WO2008084495A2 - Novel agricultural composition - Google Patents
Novel agricultural composition Download PDFInfo
- Publication number
- WO2008084495A2 WO2008084495A2 PCT/IN2007/000518 IN2007000518W WO2008084495A2 WO 2008084495 A2 WO2008084495 A2 WO 2008084495A2 IN 2007000518 W IN2007000518 W IN 2007000518W WO 2008084495 A2 WO2008084495 A2 WO 2008084495A2
- Authority
- WO
- WIPO (PCT)
- Prior art keywords
- composition
- agricultural composition
- salts
- range
- naphthalene
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Ceased
Links
Classifications
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N31/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic oxygen or sulfur compounds
-
- C—CHEMISTRY; METALLURGY
- C05—FERTILISERS; MANUFACTURE THEREOF
- C05D—INORGANIC FERTILISERS NOT COVERED BY SUBCLASSES C05B, C05C; FERTILISERS PRODUCING CARBON DIOXIDE
- C05D9/00—Other inorganic fertilisers
-
- C—CHEMISTRY; METALLURGY
- C05—FERTILISERS; MANUFACTURE THEREOF
- C05G—MIXTURES OF FERTILISERS COVERED INDIVIDUALLY BY DIFFERENT SUBCLASSES OF CLASS C05; MIXTURES OF ONE OR MORE FERTILISERS WITH MATERIALS NOT HAVING A SPECIFIC FERTILISING ACTIVITY, e.g. PESTICIDES, SOIL-CONDITIONERS, WETTING AGENTS; FERTILISERS CHARACTERISED BY THEIR FORM
- C05G5/00—Fertilisers characterised by their form
- C05G5/10—Solid or semi-solid fertilisers, e.g. powders
- C05G5/14—Tablets, spikes, rods, blocks or balls
Definitions
- the present invention relates to an agricultural composition comprising an effective amount of a sulphur active ingredient and at least one dispersing agent.
- Sulphur is known as an elemental fertilizer for feeding plants and is an essential component of certain vitamins and enzymes of plants. Sulphur, together with phosphorus and nitrogen takes part in the synthesis of certain plant proteins. Sulphur is insoluble in water, is easily inflammable and also displays irritable action on the human body. These properties of sulphur influence both its production as well as its use in the agricultural field.
- Sulphur is also used as a rectifier of certain structural characteristics of the soil, including in particular its pH, which it shifts towards acidic values for alkaline soils. Sulphur is naturally present in the soil as a component of certain salts. When sulphur is oxidized to its sulphate form it serves as an essential nutrient for plant growth as sulphate is the only form in which plants can take up sulphur.
- sulphur is typically blended with other granular fertilizers such as phosphates, nitrates, urea and potash among others to provide it in a form suitable for application to the soil. Sulphur is available commercially as prills, soluble sulphur liquids, wettable powders and micronized powders. These compositions are then applied to the soil by various means such as broadcasting or banding to supply the soil with sulfur, as well as additional nutrients found in the granular fertilizers.
- the conventional fertilizers comprising sulphur or sulphur plus bentonite mixtures cannot be applied through drip irrigation as the particle size of these compositions are large and the particles do not disperse in water, causing nozzle clogging in the irrigation equipment and resulting in a non-homogenous tank mixture at the time of application.
- These conventional compositions such as pellets and wettable powders do not exhibit uniform suspension resulting in uneven coverage on the plant and thereby affecting and minimizing the bio-efficacy of the product. They also need to be applied two to three months in advance so as to ensure timely conversion to sulphate and its uptake by the plant for which there is additional application and cost.
- acids such as sulfuric acid, nitric acid and/ or phosphoric acid and ammonia (anhydrous) are used to produce these conventional fertilizers.
- acids such as sulfuric acid, nitric acid and/ or phosphoric acid and ammonia (anhydrous) are used to produce these conventional fertilizers.
- the use of these chemicals creates a potentially hazardous environment for production of the fertilizer. In developing countries, these chemicals may be less available with the consequence that fertilizer must be imported at a considerable expense and crop yields are reduced in areas where food is most needed.
- Sulphur has also been incorporated in fertilizer compositions for a different purpose. Specifically, sulphur has been used in the manufacture of compositions such as Sulphur bentonite pellets, Calcium Sulphate, Ammonium Sulphate and other sulphate based compostitions of fertilizers, the process of conversion of Sulphur to sulphate form is slow and sulphate is the only form in which plants can take up sulphur. In the conventional sulphur based fertilizers it is observed that sulphur is not timely converted into sulphate and hence is not readily available to the plant.
- the present invention relates to a novel composition for agricultural use comprising an effective amount of a sulphur active ingredient and an at least one dispersing agent.
- the sulphur active ingredient is in the range of about 40% to about 98% (w/w) and the at least one dispersing agent is in the range of about 2% to about 60% (w/w).
- the agricultural composition is used as at least one of a fertilizer composition, a nutrient composition, a plant strengthener composition, a plant protectant composition, a soil conditioner composition and a yield enhancer composition.
- the agricultural composition is formulated in a form selected from a group comprising at least one of wettable powders, water dispersible granules, dusting powders, suspension concentrates, emulsifiable concentrates, tablets, liquids and oil suspensions.
- the agricultural composition is a water dispersible granule composition.
- the invention also relates to a method of treating the plant by applying the agricultural composition primarily to the basal and also to the foliar parts of the plant.
- the invention relates to an agricultural composition comprising an effective amount of a sulphur active ingredient and at least one dispersing agent.
- the sulphur active ingredient in the agricultural composition can be in the range of about 40% to about 98% on a weight by weight basis.
- the at least one dispersing agent can be in the range of about 2% to about 60 % on a dry weight by weight basis.
- Various dispersing agents are commercially available for use in agricultural compositions, such as those marketed by Rhone Poulenc, Witco, Westvaco, International Speciality products, Croda chemicals, Borregaard, BASF, Rhodia, etc.
- the dispersing agents which can be used in the agricultural composition can be chosen from a group comprising polyvinylpyrrolidone, polyvinylalcohol, lignosulphonates, phenyl naphthalene sulphonates, ethoxylated alkyl phenols, ethoxylated fatty acids, alkoxylated linear alcohols, polyaromatic sulfonates, sodium alkyl aryl sulfonates, glyceryl esters, maleic anhydride copolymers, phosphate esters, condensation products of aryl sulphonic acids and formaldehyde, condensation products of alkylaryl sulphonic acids and formaldehye, addition products of ethylene oxide and fatty acid esters, salts of addition products of ethylene oxide and fatty acid esters, sulfonates of condensed naphthalene, addition products of ethylene oxide and fatty acid esters, salts of addition products of ethylene oxide and fatty acid est
- the total number of percentage parts of the sulphur active ingredient and the at least one dispersing agent does not exceed 100 on a dry (w/w) basis.
- the agricultural composition can further comprise at least one of a wetting agent, a binding agent, a filler and an organic additive.
- the wetting agent can be in the range of about 0.1% to about 5%.
- the wetting agent which can be used in the agricultural composition can be chosen from a group comprising phenyl naphthalene sulphonates, alkyl naphthalene sulfonate, sodium alkyl naphthalene sulfonate, sodium salt of sulfonated alkylcarboxylate, polyoxyalkylated ethyl phenols, polyoxyethoylated fatty alcohols, polyoxythoxylated fatty amines, lignin derivatives, alkane sulfonates, alkylbenzene sulfonates, salts of polycarboxylic acids, salts of esters of sulfosuccinic acid, alkylnaphthalenesulphon
- the binding agent can be in the range of about 0.1% to about 7%.
- the binding agent which can be used in the agricultural composition can be selected from a group comprising polyvinyl alcohols, phenyl naphthalene sulphonate, lignin derivatives, polyvinyl pyrrolidone, polyalkylpyrrolidone, carboxymethylcellulose, xanthan gum, polyethoxylated fatty acids, polyethoxylated fatty alcohols, ethylene oxide copolymer, propylene oxide copolymer, polyethylene glycols and polyethylene oxides.
- a group comprising polyvinyl alcohols, phenyl naphthalene sulphonate, lignin derivatives, polyvinyl pyrrolidone, polyalkylpyrrolidone, carboxymethylcellulose, xanthan gum, polyethoxylated fatty acids, polyethoxylated fatty alcohols, ethylene oxide copolymer, propylene oxide copo
- the filler can be in the range of about 0.1% to about 10%.
- the filler can be selected from a group comprising bentonite, sub-bentonite, attapulgite, kaolinites, montmorillonite, bauxite, hydrated aluminas, calcined aluminas, diatomaceous earth, chalk, fuller's earth, dolomite, kiesulguhr, loess, prophyllites, talc, vermiculites, limestone, natural and synthetic silicates, silicas and china clay.
- a group comprising bentonite, sub-bentonite, attapulgite, kaolinites, montmorillonite, bauxite, hydrated aluminas, calcined aluminas, diatomaceous earth, chalk, fuller's earth, dolomite, kiesulguhr, loess, prophyllites, talc, vermiculites, limestone, natural and synthetic silicates,
- the organic additive used in the agricultural use composition can be in the range of about 0.01% to about 50%.
- the organic additive can be selected from a group comprising macronutrients, micronutrients compost fertilizers, natural elements, natural organisms, trichoderma, humic acid extracts, bacillus thuringiensis, viruses, natural fungi, plant extracts, pyrethrums, biological control products, natural oils, natural extracts, minerals and urea groups.
- the micronutrients can be selected from zinc, iron, manganese, copper, boron, cobalt, vanadium, selenium, silicon, and nickel.
- the macronutrients can be selected from the group comprising nitrogen, phosphorous, potassium, calcium and magnesium.
- the agricultural composition can be formulated in a form selected from a group comprising wettable powders, dusting powders, water dispersible granules, suspension concentrates, emulsifiable concentrates, tablets, pellets, liquids and oil suspensions.
- the agricultural composition can be formulated as water dispersible granules.
- the water dispersible granules are in the size range of about 0.1mm to about 2.5mm.
- the water dispersible granules can comprise particles. The particles can be in a size range of about 1 microns to about 12 microns.
- the agricultural composition can be used as at least one of a fertilizer composition, a nutrient composition, a plant strengthener composition, a plant protectant composition, a soil conditioner composition and a yield enhancer composition.
- a process of making the agricultural composition comprises initially blending the at least one dispersing agent and the sulphur active ingredient with an effective amount of water in a blending tank.
- the sulphur active ingredient and the at least one dispersing agent can be in a dry powder form. Blending in the tank, gives a slurry which is fairly homogenous in nature.
- the slurry comprises water, which may vary from about 25% to about 55% of the total slurry.
- the blending step can further comprise adding at least one of the wetting agent, a binding agent, a filler and an organic additive in dry powder form to the blending tank.
- the slurry is then processed in a suitable wet grinding equipment, where the particle size is brought down to a range of about 1 microns to about 12 microns.
- the slurry formed after grinding is then screened for any oversize particles, if required.
- the slurry is then subjected to drying and agglomeration in suitable spray drying equipment to obtain the agricultural composition.
- a method of treating a plant can comprise applying an effective amount of the agricultural composition to the basal and the foliar parts of the plant wherein the composition can comprise sulphur active ingredient in the range of about 40% to about 98%(w/w) and at least one dispersing agent in the range of about 2% to about 60% .
- BIOEFFICACY TESTS AND STUDIES BIOEFFICACY TESTS AND STUDIES :
- a suspension of known concentration in standard water or distilled water is prepared, placed in a prescribed measuring cylinder at a constant temperature and is allowed to remain undisturbed for the specified time.
- the top 9/10ths are drawn off and the content of the ingredient in the bottom l/10 th determined, so allowing the content of the top to be calculated.
- a known amount of water dispersible granule is added to a defined volume of water and mixed by stirring to form a suspension. After standing for a short period, the top nine-tenths are drawn off and the remaining tenth dried and determined gravimetrically. The method is virtually a shortened test of suspensibility and is appropriate for establishing the ease with which a WG is dispersed uniformly in water.
- composition for agricultural use was described with reference to the following examples. 'Percentages in the examples are stated as a percentage of the total composition. These examples are provided as an illustration of the invention and are not intended to limit the scope of the invention.
- a slurry is obtained by blending about 91% of the sulphur active ingredient, about 0.5% phenyl naphthalene sulphonate, 1% polyvinyl pyrrolidone, 5.5% of lignosulfonate and about 2% of an ethoxylated alkyl phenol in an effective amount of water.
- the slurry so formed is wet grinded in a suitable wet grinding equipment to obtain particles in the size range of about 1 micron to about 12 microns.
- the slurry is then dried in a fluidized bed drier and the particles are agglomerated to obtain the agricultural composition which is in the size range of about 0.1 mm to about 2.5 mm.
- the composition gave good results of suspension and dispersibility.
- a slurry is obtained by blending about 84% of the sulphur active ingredient, about 9% phenyl naphthalene sulphonate, 1% polyvinyl pyrrolidone, 2.5% of lignosulfonate and about 3.5% of a polyvinyl alcohol in an effective amount of water.
- the slurry so formed is wet grinded in a suitable wet grinding equipment to obtain particles in the size range of about 2 microns to about 12 microns.
- the slurry is then dried in a fluidized bed drier and the particles are agglomerated to obtain the agricultural composition which is in the size range of about 0.1 mm to about 2.5 mm.
- the composition displayed good results of suspension and dispersibility. (82%)
- a slurry is obtained by blending about 91% of the sulphur active ingredient and about 9% phenyl naphthalene sulphonate in effective amount of water.
- the slurry so formed is wet grinded in a suitable wet grinding equipment to obtain particles in the size range of about 2 microns to about 12 microns.
- the slurry is then dried in a fluidized bed drier and the particles are agglomerated to obtain the agricultural composition which is in the size range of about 0.1 mm to about 2.5 mm.
- the composition displayed good results of suspension and dispersibility (84%).
- a slurry is obtained by blending about 65% of the sulphur active ingredient, about 5% phenyl naphthalene sulphonate, 25% polyvinyl pyrrolidone, 2.5% of lignosulfonate and about 2.5 % of zinc in an effective amount of water.
- the slurry so . formed is wet grinded in a suitable wet grinding equipment to obtain particles in the size range of about 2 microns to about 12 microns.
- the slurry is then dried in a fluidized bed drier and the particles are agglomerated to obtain the agricultural composition which is in the size range of about 0.1 mm to about 2.5 mm.
- the composition displayed good results of suspension and dispersibility. (80%).
- a slurry is obtained by blending about 70% of the sulphur active ingredient, about 7% phenyl naphthalene sulphonate, 20% polyvinyl pyrrolidone, 0.5% of lignosulfonate and about 2.5% of naphthalene formaldehyde condensate in an effective amount of water.
- the slurry so formed is wet grinded in a suitable wet grinding equipment to obtain particles in the size range of about 1 micron to about 12 microns.
- the slurry is then dried in a fluidized bed drier and the particles are agglomerated to obtain the agricultural composition which is in the size range of about 0.1 mm to about 2.5 mm.
- the composition displayed good results of suspension and dispersibility (82.5%)
- a slurry is obtained by blending about 91% of the sulphur active ingredient, about 2% of a maleic anhydride copolymer, 1% of a polyethoxylated alkyl phenol and 6% of lignosulfonate in an effective amount of water.
- the slurry so formed is wet grinded in a suitable wet grinding equipment to obtain particles in the size range of about 1 micron to about 12 microns.
- the slurry is then dried in a fluidized bed drier and the particles are agglomerated to obtain the agricultural composition which is in the size range of about 0.1 mm to about 2.5 mm.
- This agricultural composition obtained was used on different crops.
- the composition was applied on crucifers in a dosage of 3kg/ acre at about 3 to 10 days after transplantation. Urea was also applied and broadcasted along with the agricultural composition. It was observed at the time of harvesting that there was a 15% to 20% increase in the yield with each head having more weight. Moreover, the foliage was dark green and there was tertiary and secondary profuse root development.
- the composition was also applied to crops under the soil such as bulbs and tubers.
- crops under the soil such as bulbs and tubers.
- a dosage of 4 kg/ acre was applied on onions and garlic in the nursery at about 20 days and 45 days after transplantation the bulbs exhibited a 10% increase in the size and more uniformity with a higher yield. Also the bulbs exhibited more pungency and the produce had a higher shelf life under normal conditions.
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- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Organic Chemistry (AREA)
- Pest Control & Pesticides (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Inorganic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Plant Pathology (AREA)
- Agronomy & Crop Science (AREA)
- Engineering & Computer Science (AREA)
- Dentistry (AREA)
- General Health & Medical Sciences (AREA)
- Wood Science & Technology (AREA)
- Zoology (AREA)
- Environmental Sciences (AREA)
- Agricultural Chemicals And Associated Chemicals (AREA)
- Fertilizers (AREA)
Abstract
Description
Claims
Priority Applications (5)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| AU2007343066A AU2007343066C1 (en) | 2007-01-08 | 2007-11-01 | Novel agricultural composition |
| KR1020097015317A KR101253264B1 (en) | 2007-01-08 | 2007-11-01 | Novel Agricultural Composition |
| CN200780051067.6A CN101657395B (en) | 2007-01-08 | 2007-11-01 | Agricultural composition |
| US12/522,259 US8241387B2 (en) | 2007-01-08 | 2007-11-01 | Agricultural composition |
| NZ578325A NZ578325A (en) | 2007-01-08 | 2007-11-01 | Agricultural composition comprising an active sulphur ingredient |
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| IN40/MUM/2007 | 2007-01-08 | ||
| IN40MU2007 | 2007-01-08 |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| WO2008084495A2 true WO2008084495A2 (en) | 2008-07-17 |
| WO2008084495A3 WO2008084495A3 (en) | 2008-10-02 |
Family
ID=39609133
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| PCT/IN2007/000518 Ceased WO2008084495A2 (en) | 2007-01-08 | 2007-11-01 | Novel agricultural composition |
Country Status (7)
| Country | Link |
|---|---|
| US (1) | US8241387B2 (en) |
| KR (1) | KR101253264B1 (en) |
| CN (1) | CN101657395B (en) |
| AU (1) | AU2007343066C1 (en) |
| MY (1) | MY149529A (en) |
| NZ (1) | NZ578325A (en) |
| WO (1) | WO2008084495A2 (en) |
Cited By (12)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2009125435A3 (en) * | 2008-04-11 | 2009-12-03 | Excel Crop Care Limited | Improved sulfur formulation suitable for organic agriculture |
| WO2010086396A1 (en) | 2009-01-29 | 2010-08-05 | Shell Internationale Research Maatschappij B.V. | Sulphur-containing fertilizers and process for the preparation thereof |
| US20100330884A1 (en) * | 2009-06-29 | 2010-12-30 | Ferro Corporation | Diatomaceous Earth-Containing Slurry Composition And Method For Polishing Organic Polymer-Based Ophthalmic Substrates Using The Same |
| US20120036906A1 (en) * | 2009-04-16 | 2012-02-16 | Sulphur Solutions, Inc. | Dispersible sulphur fertilizer pellets |
| WO2012053894A3 (en) * | 2010-10-18 | 2012-07-26 | Ceradis B.V. | Novel biosulfur formulations |
| WO2012131702A1 (en) * | 2011-03-10 | 2012-10-04 | Deepak Pranjivandas Shah | A fertilizer composition |
| US20140216120A1 (en) * | 2013-02-07 | 2014-08-07 | Tiger-Sul Products (Canada) Co. | Sulphur-based fertilizer composition with low rock phosphate content |
| WO2018207124A1 (en) | 2017-05-10 | 2018-11-15 | Thankapan VADAKEKUTTU | Agricultural compositions |
| EP3831206A1 (en) | 2011-01-28 | 2021-06-09 | Deepak Pranjivandas Shah | Pesticidal composition comprising sulphur, a fungicide and an agrochemical excipient |
| US11414357B2 (en) | 2018-05-10 | 2022-08-16 | Arun Vitthal SAWANT | Crop nutrition and fortification composition |
| US11465946B2 (en) | 2018-05-10 | 2022-10-11 | Arun Vitthal SAWANT | Crop nutrition and fortification composition |
| US12454495B2 (en) | 2018-05-10 | 2025-10-28 | SML Limitied | Crop nutrition and fortification composition |
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| US8192520B2 (en) * | 2009-10-05 | 2012-06-05 | Specialty Fertilizer Products, Llc | Enhanced fertilizer products with polymer adjuvants |
| US8975214B2 (en) * | 2010-02-23 | 2015-03-10 | Innovative Chemical Services Pty Ltd | Emulsion adjuvant for herbicides |
| CN102391047B (en) * | 2011-08-08 | 2013-04-17 | 江苏浩波农业科技开发有限公司 | Sustained-release soil selenium fertilizer used for degrading residual pesticide and reducing heavy metal content, and preparation method thereof |
| US9145340B2 (en) | 2012-08-13 | 2015-09-29 | Verdesian Life Sciences, Llc | Method of reducing atmospheric ammonia in livestock and poultry containment facilities |
| US9961922B2 (en) | 2012-10-15 | 2018-05-08 | Verdesian Life Sciences, Llc | Animal feed and/or water amendments for lowering ammonia concentrations in animal excrement |
| CN103058758A (en) * | 2012-12-26 | 2013-04-24 | 施可丰化工股份有限公司 | Slow release compound fertilizer applicable to plantation of vegetable |
| CN103086791A (en) * | 2012-12-26 | 2013-05-08 | 施可丰化工股份有限公司 | Environment-friendly chlorine-based nitro potash composite slow-release fertilizer |
| US9133065B2 (en) * | 2013-07-23 | 2015-09-15 | Compass Minerals Manitoba Inc. | High efficiency magnesium fertilizer |
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| US10519070B2 (en) | 2014-05-21 | 2019-12-31 | Verdesian Life Sciences U.S., Llc | Polymer soil treatment compositions including humic acids |
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| CN104286023A (en) * | 2014-08-18 | 2015-01-21 | 新疆兴林农资有限公司 | Sulfur suspension agent and production method thereof |
| CA2969851A1 (en) | 2015-01-16 | 2016-07-21 | Stoller Enterprises, Inc. | Flowable mixture including elemental sulfur and hydrated clay |
| US10703682B2 (en) * | 2015-05-19 | 2020-07-07 | Sulvaris Inc. | Fertilizer pellets with micronized sulphur |
| DE102015213635A1 (en) * | 2015-07-20 | 2017-01-26 | Clariant International Ltd | Plant nutrient suspensions and their use for fertilizing plants |
| WO2017195173A1 (en) | 2016-05-12 | 2017-11-16 | Verdesian Life Sciences, U.S., Llc | Compositions for controlling enzyme-induced urea decomposition |
| WO2018051372A1 (en) * | 2016-09-16 | 2018-03-22 | Sawant Arun | Stable formulation of water sensitive active |
| US10519072B2 (en) | 2017-02-23 | 2019-12-31 | Produquímica Indústria E Comércio S.A. | Multi-nutrient granular fertilizer compositions and methods of using the same |
| US11261136B2 (en) | 2017-03-28 | 2022-03-01 | Verdesian Life Sciences U.S., Llc | Triarylmethane compounds for controlling enzyme-induced urea decomposition |
| JOP20190274A1 (en) * | 2017-05-23 | 2019-11-24 | Mosaic Co | Swellable fertilizer granules containing elemental sulfur with increased oxidation rates |
| CA3069790C (en) * | 2017-07-27 | 2021-11-23 | Arun Vitthal SAWANT | Novel crop fortification, nutrition and crop protection composition |
| WO2020255934A1 (en) * | 2019-06-17 | 2020-12-24 | 昭和電工株式会社 | Plant activator containing amino acid or salt thereof, and oligosaccharide, and use thereof |
| US10995271B1 (en) | 2020-07-16 | 2021-05-04 | Kuwait Institute For Scientific Research | Bioorganic soil conditioner |
| KR102540101B1 (en) * | 2020-12-03 | 2023-06-05 | 주식회사 자연과 미래 | Control compositions for crop pests capable of water and soil treatment And Methods for preparing the same |
| KR102850730B1 (en) * | 2022-12-14 | 2025-08-25 | 박종화 | Manufacturing method of liquid type fertilizer and germicidal agent using sulfer and silicic acid, and liquid fertilizer thereof |
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| US1795364A (en) * | 1924-11-24 | 1931-03-10 | Ellis Foster Co | Sulphur product and process of making same |
| DE1024934B (en) * | 1955-12-01 | 1958-02-27 | Basf Ag | Process for the production of powdery, dispersible sulfur, especially suitable for the purposes of crop protection |
| IT1224553B (en) * | 1988-09-30 | 1990-10-04 | Fps Finances Prod Serv Srl | CORRECTIVE AND AMENDING PRODUCT FOR AGRICULTURAL USE BASED ON SULFUR IN PELLETS |
| US5599373A (en) * | 1988-09-30 | 1997-02-04 | F.P.S.- Finances Products Services, S.R.L. | Sulfur-based chemical soil-corrective in the form of pellets for agricultural use |
| GB9416402D0 (en) * | 1994-08-13 | 1994-10-05 | Hays Chemical Distribution Ltd | Application of sulpher in agriculture |
| US5571303B1 (en) * | 1995-03-06 | 2000-10-17 | Cominco Ltd | Sulfur-based fertilizer and process for production thereof |
| US6749659B1 (en) * | 2001-10-09 | 2004-06-15 | Enersul, Inc. | Controlled release rate fertilizers and methods of making same |
-
2007
- 2007-11-01 AU AU2007343066A patent/AU2007343066C1/en active Active
- 2007-11-01 CN CN200780051067.6A patent/CN101657395B/en active Active
- 2007-11-01 KR KR1020097015317A patent/KR101253264B1/en active Active
- 2007-11-01 NZ NZ578325A patent/NZ578325A/en unknown
- 2007-11-01 MY MYPI20092868A patent/MY149529A/en unknown
- 2007-11-01 WO PCT/IN2007/000518 patent/WO2008084495A2/en not_active Ceased
- 2007-11-01 US US12/522,259 patent/US8241387B2/en active Active
Cited By (20)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2009125435A3 (en) * | 2008-04-11 | 2009-12-03 | Excel Crop Care Limited | Improved sulfur formulation suitable for organic agriculture |
| WO2010086396A1 (en) | 2009-01-29 | 2010-08-05 | Shell Internationale Research Maatschappij B.V. | Sulphur-containing fertilizers and process for the preparation thereof |
| US8702834B2 (en) | 2009-01-29 | 2014-04-22 | Shell Oil Company | Sulphur-containing fertilizers and process for the preparation thereof |
| US8814976B2 (en) * | 2009-04-16 | 2014-08-26 | Sulvaris Inc. | Dispersible sulphur fertilizer pellets |
| US20120036906A1 (en) * | 2009-04-16 | 2012-02-16 | Sulphur Solutions, Inc. | Dispersible sulphur fertilizer pellets |
| US20100330884A1 (en) * | 2009-06-29 | 2010-12-30 | Ferro Corporation | Diatomaceous Earth-Containing Slurry Composition And Method For Polishing Organic Polymer-Based Ophthalmic Substrates Using The Same |
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| CN110868861B (en) * | 2017-05-10 | 2022-03-15 | 萨卡帕·瓦达卡库塔 | agricultural composition |
| US11414357B2 (en) | 2018-05-10 | 2022-08-16 | Arun Vitthal SAWANT | Crop nutrition and fortification composition |
| US11465946B2 (en) | 2018-05-10 | 2022-10-11 | Arun Vitthal SAWANT | Crop nutrition and fortification composition |
| US12454495B2 (en) | 2018-05-10 | 2025-10-28 | SML Limitied | Crop nutrition and fortification composition |
Also Published As
| Publication number | Publication date |
|---|---|
| AU2007343066B2 (en) | 2011-09-01 |
| KR20090105935A (en) | 2009-10-07 |
| AU2007343066C1 (en) | 2017-06-08 |
| US8241387B2 (en) | 2012-08-14 |
| KR101253264B1 (en) | 2013-04-10 |
| WO2008084495A3 (en) | 2008-10-02 |
| CN101657395A (en) | 2010-02-24 |
| NZ578325A (en) | 2012-08-31 |
| US20090308122A1 (en) | 2009-12-17 |
| MY149529A (en) | 2013-09-13 |
| AU2007343066A1 (en) | 2008-07-17 |
| CN101657395B (en) | 2014-03-12 |
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