[go: up one dir, main page]

WO1997000995A1 - Composition et procede permettant de conferer des proprietes repulsives durables a des substrats - Google Patents

Composition et procede permettant de conferer des proprietes repulsives durables a des substrats Download PDF

Info

Publication number
WO1997000995A1
WO1997000995A1 PCT/US1996/008302 US9608302W WO9700995A1 WO 1997000995 A1 WO1997000995 A1 WO 1997000995A1 US 9608302 W US9608302 W US 9608302W WO 9700995 A1 WO9700995 A1 WO 9700995A1
Authority
WO
WIPO (PCT)
Prior art keywords
composition
carpet
fluorochemical
grafted
water
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Ceased
Application number
PCT/US1996/008302
Other languages
English (en)
Inventor
Lori P. Engle
Steven J. Hamrock
Mark J. Pellerite
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
3M Co
Original Assignee
Minnesota Mining and Manufacturing Co
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority claimed from US08/653,548 external-priority patent/US5888290A/en
Application filed by Minnesota Mining and Manufacturing Co filed Critical Minnesota Mining and Manufacturing Co
Priority to JP9503848A priority Critical patent/JPH11509585A/ja
Priority to EP96916933A priority patent/EP0837963A1/fr
Priority to AU59645/96A priority patent/AU704867B2/en
Publication of WO1997000995A1 publication Critical patent/WO1997000995A1/fr
Anticipated expiration legal-status Critical
Ceased legal-status Critical Current

Links

Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B82—NANOTECHNOLOGY
    • B82Y—SPECIFIC USES OR APPLICATIONS OF NANOSTRUCTURES; MEASUREMENT OR ANALYSIS OF NANOSTRUCTURES; MANUFACTURE OR TREATMENT OF NANOSTRUCTURES
    • B82Y30/00—Nanotechnology for materials or surface science, e.g. nanocomposites
    • C—CHEMISTRY; METALLURGY
    • C03—GLASS; MINERAL OR SLAG WOOL
    • C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
    • C03C17/00—Surface treatment of glass, not in the form of fibres or filaments, by coating
    • C03C17/006—Surface treatment of glass, not in the form of fibres or filaments, by coating with materials of composite character
    • C03C17/007—Surface treatment of glass, not in the form of fibres or filaments, by coating with materials of composite character containing a dispersed phase, e.g. particles, fibres or flakes, in a continuous phase
    • C—CHEMISTRY; METALLURGY
    • C03—GLASS; MINERAL OR SLAG WOOL
    • C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
    • C03C17/00—Surface treatment of glass, not in the form of fibres or filaments, by coating
    • C03C17/006—Surface treatment of glass, not in the form of fibres or filaments, by coating with materials of composite character
    • C03C17/008—Surface treatment of glass, not in the form of fibres or filaments, by coating with materials of composite character comprising a mixture of materials covered by two or more of the groups C03C17/02, C03C17/06, C03C17/22 and C03C17/28
    • C03C17/009—Mixtures of organic and inorganic materials, e.g. ormosils and ormocers
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09C—TREATMENT OF INORGANIC MATERIALS, OTHER THAN FIBROUS FILLERS, TO ENHANCE THEIR PIGMENTING OR FILLING PROPERTIES ; PREPARATION OF CARBON BLACK  ; PREPARATION OF INORGANIC MATERIALS WHICH ARE NO SINGLE CHEMICAL COMPOUNDS AND WHICH ARE MAINLY USED AS PIGMENTS OR FILLERS
    • C09C1/00—Treatment of specific inorganic materials other than fibrous fillers; Preparation of carbon black
    • C09C1/28—Compounds of silicon
    • C09C1/30—Silicic acid
    • C09C1/309—Combinations of treatments provided for in groups C09C1/3009 - C09C1/3081
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09C—TREATMENT OF INORGANIC MATERIALS, OTHER THAN FIBROUS FILLERS, TO ENHANCE THEIR PIGMENTING OR FILLING PROPERTIES ; PREPARATION OF CARBON BLACK  ; PREPARATION OF INORGANIC MATERIALS WHICH ARE NO SINGLE CHEMICAL COMPOUNDS AND WHICH ARE MAINLY USED AS PIGMENTS OR FILLERS
    • C09C1/00—Treatment of specific inorganic materials other than fibrous fillers; Preparation of carbon black
    • C09C1/36—Compounds of titanium
    • C09C1/3692—Combinations of treatments provided for in groups C09C1/3615 - C09C1/3684
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09C—TREATMENT OF INORGANIC MATERIALS, OTHER THAN FIBROUS FILLERS, TO ENHANCE THEIR PIGMENTING OR FILLING PROPERTIES ; PREPARATION OF CARBON BLACK  ; PREPARATION OF INORGANIC MATERIALS WHICH ARE NO SINGLE CHEMICAL COMPOUNDS AND WHICH ARE MAINLY USED AS PIGMENTS OR FILLERS
    • C09C3/00—Treatment in general of inorganic materials, other than fibrous fillers, to enhance their pigmenting or filling properties
    • C09C3/006—Combinations of treatments provided for in groups C09C3/04 - C09C3/12
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09C—TREATMENT OF INORGANIC MATERIALS, OTHER THAN FIBROUS FILLERS, TO ENHANCE THEIR PIGMENTING OR FILLING PROPERTIES ; PREPARATION OF CARBON BLACK  ; PREPARATION OF INORGANIC MATERIALS WHICH ARE NO SINGLE CHEMICAL COMPOUNDS AND WHICH ARE MAINLY USED AS PIGMENTS OR FILLERS
    • C09C3/00—Treatment in general of inorganic materials, other than fibrous fillers, to enhance their pigmenting or filling properties
    • C09C3/10—Treatment with macromolecular organic compounds
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09C—TREATMENT OF INORGANIC MATERIALS, OTHER THAN FIBROUS FILLERS, TO ENHANCE THEIR PIGMENTING OR FILLING PROPERTIES ; PREPARATION OF CARBON BLACK  ; PREPARATION OF INORGANIC MATERIALS WHICH ARE NO SINGLE CHEMICAL COMPOUNDS AND WHICH ARE MAINLY USED AS PIGMENTS OR FILLERS
    • C09C3/00—Treatment in general of inorganic materials, other than fibrous fillers, to enhance their pigmenting or filling properties
    • C09C3/12—Treatment with organosilicon compounds
    • C—CHEMISTRY; METALLURGY
    • C14—SKINS; HIDES; PELTS; LEATHER
    • C14C—CHEMICAL TREATMENT OF HIDES, SKINS OR LEATHER, e.g. TANNING, IMPREGNATING, FINISHING; APPARATUS THEREFOR; COMPOSITIONS FOR TANNING
    • C14C9/00—Impregnating leather for preserving, waterproofing, making resistant to heat or similar purposes
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M11/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising
    • D06M11/77—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with silicon or compounds thereof
    • D06M11/79—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with silicon or compounds thereof with silicon dioxide, silicic acids or their salts
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
    • D06M13/50—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with organometallic compounds; with organic compounds containing boron, silicon, selenium or tellurium atoms
    • D06M13/51—Compounds with at least one carbon-metal or carbon-boron, carbon-silicon, carbon-selenium, or carbon-tellurium bond
    • D06M13/513—Compounds with at least one carbon-metal or carbon-boron, carbon-silicon, carbon-selenium, or carbon-tellurium bond with at least one carbon-silicon bond
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
    • D06M13/50—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with organometallic compounds; with organic compounds containing boron, silicon, selenium or tellurium atoms
    • D06M13/51—Compounds with at least one carbon-metal or carbon-boron, carbon-silicon, carbon-selenium, or carbon-tellurium bond
    • D06M13/513—Compounds with at least one carbon-metal or carbon-boron, carbon-silicon, carbon-selenium, or carbon-tellurium bond with at least one carbon-silicon bond
    • D06M13/517—Compounds with at least one carbon-metal or carbon-boron, carbon-silicon, carbon-selenium, or carbon-tellurium bond with at least one carbon-silicon bond containing silicon-halogen bonds
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
    • D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
    • D06M15/21—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • D06M15/263—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds of unsaturated carboxylic acids; Salts or esters thereof
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
    • D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
    • D06M15/21—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • D06M15/263—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds of unsaturated carboxylic acids; Salts or esters thereof
    • D06M15/277—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds of unsaturated carboxylic acids; Salts or esters thereof containing fluorine
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
    • D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
    • D06M15/21—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • D06M15/356—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds of other unsaturated compounds containing nitrogen, sulfur, silicon or phosphorus atoms
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
    • D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
    • D06M15/21—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • D06M15/356—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds of other unsaturated compounds containing nitrogen, sulfur, silicon or phosphorus atoms
    • D06M15/3568—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds of other unsaturated compounds containing nitrogen, sulfur, silicon or phosphorus atoms containing silicon
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
    • D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
    • D06M15/37—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • D06M15/643—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds containing silicon in the main chain
    • D06M15/657—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds containing silicon in the main chain containing fluorine
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
    • C01P2004/00—Particle morphology
    • C01P2004/51—Particles with a specific particle size distribution
    • C01P2004/52—Particles with a specific particle size distribution highly monodisperse size distribution
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
    • C01P2004/00—Particle morphology
    • C01P2004/60—Particles characterised by their size
    • C01P2004/62—Submicrometer sized, i.e. from 0.1-1 micrometer
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
    • C01P2004/00—Particle morphology
    • C01P2004/60—Particles characterised by their size
    • C01P2004/64—Nanometer sized, i.e. from 1-100 nanometer
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
    • C01P2004/00—Particle morphology
    • C01P2004/80—Particles consisting of a mixture of two or more inorganic phases
    • C01P2004/82—Particles consisting of a mixture of two or more inorganic phases two phases having the same anion, e.g. both oxidic phases
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
    • C01P2006/00—Physical properties of inorganic compounds
    • C01P2006/22—Rheological behaviour as dispersion, e.g. viscosity, sedimentation stability
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
    • C01P2006/00—Physical properties of inorganic compounds
    • C01P2006/90—Other properties not specified above
    • C—CHEMISTRY; METALLURGY
    • C03—GLASS; MINERAL OR SLAG WOOL
    • C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
    • C03C2217/00—Coatings on glass
    • C03C2217/40—Coatings comprising at least one inhomogeneous layer
    • C03C2217/43—Coatings comprising at least one inhomogeneous layer consisting of a dispersed phase in a continuous phase
    • C03C2217/46—Coatings comprising at least one inhomogeneous layer consisting of a dispersed phase in a continuous phase characterized by the dispersed phase
    • C03C2217/47—Coatings comprising at least one inhomogeneous layer consisting of a dispersed phase in a continuous phase characterized by the dispersed phase consisting of a specific material
    • C03C2217/475—Inorganic materials
    • C03C2217/478—Silica

Definitions

  • this invention provides a fluorochemical treatment composition which can be used to impart durable water and oil repellency, durable stain release, and durable dry soil resistance to substrates, e.g., carpets, fabrics (both woven and non-woven), papers, wood, concrete, and leather.
  • the composition comprises (a) a sol comprising a colloidal dispersion of substantially discrete, substantially monodisperse in size, polymer-grafted, inorganic microparticles in liquid; and (b) at least one fluorochemical. Microparticles having polymodal size distributions prepared from blends of monodisperse distributions can also be utilized in forming the sol.
  • silica microparticles can be treated with hydrolyzable, chain transfer group- containing organosilanes under conditions such that silanol groups on the surface of the particles chemically bond with hydrolyzed silane groups to produce covalent silicon-oxyge -silicon bonds.
  • Dynamic water resistance of a carpet sample was determined by inclining a test sample (15.2 cm X 30.5 cm) at an angle of 45° from horizontal and impinging deionized (D.I.) water (20 ml) onto the center of the carpet sample through a 5 mm i.d. tube positioned 45.7 cm above the sample.
  • the increase in weight of the test sample provided an indication of its ability to repel water, with lower weight gains indicating better repellency properties.
  • D.I. water 50 g was added to a Sn0 2 suspension (50 g, 88SN-123, 20% solids, ⁇ 10 nm particle size, pH 10, available from Nalco Chemical Co.) to produce an approximately 10% solids colloidal suspension.
  • Mercaptopropyl trimethoxy silane (0.25g, 0.13 mM/g) was added to this suspension and the mixture heated, with stirring, at 80°C for 16h.

Landscapes

  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Textile Engineering (AREA)
  • General Chemical & Material Sciences (AREA)
  • Inorganic Chemistry (AREA)
  • Materials Engineering (AREA)
  • Composite Materials (AREA)
  • Geochemistry & Mineralogy (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Nanotechnology (AREA)
  • Dispersion Chemistry (AREA)
  • Physics & Mathematics (AREA)
  • Condensed Matter Physics & Semiconductors (AREA)
  • General Physics & Mathematics (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
  • Paints Or Removers (AREA)
  • Silicon Polymers (AREA)
  • Materials Applied To Surfaces To Minimize Adherence Of Mist Or Water (AREA)
  • Chemical Or Physical Treatment Of Fibers (AREA)

Abstract

Cette invention concerne une composition fluorochimique de traitement, laquelle comprend (a) un sol contenant une dispersion colloïdale dans un liquide, de microparticules non organiques, à greffe polymère, sensiblement monodispersées en taille et sensiblement discrètes, et (b) au moins un produit fluorochimique. Cette composition peut être utilisée afin de conférer à des substrats divers des propriétés oléorésistantes et imperméabilisantes durables, d'aptitude au détachage et de résistance aux salissures sèches.
PCT/US1996/008302 1995-06-23 1996-06-03 Composition et procede permettant de conferer des proprietes repulsives durables a des substrats Ceased WO1997000995A1 (fr)

Priority Applications (3)

Application Number Priority Date Filing Date Title
JP9503848A JPH11509585A (ja) 1995-06-23 1996-06-03 支持体に持続的な撥液性を付与するための組成物および方法
EP96916933A EP0837963A1 (fr) 1995-06-23 1996-06-03 Composition et procede permettant de conferer des proprietes repulsives durables a des substrats
AU59645/96A AU704867B2 (en) 1995-06-23 1996-06-03 Composition and process for imparting durable repellency to substrates

Applications Claiming Priority (4)

Application Number Priority Date Filing Date Title
US46895P 1995-06-23 1995-06-23
US08/653,548 1996-05-24
US08/653,548 US5888290A (en) 1996-05-24 1996-05-24 Composition and process for imparting durable repellency to substrates
US60/000,468 1996-05-24

Publications (1)

Publication Number Publication Date
WO1997000995A1 true WO1997000995A1 (fr) 1997-01-09

Family

ID=26667687

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/US1996/008302 Ceased WO1997000995A1 (fr) 1995-06-23 1996-06-03 Composition et procede permettant de conferer des proprietes repulsives durables a des substrats

Country Status (5)

Country Link
EP (1) EP0837963A1 (fr)
JP (1) JPH11509585A (fr)
AU (1) AU704867B2 (fr)
CA (1) CA2225526A1 (fr)
WO (1) WO1997000995A1 (fr)

Cited By (16)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO1999057205A1 (fr) * 1998-05-04 1999-11-11 3M Innovative Properties Company Composition de ceramere possedant des caracteristiques de resistance a l'abrasion et aux taches
WO2000009798A1 (fr) * 1998-08-17 2000-02-24 The Dow Chemical Company Dossier de tapis anti-deversement
WO2000050517A1 (fr) * 1999-02-22 2000-08-31 3M Innovative Properties Company Composition et composite de ceramere contenant une composante de compose fluore a durcissement radicalaire
WO2001075216A1 (fr) * 2000-04-04 2001-10-11 Schoeller Textil Ag Appret de fibres textiles, de tissus et de structures planes
DE10021726A1 (de) * 2000-05-04 2001-11-15 Henkel Kgaa Verwendung von nanoskaligen Teilchen zur Verbesserung der Schmutzablösung
WO2001096511A3 (fr) * 2000-06-14 2002-07-25 Procter & Gamble Compositions de revetement servant a modifier des surfaces dures
EP1245658A1 (fr) * 2001-03-30 2002-10-02 Central Glass Company, Limited Article hydrophobe
US6479612B1 (en) 1999-08-10 2002-11-12 E. I. Du Pont De Nemours And Company Fluorochemical water and oil repellents
US6743844B1 (en) 1998-08-17 2004-06-01 Dow Global Technologies Inc. Spill resistant carpet backing
WO2004074568A1 (fr) * 2003-02-18 2004-09-02 Basf Aktiengesellschaft Procede d'impermeabilisation de matieres textiles
US7115688B1 (en) 1998-11-30 2006-10-03 Nanosphere, Inc. Nanoparticles with polymer shells
US7160480B2 (en) 2005-02-22 2007-01-09 E. I. Du Pont De Nemours And Company Leather treated with fluorochemicals
US7192986B2 (en) * 1997-03-12 2007-03-20 Catalysts & Chemicals Industries Co., Ltd. Inorganic compound sol modified by organic compound
WO2007031490A1 (fr) * 2005-09-16 2007-03-22 Basf Se Procede d'application de revetements sur des surfaces et particules adaptees a cet effet
WO2008090191A3 (fr) * 2007-01-26 2010-01-07 Basf Se Particules, procédé de fabrication et utilisation
CN103451924A (zh) * 2013-07-24 2013-12-18 吴江市七都镇庙港雅迪针织制衣厂 一种含有甘露醇的羊毛衫拒水拒油整理剂

Families Citing this family (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2001012166A2 (fr) 1999-08-17 2001-02-22 University Of Saskatchewan Technologies Inc. Traitement ameliore de troubles physiques aigus du systeme nerveux central
DE60232701D1 (de) * 2001-07-20 2009-08-06 Rohm & Haas Polymerverbindung enthaltend Siliciumestergruppen und diese enthaltende Zusammensetzungen
DE102004020112A1 (de) * 2003-07-04 2005-01-20 Bayer Chemicals Ag Papierherstellung mit modifizierten Kieselsolen als Mikropartikel
EP1533356A1 (fr) * 2003-11-24 2005-05-25 3M Innovative Properties Company Composition fluorochimique pour rendre des substrats oléophobes et/ou hydrophobes
EP1751345B1 (fr) * 2004-05-19 2008-04-09 Basf Se Procédé de finissage de matières absorbantes
KR101651307B1 (ko) * 2008-11-14 2016-08-25 이 아이 듀폰 디 네모아 앤드 캄파니 플루오로폴리머 조성물 및 처리된 기재

Citations (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB1159124A (en) * 1965-10-01 1969-07-23 Spitzer Joseph G Aerosol Composition for Treatment of Garments
EP0121078A1 (fr) * 1983-03-03 1984-10-10 Bayer Ag Produits auxiliaires textiles
US4617057A (en) * 1985-06-04 1986-10-14 Dow Corning Corporation Oil and water repellent coating compositions
SU1298213A1 (ru) * 1983-06-10 1987-03-23 Предприятие П/Я В-2913 Способ получени модифицированного кремнеземного наполнител
EP0433906A2 (fr) * 1989-12-18 1991-06-26 Toshiba Silicone Co., Ltd. Résine thermoplastique et son procédé de fabrication
EP0457939A1 (fr) * 1990-05-21 1991-11-27 BASF Corporation Additif de contrôle de rhéologie pour peintures contenant de la silice colloidale hydrophobe
WO1993001348A1 (fr) * 1991-07-10 1993-01-21 Minnesota Mining And Manufacturing Company Compositions de traitement fluorochimique impermeables a l'eau et a l'huile
EP0550915A1 (fr) * 1992-01-10 1993-07-14 Idemitsu Kosan Company Limited Composition hydrofuge d'émulsion et procédé de production

Patent Citations (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB1159124A (en) * 1965-10-01 1969-07-23 Spitzer Joseph G Aerosol Composition for Treatment of Garments
EP0121078A1 (fr) * 1983-03-03 1984-10-10 Bayer Ag Produits auxiliaires textiles
SU1298213A1 (ru) * 1983-06-10 1987-03-23 Предприятие П/Я В-2913 Способ получени модифицированного кремнеземного наполнител
US4617057A (en) * 1985-06-04 1986-10-14 Dow Corning Corporation Oil and water repellent coating compositions
EP0433906A2 (fr) * 1989-12-18 1991-06-26 Toshiba Silicone Co., Ltd. Résine thermoplastique et son procédé de fabrication
EP0457939A1 (fr) * 1990-05-21 1991-11-27 BASF Corporation Additif de contrôle de rhéologie pour peintures contenant de la silice colloidale hydrophobe
WO1993001348A1 (fr) * 1991-07-10 1993-01-21 Minnesota Mining And Manufacturing Company Compositions de traitement fluorochimique impermeables a l'eau et a l'huile
EP0550915A1 (fr) * 1992-01-10 1993-07-14 Idemitsu Kosan Company Limited Composition hydrofuge d'émulsion et procédé de production

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
DATABASE WPI Section Ch Week 8741, Derwent World Patents Index; Class A60, AN 87-290933, XP002019405 *

Cited By (24)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US7192986B2 (en) * 1997-03-12 2007-03-20 Catalysts & Chemicals Industries Co., Ltd. Inorganic compound sol modified by organic compound
WO1999057205A1 (fr) * 1998-05-04 1999-11-11 3M Innovative Properties Company Composition de ceramere possedant des caracteristiques de resistance a l'abrasion et aux taches
WO2000009798A1 (fr) * 1998-08-17 2000-02-24 The Dow Chemical Company Dossier de tapis anti-deversement
US6743844B1 (en) 1998-08-17 2004-06-01 Dow Global Technologies Inc. Spill resistant carpet backing
US7115688B1 (en) 1998-11-30 2006-10-03 Nanosphere, Inc. Nanoparticles with polymer shells
US6497961B2 (en) 1999-02-22 2002-12-24 3M Innovative Properties Company Ceramer composition and composite comprising free radically curable fluorochemical component
US6238798B1 (en) 1999-02-22 2001-05-29 3M Innovative Properties Company Ceramer composition and composite comprising free radically curable fluorochemical component
WO2000050517A1 (fr) * 1999-02-22 2000-08-31 3M Innovative Properties Company Composition et composite de ceramere contenant une composante de compose fluore a durcissement radicalaire
US6479612B1 (en) 1999-08-10 2002-11-12 E. I. Du Pont De Nemours And Company Fluorochemical water and oil repellents
US7056845B2 (en) * 2000-04-04 2006-06-06 Schoeller Textil Ag Finishing of textile fibers, tissues and fabrics
WO2001075216A1 (fr) * 2000-04-04 2001-10-11 Schoeller Textil Ag Appret de fibres textiles, de tissus et de structures planes
DE10021726A1 (de) * 2000-05-04 2001-11-15 Henkel Kgaa Verwendung von nanoskaligen Teilchen zur Verbesserung der Schmutzablösung
WO2001096511A3 (fr) * 2000-06-14 2002-07-25 Procter & Gamble Compositions de revetement servant a modifier des surfaces dures
US7452605B2 (en) 2001-03-30 2008-11-18 Central Glass Company, Limited Article superior in slipping waterdrops down surface thereof
EP1398362A1 (fr) * 2001-03-30 2004-03-17 Central Glass Company, Limited Article hydrophobe
EP1245658A1 (fr) * 2001-03-30 2002-10-02 Central Glass Company, Limited Article hydrophobe
WO2004074568A1 (fr) * 2003-02-18 2004-09-02 Basf Aktiengesellschaft Procede d'impermeabilisation de matieres textiles
US7790238B2 (en) 2003-02-18 2010-09-07 Basf Aktiengesellschaft Method for hydrophobing textile materials
US7955518B2 (en) 2003-02-18 2011-06-07 Basf Aktiengesellschaft Method for hydrophobing textile materials
US7160480B2 (en) 2005-02-22 2007-01-09 E. I. Du Pont De Nemours And Company Leather treated with fluorochemicals
WO2007031490A1 (fr) * 2005-09-16 2007-03-22 Basf Se Procede d'application de revetements sur des surfaces et particules adaptees a cet effet
US7906172B2 (en) 2005-09-16 2011-03-15 Basf Aktiengesellschaft Method for coating surfaces and suitable particles therefor
WO2008090191A3 (fr) * 2007-01-26 2010-01-07 Basf Se Particules, procédé de fabrication et utilisation
CN103451924A (zh) * 2013-07-24 2013-12-18 吴江市七都镇庙港雅迪针织制衣厂 一种含有甘露醇的羊毛衫拒水拒油整理剂

Also Published As

Publication number Publication date
CA2225526A1 (fr) 1997-01-09
AU704867B2 (en) 1999-05-06
JPH11509585A (ja) 1999-08-24
EP0837963A1 (fr) 1998-04-29
AU5964596A (en) 1997-01-22

Similar Documents

Publication Publication Date Title
US5888290A (en) Composition and process for imparting durable repellency to substrates
AU704867B2 (en) Composition and process for imparting durable repellency to substrates
US5908663A (en) Topical carpet treatment
US6855772B2 (en) Water-repellent and soil-resistant finish for textiles
US5714082A (en) Aqueous anti-soiling composition
JP5529121B2 (ja) 水性重合体分散組成物および表面処理剤
JPH05271351A (ja) フツ素含有コポリマー類およびそれらから製造した水分散液
JP5680529B2 (ja) フルオロシリコーンおよび表面処理剤
JPH05279541A (ja) フツ素含有コポリマー類の混合物
JP2020056031A (ja) 撥水性で防汚性の無フッ素組成物
JP2014129532A (ja) 撥水撥油剤組成物
TW301671B (fr)
CN106460309A (zh) 拒水防污无氟组合物
WO2005056711A1 (fr) Composition chimique fluoree destinee a rendre des substrats oleofuges et/ou hydrofuges
JP2011500949A (ja) 親水性フッ素化防汚性共重合体
US20110111659A1 (en) Method using fluoropolymer emulsions
EP1227183B1 (fr) Agent de traitement de surface comprenant un matiere mixte organique/inorganique
WO2001018304A1 (fr) Appret pour textiles infroissables et resistants au frottement
CN111944106B (zh) 一种含叔胺高分子刷接枝纳米二氧化硅的复配型拒水剂
JP7417141B2 (ja) 含フッ素重合体および含フッ素組成物
US20110112233A1 (en) Fluoropolymer emulsions
EP1167616A1 (fr) Agent de traitement de surface comprenant un materiau hybride inorganique/organique
HK1173463B (en) Fluoropolymer emulsions
HK1173463A1 (en) Fluoropolymer emulsions
MXPA00011524A (en) Polymeric compositions for soil release on fabrics

Legal Events

Date Code Title Description
AK Designated states

Kind code of ref document: A1

Designated state(s): AU CA JP

AL Designated countries for regional patents

Kind code of ref document: A1

Designated state(s): AT BE CH DE DK ES FI FR GB GR IE IT LU MC NL PT SE

DFPE Request for preliminary examination filed prior to expiration of 19th month from priority date (pct application filed before 20040101)
121 Ep: the epo has been informed by wipo that ep was designated in this application
WWE Wipo information: entry into national phase

Ref document number: 1996916933

Country of ref document: EP

ENP Entry into the national phase

Ref country code: JP

Ref document number: 1997 503848

Kind code of ref document: A

Format of ref document f/p: F

ENP Entry into the national phase

Ref document number: 2225526

Country of ref document: CA

Ref country code: CA

Ref document number: 2225526

Kind code of ref document: A

Format of ref document f/p: F

WWP Wipo information: published in national office

Ref document number: 1996916933

Country of ref document: EP

WWW Wipo information: withdrawn in national office

Ref document number: 1996916933

Country of ref document: EP