TWI292415B - - Google Patents

Info

Publication number

TWI292415B

TWI292415B TW89116779A TW89116779A TWI292415B TW I292415 B TWI292415 B TW I292415B TW 89116779 A TW89116779 A TW 89116779A TW 89116779 A TW89116779 A TW 89116779A TW I292415 B TWI292415 B TW I292415B

Authority

TW

Taiwan

Prior art keywords

weight

rubber

filler

group

cerium oxide

Prior art date

1999-08-19

Links

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• Global Dossier
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• 239000000945 filler Substances 0.000 claims description 93
• 229920001971 elastomer Polymers 0.000 claims description 86
• 239000005060 rubber Substances 0.000 claims description 82
• 239000000203 mixture Substances 0.000 claims description 75
• DIOQZVSQGTUSAI-UHFFFAOYSA-N decane Chemical compound CCCCCCCCCC DIOQZVSQGTUSAI-UHFFFAOYSA-N 0.000 claims description 59
• 229910000420 cerium oxide Inorganic materials 0.000 claims description 44
• BMMGVYCKOGBVEV-UHFFFAOYSA-N oxo(oxoceriooxy)cerium Chemical compound [Ce]=O.O=[Ce]=O BMMGVYCKOGBVEV-UHFFFAOYSA-N 0.000 claims description 44
• 229910052809 inorganic oxide Inorganic materials 0.000 claims description 38
• 229920000642 polymer Polymers 0.000 claims description 35
• OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims description 28
• 229910052799 carbon Inorganic materials 0.000 claims description 28
• 238000006243 chemical reaction Methods 0.000 claims description 27
• 239000002253 acid Substances 0.000 claims description 20
• 125000003396 thiol group Chemical class [H]S* 0.000 claims description 17
• 239000002904 solvent Substances 0.000 claims description 15
• 238000005728 strengthening Methods 0.000 claims description 15
• 238000007639 printing Methods 0.000 claims description 14
• 229920002857 polybutadiene Polymers 0.000 claims description 13
• 239000002002 slurry Substances 0.000 claims description 12
• 239000003960 organic solvent Substances 0.000 claims description 11
• 239000005062 Polybutadiene Substances 0.000 claims description 10
• 239000004594 Masterbatch (MB) Substances 0.000 claims description 7
• 229920005989 resin Polymers 0.000 claims description 5
• 239000011347 resin Substances 0.000 claims description 5
• 239000005995 Aluminium silicate Substances 0.000 claims description 4
• 235000012211 aluminium silicate Nutrition 0.000 claims description 4
• 229910000323 aluminium silicate Inorganic materials 0.000 claims description 4
• NLYAJNPCOHFWQQ-UHFFFAOYSA-N kaolin Chemical compound O.O.O=[Al]O[Si](=O)O[Si](=O)O[Al]=O NLYAJNPCOHFWQQ-UHFFFAOYSA-N 0.000 claims description 4
• 230000002787 reinforcement Effects 0.000 claims description 4
• 150000003839 salts Chemical class 0.000 claims description 4
• 229920001187 thermosetting polymer Polymers 0.000 claims description 4
• 229910052684 Cerium Inorganic materials 0.000 claims description 3
• VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims description 3
• PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 claims description 3
• 150000004945 aromatic hydrocarbons Chemical class 0.000 claims description 3
• MTAZNLWOLGHBHU-UHFFFAOYSA-N butadiene-styrene rubber Chemical compound C=CC=C.C=CC1=CC=CC=C1 MTAZNLWOLGHBHU-UHFFFAOYSA-N 0.000 claims description 3
• 150000001924 cycloalkanes Chemical class 0.000 claims description 3
• 229920001296 polysiloxane Polymers 0.000 claims description 3
• 150000001338 aliphatic hydrocarbons Chemical class 0.000 claims description 2
• 239000004927 clay Substances 0.000 claims description 2
• HNPSIPDUKPIQMN-UHFFFAOYSA-N dioxosilane;oxo(oxoalumanyloxy)alumane Chemical compound O=[Si]=O.O=[Al]O[Al]=O HNPSIPDUKPIQMN-UHFFFAOYSA-N 0.000 claims description 2
• 150000002576 ketones Chemical class 0.000 claims description 2
• 229920005992 thermoplastic resin Polymers 0.000 claims description 2
• GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 claims 2
• 239000005909 Kieselgur Substances 0.000 claims 1
• RREGISFBPQOLTM-UHFFFAOYSA-N alumane;trihydrate Chemical compound O.O.O.[AlH3] RREGISFBPQOLTM-UHFFFAOYSA-N 0.000 claims 1
• ZWOQODLNWUDJFT-UHFFFAOYSA-N aluminum lanthanum Chemical compound [Al].[La] ZWOQODLNWUDJFT-UHFFFAOYSA-N 0.000 claims 1
• 125000000484 butyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 claims 1
• ZMIGMASIKSOYAM-UHFFFAOYSA-N cerium Chemical compound [Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce] ZMIGMASIKSOYAM-UHFFFAOYSA-N 0.000 claims 1
• 150000008282 halocarbons Chemical class 0.000 claims 1
• XMHIUKTWLZUKEX-UHFFFAOYSA-N hexacosanoic acid Chemical class CCCCCCCCCCCCCCCCCCCCCCCCCC(O)=O XMHIUKTWLZUKEX-UHFFFAOYSA-N 0.000 claims 1
• 150000002484 inorganic compounds Chemical class 0.000 claims 1
• 229910010272 inorganic material Inorganic materials 0.000 claims 1
• 239000004408 titanium dioxide Substances 0.000 claims 1
• 230000035897 transcription Effects 0.000 claims 1
• 238000013518 transcription Methods 0.000 claims 1
• -1 alkoxy decane Chemical compound 0.000 description 65
• 238000000034 method Methods 0.000 description 45
• YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 33
• 229910052717 sulfur Inorganic materials 0.000 description 31
• 239000011593 sulfur Substances 0.000 description 31
• 239000000523 sample Substances 0.000 description 29
• 230000000052 comparative effect Effects 0.000 description 27
• 239000000126 substance Substances 0.000 description 25
• 150000001875 compounds Chemical class 0.000 description 22
• 239000000243 solution Substances 0.000 description 20
• 239000004575 stone Substances 0.000 description 20
• IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 18
• NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 18
• XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 18
• 239000007900 aqueous suspension Substances 0.000 description 17
• 230000002079 cooperative effect Effects 0.000 description 17
• 150000002902 organometallic compounds Chemical class 0.000 description 17
• 229910001868 water Inorganic materials 0.000 description 17
• KFZMGEQAYNKOFK-UHFFFAOYSA-N Isopropanol Chemical compound CC(C)O KFZMGEQAYNKOFK-UHFFFAOYSA-N 0.000 description 16
• HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 15
• 239000000463 material Substances 0.000 description 15
• 239000000376 reactant Substances 0.000 description 15
• QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 12
• 125000004432 carbon atom Chemical group C* 0.000 description 12
• 230000002209 hydrophobic effect Effects 0.000 description 12
• 239000001301 oxygen Substances 0.000 description 12
• 229910052760 oxygen Inorganic materials 0.000 description 12
• 230000008569 process Effects 0.000 description 12
• KJTLSVCANCCWHF-UHFFFAOYSA-N Ruthenium Chemical group [Ru] KJTLSVCANCCWHF-UHFFFAOYSA-N 0.000 description 10
• 239000003795 chemical substances by application Substances 0.000 description 10
• 239000007822 coupling agent Substances 0.000 description 10
• 239000007788 liquid Substances 0.000 description 10
• 239000000047 product Substances 0.000 description 10
• 230000035882 stress Effects 0.000 description 10
• 238000012360 testing method Methods 0.000 description 10
• RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 9
• OAKJQQAXSVQMHS-UHFFFAOYSA-N Hydrazine Chemical compound NN OAKJQQAXSVQMHS-UHFFFAOYSA-N 0.000 description 9
• 238000002156 mixing Methods 0.000 description 9
• 229910052757 nitrogen Inorganic materials 0.000 description 9
• 125000002524 organometallic group Chemical group 0.000 description 9
• 239000005077 polysulfide Substances 0.000 description 9
• 229920001021 polysulfide Polymers 0.000 description 9
• 150000008117 polysulfides Polymers 0.000 description 9
• 229920001577 copolymer Polymers 0.000 description 8
• 239000007789 gas Substances 0.000 description 8
• 150000002430 hydrocarbons Chemical group 0.000 description 8
• 229910052707 ruthenium Inorganic materials 0.000 description 8
• 239000000725 suspension Substances 0.000 description 8
• QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 7
• 239000000654 additive Substances 0.000 description 7
• 125000000217 alkyl group Chemical group 0.000 description 7
• 239000008346 aqueous phase Substances 0.000 description 7
• 238000000605 extraction Methods 0.000 description 7
• 230000003993 interaction Effects 0.000 description 7
• QIQXTHQIDYTFRH-UHFFFAOYSA-N octadecanoic acid Chemical compound CCCCCCCCCCCCCCCCCC(O)=O QIQXTHQIDYTFRH-UHFFFAOYSA-N 0.000 description 7
• 239000003921 oil Substances 0.000 description 7
• 235000019198 oils Nutrition 0.000 description 7
• UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 description 6
• PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 description 6
• XLOMVQKBTHCTTD-UHFFFAOYSA-N Zinc monoxide Chemical compound [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 description 6
• 230000009471 action Effects 0.000 description 6
• 238000000576 coating method Methods 0.000 description 6
• 125000002887 hydroxy group Chemical group [H]O* 0.000 description 6
• 229920003052 natural elastomer Polymers 0.000 description 6
• 229920001194 natural rubber Polymers 0.000 description 6
• KAKZBPTYRLMSJV-UHFFFAOYSA-N Butadiene Chemical compound C=CC=C KAKZBPTYRLMSJV-UHFFFAOYSA-N 0.000 description 5
• BWGNESOTFCXPMA-UHFFFAOYSA-N Dihydrogen disulfide Chemical compound SS BWGNESOTFCXPMA-UHFFFAOYSA-N 0.000 description 5
• 244000043261 Hevea brasiliensis Species 0.000 description 5
• DRVWBEJJZZTIGJ-UHFFFAOYSA-N cerium(3+);oxygen(2-) Chemical class [O-2].[O-2].[O-2].[Ce+3].[Ce+3] DRVWBEJJZZTIGJ-UHFFFAOYSA-N 0.000 description 5
• 239000011248 coating agent Substances 0.000 description 5
• 230000008878 coupling Effects 0.000 description 5
• 238000010168 coupling process Methods 0.000 description 5
• 238000005859 coupling reaction Methods 0.000 description 5
• 239000000839 emulsion Substances 0.000 description 5
• 239000001257 hydrogen Substances 0.000 description 5
• 229910052739 hydrogen Inorganic materials 0.000 description 5
• 125000004435 hydrogen atom Chemical group [H]* 0.000 description 5
• 239000004615 ingredient Substances 0.000 description 5
• 238000004519 manufacturing process Methods 0.000 description 5
• 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 5
• 150000002923 oximes Chemical class 0.000 description 5
• SIWVEOZUMHYXCS-UHFFFAOYSA-N oxo(oxoyttriooxy)yttrium Chemical compound O=[Y]O[Y]=O SIWVEOZUMHYXCS-UHFFFAOYSA-N 0.000 description 5
• 229920003023 plastic Polymers 0.000 description 5
• 239000004033 plastic Substances 0.000 description 5
• 229920001223 polyethylene glycol Polymers 0.000 description 5
• WOCIAKWEIIZHES-UHFFFAOYSA-N ruthenium(iv) oxide Chemical compound O=[Ru]=O WOCIAKWEIIZHES-UHFFFAOYSA-N 0.000 description 5
• 239000012258 stirred mixture Substances 0.000 description 5
• 229920003048 styrene butadiene rubber Polymers 0.000 description 5
• 239000004094 surface-active agent Substances 0.000 description 5
• 230000004580 weight loss Effects 0.000 description 5
• DFYGYTNMHPUJBY-UHFFFAOYSA-N 4-(trimethoxymethyl)dodecane-1-thiol Chemical compound SCCCC(C(OC)(OC)OC)CCCCCCCC DFYGYTNMHPUJBY-UHFFFAOYSA-N 0.000 description 4
• ZCYVEMRRCGMTRW-UHFFFAOYSA-N 7553-56-2 Chemical compound [I] ZCYVEMRRCGMTRW-UHFFFAOYSA-N 0.000 description 4
• LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 4
• VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 description 4
• 239000005977 Ethylene Substances 0.000 description 4
• VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 4
• 239000004698 Polyethylene Substances 0.000 description 4
• 239000002202 Polyethylene glycol Substances 0.000 description 4
• WPYMKLBDIGXBTP-UHFFFAOYSA-N benzoic acid Chemical compound OC(=O)C1=CC=CC=C1 WPYMKLBDIGXBTP-UHFFFAOYSA-N 0.000 description 4
• 238000007385 chemical modification Methods 0.000 description 4
• 238000004140 cleaning Methods 0.000 description 4
• 238000013329 compounding Methods 0.000 description 4
• 238000001035 drying Methods 0.000 description 4
• 125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 description 4
• 238000010438 heat treatment Methods 0.000 description 4
• 229910052740 iodine Inorganic materials 0.000 description 4
• 239000011630 iodine Substances 0.000 description 4
• 230000004048 modification Effects 0.000 description 4
• 238000012986 modification Methods 0.000 description 4
• HDZGCSFEDULWCS-UHFFFAOYSA-N monomethylhydrazine Chemical compound CNN HDZGCSFEDULWCS-UHFFFAOYSA-N 0.000 description 4
• 230000003647 oxidation Effects 0.000 description 4
• 238000007254 oxidation reaction Methods 0.000 description 4
• 239000012071 phase Substances 0.000 description 4
• 229920000573 polyethylene Polymers 0.000 description 4
• 230000005070 ripening Effects 0.000 description 4
• 238000000926 separation method Methods 0.000 description 4
• 239000002689 soil Substances 0.000 description 4
• 239000007787 solid Substances 0.000 description 4
• 150000003573 thiols Chemical class 0.000 description 4
• 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 description 4
• 239000004636 vulcanized rubber Substances 0.000 description 4
• YMWUJEATGCHHMB-UHFFFAOYSA-N Dichloromethane Chemical compound ClCCl YMWUJEATGCHHMB-UHFFFAOYSA-N 0.000 description 3
• RRHGJUQNOFWUDK-UHFFFAOYSA-N Isoprene Chemical compound CC(=C)C=C RRHGJUQNOFWUDK-UHFFFAOYSA-N 0.000 description 3
• OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 3
• 238000005481 NMR spectroscopy Methods 0.000 description 3
• KWYUFKZDYYNOTN-UHFFFAOYSA-M Potassium hydroxide Chemical compound [OH-].[K+] KWYUFKZDYYNOTN-UHFFFAOYSA-M 0.000 description 3
• 235000021355 Stearic acid Nutrition 0.000 description 3
• 239000002174 Styrene-butadiene Substances 0.000 description 3
• UCKMPCXJQFINFW-UHFFFAOYSA-N Sulphide Chemical compound [S-2] UCKMPCXJQFINFW-UHFFFAOYSA-N 0.000 description 3
• 230000002378 acidificating effect Effects 0.000 description 3
• NIXOWILDQLNWCW-UHFFFAOYSA-N acrylic acid group Chemical group C(C=C)(=O)O NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 3
• 230000000996 additive effect Effects 0.000 description 3
• 229920000180 alkyd Polymers 0.000 description 3
• 239000006229 carbon black Substances 0.000 description 3
• 125000001309 chloro group Chemical group Cl* 0.000 description 3
• 239000002131 composite material Substances 0.000 description 3
• 238000004132 cross linking Methods 0.000 description 3
• DIOQZVSQGTUSAI-NJFSPNSNSA-N decane Chemical group CCCCCCCCC[14CH3] DIOQZVSQGTUSAI-NJFSPNSNSA-N 0.000 description 3
• 210000003298 dental enamel Anatomy 0.000 description 3
• 150000001993 dienes Chemical class 0.000 description 3
• 230000000694 effects Effects 0.000 description 3
• 239000000806 elastomer Substances 0.000 description 3
• 150000002170 ethers Chemical class 0.000 description 3
• 125000001153 fluoro group Chemical group F* 0.000 description 3
• 238000002309 gasification Methods 0.000 description 3
• 229910052736 halogen Inorganic materials 0.000 description 3
• 230000007062 hydrolysis Effects 0.000 description 3
• 238000006460 hydrolysis reaction Methods 0.000 description 3
• 230000001965 increasing effect Effects 0.000 description 3
• MWUXSHHQAYIFBG-UHFFFAOYSA-N nitrogen oxide Inorganic materials O=[N] MWUXSHHQAYIFBG-UHFFFAOYSA-N 0.000 description 3
• OQCDKBAXFALNLD-UHFFFAOYSA-N octadecanoic acid Natural products CCCCCCCC(C)CCCCCCCCC(O)=O OQCDKBAXFALNLD-UHFFFAOYSA-N 0.000 description 3
• 150000002978 peroxides Chemical class 0.000 description 3
• 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 description 3
• 230000000704 physical effect Effects 0.000 description 3
• 125000001436 propyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])[H] 0.000 description 3
• QQONPFPTGQHPMA-UHFFFAOYSA-N propylene Natural products CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 description 3
• 125000004805 propylene group Chemical group [H]C([H])([H])C([H])([*:1])C([H])([H])[*:2] 0.000 description 3
• 238000010992 reflux Methods 0.000 description 3
• 239000012763 reinforcing filler Substances 0.000 description 3
• 238000010058 rubber compounding Methods 0.000 description 3
• 229910001925 ruthenium oxide Inorganic materials 0.000 description 3
• 229920002379 silicone rubber Polymers 0.000 description 3
• 239000004945 silicone rubber Substances 0.000 description 3
• 239000008117 stearic acid Substances 0.000 description 3
• 229920003051 synthetic elastomer Polymers 0.000 description 3
• 239000005061 synthetic rubber Substances 0.000 description 3
• 229920001169 thermoplastic Polymers 0.000 description 3
• 239000004416 thermosoftening plastic Substances 0.000 description 3
• 239000010936 titanium Substances 0.000 description 3
• 238000004448 titration Methods 0.000 description 3
• YBQZXXMEJHZYMB-UHFFFAOYSA-N 1,2-diphenylhydrazine Chemical compound C=1C=CC=CC=1NNC1=CC=CC=C1 YBQZXXMEJHZYMB-UHFFFAOYSA-N 0.000 description 2
• VXNZUUAINFGPBY-UHFFFAOYSA-N 1-Butene Chemical compound CCC=C VXNZUUAINFGPBY-UHFFFAOYSA-N 0.000 description 2
• DURPTKYDGMDSBL-UHFFFAOYSA-N 1-butoxybutane Chemical compound CCCCOCCCC DURPTKYDGMDSBL-UHFFFAOYSA-N 0.000 description 2
• YTPFRRRNIYVFFE-UHFFFAOYSA-N 2,2,3,3,5,5-hexamethyl-1,4-dioxane Chemical compound CC1(C)COC(C)(C)C(C)(C)O1 YTPFRRRNIYVFFE-UHFFFAOYSA-N 0.000 description 2
• AWBIJARKDOFDAN-UHFFFAOYSA-N 2,5-dimethyl-1,4-dioxane Chemical compound CC1COC(C)CO1 AWBIJARKDOFDAN-UHFFFAOYSA-N 0.000 description 2
• NIXOWILDQLNWCW-UHFFFAOYSA-M Acrylate Chemical compound [O-]C(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-M 0.000 description 2
• 239000005711 Benzoic acid Substances 0.000 description 2
• FERIUCNNQQJTOY-UHFFFAOYSA-N Butyric acid Chemical compound CCCC(O)=O FERIUCNNQQJTOY-UHFFFAOYSA-N 0.000 description 2
• 239000004215 Carbon black (E152) Substances 0.000 description 2
• CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 description 2
• HEDRZPFGACZZDS-UHFFFAOYSA-N Chloroform Chemical compound ClC(Cl)Cl HEDRZPFGACZZDS-UHFFFAOYSA-N 0.000 description 2
• VQTUBCCKSQIDNK-UHFFFAOYSA-N Isobutene Chemical group CC(C)=C VQTUBCCKSQIDNK-UHFFFAOYSA-N 0.000 description 2
• IMNFDUFMRHMDMM-UHFFFAOYSA-N N-Heptane Chemical compound CCCCCCC IMNFDUFMRHMDMM-UHFFFAOYSA-N 0.000 description 2
• 238000003723 Smelting Methods 0.000 description 2
• UIIMBOGNXHQVGW-UHFFFAOYSA-M Sodium bicarbonate Chemical compound [Na+].OC([O-])=O UIIMBOGNXHQVGW-UHFFFAOYSA-M 0.000 description 2
• 229910000831 Steel Inorganic materials 0.000 description 2
• 239000005864 Sulphur Substances 0.000 description 2
• WYURNTSHIVDZCO-UHFFFAOYSA-N Tetrahydrofuran Chemical compound C1CCOC1 WYURNTSHIVDZCO-UHFFFAOYSA-N 0.000 description 2
• DHXVGJBLRPWPCS-UHFFFAOYSA-N Tetrahydropyran Chemical compound C1CCOCC1 DHXVGJBLRPWPCS-UHFFFAOYSA-N 0.000 description 2
• RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 description 2
• 238000005299 abrasion Methods 0.000 description 2
• GPWHDDKQSYOYBF-UHFFFAOYSA-N ac1l2u0q Chemical compound Br[Br-]Br GPWHDDKQSYOYBF-UHFFFAOYSA-N 0.000 description 2
• 239000003377 acid catalyst Substances 0.000 description 2
• 150000001335 aliphatic alkanes Chemical group 0.000 description 2
• 125000001931 aliphatic group Chemical group 0.000 description 2
• 125000002009 alkene group Chemical group 0.000 description 2
• 125000003545 alkoxy group Chemical group 0.000 description 2
• 125000002947 alkylene group Chemical group 0.000 description 2
• XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical group [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 2
• 239000003963 antioxidant agent Substances 0.000 description 2
• 239000007864 aqueous solution Substances 0.000 description 2
• 125000004429 atom Chemical group 0.000 description 2
• 230000008901 benefit Effects 0.000 description 2
• 235000010233 benzoic acid Nutrition 0.000 description 2
• 125000001797 benzyl group Chemical group [H]C1=C([H])C([H])=C(C([H])=C1[H])C([H])([H])* 0.000 description 2
• 230000000903 blocking effect Effects 0.000 description 2
• 239000003054 catalyst Substances 0.000 description 2
• 230000003197 catalytic effect Effects 0.000 description 2
• GWXLDORMOJMVQZ-UHFFFAOYSA-N cerium Chemical compound [Ce] GWXLDORMOJMVQZ-UHFFFAOYSA-N 0.000 description 2
• 230000008859 change Effects 0.000 description 2
• 238000000748 compression moulding Methods 0.000 description 2
• 230000000875 corresponding effect Effects 0.000 description 2
• 238000005520 cutting process Methods 0.000 description 2
• 230000006378 damage Effects 0.000 description 2
• VTXVGVNLYGSIAR-UHFFFAOYSA-N decane-1-thiol Chemical compound CCCCCCCCCCS VTXVGVNLYGSIAR-UHFFFAOYSA-N 0.000 description 2
• 125000002704 decyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 description 2
• 125000000118 dimethyl group Chemical group [H]C([H])([H])* 0.000 description 2
• 239000006185 dispersion Substances 0.000 description 2
• MOTZDAYCYVMXPC-UHFFFAOYSA-N dodecyl hydrogen sulfate Chemical compound CCCCCCCCCCCCOS(O)(=O)=O MOTZDAYCYVMXPC-UHFFFAOYSA-N 0.000 description 2
• 150000002148 esters Chemical class 0.000 description 2
• 125000001301 ethoxy group Chemical group [H]C([H])([H])C([H])([H])O* 0.000 description 2
• DECIPOUIJURFOJ-UHFFFAOYSA-N ethoxyquin Chemical compound N1C(C)(C)C=C(C)C2=CC(OCC)=CC=C21 DECIPOUIJURFOJ-UHFFFAOYSA-N 0.000 description 2
• 239000005038 ethylene vinyl acetate Substances 0.000 description 2
• 238000001914 filtration Methods 0.000 description 2
• 239000012467 final product Substances 0.000 description 2
• 238000009472 formulation Methods 0.000 description 2
• 239000008187 granular material Substances 0.000 description 2
• 125000005843 halogen group Chemical group 0.000 description 2
• 150000002367 halogens Chemical class 0.000 description 2
• 239000001307 helium Substances 0.000 description 2
• 229910052734 helium Inorganic materials 0.000 description 2
• SWQJXJOGLNCZEY-UHFFFAOYSA-N helium atom Chemical compound [He] SWQJXJOGLNCZEY-UHFFFAOYSA-N 0.000 description 2
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