes. Preferably, the annealing temperature is 9000 ° C and the annealing time is 60 minutes. In the reaction, argon is a carrier gas, and under high temperature metal catalysis, hydrogen sulfide reacts with a transition metal oxide or a transition metal chloride to form a transition metal sulfide attached to the surface of the field effect transistor structure forming the gate and epitaxially grown.
在该过程中,栅极作为过渡族金属氧化物生长的催化剂,在退火作用下形成过渡族金属氧化物导电薄膜层,因而过渡族金属氧化物生长时,由栅极表面及附近区域向周围延伸,且延伸长度与退火温度和时间相关;在过渡族金属氧化物导电薄膜层生长的过程,过渡族金属氧化物导电薄膜向周围延伸速度缓慢,可以通过控制退火时间来控制过渡族金属氧化物导电薄膜延伸的长度。In this process, the gate acts as a catalyst for the growth of the transition metal oxide, forming a transition metal oxide conductive thin film layer under annealing, and thus the transition metal oxide grows from the gate surface and the vicinity to the periphery. And the extension length is related to the annealing temperature and time; during the growth process of the transition metal oxide conductive film layer, the transition metal oxide conductive film extends slowly to the periphery, and the transition metal oxide can be controlled by controlling the annealing time. The length of the film extension.
以上所述仅为本发明的较佳实施例,但本发明的保护范围并不局限于此,任何熟悉本技术领域的技术人员在本发明揭露的技术范围内,可轻易想到的变化或替换,都应涵盖在本发明的保护范围之内。因此,本发明的保护范围应该以权利要求的保护范围为准。 The above is only the preferred embodiment of the present invention, but the scope of the present invention is not limited thereto, and any change or replacement that can be easily conceived by those skilled in the art within the technical scope of the present disclosure is All should be covered by the scope of the present invention. Therefore, the scope of protection of the present invention should be determined by the scope of the claims.
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| CN103000669A (en) * | 2011-09-09 | 2013-03-27 | 中国科学院微电子研究所 | Source-drain buried graphene transistor device on diamond-like carbon substrate and manufacturing method |
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