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TWI755449B - Support glass substrate and laminate using the same, semiconductor package, method for producing the same, and electronic device - Google Patents

Support glass substrate and laminate using the same, semiconductor package, method for producing the same, and electronic device Download PDF

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Publication number
TWI755449B
TWI755449B TW106140335A TW106140335A TWI755449B TW I755449 B TWI755449 B TW I755449B TW 106140335 A TW106140335 A TW 106140335A TW 106140335 A TW106140335 A TW 106140335A TW I755449 B TWI755449 B TW I755449B
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glass substrate
supporting
substrate
supporting glass
processing
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TW106140335A
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Chinese (zh)
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TW201833049A (en
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鈴木良太
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日商日本電氣硝子股份有限公司
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    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B17/00Layered products essentially comprising sheet glass, or glass, slag, or like fibres
    • CCHEMISTRY; METALLURGY
    • C03GLASS; MINERAL OR SLAG WOOL
    • C03CCHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
    • C03C3/00Glass compositions
    • C03C3/04Glass compositions containing silica
    • C03C3/076Glass compositions containing silica with 40% to 90% silica, by weight
    • C03C3/083Glass compositions containing silica with 40% to 90% silica, by weight containing aluminium oxide or an iron compound
    • C03C3/085Glass compositions containing silica with 40% to 90% silica, by weight containing aluminium oxide or an iron compound containing an oxide of a divalent metal
    • CCHEMISTRY; METALLURGY
    • C03GLASS; MINERAL OR SLAG WOOL
    • C03CCHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
    • C03C3/00Glass compositions
    • C03C3/04Glass compositions containing silica
    • C03C3/076Glass compositions containing silica with 40% to 90% silica, by weight
    • C03C3/089Glass compositions containing silica with 40% to 90% silica, by weight containing boron
    • C03C3/091Glass compositions containing silica with 40% to 90% silica, by weight containing boron containing aluminium
    • CCHEMISTRY; METALLURGY
    • C03GLASS; MINERAL OR SLAG WOOL
    • C03CCHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
    • C03C3/00Glass compositions
    • C03C3/04Glass compositions containing silica
    • C03C3/076Glass compositions containing silica with 40% to 90% silica, by weight
    • C03C3/089Glass compositions containing silica with 40% to 90% silica, by weight containing boron
    • C03C3/091Glass compositions containing silica with 40% to 90% silica, by weight containing boron containing aluminium
    • C03C3/093Glass compositions containing silica with 40% to 90% silica, by weight containing boron containing aluminium containing zinc or zirconium
    • H10P72/70
    • H10W70/60
    • H10W70/692
    • H10W72/0198
    • H10W72/241

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  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Geochemistry & Mineralogy (AREA)
  • Materials Engineering (AREA)
  • Organic Chemistry (AREA)
  • Glass Compositions (AREA)

Abstract

本發明的支撐玻璃基板用以支撐加工基板,且所述支撐玻璃基板的特徵在於:作為玻璃組成,以質量%計含有45%~70%的SiO2、超過10.5%~35%的Al2O3、0%~20%的B2O3、5%~25%的Na2O、0%~10%的K2O、1%~10%的MgO、以及0%~5%的ZnO,且裂紋阻力為500gf以上。 The supporting glass substrate of the present invention is used to support a processing substrate, and the supporting glass substrate is characterized in that, as a glass composition, 45% to 70% of SiO 2 and more than 10.5% to 35% of Al 2 O are contained in mass %. 3. 0%~20% B 2 O 3 , 5%~25% Na 2 O, 0%~10% K 2 O, 1%~10% MgO, and 0%~5% ZnO, And the crack resistance is 500gf or more.

Description

支撐玻璃基板及使用其的積層體、半導體封裝 體及其製造方法以及電子機器 Support glass substrate and laminate and semiconductor package using the same body, method of making the same, and electronic machine

本發明是有關於一種用以支撐加工基板的支撐玻璃基板及使用其的積層體,具體而言,是有關於一種在半導體封裝體(半導體裝置)的製造步驟中用於加工基板的支撐的支撐玻璃基板及使用其的積層體。 The present invention relates to a support glass substrate for supporting a processing substrate and a laminate using the same, and more specifically, to a support for supporting a processing substrate in a manufacturing step of a semiconductor package (semiconductor device). A glass substrate and a laminate using the same.

對行動電話、筆記型個人電腦、個人數位助理(Personal Data Assistance,PDA)等可攜式電子機器要求小型化及輕量化。伴隨於此,該些電子機器中使用的半導體晶片(chip)的安裝空間亦受到嚴格限制,從而半導體晶片的高密度安裝成為課題。因此,近年來,藉由三維安裝技術,即,將半導體晶片彼此積層而將各半導體晶片間進行配線連接,來實現半導體封裝體的高密度安裝。 Portable electronic devices such as mobile phones, notebook personal computers, and personal digital assistants (PDAs) are required to be miniaturized and lightweight. Along with this, the mounting space of semiconductor chips (chips) used in these electronic devices is also severely restricted, and high-density mounting of semiconductor chips has become a problem. Therefore, in recent years, high-density mounting of semiconductor packages has been realized by three-dimensional mounting technology, that is, by laminating semiconductor wafers to each other and connecting the semiconductor wafers with wires.

另外,現有的晶圓級封裝體(Wafer Level Package,WLP)是藉由以晶圓的狀態形成凸塊後,利用切割加以單片化而製作。然而,現有的WLP中難以增加接腳數,除此之外是以半導體晶片的背面露出的狀態安裝,故有半導體晶片容易產生缺損等問題。 In addition, the conventional Wafer Level Package (WLP) is fabricated by forming bumps in the state of wafers, and then singulation by dicing. However, in the conventional WLP, it is difficult to increase the number of pins, and in addition to that, the semiconductor wafer is mounted in a state where the back surface of the semiconductor wafer is exposed, so there is a problem that the semiconductor wafer is easily damaged.

因此,作為新的WLP,提出一種扇出(fan out)型WLP。扇出型WLP能夠增加接腳數,且藉由保護半導體晶片的端部,可防止半導體晶片的缺損等。 Therefore, as a new WLP, a fan out type WLP is proposed. The fan-out type WLP can increase the number of pins, and by protecting the end of the semiconductor chip, it can prevent chipping of the semiconductor chip, etc.

扇出型WLP的製造步驟中例如包括:於將多個半導體晶片排列於支撐玻璃基板上後,利用樹脂的密封材進行成形而形成加工基板後,在加工基板的一表面進行配線的步驟;以及形成焊料凸塊的步驟等。 The manufacturing steps of the fan-out WLP include, for example, the steps of arranging a plurality of semiconductor wafers on a supporting glass substrate, molding with a resin sealing material to form a processing substrate, and performing wiring on one surface of the processing substrate; and Steps of forming solder bumps, etc.

且說,包括加工基板與支撐玻璃基板的積層體於扇出型WLP的製造步驟中在支撐玻璃基板側與搬送輸送機接觸的狀態下沿水平方向搬送。另外,於由機器臂等握持支撐玻璃基板的端緣部的狀態下進行搬送。 In addition, in the manufacturing process of a fan-out WLP, the laminated body which consists of a process board|substrate and a support glass substrate is conveyed in the horizontal direction in the state in which the support glass substrate side was in contact with the conveyance conveyor. Moreover, it conveys in the state which hold|grip and support the edge part of a glass substrate by a robot arm or the like.

但是,支撐玻璃基板在積層體的搬送時容易受到來自搬送輸送機或機器臂的機械性衝擊。而且,若支撐玻璃基板受到機械性衝擊,則有時支撐玻璃基板產生裂紋,且以所述裂紋為起點支撐玻璃基板發生破損。 However, the support glass substrate is liable to receive mechanical shock from a conveyance conveyor or a robot arm at the time of conveyance of the laminate. Moreover, when a support glass substrate receives a mechanical impact, a crack may generate|occur|produce in a support glass substrate, and a support glass substrate may be damaged from the said crack as a starting point.

本發明是鑒於所述情況而成者,其技術性課題在於創造一種於扇出型WLP的製造步驟中在積層體的搬送時不易產生裂紋的支撐玻璃基板。 The present invention was made in view of the above-mentioned circumstances, and its technical subject is to create a supporting glass substrate in which cracks are less likely to occur at the time of conveyance of the laminate in the production process of the fan-out WLP.

本發明者反覆進行了各種實驗,結果發現,選擇鹼性矽酸鋁玻璃作為支撐玻璃基板,並且嚴密地限制該鹼性矽酸鋁玻璃的玻璃組成範圍,並提高裂紋阻力,藉此可解決所述技術性課題,從而提出本發明。即,本發明的支撐玻璃基板用以支撐加工基板, 且所述支撐玻璃基板的特徵在於:作為玻璃組成,以質量%計含有45%~70%的SiO2、超過10.5%~35%的Al2O3、0%~20%的B2O3、5%~25%的Na2O、0%~10%的K2O、1%~10%的MgO、以及0%~5%的ZnO,且裂紋阻力為500gf以上。此處,所謂「裂紋阻力」是指裂紋產生率為50%的負荷。「裂紋產生率」是指以如下方式測定而得的值。首先,於保持為濕度30%、溫度25℃的恒溫恒濕槽內,將設定為規定負荷的維氏壓頭朝玻璃表面(光學研磨面)打入15秒,於所述15秒後對自壓痕的四角產生的裂紋的數量進行計數(設為一個壓痕最大為4)。如此,將壓頭打入20次,於求出總裂紋產生數後,藉由(總裂紋產生數/80)×100的式子求出。裂紋阻力的測定裝置例如可使用未來科技(Future Tech)公司製造的幕太維氏(multi Vickers)硬度計FLC-50VX。 The inventors have repeatedly carried out various experiments, and found that, by selecting alkali aluminosilicate glass as the supporting glass substrate, and strictly limiting the glass composition range of the alkali aluminosilicate glass, and increasing the crack resistance, the problem can be solved. The present invention has been proposed in order to solve the technical problem. That is, the supporting glass substrate of the present invention is used to support a processing substrate, and the supporting glass substrate is characterized in that, as a glass composition, 45% to 70% of SiO 2 and more than 10.5% to 35% of Al are contained in mass %. 2 O 3 , 0%~20% B 2 O 3 , 5%~25% Na 2 O, 0%~10% K 2 O, 1%~10% MgO, and 0%~5% ZnO, and the crack resistance is 500 gf or more. Here, "crack resistance" refers to a load with a crack occurrence rate of 50%. "Crack occurrence rate" means the value measured as follows. First, in a constant temperature and humidity tank maintained at a humidity of 30% and a temperature of 25°C, a Vickers indenter set to a predetermined load was driven into the glass surface (optical polishing surface) for 15 seconds, and after the 15 seconds The number of cracks generated at the four corners of the indentation was counted (a maximum of 4 indentations was set). In this way, the indenter was driven 20 times, and after obtaining the total number of cracks, it was obtained by the formula of (total number of cracks/80)×100. As a measuring device for crack resistance, for example, a multi Vickers hardness tester FLC-50VX manufactured by Future Tech can be used.

第二,本發明的支撐玻璃基板較佳為作為玻璃組成,以質量%計含有50%~67%的SiO2、19.7%~33%的Al2O3、0%~15%的B2O3、5%~20%的Na2O、0%~3%的K2O、1%~5.5%的MgO、以及0%~3%的ZnO,且裂紋阻力為700gf以上。 Second, the supporting glass substrate of the present invention is preferably composed of glass, and contains 50%-67% SiO 2 , 19.7%-33% Al 2 O 3 , and 0%-15% B 2 O in mass %. 3. 5%~20% Na 2 O, 0%~3% K 2 O, 1%~5.5% MgO, and 0%~3% ZnO, and the crack resistance is more than 700gf.

第三,本發明的支撐玻璃基板較佳為在20℃~220℃的溫度範圍內的平均線熱膨脹係數為40×10-7/℃以上且120×10-7/℃以下。據此,於在加工基板內對半導體晶片與密封材的比例進行變更的情況下,容易使加工基板與支撐玻璃基板的線熱膨脹係數嚴密地匹配。而且,若兩者的線熱膨脹係數相匹配,則於加工處理時容易抑制加工基板的尺寸變化(尤其是翹曲變形)。結果能夠 在加工基板的一表面進行高密度配線,且亦可準確地形成焊料凸塊。此處,「在20℃~220℃的溫度範圍內的平均線熱膨脹係數」可利用膨脹計(dilatometer)進行測定。 Third, the supporting glass substrate of the present invention preferably has an average linear thermal expansion coefficient in a temperature range of 20°C to 220°C of 40×10 -7 /°C or more and 120×10 -7 /°C or less. Thereby, when changing the ratio of a semiconductor wafer and a sealing material in a process board|substrate, it becomes easy to closely match the linear thermal expansion coefficient of a process board|substrate and a support glass substrate. Furthermore, when the linear thermal expansion coefficients of the two are matched, it is easy to suppress dimensional changes (especially warpage deformation) of the processed substrate during processing. As a result, high-density wiring can be performed on one surface of the processed substrate, and solder bumps can also be accurately formed. Here, "the average linear thermal expansion coefficient in the temperature range of 20 degreeC - 220 degreeC" can be measured with a dilatometer.

第四,本發明的支撐玻璃基板較佳為在20℃~260℃的溫度範圍內的平均線熱膨脹係數為40×10-7/℃以上且120×10-7/℃以下。此處,「在20℃~260℃的溫度範圍內的平均線熱膨脹係數」可利用膨脹計進行測定。 Fourth, the supporting glass substrate of the present invention preferably has an average linear thermal expansion coefficient in a temperature range of 20°C to 260°C of 40×10 −7 /°C or more and 120×10 −7 /°C or less. Here, the "average coefficient of linear thermal expansion in the temperature range of 20°C to 260°C" can be measured with a dilatometer.

第五,本發明的支撐玻璃基板較佳為在30℃~380℃的溫度範圍內的平均線熱膨脹係數為42×10-7/℃以上且125×10-7/℃以下。此處,「在30℃~380℃的溫度範圍內的平均線熱膨脹係數」可利用膨脹計進行測定。 Fifth, the supporting glass substrate of the present invention preferably has an average linear thermal expansion coefficient in a temperature range of 30°C to 380°C of 42×10 −7 /°C or more and 125×10 −7 /°C or less. Here, "the average coefficient of linear thermal expansion in the temperature range of 30°C to 380°C" can be measured with a dilatometer.

第六,本發明的支撐玻璃基板較佳為具有直徑100mm~500mm的晶圓形狀或大致圓板形狀,板厚小於2.0mm,整體板厚偏差(Total Thickness Variation,TTV)為5μm以下,且翹曲量為60μm以下。此處,「翹曲量」是指支撐玻璃基板整體中的最高位點與最小平方焦點面之間的最大距離的絕對值、和最低位點與最小平方焦點面的絕對值的合計,例如可藉由神鋼(KOBELCO)科研公司製造的彎曲/翹曲(Bow/Warp)測定裝置SBW-331M/Ld進行測定。 Sixth, the supporting glass substrate of the present invention preferably has a wafer shape with a diameter of 100 mm to 500 mm or a roughly circular plate shape, a thickness of less than 2.0 mm, a Total Thickness Variation (TTV) of less than 5 μm, and a warped shape. The amount of curvature is 60 μm or less. Here, the "warpage amount" refers to the total of the absolute value of the maximum distance between the highest point and the least square focal plane in the entire supporting glass substrate, and the absolute value of the lowest point and the least square focal plane, and may be, for example, The measurement was performed with a Bow/Warp measuring device SBW-331M/Ld manufactured by KOBELCO Scientific Corporation.

第七,本發明的積層體較佳為至少包括加工基板及用以支撐加工基板的支撐玻璃基板,且支撐玻璃基板為所述支撐玻璃基板。 Seventh, the laminated body of the present invention preferably includes at least a processing substrate and a supporting glass substrate for supporting the processing substrate, and the supporting glass substrate is the supporting glass substrate.

第八,本發明的積層體較佳為加工基板至少包括利用密封材進行了成形的半導體晶片。 Eighthly, in the layered product of the present invention, it is preferable that the processing substrate includes at least a semiconductor wafer formed by a sealing material.

第九,本發明的半導體封裝體的製造方法較佳為包括:準備至少包括加工基板及用以支撐加工基板的支撐玻璃基板的積層體的步驟;以及對加工基板進行加工處理的步驟,並且支撐玻璃基板為所述支撐玻璃基板。 Ninth, the method for manufacturing a semiconductor package of the present invention preferably includes: a step of preparing a laminate including at least a processed substrate and a supporting glass substrate for supporting the processed substrate; and a step of processing the processed substrate, and supporting The glass substrate is the supporting glass substrate.

第十,本發明的半導體封裝體的製造方法較佳為加工處理包括在加工基板的一表面進行配線的步驟。 Tenth, in the manufacturing method of the semiconductor package of the present invention, it is preferable that the processing includes the step of wiring on one surface of the processing substrate.

第十一,本發明的半導體封裝體的製造方法較佳為加工處理包括在加工基板的一表面形成焊料凸塊的步驟。 Eleventh, in the manufacturing method of the semiconductor package of the present invention, preferably, the processing includes the step of forming solder bumps on a surface of the processing substrate.

第十二,本發明的半導體封裝體較佳為利用所述半導體封裝體的製造方法製作。 Twelfth, the semiconductor package of the present invention is preferably fabricated by using the manufacturing method of the semiconductor package.

第十三,本發明的電子機器較佳為包括半導體封裝體,且半導體封裝體為所述半導體封裝體。 Thirteenth, the electronic apparatus of the present invention preferably includes a semiconductor package, and the semiconductor package is the semiconductor package.

1、27:積層體 1, 27: Laminate

10、26、31、35:支撐玻璃基板 10, 26, 31, 35: Supporting glass substrate

11、24:加工基板 11, 24: Processing substrate

12:剝離層 12: Peel layer

13、21、25:接著層 13, 21, 25: Next layer

20:支撐構件 20: Support member

22:半導體晶片 22: Semiconductor wafer

23:密封材 23: Sealing material

28:配線 28: Wiring

29:焊料凸塊 29: Solder bumps

32、36:凹口部 32, 36: Notches

33、37:外形部 33, 37: External appearance

34、38:凹口部的深部 34, 38: Deep part of the notch

39、40:支撐玻璃基板的表面 39, 40: Supporting the surface of the glass substrate

41:支撐玻璃基板的端面 41: Supporting the end face of the glass substrate

42、43:支撐玻璃基板的倒角面 42, 43: The chamfered surface of the supporting glass substrate

X、Y+Y':倒角寬度 X, Y+Y': chamfer width

t:板厚 t: plate thickness

圖1是表示本發明的積層體的一例的概念立體圖。 FIG. 1 is a conceptual perspective view showing an example of the laminate of the present invention.

圖2(a)~圖2(g)是表示扇出型WLP的製造步驟的概念剖面圖。 FIGS. 2( a ) to 2 ( g ) are conceptual cross-sectional views showing manufacturing steps of the fan-out WLP.

圖3(a)、圖3(b)為表示本發明的支撐玻璃基板的一例的上方概念圖。 FIG.3(a), FIG.3(b) is an upper conceptual diagram which shows an example of the support glass substrate of this invention.

圖4為圖3(a)的A-A'方向的剖面概念圖。 Fig. 4 is a conceptual cross-sectional view taken in the AA' direction of Fig. 3(a).

本發明的支撐玻璃基板的特徵在於:作為玻璃組成,以質量%計含有45%~70%的SiO2、超過10.5%~35%的Al2O3、0%~20%的B2O3、5%~25%的Na2O、0%~10%的K2O、1%~10%的MgO、以及0%~5%的ZnO。以下表示如所述般限定各成分的含量的理由。再者,各成分的含量的說明中,%表達是表示質量%。 The supporting glass substrate of the present invention is characterized in that, as a glass composition, 45% to 70% of SiO 2 , more than 10.5% to 35% of Al 2 O 3 , and 0% to 20% of B 2 O 3 are contained in mass %. , 5%~25% Na 2 O, 0%~10% K 2 O, 1%~10% MgO, and 0%~5% ZnO. The reason for limiting the content of each component as described above is shown below. In addition, in the description of the content of each component, % expression means mass %.

SiO2是形成玻璃的骨架的主成分。若SiO2的含量過少,則楊氏模量、耐酸性容易下降。但是,若SiO2的含量過多,則高溫黏度增高,熔融性、成形性容易下降,除此之外白矽石(cristobalite)等的失透結晶容易析出,液相溫度容易上升。因此,SiO2的下限範圍為45%以上,較佳為47%以上、尤其是49%以上,上限範圍為70%以下,較佳為68%以下、66%以下、尤其是65%以下,於使熔融性優先的情況下,為64%以下、63%以下、尤其是62%以下。 SiO 2 is the main component that forms the skeleton of glass. When the content of SiO 2 is too small, the Young's modulus and acid resistance tend to decrease. However, when the content of SiO 2 is too large, the high-temperature viscosity increases, and the meltability and formability tend to decrease. In addition, devitrification crystals such as cristobalite tend to precipitate, and the liquidus temperature tends to rise. Therefore, the lower limit range of SiO 2 is 45% or more, preferably 47% or more, especially 49% or more, and the upper limit range is 70% or less, preferably 68% or less, 66% or less, especially 65% or less. When giving priority to meltability, it is 64% or less, 63% or less, especially 62% or less.

Al2O3是提高裂紋阻力的成分。且是抑制分相、失透的成分。但是,若Al2O3的含量過多,則高溫黏度增高,熔融性與成形性容易下降。因此,Al2O3的下限範圍超過10.5%,較佳為11%以上、13%以上、15%以上、17%以上、尤其是19.7%以上,上限範圍為35%以下,較佳為30%以下,於使熔融性、成形性優先的情況下,為25%以下、尤其是20%以下。 Al 2 O 3 is a component that improves crack resistance. Furthermore, it is a component that suppresses phase separation and devitrification. However, when the content of Al 2 O 3 is too large, the high temperature viscosity increases, and the meltability and formability tend to decrease. Therefore, the lower limit range of Al 2 O 3 exceeds 10.5%, preferably 11% or more, 13% or more, 15% or more, 17% or more, especially 19.7% or more, and the upper limit range is 35% or less, preferably 30% Hereinafter, when giving priority to meltability and formability, it is 25% or less, especially 20% or less.

B2O3是提高熔融性、耐失透性的成分,且為改善裂紋阻力的成分。但是,若B2O3的含量過多,則楊氏模量、耐酸性容易 下降。因此,B2O3的下限範圍為0%以上,較佳為1%以上、2%以上、3%以上、尤其是4%以上,上限範圍為20%以下,較佳為15%以下、13%以下、11%以下、尤其是9%以下。 B 2 O 3 is a component that improves meltability and devitrification resistance, and is a component that improves crack resistance. However, when the content of B 2 O 3 is too large, the Young's modulus and acid resistance tend to decrease. Therefore, the lower limit range of B 2 O 3 is 0% or more, preferably 1% or more, 2% or more, 3% or more, especially 4% or more, and the upper limit range is 20% or less, preferably 15% or less, 13% or more % or less, 11% or less, especially 9% or less.

Na2O是用以調整線熱膨脹係數的重要的成分,且是有助於玻璃原料的初期的熔融的成分。但是,若Na2O的含量過多,則有線熱膨脹係數不合理地增高之虞。因此,Na2O的下限範圍為5%以上,較佳為6%以上、7%以上、8%以上、尤其是9%以上,上限範圍為25%以下,較佳為23%以下、21%以下、尤其是18%以下。 Na 2 O is an important component for adjusting the coefficient of linear thermal expansion, and is a component that contributes to the initial melting of glass raw materials. However, when the content of Na 2 O is too large, the linear thermal expansion coefficient may increase unreasonably. Therefore, the lower limit range of Na 2 O is 5% or more, preferably 6% or more, 7% or more, 8% or more, especially 9% or more, and the upper limit range is 25% or less, preferably 23% or less, 21% below, especially below 18%.

K2O是用以調整線熱膨脹係數的成分,且是有助於玻璃原料的初期的熔融的成分。但是,若K2O的含量過多,則有線熱膨脹係數不合理地增高之虞。因此,K2O的含量為0%~10%,較佳為0%~6%、0%~5%、0.1%~1.9%、尤其是0.2%~小於1%。 K 2 O is a component for adjusting the coefficient of linear thermal expansion, and is a component that contributes to the initial melting of the glass raw material. However, when the content of K 2 O is too large, the linear thermal expansion coefficient may increase unreasonably. Therefore, the content of K 2 O is 0% to 10%, preferably 0% to 6%, 0% to 5%, 0.1% to 1.9%, especially 0.2% to less than 1%.

MgO是提高裂紋阻力的成分。另外是降低高溫黏性而提高熔融性的成分,且為鹼土類金屬氧化物中顯著提高楊氏模量的成分。但是,若MgO的含量變多,則耐失透性容易下降。因此,MgO的含量為1%~10%,較佳為1%~6%、1%~5.5%、2%~5%、尤其是3%~小於4%。 MgO is a component that improves crack resistance. In addition, it is a component that reduces high temperature viscosity and improves meltability, and is a component that significantly increases Young's modulus among alkaline earth metal oxides. However, when the content of MgO increases, the devitrification resistance tends to decrease. Therefore, the content of MgO is 1% to 10%, preferably 1% to 6%, 1% to 5.5%, 2% to 5%, especially 3% to less than 4%.

質量比(Al2O3+B2O3+MgO)/(Na2O+K2O)較佳為1.3以上、1.5以上、2.0以上、2.5以上、尤其是3.0以上。若質量比(Al2O3+B2O3+MgO)/(Na2O+K2O)過小,則裂紋阻力下降,或者容易受到損傷,支撐玻璃基板容易因裂紋發生破損。 The mass ratio (Al 2 O 3 +B 2 O 3 +MgO)/(Na 2 O+K 2 O) is preferably 1.3 or more, 1.5 or more, 2.0 or more, 2.5 or more, especially 3.0 or more. When the mass ratio (Al 2 O 3 +B 2 O 3 +MgO)/(Na 2 O+K 2 O) is too small, crack resistance decreases or damage is likely to occur, and the supporting glass substrate is likely to be damaged by cracks.

ZnO是降低高溫黏性而顯著提高熔融性、成形性的成分,且是提高耐候性的成分。但是,若ZnO的含量過多,則玻璃容易失透。因此,ZnO的含量為0%~5%,較佳為0%~4%、0.1%~2%、尤其是0.3%~1.5%。 ZnO is a component that reduces high-temperature viscosity to remarkably improve meltability and formability, and is a component that improves weather resistance. However, when the content of ZnO is too large, the glass tends to devitrify. Therefore, the content of ZnO is 0% to 5%, preferably 0% to 4%, 0.1% to 2%, especially 0.3% to 1.5%.

除所述成分以外,亦可導入其他成分作為任意成分。再者,自的確享有本發明的效果的觀點考慮,所述成分以外的其他成分的含量較佳為以合計量計為25%以下、20%以下、15%以下、10%以下、尤其是5%以下。 In addition to the above-mentioned components, other components may be introduced as optional components. Furthermore, from the viewpoint of actually enjoying the effects of the present invention, the content of other components other than the above-mentioned components is preferably 25% or less, 20% or less, 15% or less, 10% or less, especially 5% in total. %the following.

Li2O是降低高溫黏性而顯著提高熔融性、成形性的成分。且是提高楊氏模量的成分。但是,若Li2O的含量過多,則玻璃容易失透。因此,Li2O的含量較佳為0%~7%、0%~3%、0%~1%、尤其是0.01%~0.1%。 Li 2 O is a component that reduces high-temperature viscosity and remarkably improves meltability and formability. And it is a component which raises Young's modulus. However, when the content of Li 2 O is too large, the glass tends to devitrify. Therefore, the content of Li 2 O is preferably 0% to 7%, 0% to 3%, 0% to 1%, especially 0.01% to 0.1%.

CaO是降低高溫黏性而顯著提高熔融性、成形性的成分。且是鹼土類金屬氧化物中因導入原料相對廉價故使原料成本低廉化的成分。但是,若CaO的含量過多,則玻璃容易失透。因此,CaO的含量較佳為0%~10%、1%~8%、3%~8%、2%~6%、尤其是2%~5%。 CaO is a component that reduces high temperature viscosity and remarkably improves meltability and formability. In addition, it is a component of the alkaline earth metal oxide that reduces the cost of the raw material because the raw material to be introduced is relatively inexpensive. However, when the content of CaO is too large, the glass tends to devitrify. Therefore, the content of CaO is preferably 0% to 10%, 1% to 8%, 3% to 8%, 2% to 6%, especially 2% to 5%.

SrO是抑制分相的成分,且是提高耐失透性的成分。但是,若SrO的含量過多,則玻璃容易失透。因此,SrO的含量較佳為0%~20%、0%~15%、0%~9%、0%~5%、0%~4%、0%~3%、0%~2%、尤其是0%~小於1%。再者,於使耐失透性的提高優先的情況下,SrO的較佳的下限範圍為0.1%以上、1%以上、 2%以上、4%以上、尤其是7%以上。 SrO is a component which suppresses phase separation, and is a component which improves devitrification resistance. However, when the content of SrO is too large, the glass tends to devitrify. Therefore, the content of SrO is preferably 0%~20%, 0%~15%, 0%~9%, 0%~5%, 0%~4%, 0%~3%, 0%~2%, Especially 0% to less than 1%. In addition, when giving priority to the improvement of devitrification resistance, the preferable lower limit range of SrO is 0.1% or more, 1% or more, More than 2%, more than 4%, especially more than 7%.

BaO是提高耐失透性的成分。但是,若BaO的含量過多,則玻璃容易失透。因此,BaO的含量較佳為0%~20%、0%~14%、0%~9%、0%~5%、0%~4%、0%~3%、0%~2%、尤其是0%~小於1%。再者,於使耐失透性的提高優先的情況下,BaO的較佳的下限範圍為0.1%以上、1%以上、尤其是3%以上。 BaO is a component which improves devitrification resistance. However, when the content of BaO is too large, the glass tends to devitrify. Therefore, the content of BaO is preferably 0%~20%, 0%~14%, 0%~9%, 0%~5%, 0%~4%, 0%~3%, 0%~2%, Especially 0% to less than 1%. In addition, when giving priority to improvement of devitrification resistance, the preferable lower limit range of BaO is 0.1% or more, 1% or more, and especially 3% or more.

Fe2O3是可作為雜質成分或澄清劑成分導入的成分。但是,若Fe2O3的含量過多,則有紫外線透過率下降之虞。即,若Fe2O3的含量過多,則有時難以經由樹脂層、剝離層來適當地進行加工基板與支撐玻璃基板的黏結與脫附。因此,Fe2O3的含量較佳為0.05%以下、0.03%以下、0.001%~0.02%、尤其是0.005%~0.01%。再者,本發明中提及的「Fe2O3」包含2價氧化鐵與3價氧化鐵,2價氧化鐵換算為Fe2O3,而進行處理。關於其他氧化物,同樣地以表述的氧化物為基準而進行處理。 Fe 2 O 3 is a component that can be introduced as an impurity component or a clarifying agent component. However, when there is too much content of Fe2O3 , there exists a possibility that an ultraviolet-ray transmittance may fall. That is, when the content of Fe 2 O 3 is too large, it may be difficult to appropriately adhere and desorb the processed substrate and the supporting glass substrate via the resin layer and the peeling layer. Therefore, the content of Fe 2 O 3 is preferably 0.05% or less, 0.03% or less, 0.001% to 0.02%, especially 0.005% to 0.01%. In addition, " Fe2O3 " mentioned in this invention contains bivalent iron oxide and trivalent iron oxide, and bivalent iron oxide is converted into Fe2O3 , and is processed. Regarding other oxides, the same treatment is performed on the basis of the stated oxides.

作為澄清劑,As2O3有效地發揮作用,就環境的觀點而言,較佳為極力減少該些成分。As2O3的含量較佳為1%以下、0.5%以下、尤其是0.1%以下,理想的是實質不含有。此處,所謂「實質不含有As2O3」是指玻璃組成中的As2O3的含量小於0.05%的情況。 As a clarifying agent, As 2 O 3 functions effectively, and it is preferable to reduce these components as much as possible from the viewpoint of the environment. The content of As 2 O 3 is preferably not more than 1%, not more than 0.5%, especially not more than 0.1%, and desirably not substantially contained. Here, "substantially not containing As 2 O 3 " means that the content of As 2 O 3 in the glass composition is less than 0.05%.

Sb2O3是在低溫區域具有良好的澄清作用的成分。Sb2O3的含量較佳為0%~1%、0.001%~1%、0.01%~0.9%、尤其是0.05%~0.7%。若Sb2O3的含量過多,則玻璃容易著色。 Sb 2 O 3 is a component having a good clarifying effect in a low temperature region. The content of Sb 2 O 3 is preferably 0% to 1%, 0.001% to 1%, 0.01% to 0.9%, especially 0.05% to 0.7%. When the content of Sb 2 O 3 is too large, the glass tends to be colored.

SnO2是在高溫區域具有良好的澄清作用的成分,且是使高溫黏性下降的成分。SnO2的含量較佳為0%~1%、0.001%~1%、0.01%~0.9%、尤其是0.05%~0.7%。若SnO2的含量過多,則SnO2的失透結晶容易析出。再者,若SnO2的含量過少,則難以享有所述效果。 SnO 2 is a component which has a favorable clarifying effect in a high temperature region, and is a component which reduces high temperature viscosity. The content of SnO 2 is preferably 0% to 1%, 0.001% to 1%, 0.01% to 0.9%, especially 0.05% to 0.7%. When the content of SnO 2 is too large, devitrification crystals of SnO 2 are likely to be precipitated. Furthermore, when the content of SnO 2 is too small, it is difficult to obtain the above-mentioned effects.

SO3是具有澄清作用的成分。SO3的含量較佳為0%~1%、0.001%~1%、0.01%~0.5%、尤其是0.05%~0.3%。若SO3的含量過多,則容易產生SO2再沸(reboil)。 SO 3 is a clarifying ingredient. The content of SO 3 is preferably 0% to 1%, 0.001% to 1%, 0.01% to 0.5%, especially 0.05% to 0.3%. When the content of SO 3 is too large, SO 2 reboil is likely to occur.

進而,只要不損害玻璃特性,亦可分別導入F、C、或Al、Si等金屬粉末至1%左右作為澄清劑。而且,CeO2等亦可導入1%左右,但需要留意紫外線透過率的下降。 Furthermore, as long as the glass properties are not impaired, metal powders such as F, C, or Al, Si, etc., may be respectively introduced to about 1% as a clarifying agent. In addition, CeO 2 can also be introduced into about 1%, but it is necessary to pay attention to the decrease of ultraviolet transmittance.

Cl是促進玻璃的熔融的成分。若向玻璃組成中導入Cl,則可實現熔融溫度的低溫化、澄清作用的促進,結果,容易達成熔融成本的低廉化、玻璃製造爐的長壽命化。但是,若Cl的含量過多,則有使玻璃製造爐周圍的金屬零件腐蝕之虞。因此,Cl的含量較佳為3%以下、1%以下、0.5%以下、尤其是0.1%以下。 Cl is a component that promotes melting of glass. When Cl is introduced into the glass composition, the lowering of the melting temperature and the promotion of the clarification effect can be achieved, and as a result, the reduction of the melting cost and the prolongation of the life of the glass manufacturing furnace can be easily achieved. However, when there is too much content of Cl, there exists a possibility of corroding metal parts around a glass manufacturing furnace. Therefore, the content of Cl is preferably 3% or less, 1% or less, 0.5% or less, especially 0.1% or less.

P2O5是可抑制失透結晶的析出的成分。但是,若大量導入P2O5,則玻璃容易分相。因此,P2O5的含量較佳為0%~15%、0%~2.5%、0%~1.5%、0%~0.5%、尤其是0.1%~0.3%。 P 2 O 5 is a component that suppresses precipitation of devitrified crystals. However, when a large amount of P 2 O 5 is introduced, the glass tends to be phase-separated. Therefore, the content of P 2 O 5 is preferably 0% to 15%, 0% to 2.5%, 0% to 1.5%, 0% to 0.5%, especially 0.1% to 0.3%.

TiO2是降低高溫黏性並提高熔融性的成分,且是抑制曝曬作用(solarization)的成分。但是,若大量導入TiO2,則玻璃著色,透過率容易下降。因此,TiO2的含量較佳為0%~5%、0% ~3%、0%~1%、尤其是0%~0.02%。 TiO 2 is a component that reduces high-temperature viscosity and improves meltability, and is a component that suppresses solarization. However, when a large amount of TiO 2 is introduced, the glass is colored and the transmittance tends to decrease. Therefore, the content of TiO 2 is preferably 0% to 5%, 0% to 3%, 0% to 1%, especially 0% to 0.02%.

ZrO2是改善耐化學品性、楊氏模量的成分。但是,若大量導入ZrO2,則玻璃容易失透,而且導入原料為難熔解性,因而有未熔解的結晶性異物混入至製品基板之虞。因此,ZrO2的含量較佳為0%~10%、0%~7%、0%~5%、0.001%~3%、0.01%~1%、尤其是0.1%~0.5%。 ZrO 2 is a component that improves chemical resistance and Young's modulus. However, when a large amount of ZrO 2 is introduced, the glass is easily devitrified, and the introduction raw material is refractory, so there is a possibility that undissolved crystalline foreign matter is mixed into the product substrate. Therefore, the content of ZrO 2 is preferably 0%~10%, 0%~7%, 0%~5%, 0.001%~3%, 0.01%~1%, especially 0.1%~0.5%.

Y2O3、Nb2O5、La2O3中具有提高應變點、楊氏模量等的作用。但是,若該些成分的含量分別為5%,尤其多於1%,則有原料成本、製品成本高漲之虞。 Y 2 O 3 , Nb 2 O 5 , and La 2 O 3 have the effect of increasing the strain point, Young's modulus, and the like. However, when the content of these components is respectively 5%, especially more than 1%, the cost of raw materials and the cost of products may increase.

本發明的支撐玻璃基板較佳為具有以下特性。 The supporting glass substrate of the present invention preferably has the following characteristics.

裂紋阻力為500gf以上,較佳為600gf以上、700gf以上、800gf以上、900gf以上、尤其是1000gf以上。若裂紋阻力低,則於扇出型WLP的製造步驟中,由於來自搬送輸送機或機器臂的機械性衝擊,支撐玻璃基板產生裂紋,以所述裂紋為起點,支撐玻璃基板容易發生破損。 The crack resistance is 500 gf or more, preferably 600 gf or more, 700 gf or more, 800 gf or more, 900 gf or more, especially 1000 gf or more. When the crack resistance is low, the supporting glass substrate is likely to be damaged due to a mechanical impact from a conveying conveyor or a robot arm in the manufacturing process of the fan-out WLP.

20℃~220℃的溫度範圍內的平均線熱膨脹係數較佳為40×10-7/℃以上且120×10-7/℃以下,更佳為超過50×10-7/℃以上且110×10-7/℃以下,進而佳為60×10-7/℃以上且100×10-7/℃以下,尤佳為70×10-7/℃以上且95×10-7/℃以下。若20℃~220℃的溫度範圍內的平均線熱膨脹係數為所述範圍外,則加工基板與支撐玻璃基板的線熱膨脹係數難以匹配。而且,若兩者的線熱膨脹係數不匹配,則加工處理時容易產生加工基板的尺寸變化(尤其是翹曲 變形)。 The average linear thermal expansion coefficient in the temperature range of 20°C to 220°C is preferably 40×10 -7 /°C or more and 120×10 -7 /°C or less, more preferably more than 50×10 -7 /°C or more and 110× 10 -7 /°C or lower, more preferably 60×10 -7 /°C or higher and 100×10 -7 /°C or lower, particularly preferably 70×10 -7 /°C or higher and 95×10 -7 /°C or lower. If the average coefficient of linear thermal expansion in the temperature range of 20° C. to 220° C. is outside the range, it is difficult to match the coefficient of linear thermal expansion of the processing substrate and the supporting glass substrate. Furthermore, if the linear thermal expansion coefficients of the two do not match, dimensional changes (especially warpage deformation) of the processed substrate are likely to occur during processing.

20℃~260℃的溫度範圍內的平均線熱膨脹係數較佳為40×10-7/℃以上且120×10-7/℃以下,更佳為超過50×10-7/℃且110×10-7/℃以下,進而佳為60×10-7/℃以上且100×10-7/℃以下,尤佳為70×10-7/℃以上且95×10-7/℃以下。若20℃~260℃的溫度範圍內的平均線熱膨脹係數為所述範圍外,則加工基板與支撐玻璃基板的線熱膨脹係數難以匹配。而且,若兩者的線熱膨脹係數不匹配,則加工處理時容易產生加工基板的尺寸變化(尤其是翹曲變形)。 The average linear thermal expansion coefficient in the temperature range of 20°C to 260°C is preferably 40×10 -7 /°C or more and 120×10 -7 /°C or less, more preferably more than 50×10 -7 /°C and 110×10 -7 /°C or lower, more preferably 60×10 -7 /°C or higher and 100×10 -7 /°C or lower, particularly preferably 70×10 -7 /°C or higher and 95×10 -7 /°C or lower. When the average coefficient of linear thermal expansion in the temperature range of 20° C. to 260° C. is outside the range, it is difficult to match the coefficient of linear thermal expansion of the processing substrate and the supporting glass substrate. Furthermore, if the linear thermal expansion coefficients of the two do not match, dimensional changes (especially warpage deformation) of the processed substrate are likely to occur during processing.

30℃~380℃的溫度範圍內的平均線熱膨脹係數較佳為42×10-7/℃以上且125×10-7/℃以下,更佳為超過50×10-7/℃且110×10-7/℃以下,進而佳為60×10-7/℃以上且100×10-7/℃以下,尤佳為70×10-7/℃以上且95×10-7/℃以下。若30℃~380℃的溫度範圍內的平均線熱膨脹係數為所述範圍外,則加工基板與支撐玻璃基板的線熱膨脹係數難以匹配。而且,若兩者的線熱膨脹係數不匹配,則加工處理時容易產生加工基板的尺寸變化(尤其是翹曲變形)。 The average linear thermal expansion coefficient in the temperature range of 30°C to 380°C is preferably 42×10 -7 /°C or more and 125×10 -7 /°C or less, more preferably more than 50×10 -7 /°C and 110×10 -7 /°C or lower, more preferably 60×10 -7 /°C or higher and 100×10 -7 /°C or lower, particularly preferably 70×10 -7 /°C or higher and 95×10 -7 /°C or lower. If the average coefficient of linear thermal expansion in the temperature range of 30° C. to 380° C. is outside the range, it is difficult to match the coefficient of linear thermal expansion of the processing substrate and the supporting glass substrate. Furthermore, if the linear thermal expansion coefficients of the two do not match, dimensional changes (especially warpage deformation) of the processed substrate are likely to occur during processing.

102.5dpa.s下的溫度較佳為1680℃以下、1620℃以下、1580℃以下、1550℃以下、1520℃以下、尤其是1500℃以下。若102.5dPa.s下的溫度變高,則熔融性下降,玻璃基板的製造成本高漲。此處,「102.5dPa.s下的溫度」能夠利用鉑球提拉法測定。再者,102.5dPa.s下的溫度相當於熔融溫度,該溫度越低,熔融性越 提高。 10 2.5 dpa. The temperature at s is preferably 1680°C or lower, 1620°C or lower, 1580°C or lower, 1550°C or lower, 1520°C or lower, particularly 1500°C or lower. If 10 2.5 dPa. When the temperature in s becomes high, the meltability decreases, and the manufacturing cost of the glass substrate increases. Here, the "temperature at 10 2.5 dPa·s" can be measured by the platinum ball pulling method. Furthermore, 10 2.5 dPa. The temperature at s corresponds to the melting temperature, and the lower the temperature, the higher the meltability.

液相溫度較佳為小於1300℃、1200℃以下、1100℃以下、1050℃以下、1000℃以下、尤其是950℃以下。液相溫度下的黏度較佳為10000dPa.s以上、30000dPa.s以上、60000dPa.s以上、100000dPa.s以上、200000dPa.s以上、300000dPa.s以上、500000dPa.s以上、800000dPa.s以上、尤其是1000000dPa.s以上。如此,由於成形時失透結晶難以析出,因此容易利用下拉法、尤其是溢流下拉法將玻璃基板成形。此處,「液相溫度」能夠藉由將通過標準篩30目(500μm)而殘留於50目(300μm)的玻璃粉末裝入鉑舟後,於溫度梯度爐中保持24小時,並測定結晶析出的溫度而算出。「液相溫度下的黏度」能夠利用鉑球提拉法測定。再者,液相溫度下的黏度為成形性的指標,液相溫度下的黏度越高,成形性越提高。 The liquidus temperature is preferably lower than 1300°C, 1200°C or lower, 1100°C or lower, 1050°C or lower, 1000°C or lower, particularly 950°C or lower. The viscosity at the liquidus temperature is preferably 10000dPa. s above, 30000dPa. s above, 60000dPa. s above, 100000dPa. s above, 200000dPa. s above, 300000dPa. s above, 500000dPa. s above, 800000dPa. s above, especially 1000000dPa. s or more. In this way, since devitrification crystals are difficult to precipitate during molding, it is easy to shape the glass substrate by the down-draw method, especially the overflow down-draw method. Here, the "liquidus temperature" can be measured by placing the glass powder that has passed through a standard sieve of 30 mesh (500 μm) and remained on a 50 mesh (300 μm) into a platinum boat, kept it in a temperature gradient furnace for 24 hours, and measured the crystal precipitation temperature is calculated. "Viscosity at liquidus temperature" can be measured by the platinum ball pulling method. Furthermore, the viscosity at the liquidus temperature is an index of the formability, and the higher the viscosity at the liquidus temperature, the higher the formability.

本發明的支撐玻璃基板中,楊氏模量較佳為65GPa以上、68GPa以上、70GPa以上、72GPa以上、73GPa以上、尤其是74GPa以上。若楊氏模量過低,則難以維持積層體的剛性,且容易產生加工基板的變形、翹曲、破損等。此處,「楊氏模量」是指利用彎曲共振法而測定的值。 In the supporting glass substrate of the present invention, the Young's modulus is preferably 65GPa or more, 68GPa or more, 70GPa or more, 72GPa or more, 73GPa or more, especially 74GPa or more. When the Young's modulus is too low, it is difficult to maintain the rigidity of the laminate, and deformation, warpage, breakage, and the like of the processed substrate are likely to occur. Here, "Young's modulus" refers to a value measured by a bending resonance method.

本發明的支撐玻璃基板較佳為具有以下形狀。 The supporting glass substrate of the present invention preferably has the following shapes.

本發明的支撐玻璃基板較佳為大致圓板狀或晶圓狀,其直徑較佳為100mm以上且500mm以下、尤其是150mm以上且450mm以下。如此,容易適用於扇出型WLP的製造步驟。亦可 視需要加工成除此以外的形狀、例如矩形等形狀。 The supporting glass substrate of the present invention is preferably substantially disc-shaped or wafer-shaped, and its diameter is preferably 100 mm or more and 500 mm or less, particularly 150 mm or more and 450 mm or less. In this way, it is easy to apply to the manufacturing steps of the fan-out WLP. can also If necessary, it may be processed into other shapes, such as rectangular shapes.

正圓度較佳為1mm以下、0.1mm以下、0.05mm以下、尤其是0.03mm以下。正圓度越小,越容易適用於扇出型WLP的製造步驟。再者,「正圓度」是除了凹口部以外從晶圓的外形的最大值減去最小值所得的值。 The roundness is preferably 1 mm or less, 0.1 mm or less, 0.05 mm or less, especially 0.03 mm or less. The smaller the roundness, the easier it is to apply to the manufacturing steps of the fan-out WLP. In addition, "roundness" is the value obtained by subtracting the minimum value from the maximum value of the outer shape of a wafer except a notch part.

板厚較佳為小於2.0mm、1.5mm以下、1.2mm以下、1.1mm以下、1.0mm以下、尤其是0.9mm以下。板厚越薄,積層體的質量越變輕,故操作性提高。另一方面,若板厚過薄,則支撐玻璃基板本身的強度下降,變得難以發揮作為支撐基板的功能。因此,板厚較佳為0.1mm以上、0.2mm以上、0.3mm以上、0.4mm以上、0.5mm以上、0.6mm以上、尤其是超過0.7mm。 The plate thickness is preferably less than 2.0 mm, 1.5 mm or less, 1.2 mm or less, 1.1 mm or less, 1.0 mm or less, especially 0.9 mm or less. The thinner the plate thickness is, the lighter the mass of the layered product is, and the workability is improved. On the other hand, when the plate thickness is too thin, the strength of the supporting glass substrate itself decreases, and it becomes difficult to function as a supporting substrate. Therefore, the plate thickness is preferably 0.1 mm or more, 0.2 mm or more, 0.3 mm or more, 0.4 mm or more, 0.5 mm or more, 0.6 mm or more, and especially more than 0.7 mm.

整體板厚偏差(TTV)較佳為5μm以下、4μm以下、3μm以下、2μm以下、1μm以下、尤其是0.1μm~小於1μm。另外,算術平均粗糙度Ra較佳為20nm以下、10nm以下、5nm以下、2nm以下、1nm以下、尤其是0.5nm以下。表面精度越高,越可容易提高加工處理的精度。因尤其可提高配線精度,故可進行高密度的配線。另外,支撐玻璃基板的強度提高,支撐玻璃基板及積層體不易破損。進而,可增加支撐玻璃基板的再利用次數。再者,「算術平均粗糙度Ra」可藉由觸針式表面粗糙度計或原子力顯微鏡(atomic force microscope,AFM)進行測定。 The overall thickness variation (TTV) is preferably 5 μm or less, 4 μm or less, 3 μm or less, 2 μm or less, 1 μm or less, especially 0.1 μm to less than 1 μm. In addition, the arithmetic mean roughness Ra is preferably 20 nm or less, 10 nm or less, 5 nm or less, 2 nm or less, 1 nm or less, especially 0.5 nm or less. The higher the surface accuracy, the easier it is to improve the accuracy of the machining process. In particular, since wiring accuracy can be improved, high-density wiring can be performed. Moreover, the intensity|strength of a support glass substrate improves, and a support glass substrate and a laminated body are hard to be damaged. Furthermore, the number of times of reuse of the supporting glass substrate can be increased. In addition, the "arithmetic mean roughness Ra" can be measured by a stylus surface roughness meter or an atomic force microscope (AFM).

本發明的支撐玻璃基板較佳為在利用溢流下拉法成形後,對表面進行研磨而成。如此,容易將整體板厚偏差(TTV) 限制在小於2.0μm、1.5μm以下、1.0μm以下、尤其是0.1μm~小於1.0μm。 The supporting glass substrate of the present invention is preferably formed by an overflow down-draw method, and then the surface thereof is ground. In this way, it is easy to adjust the overall thickness deviation (TTV) It is limited to less than 2.0 μm, 1.5 μm or less, 1.0 μm or less, especially 0.1 μm to less than 1.0 μm.

翹曲量較佳為60μm以下、55μm以下、50μm以下、1μm~45μm、尤其是5μm~40μm。翹曲量越小,越容易提高加工處理的精度。因尤其可提高配線精度,故可進行高密度的配線。 The warpage amount is preferably 60 μm or less, 55 μm or less, 50 μm or less, 1 μm to 45 μm, especially 5 μm to 40 μm. The smaller the amount of warpage, the easier it is to improve the accuracy of processing. In particular, since wiring accuracy can be improved, high-density wiring can be performed.

本發明的支撐玻璃基板較佳為具有凹口部(凹口形狀的對準部),凹口部的深度更佳為於平面視時為大致圓形狀或大致V槽形狀。藉此,使定位銷等定位構件抵接於支撐玻璃基板的凹口部,容易對支撐玻璃基板進行位置固定。結果,支撐玻璃基板與加工基板的對準變得容易。尤其,若亦於加工基板上形成凹口部且使定位構件抵接,則積層體整體的對準變得容易。再者,凹口部由於抵接有定位構件,因此容易產生裂紋,但本發明的支撐玻璃基板由於裂紋阻力高,因此於具有凹口部的情況下尤其有效。 The supporting glass substrate of the present invention preferably has a notch portion (a notch-shaped alignment portion), and the depth of the notch portion is more preferably a substantially circular shape or a substantially V-groove shape in plan view. Thereby, positioning members, such as a positioning pin, are contact|abutted to the notch part of a support glass substrate, and it becomes easy to fix a position of a support glass substrate. As a result, alignment of the supporting glass substrate and the processing substrate becomes easy. In particular, if a notch portion is also formed in the processing substrate and the positioning member is brought into contact with each other, the alignment of the entire laminate will be facilitated. In addition, since the notch part is in contact with the positioning member, cracks are likely to occur, but the supporting glass substrate of the present invention is particularly effective when it has the notch part because of its high crack resistance.

若將定位構件抵接於支撐玻璃基板的凹口部,則應力容易集中於凹口部,以凹口部為起點,支撐玻璃基板容易發生破損。尤其,於支撐玻璃基板因外力而發生彎曲時,所述傾向變得顯著。因此,本發明的支撐玻璃基板較佳為凹口部的表面與端面交差的端緣區域的全部或一部分被倒角。藉此,可有效地避免以凹口部為起點的破損。 When the positioning member is brought into contact with the notch portion of the supporting glass substrate, stress tends to concentrate on the notch portion, and the supporting glass substrate is likely to be damaged from the notch portion as a starting point. In particular, when the supporting glass substrate is bent by an external force, the tendency becomes remarkable. Therefore, in the supporting glass substrate of the present invention, it is preferable that all or a part of the edge region where the surface of the notch portion intersects with the end surface is chamfered. Thereby, the breakage from the notch part as a starting point can be avoided effectively.

本發明的支撐玻璃基板的凹口部的表面與端面交差的端緣區域的全部或一部分被倒角,較佳為凹口部的表面與端面交差的端緣區域的50%以上被倒角,更佳為凹口部的表面與端面交 差的端緣區域的90%以上被倒角,進而佳為凹口部的表面與端面交差的端緣區域全部被倒角。凹口部中被倒角的區域越大,越能夠減少以凹口部為起點的破損的概率。 All or part of the edge region where the surface of the notch portion of the supporting glass substrate of the present invention intersects with the end face is chamfered, preferably more than 50% of the edge region where the surface of the notch portion intersects with the end face is chamfered, More preferably, the surface of the notch part intersects the end surface 90% or more of the poor edge region is chamfered, and it is more preferable that the entire edge region where the surface of the notch portion intersects with the end surface is chamfered. The larger the chamfered region in the notch portion, the more likely it is possible to reduce the probability of breakage starting from the notch portion.

凹口部的表面方向的倒角寬度較佳為50μm~900μm、200μm~800μm、300μm~700μm、400μm~650μm、尤其是500μm~600μm。若凹口部的表面方向的倒角寬度過小,則以凹口部為起點,支撐玻璃基板容易發生破損。另一方面,若凹口部的表面方向的倒角寬度過大,則倒角效率下降,支撐玻璃基板的製造成本容易高漲。 The chamfer width in the surface direction of the notch portion is preferably 50 μm to 900 μm, 200 μm to 800 μm, 300 μm to 700 μm, 400 μm to 650 μm, especially 500 μm to 600 μm. When the chamfering width of the surface direction of a notch part is too small, a support glass substrate is easily damaged from a notch part as a starting point. On the other hand, when the chamfering width of the surface direction of a notch part is too large, the chamfering efficiency falls, and the manufacturing cost of a support glass substrate tends to increase.

凹口部的板厚方向的倒角寬度較佳為板厚的5%~80%、20%~75%、30%~70%、35%~65%、尤其是40%~60%。若凹口部的板厚方向的倒角寬度過小,則以凹口部為起點,支撐玻璃基板容易發生破損。另一方面,若凹口部的板厚方向的倒角寬度過大,則外力容易集中於凹口部的端面,以凹口部的端面為起點,支撐玻璃基板容易發生破損。 The chamfer width in the plate thickness direction of the notch portion is preferably 5% to 80%, 20% to 75%, 30% to 70%, 35% to 65%, especially 40% to 60% of the plate thickness. When the chamfer width in the plate thickness direction of the notch portion is too small, the support glass substrate is likely to be damaged from the notch portion as a starting point. On the other hand, if the chamfer width in the thickness direction of the notch is too large, external force tends to concentrate on the end face of the notch, and the support glass substrate is likely to be damaged from the end face of the notch as a starting point.

本發明的支撐玻璃基板較佳為於表面形成(做標記(marking))有二維碼的資訊識別部(標記)。如此,可管理、認識支撐玻璃基板的生產資訊等(例如、玻璃基板的尺寸、線熱膨脹係數、批次、整體板厚偏差、製造者名、販賣者名)。再者,資訊辨別部通常形成於支撐玻璃基板的周邊區域,且以文字、記號等的形式由人的眼腈等來識別。或者,有時支撐玻璃基板的資訊辨別部亦藉由電荷耦合元件(Charge Coupled Device,CCD)相機 等光學元件來自動地辨別。 The supporting glass substrate of the present invention is preferably formed (marked) on the surface with an information identification portion (mark) having a two-dimensional code. In this way, it is possible to manage and recognize the production information of the supporting glass substrate, etc. (for example, the size of the glass substrate, the coefficient of linear thermal expansion, the batch, the deviation of the overall thickness, the name of the manufacturer, the name of the seller). In addition, the information identification part is normally formed in the peripheral area of a support glass substrate, and is recognized by a human eye nitrile etc. in the form of a character, a symbol, etc. Alternatively, sometimes the information identification part supporting the glass substrate is also equipped with a Charge Coupled Device (CCD) camera. and other optical components to automatically identify.

資訊識別部可利用各種方法形成,但本發明中較佳為照射脈波雷射,對所述照射區域的玻璃進行剝蝕而形成資訊識別部,即藉由雷射剝蝕而形成資訊識別部。如此,可於照射區域的玻璃中不蓄積過剩量的熱而產生剝蝕。結果,不僅可減少厚度方向的裂紋的長度,而且可減少自點延伸的表面方向的裂紋的長度。再者,本發明的支撐玻璃基板具有如下優點:由於裂紋阻力高,因此於藉由雷射剝蝕形成資訊識別部(尤其是點)時,不易產生裂紋。 The information identification portion can be formed by various methods, but in the present invention, it is preferable to irradiate a pulse wave laser and ablate the glass in the irradiated area to form the information identification portion, that is, to form the information identification portion by laser ablation. In this way, it is possible to prevent the occurrence of erosion due to excessive heat accumulation in the glass in the irradiation area. As a result, not only the length of the crack in the thickness direction but also the length of the crack in the surface direction extending from the point can be reduced. Furthermore, the supporting glass substrate of the present invention has the following advantages: since the crack resistance is high, when the information identification portion (especially the dot) is formed by laser ablation, cracks are not easily generated.

資訊識別部較佳為包含多個點。點的外徑尺寸較佳為0.05mm~0.20mm、0.07mm~0.13mm、尤其是0.09mm~0.11mm。若點的外徑尺寸過小,則資訊識別部的視認性容易下降。另一方面,若點的外徑尺寸過大,則不易確保支撐玻璃基板的強度。 The information identification portion preferably includes a plurality of points. The outer diameter of the dots is preferably 0.05mm to 0.20mm, 0.07mm to 0.13mm, especially 0.09mm to 0.11mm. When the outer diameter of the dots is too small, the visibility of the information recognition portion tends to decrease. On the other hand, when the outer diameter dimension of a dot is too large, it will become difficult to ensure the intensity|strength of a support glass substrate.

彼此相互鄰接的點的中心間距離較佳為0.06mm~0.25mm。若彼此相互鄰接的點的中心間距離過小,則不易確保支撐玻璃基板的強度。另一方面,若彼此相互鄰接的點的中心間距離過大,則資訊識別部的視認性容易下降。 The distance between the centers of the points adjacent to each other is preferably 0.06 mm to 0.25 mm. If the distance between the centers of the points adjacent to each other is too small, it is difficult to ensure the strength of the supporting glass substrate. On the other hand, if the distance between the centers of the points adjacent to each other is too large, the visibility of the information recognition unit tends to decrease.

點的形狀較佳為環狀的槽。如此,若使點為環狀的槽,則由所述環狀的槽包圍的區域(相較於槽更靠內側的區域)不會藉由雷射被去除而殘存,因此能夠盡可能地防止設置有資訊識別部的區域的強度下降。另外,若為環狀的槽,只要外徑尺寸不發生變化,則即便減小槽的寬度尺寸,視認性亦不會下降那麼大程 度。因此,若不改變槽的外徑尺寸而減小寬度尺寸,則相應地可大量獲取相較於槽更靠內側的區域的體積,藉此可確保視認性且確保所需的強度。 The shape of the dot is preferably an annular groove. In this way, if the dots are formed as annular grooves, the regions surrounded by the annular grooves (regions on the inner side of the grooves) are not removed by the laser and remain, so it is possible to prevent as much as possible. The intensity of the area where the information recognition unit is provided decreases. In addition, if the groove is an annular groove, as long as the outer diameter does not change, even if the width of the groove is reduced, the visibility will not decrease so much. Spend. Therefore, if the width dimension is reduced without changing the outer diameter dimension of the groove, a correspondingly large volume of the region inside the groove can be obtained, whereby visibility and required strength can be ensured.

形成點的槽的深度尺寸較佳為2μm~30μm。若槽的深度尺寸過小,則資訊識別部的視認性容易下降。另一方面,若槽的深度尺寸過大,則不易確保支撐玻璃基板的強度。 The depth dimension of the groove in which the dots are formed is preferably 2 μm to 30 μm. When the depth dimension of the groove is too small, the visibility of the information identification portion tends to decrease. On the other hand, when the depth dimension of a groove|channel is too large, it becomes difficult to ensure the intensity|strength which supports a glass substrate.

本發明的支撐玻璃基板較佳為利用下拉法、尤其是溢流下拉法進行成形而成。溢流下拉法為如下方法,即,使熔融玻璃從耐熱性的流槽狀結構物的兩側溢出,使溢出的熔融玻璃一邊在流槽狀結構物的下頂端合流,一邊向下方延伸成形而製造玻璃基板。溢流下拉法中,應成為玻璃基板的表面的面不與流槽狀耐火物接觸,而以自由表面的狀態成形。因此,藉由少量的研磨,可將整體板厚偏差(TTV)減少至小於2.0μm、尤其是小於1.0μm。結果可使玻璃基板的製造成本低廉化。 The supporting glass substrate of the present invention is preferably formed by a down-draw method, especially an overflow down-draw method. The overflow down-draw method is a method in which molten glass overflows from both sides of a heat-resistant launder-shaped structure, and the overflowed molten glass merges at the lower end of the launder-shaped structure while extending and molding downward. Manufacture of glass substrates. In the overflow down-draw method, the surface that should be the surface of the glass substrate is not in contact with the launder-shaped refractory, but is formed in the state of a free surface. Therefore, with a small amount of grinding, the overall thickness variation (TTV) can be reduced to less than 2.0 μm, especially less than 1.0 μm. As a result, the manufacturing cost of a glass substrate can be reduced.

本發明的支撐玻璃基板較佳為不進行離子交換處理,且較佳為表面不具有壓縮應力層。若進行離子交換處理,則支撐玻璃基板的製造成本高漲,但若不進行離子交換處理,則可使支撐玻璃基板的製造成本下降。進而,若進行離子交換處理,則難以減少支撐玻璃基板的整體板厚偏差(TTV),但若不進行離子交換處理,則容易消除所述不良情況。再者,本發明的支撐玻璃基板不排除進行離子交換處理而在表面形成壓縮應力層的形態。若僅著眼於提高機械性強度的觀點,則較佳為進行離子交換處理並在 表面形成壓縮應力層。 The supporting glass substrate of the present invention preferably does not undergo ion exchange treatment, and preferably does not have a compressive stress layer on the surface. If the ion exchange treatment is performed, the production cost of the supporting glass substrate will increase, but if the ion exchange treatment is not performed, the production cost of the supporting glass substrate can be reduced. Furthermore, if the ion exchange treatment is performed, it is difficult to reduce the overall thickness variation (TTV) of the supporting glass substrate, but if the ion exchange treatment is not performed, the above-mentioned inconvenience can be easily resolved. In addition, the supporting glass substrate of the present invention does not exclude the form in which a compressive stress layer is formed on the surface by performing an ion exchange treatment. From the viewpoint of merely improving the mechanical strength, it is preferable to perform ion exchange treatment and A compressive stress layer is formed on the surface.

本發明的積層體至少包括加工基板及用以支撐加工基板的支撐玻璃基板,且所述積層體的特徵在於:支撐玻璃基板為所述支撐玻璃基板。本發明的積層體較佳為於加工基板與支撐玻璃基板之間具有接著層。接著層較佳為樹脂,且較佳為例如熱硬化性樹脂、光硬化性樹脂(尤其是紫外線硬化樹脂)等。另外,較佳為具有可耐受扇出型WLP的製造步驟中的熱處理的耐熱性。藉此,於扇出型WLP的製造步驟中接著層難以熔解,可提高加工處理的精度。再者,因容易將加工基板與支撐玻璃基板固定,故亦可將紫外線硬化型膠帶用作接著層。 The laminate of the present invention includes at least a processing substrate and a supporting glass substrate for supporting the processing substrate, and the laminate is characterized in that the supporting glass substrate is the supporting glass substrate. The laminate of the present invention preferably has an adhesive layer between the processing substrate and the supporting glass substrate. The next layer is preferably a resin, and preferably, for example, a thermosetting resin, a photocurable resin (especially an ultraviolet curing resin), or the like. In addition, it is preferable to have heat resistance capable of withstanding the heat treatment in the manufacturing step of the fan-out WLP. This makes it difficult for the adhesive layer to be melted in the manufacturing step of the fan-out WLP, so that the precision of the processing can be improved. Furthermore, since it is easy to fix a process board|substrate and a support glass substrate, an ultraviolet curable adhesive tape can also be used as an adhesive layer.

本發明的積層體較佳為進而於加工基板與支撐玻璃基板之間,更具體而言於加工基板與接著層之間具有剝離層,或者於支撐玻璃基板與接著層之間具有剝離層。如此對加工基板進行規定的加工處理後,容易將加工基板自支撐玻璃基板剝離。自生產性的觀點考慮,加工基板的剝離較佳為藉由雷射光等照射光而進行。作為雷射光源,可使用釔鋁石榴石(Yttrium Aluminium Garnet,YAG)雷射(波長1064nm)、半導體雷射(波長780nm~1300nm)等紅外光雷射光源。另外,於剝離層中可使用藉由照射紅外線雷射而分解的樹脂。另外,亦可將效率優良地吸收紅外線並轉換為熱的物質添加到樹脂中。例如,亦可將碳黑、石墨粉、微粒子金屬粉末、染料、顏料等添加到樹脂中。 The layered product of the present invention preferably further has a release layer between the processing substrate and the supporting glass substrate, more specifically, a release layer between the processing substrate and the adhesive layer, or a release layer between the supporting glass substrate and the adhesive layer. After the predetermined processing is performed on the processing substrate in this way, the processing substrate is easily peeled off from the supporting glass substrate. From the viewpoint of productivity, peeling of the processed substrate is preferably performed by irradiating light with laser light or the like. As the laser light source, an infrared laser light source such as a Yttrium Aluminium Garnet (YAG) laser (wavelength of 1064 nm) and a semiconductor laser (wavelength of 780 nm to 1300 nm) can be used. Moreover, the resin decomposed|disassembled by irradiation of an infrared laser can be used for a peeling layer. In addition, a substance that absorbs infrared rays efficiently and is converted into heat may be added to the resin. For example, carbon black, graphite powder, fine particle metal powder, dye, pigment, etc. may also be added to the resin.

剝離層包括藉由雷射光等照射光而產生「層內剝離」或 「界面剝離」的材料。即包括以下材料:若照射一定強度的光,則原子或分子中的原子間或分子間的結合力消失或減少,發生剝蝕(ablation)等,從而產生剝離的材料。再者,有藉由照射光的照射,剝離層中所含有的成分成為氣體被放出而導致分離的情況、與剝離層吸收光成為氣體並放出其蒸氣而導致分離的情況。 The peeling layer includes "in-layer peeling" by irradiating light such as laser light or "Interface peel" material. That is, it includes materials in which, when irradiated with light of a certain intensity, the bonding force between atoms or molecules between atoms or molecules disappears or decreases, and ablation or the like occurs, thereby causing exfoliation. Furthermore, by irradiation of irradiation light, the components contained in the peeling layer may become gas and be released to cause separation, and the separation layer may absorb light and become gas and release its vapor to cause separation.

本發明的積層體中,支撐玻璃基板較佳為比加工基板大。藉此於對加工基板與支撐玻璃基板進行支撐時兩者的中心位置稍有分離的情況下,加工基板的邊緣部亦難以超出支撐玻璃基板。 In the layered product of the present invention, the supporting glass substrate is preferably larger than the processing substrate. This makes it difficult for the edge portion of the processing substrate to protrude beyond the supporting glass substrate even when the center positions of the two are slightly separated when the processing substrate and the supporting glass substrate are supported.

本發明的半導體封裝體的製造方法的特徵在於包括:準備至少包括加工基板及用以支撐加工基板的支撐玻璃基板的積層體的步驟;以及對加工基板進行加工處理的步驟;並且支撐玻璃基板為所述支撐玻璃基板。 The manufacturing method of the semiconductor package of the present invention is characterized by comprising: preparing a laminate including at least a processing substrate and a supporting glass substrate for supporting the processing substrate; and processing the processing substrate; and the supporting glass substrate is the supporting glass substrate.

本發明的半導體封裝體的製造方法較佳為進而包括搬送積層體的步驟。藉此,可提高加工處理的處理效率。再者,「搬送積層體的步驟」與「對加工基板進行加工處理的步驟」無須分開進行,亦可同時進行。 It is preferable that the manufacturing method of the semiconductor package of this invention further includes the process of conveying a laminated body. Thereby, the processing efficiency of a processing can be improved. In addition, "the step of conveying the laminated body" and the "step of processing the processing substrate" need not be performed separately, and may be performed simultaneously.

本發明的半導體封裝體的製造方法中,加工處理較佳為在加工基板的一表面進行配線的處理或在加工基板的一表面形成焊料凸塊的處理。本發明的半導體封裝體的製造方法中,在該些處理時加工基板尺寸不易變化,因而可適當地進行該些步驟。 In the manufacturing method of the semiconductor package of the present invention, the processing is preferably a process of performing wiring on one surface of the processed substrate or a process of forming solder bumps on one surface of the processed substrate. In the manufacturing method of the semiconductor package of the present invention, the dimensions of the processed substrate are not easily changed during these processes, and therefore these steps can be appropriately performed.

除所述以外,作為加工處理亦可為以下處理中的任一 個:對加工基板的一表面(通常與支撐玻璃基板為相反側的表面)以機械方式進行研磨的處理、對加工基板的一表面(通常與支撐玻璃基板為相反側的表面)進行乾式蝕刻的處理、對加工基板的一表面(通常與支撐玻璃基板為相反側的表面)進行濕式蝕刻的處理。再者,本發明的半導體封裝體的製造方法中,在加工基板上不易產生翹曲,並且可維持積層體的剛性。結果,可適當進行所述加工處理。 In addition to the above, the processing may be any of the following treatments One: One surface of the processing substrate (usually the surface opposite to the supporting glass substrate) is mechanically ground, and one surface of the processing substrate (usually the surface opposite to the supporting glass substrate) is dry-etched Treatment is a treatment of performing wet etching on one surface (usually the surface opposite to the support glass substrate) of the processing substrate. Furthermore, in the manufacturing method of the semiconductor package of this invention, a warpage is hard to generate|occur|produce in a process board|substrate, and the rigidity of a laminated body can be maintained. As a result, the processing can be appropriately performed.

一邊參照圖式一邊對本發明進一步進行說明。 The present invention will be further described with reference to the drawings.

圖1為表示本發明的積層體1的一例的概念立體圖。圖1中,積層體1包括支撐玻璃基板10及加工基板11。支撐玻璃基板10為了防止加工基板11的尺寸變化,而貼附於加工基板11。支撐玻璃基板10與加工基板11之間配置有剝離層12與接著層13。剝離層12與支撐玻璃基板10接觸,接著層13與加工基板11接觸。 FIG. 1 is a conceptual perspective view showing an example of the layered body 1 of the present invention. In FIG. 1 , the laminate 1 includes a supporting glass substrate 10 and a processing substrate 11 . The supporting glass substrate 10 is attached to the processing substrate 11 in order to prevent the dimensional change of the processing substrate 11 . The peeling layer 12 and the adhesive layer 13 are arranged between the supporting glass substrate 10 and the processing substrate 11 . The peeling layer 12 is in contact with the supporting glass substrate 10 , and the subsequent layer 13 is in contact with the processing substrate 11 .

即,積層體1以支撐玻璃基板10、剝離層12、接著層13、加工基板11的順序積層配置。支撐玻璃基板10的形狀根據加工基板11而決定,圖1中,支撐玻璃基板10及加工基板11的形狀均為大致圓板形狀。剝離層12例如可使用藉由照射雷射而分解的樹脂。另外,亦可向樹脂中添加效率優良地吸收雷射光並轉換成熱的物質。例如為碳黑、石墨粉、微粒子金屬粉末、染料、顏料等。剝離層12藉由電漿化學氣相沈積法(Chemical vapor deposition,CVD)、溶膠-凝膠法的旋塗等而形成。接著層13包括 樹脂,例如藉由各種印刷法、噴墨法、旋塗法、輥塗法等塗佈形成。另外,亦能夠使用紫外線硬化型膠帶。接著層13在藉由剝離層12從加工基板11剝離支撐玻璃基板10後,藉由溶劑等加以溶解去除。紫外線硬化型膠帶在照射紫外線後,可藉由剝離用膠帶而去除。 That is, the laminated body 1 is laminated|stacked and arrange|positioned in this order of the support glass substrate 10, the peeling layer 12, the adhesive layer 13, and the process board|substrate 11. The shape of the supporting glass substrate 10 is determined according to the processing substrate 11 . In FIG. 1 , the shapes of the supporting glass substrate 10 and the processing substrate 11 are both substantially disc shapes. For the peeling layer 12, a resin decomposed by laser irradiation can be used, for example. In addition, a substance that efficiently absorbs laser light and converts it into heat may be added to the resin. For example, carbon black, graphite powder, particulate metal powder, dyes, pigments and the like. The peeling layer 12 is formed by plasma chemical vapor deposition (CVD), spin coating by a sol-gel method, or the like. Then layer 13 includes The resin is formed by coating, for example, by various printing methods, ink jet methods, spin coating methods, roll coating methods, and the like. In addition, an ultraviolet curable adhesive tape can also be used. After the support glass substrate 10 is peeled off from the processing substrate 11 by the peeling layer 12, the layer 13 is dissolved and removed by a solvent or the like. The UV-curable tape can be removed by a peeling tape after irradiating with UV light.

圖2(a)~圖2(g)是表示扇出型WLP的製造步驟的概念剖面圖。圖2(a)表示在支撐構件20的一表面形成接著層21的狀態。亦可視需要在支撐構件20與接著層21之間形成剝離層。繼而,如圖2(b)所示,於接著層21之上貼附多個半導體晶片22。此時,使半導體晶片22的主動側的面與接著層21接觸。繼而,如圖2(c)所示,利用樹脂的密封材23對半導體晶片22進行成形。密封材23使用壓縮成形後的尺寸變化、將配線成形時的尺寸變化少的材料。接著,如圖2(d)、圖2(e)所示,將半導體晶片22經成形的加工基板24自支撐構件20分離後,經由接著層25而與支撐玻璃基板26接著固定。此時,將加工基板24的表面內的與埋入半導體晶片22側的表面為相反側的表面配置於支撐玻璃基板26側。如此可獲得積層體27。再者,亦可視需要於接著層25與支撐玻璃基板26之間形成剝離層。進而搬送所獲得的積層體27後,如圖2(f)所示,於加工基板24的埋入半導體晶片22側的表面形成配線28後,形成多個焊料凸塊29。最後,在加工基板24從支撐玻璃基板26分離後,將加工基板24切斷為每個半導體晶片22,並用於之後的封裝步驟(圖2(g))。 FIGS. 2( a ) to 2 ( g ) are conceptual cross-sectional views showing manufacturing steps of the fan-out WLP. FIG. 2( a ) shows a state in which the adhesive layer 21 is formed on one surface of the support member 20 . A peeling layer may also be formed between the support member 20 and the adhesive layer 21 as required. Then, as shown in FIG. 2( b ), a plurality of semiconductor chips 22 are attached on the adhesive layer 21 . At this time, the surface on the active side of the semiconductor wafer 22 is brought into contact with the adhesive layer 21 . Next, as shown in FIG.2(c), the semiconductor wafer 22 is shape|molded by the sealing material 23 of resin. The sealing material 23 uses a material with little dimensional change after compression molding and less dimensional change when wiring is molded. Next, as shown in FIGS. 2( d ) and 2( e ), the processed substrate 24 formed by the semiconductor wafer 22 is separated from the supporting member 20 , and then fixed to the supporting glass substrate 26 via the adhesive layer 25 . At this time, the surface on the opposite side to the surface on the side where the semiconductor wafer 22 is embedded in the surface of the processing substrate 24 is arranged on the side of the supporting glass substrate 26 . In this way, the layered body 27 can be obtained. Furthermore, a peeling layer may also be formed between the adhesive layer 25 and the supporting glass substrate 26 as required. Further, after conveying the obtained laminated body 27 , as shown in FIG. 2( f ), wirings 28 are formed on the surface of the processing substrate 24 on the side where the semiconductor wafer 22 is embedded, and then a plurality of solder bumps 29 are formed. Finally, after the processed substrate 24 is separated from the supporting glass substrate 26, the processed substrate 24 is cut into each semiconductor wafer 22 and used for the subsequent packaging step (FIG. 2(g)).

圖3(a)、圖3(b)為表示本發明的支撐玻璃基板的一例的上方概念圖。如圖3(a)所示,支撐玻璃基板31的外形為大致正圓的晶圓狀。另外,支撐玻璃基板31的外形包含凹口部32以及佔凹口部32以外的外形區域的外形部33。凹口部32具有凹口形狀、即具有凹陷的形狀。凹口形狀的深部34於平面視時為帶圓弧的大致圓形狀,凹口部32與外形部33的邊界亦為帶圓弧的大致圓形狀。如圖3(b)所示,支撐玻璃基板35的外形為大致正圓的晶圓狀。另外,支撐玻璃基板35的外形包含凹口部36以及佔凹口部36以外的外形區域的外形部37。支撐玻璃基板35的凹口部36具有凹口形狀,凹口形狀的深部38成為大致V槽形狀。 FIG.3(a), FIG.3(b) is an upper conceptual diagram which shows an example of the support glass substrate of this invention. As shown in FIG. 3( a ), the outer shape of the supporting glass substrate 31 is a substantially circular wafer shape. In addition, the outer shape of the supporting glass substrate 31 includes a notch portion 32 and an outer shape portion 33 occupying an outer shape region other than the notch portion 32 . The notch portion 32 has a notch shape, that is, a concave shape. The notch-shaped deep portion 34 has a substantially circular shape with an arc in plan view, and the boundary between the notch portion 32 and the outer shape portion 33 is also substantially circular with an arc. As shown in FIG.3(b), the external shape of the support glass substrate 35 is a substantially circular wafer shape. In addition, the outer shape of the supporting glass substrate 35 includes a notch portion 36 and an outer shape portion 37 occupying an outer shape region other than the notch portion 36 . The notch part 36 of the support glass substrate 35 has a notch shape, and the deep part 38 of the notch shape has a substantially V-groove shape.

圖4為圖3(a)的A-A'方向的剖面概念圖。如圖4所示,於支撐玻璃基板31的表面39、表面40與端面41交差的端緣區域具有倒角面42、倒角面43。支撐玻璃基板31的表面39、表面40的方向的倒角寬度X例如為50μm~900μm,支撐玻璃基板31的板厚方向的倒角寬度Y+Y'例如為板厚t的20%~80%。而且,端面41與倒角面42、倒角面43於分別連續地帶有圓弧的狀態下連結,表面39、表面40與倒角面42、倒角面43於分別連續地帶有圓弧的狀態下連結。 Fig. 4 is a conceptual cross-sectional view taken in the AA' direction of Fig. 3(a). As shown in FIG. 4 , a chamfered surface 42 and a chamfered surface 43 are provided in the edge region where the surface 39 and the surface 40 of the supporting glass substrate 31 intersect with the end surface 41 . The chamfer width X in the direction of the surface 39 and the surface 40 of the supporting glass substrate 31 is, for example, 50 μm to 900 μm, and the chamfering width Y+Y′ in the plate thickness direction of the supporting glass substrate 31 is, for example, 20% to 80% of the plate thickness t . Furthermore, the end surface 41, the chamfered surface 42, and the chamfered surface 43 are connected in a state of continuous arcs, respectively, and the surface 39, the surface 40, the chamfered surface 42, and the chamfered surface 43 are in a state of continuous arcs, respectively. link below.

[實施例1] [Example 1]

以下基於實施例對本發明進行說明。再者,以下的實施例僅為例示。本發明並不受以下實施例的任何限定。 The present invention will be described below based on examples. In addition, the following Examples are only an illustration. The present invention is not limited in any way by the following examples.

表1、表2表示本發明的實施例(試樣No.1~試樣 No.23)。另外,表3表示本發明的比較例(試料No.24~試料No.38)。 Tables 1 and 2 show examples of the present invention (sample No. 1 to sample No.23). In addition, Table 3 shows the comparative examples (Sample No. 24 to Sample No. 38) of the present invention.

Figure 106140335-A0305-02-0026-2
Figure 106140335-A0305-02-0026-2
Figure 106140335-A0305-02-0027-3
Figure 106140335-A0305-02-0027-3

Figure 106140335-A0305-02-0028-5
Figure 106140335-A0305-02-0028-5
Figure 106140335-A0305-02-0029-6
Figure 106140335-A0305-02-0029-6

Figure 106140335-A0305-02-0030-7
Figure 106140335-A0305-02-0030-7
Figure 106140335-A0305-02-0031-8
Figure 106140335-A0305-02-0031-8

首先,將以成為表中的玻璃組成的方式調合玻璃原料所得的玻璃配料放入至鉑坩堝中,以1600℃熔融4小時。當玻璃配料熔解時,使用鉑攪拌器進行攪拌,而進行均質化。然後,使熔融玻璃向碳板上流出,而成形為板狀後,從比緩冷點高20℃左右的溫度開始,以3℃/min緩冷至常溫為止。對所獲得的各試樣,評價裂紋阻力、20℃~200℃的溫度範圍內的平均線熱膨脹係數α20~200,20℃~220℃的溫度範圍內的平均線熱膨脹係數α20~220,20℃~260℃的溫度範圍內的平均線熱膨脹係數α20~260,30℃~380℃的溫度範圍內的平均線熱膨脹係數α30~380,密度,應變點Ps,緩冷點Ta,軟化點Ts,高溫黏度104.0dPa.s下的溫度,高溫黏度103.0dPa.s下的溫度,高溫黏度102.5dPa.s下的溫度,液相溫度TL,液相溫度TL下的黏度η、楊氏模量、剛性係數及帕桑比。 First, the glass batches obtained by blending glass raw materials so as to have the glass compositions in the table were put into a platinum crucible and melted at 1600° C. for 4 hours. When the glass batch is melted, it is homogenized by stirring with a platinum stirrer. Then, after the molten glass was flowed out onto the carbon plate and formed into a plate shape, it was slowly cooled to normal temperature at 3°C/min from a temperature about 20°C higher than the slow cooling point. For each obtained sample, the crack resistance, the average linear thermal expansion coefficient α 20 to 200 in the temperature range of 20°C to 200°C, and the average linear thermal expansion coefficient α 20 to 220 in the temperature range of 20°C to 220°C were evaluated. Average linear thermal expansion coefficient α 20~260 in the temperature range of 20℃~260℃, average linear thermal expansion coefficient α 30 ~380 in the temperature range of 30℃~380℃, density, strain point Ps, slow cooling point Ta, softening Point Ts, high temperature viscosity 10 4.0 dPa. s temperature, high temperature viscosity 10 3.0 dPa. s temperature, high temperature viscosity 10 2.5 dPa. Temperature at s, liquidus temperature TL, viscosity η, Young's modulus, stiffness coefficient and Passan ratio at liquidus temperature TL.

裂紋阻力是指裂紋產生率為50%的負荷,裂紋產生率以如下方式測定。首先,於保持為濕度30%、溫度25℃的恒溫恒濕槽內,將設定為規定負荷的維氏壓頭朝玻璃表面(光學研磨面)打入15秒,於所述15秒後對自壓痕的四角產生的裂紋的數量進行計數(設為一個壓痕最大為4)。如此,將壓頭打入20次,於求出總裂紋產生數後,藉由(總裂紋產生數/80)×100的式子求出。 The crack resistance refers to a load with a crack occurrence rate of 50%, and the crack occurrence rate is measured as follows. First, in a constant temperature and humidity tank maintained at a humidity of 30% and a temperature of 25°C, a Vickers indenter set to a predetermined load was driven into the glass surface (optical polishing surface) for 15 seconds, and after the 15 seconds The number of cracks generated at the four corners of the indentation was counted (a maximum of 4 indentation was set). In this way, the indenter was driven 20 times, and after obtaining the total number of cracks, it was obtained by the formula of (total number of cracks/80)×100.

所述溫度範圍內的平均線熱膨脹係數為利用膨脹計進行測定而得的值。 The average linear thermal expansion coefficient in the above-mentioned temperature range is a value measured with a dilatometer.

密度為藉由周知的阿基米德(Archimedes)法進行測定而得的值。 The density is a value measured by the well-known Archimedes method.

應變點Ps、徐冷點Ta、軟化點Ts為基於美國試驗材料學會(American Society for Testing Material,ASTM)C336的方法進行測定而得的值。 The strain point Ps, the cold point Ta, and the softening point Ts are values measured based on the method of American Society for Testing Materials (ASTM) C336.

高溫黏度104.0dPa.s、高溫黏度103.0dPa.s及高溫黏度102.5dPa.s下的溫度為藉由鉑球提拉法進行測定而得的值。 High temperature viscosity 10 4.0 dPa. s, high temperature viscosity 10 3.0 dPa. s and high temperature viscosity 10 2.5 dPa. The temperature at s is a value measured by the platinum ball pulling method.

液相溫度TL為將通過標準篩30目(500μm)而殘留於50目(300μm)的玻璃粉末裝入鉑舟,於溫度梯度爐中保持24小時後,藉由顯微鏡觀察而對結晶析出的溫度進行測定而得的值。液相溫度TL下的黏度η為利用鉑球提拉法對液相溫度TL下的玻璃的黏度進行測定所得的值。 Liquidus temperature TL is the temperature at which crystals are precipitated by microscopic observation after the glass powder that has passed through a standard sieve of 30 mesh (500 μm) and remains in 50 mesh (300 μm) is loaded into a platinum boat and kept in a temperature gradient furnace for 24 hours. The value obtained by the measurement. The viscosity η at the liquidus temperature TL is a value obtained by measuring the viscosity of the glass at the liquidus temperature TL by the platinum ball pulling method.

楊氏模量、剛性係數、帕桑比是指藉由共振法進行測定而得的值。 Young's modulus, stiffness coefficient, and Passan ratio mean values measured by a resonance method.

根據表1、表2明確般,試樣No.1~試樣No.23的裂紋阻力為600gf以上,因此認為於扇出型WLP的製造步驟中在積層體的搬送時不易產生裂紋。另一方面,試樣No.24~試樣No.38的裂紋阻力為494gf以下,因此認為於扇出型WLP的製造步驟中在積層體的搬送時容易產生裂紋。 As is clear from Tables 1 and 2, the crack resistance of Sample No. 1 to Sample No. 23 is 600 gf or more, so it is considered that cracks are less likely to occur during transport of the laminate in the production process of the fan-out WLP. On the other hand, since the crack resistance of Sample No. 24 to Sample No. 38 is 494 gf or less, it is considered that cracks are likely to be generated during conveyance of the laminate in the production process of the fan-out WLP.

[實施例2] [Example 2]

首先,以成為表1、表2中記載的試樣No.1~試樣No.23中記載的玻璃組成的方式調合玻璃原料後,供給至玻璃熔融爐中以1600℃~1700℃熔融,然後將熔融玻璃供給至溢流下拉成形裝置,分別成形為板厚0.8mm。對於所獲得的玻璃基板,對兩表面 進行機械研磨,將整體板厚偏差(TTV)減少至小於1μm。在將所獲得的玻璃基板加工為Φ300mm×0.8mm厚後,藉由研磨裝置對其兩表面進行研磨處理。具體而言,以外徑不同的一對研磨墊夾持玻璃基板的兩表面,一邊使玻璃基板與一對研磨墊一同旋轉,一邊對玻璃基板的兩表面進行研磨處理。研磨處理時,有時以玻璃基板的一部分超出研磨墊的方式進行控制。再者,研磨墊為胺基甲酸酯製,研磨處理時所使用的研磨漿料的平均粒徑為2.5μm,研磨速度為15m/min。對所獲得的各研磨處理完畢的玻璃基板,藉由神鋼(KOBELCO)科研公司製造的彎曲/翹曲(Bow/Warp)測定裝置SBW-331ML/d測定整體板厚偏差(TTV)與翹曲量。結果,整體板厚偏差(TTV)分別為0.85μm以下,翹曲量分別為35μm以下。 First, glass raw materials were prepared so as to have the glass compositions described in Sample No. 1 to Sample No. 23 described in Tables 1 and 2, and then fed into a glass melting furnace to be melted at 1600°C to 1700°C, and then The molten glass was supplied to an overflow down-draw forming apparatus, and each was formed into a plate thickness of 0.8 mm. For the obtained glass substrate, for both surfaces Mechanical polishing was performed to reduce overall thickness variation (TTV) to less than 1 μm. After the obtained glass substrate was processed into a thickness of Φ300 mm×0.8 mm, the both surfaces thereof were subjected to polishing treatment by a polishing apparatus. Specifically, both surfaces of the glass substrate are sandwiched between a pair of polishing pads having different outer diameters, and both surfaces of the glass substrate are polished while rotating the glass substrate and the pair of polishing pads. At the time of a polishing process, it may control so that a part of glass substrate may protrude from a polishing pad. In addition, the polishing pad was made of urethane, the average particle diameter of the polishing slurry used in the polishing treatment was 2.5 μm, and the polishing speed was 15 m/min. For each of the obtained polished glass substrates, the overall thickness deviation (TTV) and the amount of warpage were measured by a Bow/Warp measuring device SBW-331ML/d manufactured by KOBELCO Scientific Corporation. . As a result, the overall thickness variation (TTV) was 0.85 μm or less, and the warpage amount was 35 μm or less, respectively.

1:積層體 1: Laminate

10:支撐玻璃基板 10: Support glass substrate

11:加工基板 11: Processing substrate

12:剝離層 12: Peel layer

13:接著層 13: Next layer

Claims (14)

一種支撐玻璃基板,其用以支撐加工基板,且所述支撐玻璃基板的特徵在於:作為玻璃組成,以質量%計含有45%~70%的SiO2、16.3%~35%的Al2O3、0%~20%的B2O3、5%~25%的Na2O、0%~10%的K2O、1%~10%的MgO、以及0%~5%的ZnO,質量比(Al2O3+B2O3+MgO)/(Na2O+K2O)為1.67以上,且裂紋阻力為500gf以上。 A supporting glass substrate is used for supporting a processing substrate, and the supporting glass substrate is characterized in that: as a glass composition, it contains 45%-70% SiO 2 and 16.3%-35% Al 2 O 3 in mass %. , 0%~20% B 2 O 3 , 5%~25% Na 2 O, 0%~10% K 2 O, 1%~10% MgO, and 0%~5% ZnO, mass The ratio (Al 2 O 3 +B 2 O 3 +MgO)/(Na 2 O+K 2 O) is 1.67 or more, and the crack resistance is 500 gf or more. 如申請專利範圍第1項所述的支撐玻璃基板,其中作為玻璃組成,以質量%計含有50%~67%的SiO2、19.7%~33%的Al2O3、0%~15%的B2O3、5%~20%的Na2O、0%~3%的K2O、1%~5.5%的MgO、以及0%~3%的ZnO,質量比(Al2O3+B2O3+MgO)/(Na2O+K2O)為1.67以上,且裂紋阻力為700gf以上。 The supporting glass substrate according to claim 1, wherein the glass composition contains, in mass %, 50% to 67% of SiO 2 , 19.7% to 33% of Al 2 O 3 , and 0% to 15% of B 2 O 3 , 5%~20% Na 2 O, 0%~3% K 2 O, 1%~5.5% MgO, and 0%~3% ZnO, mass ratio (Al 2 O 3 + B 2 O 3 +MgO)/(Na 2 O+K 2 O) was 1.67 or more, and the crack resistance was 700 gf or more. 如申請專利範圍第1項或第2項所述的支撐玻璃基板,其中在20℃~220℃的溫度範圍內的平均線熱膨脹係數為40×10-7/℃以上且120×10-7/℃以下。 The supporting glass substrate according to claim 1 or claim 2, wherein the average linear thermal expansion coefficient in the temperature range of 20°C to 220°C is 40×10 -7 /°C or more and 120×10 -7 / ℃ or lower. 如申請專利範圍第1項或第2項所述的支撐玻璃基板,其中在20℃~260℃的溫度範圍內的平均線熱膨脹係數為40×10-7/℃以上且120×10-7/℃以下。 The supporting glass substrate according to claim 1 or claim 2, wherein the average linear thermal expansion coefficient in a temperature range of 20°C to 260°C is 40×10 -7 /°C or more and 120×10 -7 / ℃ or lower. 如申請專利範圍第1項或第2項所述的支撐玻璃基板,其中在30℃~380℃的溫度範圍內的平均線熱膨脹係數為42×10-7/℃以上且125×10-7/℃以下。 The supporting glass substrate according to claim 1 or claim 2, wherein the average linear thermal expansion coefficient in a temperature range of 30°C to 380°C is 42×10 -7 /°C or more and 125×10 -7 / ℃ or lower. 如申請專利範圍第1項或第2項所述的支撐玻璃基板,其具有直徑100mm~500mm的晶圓形狀或大致圓板形狀,板厚小於2.0mm,整體板厚偏差(TTV)為5μm以下,且翹曲量為60μm以下。 The supporting glass substrate according to claim 1 or claim 2, which has a wafer shape or a roughly circular plate shape with a diameter of 100 mm to 500 mm, a thickness of less than 2.0 mm, and an overall thickness variation (TTV) of less than 5 μm , and the warpage amount is 60 μm or less. 如申請專利範圍第1項或第2項所述的支撐玻璃基板,其具有凹口部。 The supporting glass substrate according to claim 1 or claim 2, which has a notch portion. 一種積層體,其至少包括加工基板及用以支撐加工基板的支撐玻璃基板,且所述積層體的特徵在於:所述支撐玻璃基板為如申請專利範圍第1項至第7項中任一項所述的支撐玻璃基板。 A laminated body at least includes a processing substrate and a supporting glass substrate for supporting the processing substrate, and the laminated body is characterized in that: the supporting glass substrate is any one of items 1 to 7 in the scope of the patent application The supporting glass substrate. 如申請專利範圍第8項所述的積層體,其中所述加工基板至少包括利用密封材進行了成形的半導體晶片。 The laminate according to claim 8, wherein the processing substrate includes at least a semiconductor wafer formed by a sealing material. 一種半導體封裝體的製造方法,其特徵在於包括:準備至少包括加工基板及用以支撐加工基板的支撐玻璃基板的積層體的步驟;以及對所述加工基板進行加工處理的步驟;並且所述支撐玻璃基板為如申請專利範圍第1項至第7項中任一項所述的支撐玻璃基板。 A method of manufacturing a semiconductor package, comprising: preparing a laminate including at least a processing substrate and a supporting glass substrate for supporting the processing substrate; and processing the processing substrate; and the supporting The glass substrate is the supporting glass substrate according to any one of the first to seventh claims. 如申請專利範圍第10項所述的半導體封裝體的製造方法,其中所述加工處理包括在所述加工基板的一表面進行配線的步驟。 The method of manufacturing a semiconductor package according to claim 10, wherein the processing includes the step of wiring on one surface of the processing substrate. 如申請專利範圍第10項或第11項所述的半導體封裝 體的製造方法,其中所述加工處理包括在所述加工基板的一表面形成焊料凸塊的步驟。 Semiconductor package as described in claim 10 or claim 11 The method for manufacturing a body, wherein the processing includes the step of forming solder bumps on a surface of the processing substrate. 一種半導體封裝體,其特徵在於利用如申請專利範圍第10項至第12項中任一項所述的半導體封裝體的製造方法製作。 A semiconductor package is characterized by being produced by the manufacturing method of a semiconductor package according to any one of claims 10 to 12 of the scope of application. 一種電子機器,其包括半導體封裝體,且所述電子機器的特徵在於:所述半導體封裝體為如申請專利範圍第13項所述的半導體封裝體。 An electronic device includes a semiconductor package, and the electronic device is characterized in that: the semiconductor package is the semiconductor package described in item 13 of the patent application scope.
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