TWI244565B - Liquid crystal display panel with fluid control wall - Google Patents
Liquid crystal display panel with fluid control wall Download PDFInfo
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- TWI244565B TWI244565B TW92122637A TW92122637A TWI244565B TW I244565 B TWI244565 B TW I244565B TW 92122637 A TW92122637 A TW 92122637A TW 92122637 A TW92122637 A TW 92122637A TW I244565 B TWI244565 B TW I244565B
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- 239000012530 fluid Substances 0.000 title claims abstract description 174
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- 239000003566 sealing material Substances 0.000 claims abstract description 87
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Abstract
Description
1244565 坎、發明說明: 【發明所屬之技術領域】 本發明係關於一種液晶顯示器面板,其使用液晶滴入填 滿方法製造。 【先前技術】 作為一輕薄及低功率消耗之顯示器裝置,液晶顯示器裝 置逐漸變為普及。液晶顯示器裝置設計為建立驅動電路與 相關私路於稱為液晶顯示器面板之平板裝置。圖1為一截 面模式圖式,以解釋一液晶顯示器面板(於本說明書中通常 僅稱為顯示器面板)之概要結構。如圖丨所示,液晶顯示器 面板9建構為具一對重疊基板,及液晶5置於其中,重疊基 板對由薄膜電晶體(僅稱為TFT)基板(亦稱為TFT基板)^與 其他彩色濾光器基板lb(亦稱*CF基板)所構成,後者基板 =正常模式由紅色(R),綠色⑼,與藍色(B)三種彩色遽光 时所構成。此外,於基板對丨&與lb間放置間隔物4,以控制 兩基板間之間隙。一密封材料7填入基板對la與lb周圍之 山封口15刀,以黏貼基板以與❶。迄今所提出製造液晶面板 9之方法大致分為液晶注入方法與液晶滴入填滿方法。 液晶注入方法為將TFT基板la與CF基板lb彼此重疊,黏 這一基板la與lb,且將液晶5注入TFT基板丨&與CF基板 lb間〈間隙。另―方面,液晶滴人填滿方法為將指定量之 液晶5滴入TFT基板與CF基板之一,彼此重疊這些基板,並 黏貼兩者。胃方法為同時組合液晶顯示器面板9與注入液晶1244565 Description of the invention: [Technical field to which the invention belongs] The present invention relates to a liquid crystal display panel, which is manufactured using a liquid crystal drop-in filling method. [Prior Art] As a thin and light display device with low power consumption, liquid crystal display devices have gradually become popular. The liquid crystal display device is designed to establish a driving circuit and related circuits in a flat device called a liquid crystal display panel. FIG. 1 is a cross-sectional schematic diagram for explaining a schematic structure of a liquid crystal display panel (usually referred to as a display panel in this specification). As shown in FIG. 丨, the liquid crystal display panel 9 is constructed with a pair of overlapping substrates, and the liquid crystal 5 is placed therein. The overlapping substrate pair is made of a thin film transistor (only referred to as a TFT) substrate (also referred to as a TFT substrate) ^ and other colors The filter substrate lb (also known as * CF substrate) is composed of the latter substrate = normal mode, which is composed of three colors of red (R), green, and blue (B). In addition, a spacer 4 is placed between the substrate pair, & and lb to control the gap between the two substrates. A sealing material 7 is filled into the mountain seal 15 around the substrate pair la and lb to adhere the substrate to the substrate. The methods proposed so far for manufacturing the liquid crystal panel 9 are roughly divided into a liquid crystal injection method and a liquid crystal drop-in filling method. The liquid crystal injection method is to overlap the TFT substrate 1a and the CF substrate 1b, adhere the substrates 1a and 1b, and inject the liquid crystal 5 into the gap between the TFT substrate 1 and the CF substrate 1b. On the other hand, the liquid crystal filling method is to drop a specified amount of liquid crystal 5 into one of a TFT substrate and a CF substrate, overlap these substrates with each other, and stick the two together. Stomach method is to combine liquid crystal display panel 9 and inject liquid crystal at the same time
87519.DOC 1244565 通常’皆構成液晶顯示器面板9之TFT基板ia與CF基板lb 間之間隙’最窄為3至5微米。因此,經由液晶滴入填滿方 法’欲將液晶5完全填入3至5微米之間隙中,需使用真空室 使液晶顯tf器面板之間隔變為真空,使液晶與顯示器面板 之液晶入口接觸,並經由毛細作用效應,及液晶顯示器面 板内外間(壓力差,將液晶注入。然而,於此方法中,使3 至5微米間隔成為真空,並注入液晶之操作需相當長時間。 尤其,當液晶顯示器面板擴大,且基板間之間隙變窄時, >王入液晶所需時間將變為相當長。此外,於注入操作完成 後亦需密封入口。於這些情況下,注入液晶之操作將變為 增加製造成本之一因素。 另一万面,液晶滴入填滿方法不需抽真空之操作,即, 不需使TFT基板la與CF基板lb間之3至5微米間隔減壓,此 兩基板皆構成液晶顯示器面板9。此外,此方法亦不需密 封液晶入口(操作。再者,填滿液晶所需時間變為較短。 因此,相較於液晶注入方法,此液晶滴入填滿方法可減少 將液晶填入顯示器面板所需之時間。 此後,將描述使用液晶注入方法或液晶滴入填滿方法之 製造。 使用液晶注入方法之製造包含下列步驟。 ⑴塗覆-密封材料,以便圍繞液晶顯示器區域,並形成 一開口(液时入口),經由其將液晶注入於周圍塗覆上。 ⑺放置間隔*,以使基板間維持3至5微米之間隔。於使 用具有間隔物包含^其中之-或兩個基板情形,不需放置 87519.DOC -7- I244565 間隔物。 (3) 將兩基板定位並黏貼兩者。 (4) 根據密封材料種麵,日力jΛ 打®頒,恥射|外先或加熱基板,以使密 封材料硬化。 上述操作完成具有間隔於該基板對間之液晶顯示器面板。 接#’ (5) 於由大型基板形成多個液晶面板之情形,將基板切割 為每個面板大小。 (6) 將液晶顯不器面板置於真空室,以將液晶注入彼此黏 貼之基板對間之間隙。 接著’藉由減壓真空室,使液晶顯示器面板内之間隔減 唇。 (7) 使液晶與顯示器面板之液晶入口接觸,並將真空室内 之壓力升高至大氣壓力或更多。 結果,液晶經由毛細作用效應,及液晶顯示器面板内外 間之壓力差注入。 (8) 於擦拭黏附於液晶入口之液晶後,使用紫外光硬化樹 脂等’將液晶入口密封。 接著,將參照圖2Α至2Ε描述液晶滴入填滿方法。圖2Α 至2Ε為概念圖式,以描述經由使用液晶滴入填滿方法,製 造液晶顯示器面板之方法。圖2Α至2Ε描繪四個液晶顯示器 面板9,每個來自圖1所示之大型基板。 使用液晶滴入填滿方法之製造包含下列步驟。 (1)放置間隔物4(見圖1),以使基板對la與lb間之間隔維87519.DOC 1244565 Generally, "the gap between the TFT substrate ia and the CF substrate lb which constitutes the liquid crystal display panel 9" is at least 3 to 5 microns. Therefore, through the liquid crystal dripping filling method, 'To fully fill the liquid crystal 5 into the gap of 3 to 5 micrometers, a vacuum chamber needs to be used to make the interval between the LCD panel and the LCD panel vacuum, so that the liquid crystal contacts the liquid crystal inlet of the display panel. And through the capillary effect, and the liquid crystal display panel (pressure difference, the liquid crystal is injected. However, in this method, the interval of 3 to 5 microns into a vacuum, and the operation of the liquid crystal injection takes a long time. Especially, when When the liquid crystal display panel is enlarged and the gap between the substrates is narrowed, the time required for Wang to enter the liquid crystal will become quite long. In addition, the inlet must be sealed after the injection operation is completed. In these cases, the operation of injecting liquid crystal will be It becomes a factor that increases the manufacturing cost. On the other hand, the liquid crystal drip-filling method does not require a vacuum operation, that is, it is not necessary to decompress the 3 to 5 micron interval between the TFT substrate la and the CF substrate 1b. Both substrates constitute a liquid crystal display panel 9. In addition, this method does not need to seal the liquid crystal inlet (operation. Moreover, the time required to fill the liquid crystal becomes shorter. Therefore, compared to liquid crystal Injecting method, this liquid crystal drip filling method can reduce the time required to fill the liquid crystal into the display panel. Hereinafter, the manufacturing using the liquid crystal injection method or the liquid crystal drip filling method will be described. Manufacturing using the liquid crystal injection method includes the following steps ⑴ Coating-sealing material so as to surround the liquid crystal display area and form an opening (liquid inlet), through which the liquid crystal is injected into the surrounding coating. ⑺ Place the interval * to maintain the substrate between 3 and 5 microns. Spacer. In the case of using spacers containing one of ^-or two substrates, there is no need to place 87519.DOC -7- I244565 spacers. (3) Position and adhere the two substrates. (4) According to the type of sealing material Surface, Nippon Electric Power Co., Ltd., shaming | outer or heating the substrate to harden the sealing material. The above operation is completed with a liquid crystal display panel spaced between the substrate pair. (5) It is formed by a large substrate In the case of multiple LCD panels, the substrate is cut to the size of each panel. (6) The LCD monitor panel is placed in a vacuum chamber to inject liquid crystal into the gap between the pair of substrates adhered to each other Then, 'the gap in the liquid crystal display panel is reduced by reducing the vacuum chamber. (7) The liquid crystal is brought into contact with the liquid crystal inlet of the display panel, and the pressure in the vacuum chamber is increased to atmospheric pressure or more. As a result, The liquid crystal is injected through the capillary effect and the pressure difference between the inside and the outside of the liquid crystal display panel. (8) After wiping the liquid crystal adhered to the liquid crystal inlet, the liquid crystal inlet is sealed with an ultraviolet curing resin or the like. Next, referring to FIGS. 2A to 2E Describe the liquid crystal drop-in filling method. Figures 2A to 2E are conceptual diagrams to describe the method of manufacturing a liquid crystal display panel by using the liquid crystal drop-in filling method. Figures 2A to 2E depict four liquid crystal display panels 9, each from The large-scale substrate shown in Figure 1. The manufacturing method using the liquid crystal drop filling method includes the following steps. (1) Place spacer 4 (see Figure 1) so that the distance between the substrate pair la and lb
87519.DOC 1244565 持3至5微米。於使用具有間隔物包含於其中之一或兩個基 板,不需放置間隔物。 (2) 經由使用一分配器(見圖2A),塗覆密封材料7,如同 一框架,以便圍繞兩基板或其中之一之顯示器區域(於圖 2A至2E,基板lb)。於塗覆密封材料7之前或之後,於製造 期間經由使用相同分配器,在密封材料7外部,塗覆密封材 料70以固定兩大型基板,由其切割為四個顯示器面板。 (3) 將指定量之液晶5滴入密封材料7内側(見圖2B)。 (4) 將基板對la與lb彼此定位後,於減壓大氣下黏貼基板 (見圖2C)。 (5) 將黏貼之基板移出至大氣壓力。接著,為使密封材料 7硬化,根據密封材料7之硬化條件,使用紫外光燈“以施 加糸外光至密封材料,或加熱基板丨(見圖2D)。 (6) 於由大型基板丨製造一批複數個液晶顯示器面板9之 情形,將大型基板1切割為面板大小(見圖2E)。 上述操作完成液晶顯示器面板9。 上述液晶滴入填滿方法,例如,於JP-A_62_89〇25(公開 木υ中提出。於此液晶滴人填滿方法,不需使黏貼基板對 間,3至5微米間隔變為真空。此外,亦不需密封液晶入口 之铱作再者,因液晶之填入為快速的,相較於液晶注入 方法’此滴人填滿方法可減少將液晶填人液晶顯示器面板 之時間。 然而,液晶滴入填滿方法具有一缺點,即密封材料與基 板對間《結合強度較低,且密封材料可能失去適當形式,87519.DOC 1244565 holds 3 to 5 microns. For using one or two substrates with spacers included, no spacers are required. (2) By using a dispenser (see FIG. 2A), the sealing material 7 is applied as a frame so as to surround the display area of one or both substrates (in FIGS. 2A to 2E, the substrate lb). Before or after the sealing material 7 is applied, the sealing material 70 is applied to the outside of the sealing material 7 to fix the two large substrates by using the same dispenser during manufacturing, and cut into four display panels. (3) Drop a specified amount of liquid crystal 5 into the inside of the sealing material 7 (see FIG. 2B). (4) After positioning the substrate pair la and lb to each other, adhere the substrate in a reduced pressure atmosphere (see FIG. 2C). (5) Remove the adhered substrate to atmospheric pressure. Next, in order to harden the sealing material 7, according to the hardening conditions of the sealing material 7, use an ultraviolet lamp "to apply external light to the sealing material, or heat the substrate 丨 (see Fig. 2D). (6) Manufactured from a large substrate 丨In the case of a batch of a plurality of liquid crystal display panels 9, the large substrate 1 is cut to a panel size (see FIG. 2E). The above operation completes the liquid crystal display panel 9. The liquid crystal drop-in filling method described above is, for example, in JP-A_62_89〇25 ( It is proposed in the open wood. In this liquid crystal filling method, there is no need to make the gap between the substrates to be adhered, and the interval between 3 and 5 microns becomes a vacuum. In addition, it is not necessary to seal the entrance of the liquid crystal with iridium. Compared with the liquid crystal injection method, the filling method can reduce the time for filling the liquid crystal into the LCD panel. However, the liquid crystal filling method has a disadvantage, that is, the sealing material and the substrate pair. The bonding strength is low and the sealing material may lose the proper form,
87519.DOC Ϊ244565 因液晶與仍未硬化之密封材料接觸。此外,未硬化密封材 料與液晶間之接觸使得液晶受到污染,其將導致顯示器故 障。 為避免此未硬化密封材料與液晶間之接觸,需使用不具 液晶污染之密封材料。此外,作為產品結構與製造過程之 万法,提出將框架狀牆置於液晶與密封材料間,以避免未 硬化沧封材料與液晶接觸之方法。此方法於 (公開案2),jP_A_6_194615(公開案3), (公開案4)中揭示。 【發明内容】 、、圖3Α至3D,圖4八與化,及圖5為概念圖式,描述於液晶 滴入填滿 < 液晶流體化。於圖3八至3D,平面圖式示於上側 而每個平面沿请頭八至A之截面示於下側。於圖4A與々Η ,平面圖式示於右側,而每個平面沿箭頭人至A之截面示於 左側。同樣地,於圖5,平面圖式示於右側,而每個平面沿 二至/之截面示於左。於經由使用上述液晶滴人填滿方法 製造液晶顯示面板之情开),及於n62-89〇25(公開案^ 揭丁之相關專利中,當將基板彼此重疊,且於間隙中填滿 液曰曰時,滴於基板上之液晶5,以滴入點為中心,同心圓狀 地分佈,如圖3A至圖3B至圖3C至圖3D所示。每_次,基 板對1碘1]3間之間隔變為更窄,直到由間隔物4所控制之預 先決定間隔。 么如上述,液晶5以滴入點為中心,同心圓狀地分佈(以虛 線^卜如_4A所示’因此’當液晶5未完全填滿液晶顯87519.DOC Ϊ 244565 due to the liquid crystal coming into contact with the sealing material that has not yet hardened. In addition, the contact between the unhardened sealing material and the liquid crystal contaminates the liquid crystal, which will cause the display to malfunction. To avoid contact between this unhardened sealing material and the liquid crystal, a sealing material without liquid crystal contamination is required. In addition, as a method of product structure and manufacturing process, a method of placing a frame-shaped wall between the liquid crystal and the sealing material to avoid contact between the unhardened sealing material and the liquid crystal is proposed. This method is disclosed in (Public Case 2), jP_A_6_194615 (Public Case 3), (Public Case 4). [Summary of the Invention] Figs. 3A to 3D, Fig. 4 and Fig. 5 and Fig. 5 are conceptual diagrams, described in the liquid crystal dripping filling < liquid crystal fluidization. In FIGS. 3A to 3D, plan views are shown on the upper side and each plane is shown on the lower side along the cross section of the first eight to A. In FIGS. 4A and 々Η, the plan view is shown on the right side, and each plane along the arrow to A section is shown on the left side. Similarly, in Fig. 5, the plan view is shown on the right, and each plane is shown on the left along a cross section of 2 to /. In the case of manufacturing a liquid crystal display panel by using the above-mentioned liquid crystal filling method), and in n62-89〇25 (published ^ related patents), when the substrates are overlapped with each other, and the gap is filled with liquid At any time, the liquid crystals 5 dropped on the substrate are distributed concentrically with the dropping point as the center, as shown in FIGS. 3A to 3B to 3C to 3D. Every _ times, the substrate pair 1 iodine 1] The interval between the three becomes narrower until the predetermined interval controlled by the spacer 4. As described above, the liquid crystal 5 is centered on the dropping point and is distributed in a concentric circle (shown by a dashed line ^ bu as shown in _4A '). Therefore 'When the LCD 5 does not completely fill the LCD display
87519.DOC 1244565 示詻面板9,且基板ia與a間十 曰+ 間 < 間隙未達到預先決定間隙時 、::了邵:12,其中液晶5與密封材料7接觸。當液晶5填入 液印頭示咨面板9之整個矣^ ^ i调表面,如圖4B所示,最後,基板la 與輯間之間隙變為更有,且因此密封材料7之寬度變為更 見。於此情形’密封材料7碰撞液晶5與基板化料接觸之 P刀(見圖4B《°卩刀U),其產生—缺點,使得此部分之密 封材料7與基板間之結合強度變為較低。 此外,為避免由於密封材料7造成之液晶污染,於上述公 開木1或3知不 < 方法,於液晶與密封材料接觸前,採用將 框架狀牆8置於密封材料内與液晶顯示器區域外,且將未 硬化之密封材料與液晶或硬化之密封材料分離之步驟。然 而於、.工由使用液晶滴入填滿方法製造液晶顯示器面板之 情形,液晶乃定量地滴人,使得基板對間之間隙達到由間 隔物所控制之預先決定間隙,即,#滴人液晶分佈於液晶 顯示器面板整個表面時,間隔與牆8具相同高度。因此,於 基板對la與lb彼此重疊之前與之後,如圖5所示,液晶5較 牆8高(h<H),使得基板1&不黏附至牆8。因此,液晶5由牆 8與相對基板lb間之間隙溢出,使得未硬化密封材料7與液 晶5於接觸部分12接觸。此將產生由於液晶污染造成之顯示 器故障。 本發明之一目的在於提供一液晶顯示器面板,其設計為 克服先前技藝之上述缺點。 本發明之另一目的在於提供一液晶顯示器面板,其使用 液晶滴入填滿方法製造,且設計為防止密封材料與基板間87519.DOC 1244565 When panel 9 is displayed, and the substrate ia and a are between ten and +, and the gap does not reach the predetermined gap. ::: Shao: 12, where liquid crystal 5 is in contact with sealing material 7. When the liquid crystal 5 is filled into the entire surface of the liquid crystal display panel 9 as shown in FIG. 4B, finally, the gap between the substrate 1a and the substrate becomes more, and therefore the width of the sealing material 7 becomes See you more. In this case, the sealing material 7 hits the P-knife of the liquid crystal 5 in contact with the substrate material (see FIG. 4B "° 卩 刀 U"), which results in a shortcoming, which makes the bonding strength between the sealing material 7 and the substrate in this part become weaker. low. In addition, in order to avoid liquid crystal contamination caused by the sealing material 7, in the above-mentioned publication 1 or 3 < method, before the liquid crystal contacts the sealing material, the frame-shaped wall 8 is placed inside the sealing material and outside the liquid crystal display area. And the step of separating the unhardened sealing material from the liquid crystal or hardened sealing material. However, in the case where the LCD panel is manufactured using the liquid crystal drop-in filling method, the liquid crystal is dripped quantitatively, so that the gap between the pair of substrates reaches a predetermined gap controlled by the spacer, that is, # 滴 人 LCD When distributed over the entire surface of the LCD panel, the interval is the same height as the wall 8. Therefore, before and after the substrate pair la and lb overlap each other, as shown in FIG. 5, the liquid crystal 5 is higher than the wall 8 (h < H), so that the substrate 1 & does not adhere to the wall 8. Therefore, the liquid crystal 5 overflows from the gap between the wall 8 and the opposite substrate 1b, so that the unhardened sealing material 7 and the liquid crystal 5 are in contact with the contact portion 12. This will cause the display to malfunction due to LCD contamination. It is an object of the present invention to provide a liquid crystal display panel, which is designed to overcome the above disadvantages of the prior art. Another object of the present invention is to provide a liquid crystal display panel, which is manufactured using a liquid crystal drop-in filling method and is designed to prevent a gap between a sealing material and a substrate.
87519.DOC -11- 1244565 強度 < 不足,及由於密封材料與基板表面一旦接觸 產生之密封材料退化形式,以防止顯示器故障之產生。 、、曰嗌月之另目的在於提供一液晶顯示器裝置,其使用 、、、曰曰商人填滿方去製造,且藉由控制滴人液晶之流體化, 防止由於硬晶與黏貼基板對之密封材料接觸造成之液晶污 染0 万、貝仃上逑目的,根據本發明之一型態,該液晶顯示器 面板力包含-對基板,於其中放置液晶,由密封材料形成之 框架狀被封邵分,及位於密封部分内侧之牆(流體控制牆) 。較佳地為將流體控制冑置於靠近液晶滴入點。 藉由將泥體控制牆靠近液晶滴入點放置,於塗覆液晶後 之黏貼過私’可控制以滴入點為中心之液晶同心圓狀分佈 ’使彳于液晶得以矩形而非圓形分佈。此得以提高液晶之填 入係數’並控制當液晶與密封部分接觸之時間實質上固定 ’直到基板對間之間隙接近由間隔物所控制之預先決定單 元間隔’而不取決於密封部分與液晶滴入點間之距離。結 果’可防止密封部分之退化形式與結合強度之變化。 較佳地’位於基板之牆可藉由塗覆或印刷感光樹脂或陶 资於基板之一或兩者,並施加微影照相於印刷之基板,或 直接塗覆或印刷此類材料而形成。 根據本發明之另一型態,該液晶顯示器面板包含一對基 板’於其中放置液晶,於基板對上由密封材料形成之一框 架狀密封部分,及流體控制牆,且流體控制牆以三層或更 多層框架狀方式放置,或以三層或更多層實質上框架狀, 87519.DOC -12- 1244565 並具部分間隙於其中之方式放置。 藉:將流體控制牆以三層或更多層框架狀或實質上框架 ί放置’於塗覆液晶後之黏貼基板過程,碰撞—流體 控制牆之液晶,可於、、云蹄祕 ^ k制牆與相鄰牆間之間隙, 一固定時間間隔。此使並得 了 〜 便,、侍以防止由未硬化密封材料造成 (液晶>了染。輕#从 分· L、丄、 、 — 依上述形成之流體控制牆位於密封 部分與顯示器區域間, 、 以規律間隙,或以所謂迷宮結構 形成。 根據本發明之另-型態,該液晶顯示器面板包含-對基 板丄其放置液晶,於基板對上由密封材料形成之-框架 、、刀非近液晶滴入點放置之一框架狀流體控制牆 ,其位於密封部分内側,且介於密封部分與顯示器區域間。 、、^ I塗覆液晶後之黏貼過程,將流體控制牆靠近 液曰曰滴入4放置,位於密封部分内側,且位於液晶顯示器 區域外側’ #近液晶滴人點放置之流體控制牆,得以控制 以滴入點為中心《液晶同心圓狀分佈,並將液晶之分佈形 式由《改變為矩形。此得以提高液晶之填人係數,並阻 止液Η曰舁仅於密封部分内側,液晶顯示器區域外側之框架 狀流體控制牆接觸,直到基板對間之間隙接近由間隔物所 控制之預先決定單元間隔。結果’位於密封部分内側之框 采狀或/、貝上框架狀之流體控制牆,用以阻止液晶之流體 化一袄固疋時間,從而阻止由於未硬化密封部分造成之液 不口而命’本發明不限於上述組成或下列提及之具體實87519.DOC -11- 1244565 Insufficient strength < and the deterioration of the sealing material due to the contact between the sealing material and the substrate surface to prevent display failure. Another purpose of, 嗌, and 嗌 is to provide a liquid crystal display device, which is manufactured by using 方, 曰, and 商人 merchants to fill the squares, and by controlling the fluidization of the liquid crystal to prevent people from sealing due to the hard crystal and the adhesive substrate Liquid crystal contamination caused by material contact is 10,000 yuan, and the purpose of the present invention is, according to one aspect of the present invention, the liquid crystal display panel includes a pair of substrates, in which liquid crystals are placed, and a frame-like sealant formed of a sealing material. And the wall (fluid control wall) located inside the sealed part. It is preferred to place the fluid-controlled chirp near the drip point of the liquid crystal. By placing the mud control wall close to the drop point of the liquid crystal, the adhesiveness after coating the liquid crystal can be controlled to "control the concentric circular distribution of the liquid crystal with the drop point as the center" so that the liquid crystal can be distributed in a rectangular shape instead of a circular shape. . This can increase the filling factor of the liquid crystal 'and control the time when the liquid crystal contacts the sealing portion is substantially fixed' until the gap between the substrate pair approaches the predetermined cell interval controlled by the spacer 'without depending on the sealing portion and the liquid crystal drop Distance between entry points. As a result, the deterioration of the sealing portion and the change in the bonding strength can be prevented. Preferably, the wall located on the substrate can be formed by coating or printing one or both of a photosensitive resin or ceramics, and applying a photolithography to the printed substrate, or directly coating or printing such a material. According to another aspect of the present invention, the liquid crystal display panel includes a pair of substrates in which liquid crystals are placed, a frame-shaped sealing portion formed of a sealing material on the substrate pair, and a fluid control wall, and the fluid control wall includes three layers. Or more than three layers of frame-like way, or three or more layers of substantially frame-like way, 87519.DOC -12- 1244565 with some gaps in it. By: Placing the fluid control wall in three or more layers in a frame-like or substantially frame structure during the process of sticking the substrate after coating the liquid crystal. Collision—The liquid crystal of the fluid control wall can be made by The gap between a wall and an adjacent wall is a fixed time interval. This makes it easy to prevent the un-hardened sealing material (liquid crystal) from being stained. Light # 从 分 · L, 丄,, — The fluid control wall formed as described above is located between the sealing portion and the display area, According to another aspect of the present invention, the liquid crystal display panel includes a pair of substrates, where the liquid crystal is placed, and a frame formed by a sealing material on the substrate pair. A frame-shaped fluid control wall is placed at the liquid crystal dropping point, which is located inside the sealing portion and is between the sealing portion and the display area. The adhesion process after the liquid crystal is applied brings the fluid control wall close to the liquid drop. The liquid control wall placed near the liquid crystal drop point can be controlled with the drop point as the center, and the liquid crystal distribution form is changed from "Change to rectangle. This can increase the fill factor of the liquid crystal, and prevent the flow of the liquid only on the inside of the sealing part and outside the liquid crystal display area. Control the wall contact until the gap between the pair of substrates approaches the predetermined cell interval controlled by the spacer. As a result, the frame-like or / or frame-shaped fluid control wall located inside the sealed portion is used to stop the liquid crystal fluid Reduce the solidification time, thereby preventing the liquidity caused by the unhardened sealing portion. The present invention is not limited to the above-mentioned composition or the specific embodiments mentioned below.
87519.DOC -13- 1244565 施例,且可於不背離本發明精神下,改變為各種形式。 【實施方式】 此後,將參照所附圖式詳細描述液晶顯示器面板之具體 實施例。圖6A至6C為示範圖式,顯示根據本發明第一具體 實施例之液晶顯示器面板。圖6 A為一透視圖式,顯示一大 型TFT基板1,由其切割為四個面板。圖6B為一放大平面圖 式,顯示圖6A所示之一液晶顯示器面板。圖6C為沿圖6B A 至A直線切割截面。 圖6A顯示四個液晶顯示器面板9中每個之位置關係,每 個面板之顯示器區域2,每個面板之密封材料7,及每個面 板之流體控制牆3。如圖6C所示,每個面板9包含TFT基板 la與CF基板lb,及液晶5於其中之組合。於顯示器區域2, 形成控制基板對la與lb間之間隙之間隔物4,及三層框架狀 流體控制牆3。於牆3外部周圍,附著以框架狀方式形成之 密封材料7。於最外部周圍形成之密封材料7用以黏貼大型 基板1。 此具體實施例之特徵為使用大型基板1,其包含預先形 成之流體控制牆3,以控制於TFT基板或CF基板顯示器區 域内側或/及外側之液晶5流速,於TFT基板或CF基板中形 成一透明電極與驅動液晶5所需之TFT電路。於使用液晶滴 入填滿方法製造液晶顯示器9之情形,液晶滴於切割成為 TFT基板之任一大型基板上,及切割成為CF基板之另一基 板上。於此具體實施例,液晶5滴於成為TFT基板之大型基 板1。接著,另一大型基板(成為CF基板)於減壓下黏貼於先 87519.DOC -14- !244565 】大土基板。此過程得以同時將液晶5填滿大型基板整個表 面,並組合液晶顯示器面板9。 、、使彼此重宜之兩大型基板間之間隙(稱為單元間隙), ,到由間隔物4所控制之預先決定大小,並將液晶$填入液 晶顯示器區域2之過程,液晶乃以滴人點為中心,同心圓狀 也刀佈如圖3所不。因此,於將液晶填入單元間隙之過程 ,,於部分12,密封部分7與液晶5接觸。於此情形,因基板 對間之間隙未料預先決定㈣,隨著填人繼續時,滴入 之液晶5分佈於顯示器面板9整個表面。最後,兩基板間之 間隙更+,如圖4B所示,使得密封材料7之寬度更寬。 於此情形,密封材料碰撞液晶5與兩基板接觸之部分(見 圖4B之部分丨1)。此產生降低密封材料7與兩基板此部分11 間結合強度 < 缺點。因此,需使用具有流體控制牆3形成於 側或兩側之基板1,藉由控制液晶5流體之同心圓狀分佈 ,以避免填入液晶,直到兩基板間之間隙達到由間隔物4 所控制之預先決定間隙時,密封材料7與液晶5間之接觸。 接著,將參照圖7A至7D描述流體控制牆3之製造。圖7A 至7D為示範圖式,說明製造流體控制牆之過程。於圖7a至 7D,首先,感光樹脂20藉由旋塗方法,狹缝塗覆方法,或 印刷方法塗覆於基板丨上,使得樹脂丨可具一預先決定厚度 (見圖7A)。接著,使用光罩21,使得流體控制牆3可中凸地 出現於基板1上。藉由光罩21,感光樹脂2〇藉由使用曝光源 22曝光(見圖7B)。之後,實施塗覆基板之顯影,並移除塗 覆於未形成流體控制牆3部分之感光樹脂2〇之過程(見圖87519.DOC -13- 1244565 embodiments, and can be changed into various forms without departing from the spirit of the invention. [Embodiment] Hereinafter, specific embodiments of the liquid crystal display panel will be described in detail with reference to the drawings. 6A to 6C are exemplary diagrams showing a liquid crystal display panel according to a first embodiment of the present invention. Fig. 6A is a perspective view showing a large TFT substrate 1, which is cut into four panels. Fig. 6B is an enlarged plan view showing a liquid crystal display panel shown in Fig. 6A. FIG. 6C is a cross-sectional view taken along a line A to A in FIG. 6B. Fig. 6A shows the positional relationship of each of the four liquid crystal display panels 9, the display area 2 of each panel, the sealing material 7 of each panel, and the fluid control wall 3 of each panel. As shown in FIG. 6C, each panel 9 includes a combination of a TFT substrate la and a CF substrate 1b, and a liquid crystal 5 therein. In the display area 2, a spacer 4 forming a gap between the control substrate pair la and lb, and a three-layer frame-like fluid control wall 3 are formed. Around the outside of the wall 3, a frame-like sealing material 7 is attached. A sealing material 7 formed around the outermost portion is used to adhere the large substrate 1. This specific embodiment is characterized in that a large substrate 1 is used, which includes a pre-formed fluid control wall 3 to control the flow rate of the liquid crystal 5 inside or / and outside the display area of the TFT substrate or CF substrate, and is formed in the TFT substrate or CF substrate. A transparent electrode and a TFT circuit required to drive the liquid crystal 5. In the case where the liquid crystal display 9 is manufactured using the liquid crystal dropping and filling method, the liquid crystal is dropped on any large substrate cut into a TFT substrate and another substrate cut into a CF substrate. In this specific embodiment, the liquid crystal 5 is dropped on a large substrate 1 which becomes a TFT substrate. Then, another large substrate (becoming a CF substrate) was adhered to a large soil substrate under reduced pressure. This process can simultaneously fill the entire surface of the large substrate with the liquid crystal 5 and combine the liquid crystal display panel 9. The process of making the gap between two large substrates (referred to as the cell gap) that is suitable for each other to the predetermined size controlled by the spacer 4 and filling the liquid crystal $ into the liquid crystal display area 2, the liquid crystal is dripped The human point is the center, and the concentric circle is also shown in Figure 3. Therefore, in the process of filling the liquid crystal into the cell gap, at the portion 12, the sealing portion 7 is in contact with the liquid crystal 5. In this case, the gap between the substrate pairs is not determined in advance. As the filling process continues, the dropped liquid crystals 5 are distributed over the entire surface of the display panel 9. Finally, the gap between the two substrates is more positive, as shown in FIG. 4B, making the width of the sealing material 7 wider. In this case, the sealing material hits a portion where the liquid crystal 5 is in contact with the two substrates (see part 1 in FIG. 4B). This causes a decrease in the bonding strength between the sealing material 7 and this portion 11 of both substrates < disadvantages. Therefore, it is necessary to use a substrate 1 with a fluid control wall 3 formed on one or both sides, and control the concentric circular distribution of the liquid crystal 5 fluid to avoid filling the liquid crystal until the gap between the two substrates is controlled by the spacer 4 When the gap is determined in advance, the contact between the sealing material 7 and the liquid crystal 5 is made. Next, the manufacture of the fluid control wall 3 will be described with reference to FIGS. 7A to 7D. 7A to 7D are exemplary diagrams illustrating a process of manufacturing a fluid control wall. In FIGS. 7a to 7D, first, the photosensitive resin 20 is coated on the substrate 丨 by a spin coating method, a slit coating method, or a printing method so that the resin 丨 can have a predetermined thickness (see FIG. 7A). Next, the photomask 21 is used so that the fluid control wall 3 can be convexly projected on the substrate 1. With the photomask 21, the photosensitive resin 20 is exposed by using an exposure source 22 (see FIG. 7B). After that, the development of the coated substrate is performed, and the process of removing the photosensitive resin 20 coated on the part where the fluid control wall 3 is not formed is performed (see the figure).
87519.DOC -15- 1244565 ^)。最後,洗去黏附至基板之顯影劑,並烘乾基板i。接 著,流體控制牆3中凸地完成於基板1上。 或者,提出一種藉由使用印刷方法或分配方法,將感光 樹脂3或熱固樹脂直接塗覆於基板上之方法,使得流體控制 舨可中凸地开^成,且接著貫施預先決定之處理,以使凸面 部分硬化。 接著,將參照圖8八至81)與9八及卯,描述由此具體實施 例之基板製造液晶顯示器面板之情形中,流體控制牆3之 效應。圖8A至8D為解釋本發明第一具體實施例之流體控制 瓜效應之圖式。於圖8A至8D上方,顯示平面圖式。於其下 万,顯示沿平面圖式A-A直線之截面。此外,圖9八與叩為 解釋本發明第一具體實施例之流體控制牆效應之圖式。於 圖9A與9B上方,顯示平面圖式。於其下方,顯示沿平面圖 式A-A直線之截面。 於具有流體控制牆3形成於其上之一大型基板丨,密封材 料7塗覆於液晶顯示器面板外側,且間隔物4放置於基板i 上。獪封材料7用於結合兩基板並防止液晶材料之洩漏。間 隔物4用以於組合液晶顯示器面板時,使基板間之間隔固定 。接著,液晶5滴於大型基板之一(此處,其對應於以數字 la表示之TFT基板)。滴入液晶5之總量,與兩基板内側及 密封材料7所定義之空間體積相等。較佳地,液晶5之總量 分為數滴。液晶可滴於任一具有流體控制牆3形成於其上之 基板,及不具流體控制牆3之另一基板。 接著,於減壓下,滴入液晶5之基板la完全地與另一基板87519.DOC -15-1244565 ^). Finally, the developer adhered to the substrate is washed away, and the substrate i is dried. Next, the fluid control wall 3 is convexly completed on the substrate 1. Alternatively, a method of directly coating the photosensitive resin 3 or the thermosetting resin on the substrate by using a printing method or a dispensing method is proposed, so that the fluid control can be formed convexly, and then a predetermined treatment is continuously performed. To harden the convex part. Next, the effects of the fluid control wall 3 in the case where a liquid crystal display panel is manufactured by the substrate of this specific embodiment will be described with reference to FIGS. 8A to 8D are diagrams explaining the fluid control effect of the first embodiment of the present invention. Above FIGS. 8A to 8D, plan views are shown. Below it, a cross section along the line A-A of the plan is shown. In addition, FIGS. 9A and 9B are diagrams for explaining a fluid control wall effect of the first embodiment of the present invention. Above FIGS. 9A and 9B, a plan view is shown. Below it, a cross section along line A-A of the plan view is displayed. On a large substrate with a fluid control wall 3 formed thereon, a sealing material 7 is coated on the outside of the liquid crystal display panel, and a spacer 4 is placed on the substrate i. The sealing material 7 is used to bond the two substrates and prevent leakage of the liquid crystal material. The spacer 4 is used to fix the interval between the substrates when the liquid crystal display panel is assembled. Next, the liquid crystal 5 is dropped on one of the large substrates (here, it corresponds to a TFT substrate indicated by the number la). The total amount of the liquid crystal 5 dropped is equal to the volume of the space defined by the inside of the two substrates and the sealing material 7. Preferably, the total amount of the liquid crystal 5 is divided into several drops. The liquid crystal can be dropped on any substrate having the fluid control wall 3 formed thereon, and another substrate without the fluid control wall 3. Next, under reduced pressure, the substrate la of the liquid crystal 5 is dropped completely with another substrate
87519.DOC -16 - Ϊ244565 1/重璺(見圖8A)。可於重疊之基板與a加壓。當基板h -、另一基板lb重疊時,液晶5可能以同心圓狀分佈(見圖8B) <、、’:而,机fa控制牆3用以作為液晶流動之阻力,且因此形 成牆邵分又流速,較無牆形成之其他部分慢。因此,藉由 以液晶滴入點為中心,放置流體控制牆3,液晶5以矩形狀 而非同心圓狀分佈(見圖8C與8D)。 流體控制牆3之提供,乃用以避免由於直接將液晶5分佈 於液晶顯示器面板9,直到兩基板。與_之間隙達到由 間隔物4所控制之預先決定單位間隔,所造成之液晶5與密 封材料7間之接觸。此得以使密封材料7碰撞基板^與⑽ 硬晶5接觸部分之量,減至最少,其解決密封材料7與兩基 板1 a與1 b間結合強度降低之問題。 f述描述乃關於滴入液晶之基板la上之密封材料7塗覆 。密封材料7可塗覆於相反基板lb。或者,密封材料7可塗 覆於兩基板。此外,上述描述亦關於液晶滴入之基板上之 間隔物4塗覆。間隔物4可塗覆於相反基板ib或兩基板上績 lb上。間隔物可為圓形狀或圓柱狀。如同流體控制牆,間 隔物可藉由使用感光樹脂等,預先形成於基板上。 如圖6八至6〇:與8八至81)所示,流體控制牆3可放置為控制 僅靠近密封材料7周圍之液晶5流體,或控制滴入液晶:周 園流體(圖9A與9B每個顯示器面板四側),如圖9八與卯所示 、,=描緣本發明之第二具體實施例。此外,上述描述乃: 於藉由流體控制牆3效應之液晶5矩形(或方形)分佈。根據 此具體實施例,放置流體控制牆3之目的在於控制液晶=87519.DOC -16-Ϊ 244565 1 / weight 璺 (see Figure 8A). Can be pressed on the overlapping substrate and a. When the substrate h − and the other substrate lb overlap, the liquid crystals 5 may be distributed in a concentric circle shape (see FIG. 8B), and the machine fa control wall 3 is used as a resistance to the liquid crystal flow, and thus forms a wall Shao Fen has a slower flow rate than other parts without walls. Therefore, by placing the fluid control wall 3 with the liquid crystal dropping point as the center, the liquid crystals 5 are distributed in a rectangular shape instead of a concentric circle shape (see FIGS. 8C and 8D). The fluid control wall 3 is provided to avoid direct distribution of the liquid crystal 5 on the liquid crystal display panel 9 up to the two substrates. The gap with _ reaches a predetermined unit interval controlled by the spacer 4, resulting in contact between the liquid crystal 5 and the sealing material 7. This makes it possible to minimize the amount of the sealing material 7 colliding with the substrate ^ and the hard-crystal 5 contact portion, which solves the problem of a decrease in the bonding strength between the sealing material 7 and the two substrates 1 a and 1 b. The description is about the application of the sealing material 7 dripped onto the substrate la of the liquid crystal. The sealing material 7 may be applied to the opposite substrate lb. Alternatively, the sealing material 7 may be coated on both substrates. In addition, the above description also concerns the coating of the spacer 4 on the substrate into which the liquid crystal is dropped. The spacer 4 may be coated on the opposite substrate ib or on the two substrates lb. The spacer may be circular or cylindrical. Like the fluid control wall, the spacer can be formed on the substrate in advance by using a photosensitive resin or the like. As shown in Fig. 6-8 to 60: and 88-81), the fluid control wall 3 can be placed to control the liquid crystal 5 fluid only near the sealing material 7, or to control the dripping of liquid crystal: Zhouyuan fluid (Figs. 9A and 9B Four sides of each display panel), as shown in Fig. 9 and Fig. 9, = depicts a second embodiment of the present invention. In addition, the above description is: the rectangular (or square) distribution of the liquid crystals 5 by the fluid control wall 3 effect. According to this specific embodiment, the purpose of placing the fluid control wall 3 is to control the liquid crystal =
87519.DOC -17- 1244565 流體:並防止密封材科7與液晶5間之接觸,直到兩基板間 1隔達到由間隔物4所指定之預先決定間隔。因此,流體 》制4 3《位置’不需使液晶5之分佈形式為矩形。僅需將 流體控制牆3放置為由密封材料設置形式所塑造。 圖l〇A至H)E為解釋流體控制牆位置之截面。若牆放置為 ::控制液晶之流體,流體控制牆3之高度hl可調整為與 早位間隔h高度相等,於液晶顯示器面板如圖10A所示組合 '此外力圖刚所不,高度hl可調整為低於單位間隔匕 。再者,流體控制牆3可形成於兩基板。㈣上。於一基板 la形成之流體控制牆3,於位置上可與形成於另一基㈣ 上<相配’如圖1()c所示重疊。或者,前者牆3位置可與後 者牆3不相配’即,牆3可安排為迷宮結構。流體控制牆3 之问度可與單兀間隔h之高度相等,於基板如圖_所示組 合後,或之後可低於單元間隔h之高度,如圖1〇E所示。、’ 圖11A至11D為示範圖 <,顯示流體控制牆之示範形式。 泥體控制牆3可由圖10A所示之棱柱狀牆,如圖11B所示之 圓柱狀牆或圓錐狀牆之緊密安排,或如圖uc所示,具有 間隔於其中之圓柱狀牆或圓錐狀牆安排所構成。於此情形 ,圓柱狀或圓錐狀流體控制牆之組合,可以規律或不規律 間隔安排。不言而喻,流體控制牆3可提供與間隔物相同之 功能’當組合基板時,使兩基板間之間隔固定。 圖丨2為一概念圖式,解釋液晶之流體化。圖13與14為概 念圖式,解釋流體控制牆之效應。圖15為一示範圖式,孽 不泥體控制牆之位置。滴入液晶之流速可根據,例如由於87519.DOC -17- 1244565 Fluid: and prevent the contact between the sealing material section 7 and the liquid crystal 5 until the interval between the two substrates reaches a predetermined interval specified by the spacer 4. Therefore, it is not necessary to make the distribution form of the liquid crystal 5 rectangular. It is only necessary to place the fluid control wall 3 in the form of a sealing material setting. 10A to 10E are cross sections explaining the position of the fluid control wall. If the wall is placed to control the liquid of the liquid crystal, the height hl of the fluid control wall 3 can be adjusted to be equal to the height of the early interval h. The LCD panel is combined as shown in FIG. 10A. In addition, the height hl can be adjusted. Dagger below unit interval. Furthermore, the fluid control wall 3 may be formed on two substrates. ㈣ 上。 The fluid control wall 3 formed on one substrate la can overlap in position with a < matching ' formed on another substrate, as shown in Fig. 1 (c). Alternatively, the position of the former wall 3 may not match the latter's wall, that is, the wall 3 may be arranged as a labyrinth structure. The resolution of the fluid control wall 3 may be equal to the height of the unit interval h, and after the combination of the substrates as shown in Figure _, or afterwards, it may be lower than the height of the unit interval h, as shown in Figure 10E. 11 'to 11D are exemplary diagrams < showing exemplary forms of the fluid control wall. The mud control wall 3 may be a close arrangement of a prismatic wall as shown in FIG. 10A, a cylindrical wall or a conical wall as shown in FIG. 11B, or a cylindrical wall or a conical shape as shown in FIG. Wall arrangement. In this case, the combination of cylindrical or conical fluid control walls can be arranged at regular or irregular intervals. It goes without saying that the fluid control wall 3 can provide the same function as the spacer ', when the substrates are combined, the interval between the two substrates is fixed. Figure 2 is a conceptual diagram explaining the fluidization of liquid crystals. Figures 13 and 14 are conceptual diagrams explaining the effects of a fluid control wall. Fig. 15 is an exemplary diagram showing the location of the Ninmumu control wall. The flow rate of the liquid crystal can be determined according to, for example,
87519.DOC -18- 1244565 TFT基板與液晶5接觸之連接步驟,CF基板之圖案,方位薄 月吴 < 印刷狀態,研磨狀態等條件,造成之滴入方向差異而 ’又化。圖12顯示γ方向流速較χ方向快,且滴入之液晶根據 上述條件以橢圓狀分佈之情形。若χ方向流速與丫方向流速 不同,控制液晶流速之液晶流體控制,87519.DOC -18- 1244565 The steps of connecting the TFT substrate to the liquid crystal 5; the pattern of the CF substrate, the orientation is thin; and the conditions such as the printing state and the grinding state cause the drop direction to be different. Fig. 12 shows a case where the flow velocity in the? Direction is faster than that in the? Direction, and the dropped liquid crystals are distributed in an elliptical shape according to the above conditions. If the velocity in the χ direction is different from the velocity in the Y direction, the liquid crystal fluid control that controls the liquid crystal velocity,
方,Υ方向之牆位置不同,即,於較快:::放X ^此得以增加流體阻力並因此較易控制流體。 圖顯示液晶流體控制牆3之位置,僅控制靠近密封部分 周圍《硬晶5流體(其表示於顯示器面板中心無流體控制) 圖夜晶流體控制牆3之位置,以控制滴於基板之周 顧=5流體(圖14之四側)。在液晶流體控制牆地於液晶 PXFI安面板《頭不态區域情形,較佳地將這些牆3置於圖素 ΡΧ圖案間,如圖15所千 之數 ,、。通吊,此目的乃為防止液晶面板 於^辛門徑門此外,需使位於圖素圖案間之每個牆3寬度小 =Γ。圖16為-示範圖式,顯示液晶流體控制 、人你I χ佳地,牆3之寬度需於10至50微米範圍。 生:=晶Γ填滿方法製造顯示器面板之情形,亦產 封材料接觸而“於=材料完全硬化前’液晶由於與密 於未硬化f日丨> /衣可能產生顯示器故障。為防止由 、禾更化夜日曰與密封材料 、、 液晶與密封材料之 染,最好防止 之框架狀牆所控二直到液晶流體由圍繞顯示器區域 17C描述本發明 在、封材料已硬化。將參照圖17A至 知月芡弟二具體實施例。 圖17A至17C為示範 β $,颂7F根據本發明第三具體實施The positions of the walls in the square and Υ directions are different, that is, faster: :: put X ^ This can increase the fluid resistance and therefore it is easier to control the fluid. The figure shows the position of the liquid crystal fluid control wall 3, and only controls the vicinity of the sealed part. "Hard crystal 5 fluid (which is shown in the center of the display panel without fluid control). Figure Yejing fluid control wall 3 position to control the drip of the substrate. = 5 fluids (four sides of Figure 14). In the case of the liquid crystal fluid control wall in the liquid crystal PXFI security panel "head stateless area, it is better to place these walls 3 between the pixel Pix patterns, as shown in Fig. 15. The purpose of hanging is to prevent the LCD panel from being closed. In addition, it is necessary to make the width of each wall 3 between the pixel patterns small = Γ. FIG. 16 is an exemplary diagram showing the liquid crystal fluid control, the best place for the wall, and the width of the wall 3 needs to be in the range of 10 to 50 microns. Health: = Crystal Γ filling method for the manufacture of display panels, but also produces sealing materials in contact with "before = material is completely hardened," the liquid crystal due to the close and unhardened f days 丨 > / clothing may cause display failure. In order to prevent It is better to prevent the contamination of the liquid crystal and the sealing material from the sealing material, and prevent the frame-like wall from being controlled until the liquid crystal fluid is surrounded by the display area 17C. The sealing material of the present invention has been hardened. 17A to 2nd embodiment of Zhiyue. Figures 17A to 17C are exemplary β $, and 7F is a third embodiment of the present invention.
87519.DOC -19- 1244565 例之液晶顯示器面板。圖17A為一透視圖式,顯示切割為 四個液晶顯示器面板之灯丁基板。圖17B為一放大平面圖式 ,顯示圖17A所示之一液晶顯示器面板。圖17C為圖nB沿 A-A直線切割之截面。圖17C顯示TF 丁基板la重疊於另一基 板上即,CF基板lb。圖1 8A至1 8C為示範圖式,顯示根據 本發明第三具體實施例之液晶顯示器面板之效應。圖18A 為一放大平面圖式,顯示圖17B所示之一液晶顯示器面板 。圖18B與18C為放大圖式,顯示圖18A之角落部分。於圖 ΠA至17C ’液晶滴入之基板以基板1表示。 於此具體實施例,如圖17A至17C所示,框架狀第一流體 控制牆3a,於塗覆為圍繞顯示器區域2之密封材料7内側, 與顯π器區域2外側形成。較佳地中凸地形成第一流體控 制牆3a,並不許第一流體控制牆3a與密封材料7接觸,但將 牆3a盡可能靠近密封材料7放置。此外,第二流體控制牆孙 位於第一流體控制牆3a内側,且第三流體控制牆3c位於第 二流體控制牆3b内侧。較佳地,牆“與补,或牆补與“間 <間隔需約為2.5釐米。當然,其他間隔可提供相同效應。 因此,間隔大小不限於此值。 第一流體控制牆3a以矩形狀形成,且不具狹缝。第二流 體控制牆3b於每側一半位置包含一狹缝。第三流體控制牆 3c於每個角落包含一狹缝。於此具體實施例,牆3&與几, 或牆3b與3c間之寬度為45微米,且狹缝為3〇微米。現在, 將描述使用液晶滴入填滿方法,由此具體實施例之基板製 造液晶顯示器面板之情形中,液晶之流體過程。 87519.DOC -20- 1244565 首先,實施滴入液晶5之過程,其對應於由兩基板内側與 密封材料7所定義間隔之體積。液晶5分為數次滴入。接著 ’於減壓下,滴入液晶5之基板la與另一基板lb重疊。於此 時,可施加壓力至兩基板,使得這些基板間之間隙,可達 到由間隔物4所控制之預先決定間隔h。於基板丨&與另一基 板113重@後,滴於基板ia之液晶5逐漸地分佈於基板整個表 面。於第一階段,分佈之液晶5到達第三流體控制牆3(見圖 18A)。 液晶5沿流體控制牆3c分佈且位於基板整個表面。接著, 液晶5由形成於每個角落之狹缝溢出,且接著分佈至基板丄 外部周圍。由第三流體控制牆3c角落形成之狹缝溢出之液 晶5,到達第二流體控制牆31^接著,其沿第二流體控制牆 3b分体,並到達面板外部周圍(見圖18B)。於第二流體控^ 牆3b,於每側中心形成狹縫。因此,液晶5由形成於第二流 體控制,313之狹缝流出,且接著進—步分佈至基板外部: 圍。由第二流體控制牆3b狹缝溢出之液晶5,到達第一流體 控制牆3a’且接著沿第—流體控制牆以分佈,並於面板= ,圖8C所不’當液晶足以填滿第一流體控制牆h内側 ’密封材料7便硬化。較佳地,用於液晶滴人填滿方法之密 封材科為紫外光反應類型,或紫外光及/或熱反應麵刑。為 於此時使密封材料7硬化’照射紫外光至 ::: =:封一5間之接觸…此防止由 印万木坆成又顯示器故障。因無狹缝形成於第一流體87519.DOC -19- 1244565 examples of liquid crystal display panels. Fig. 17A is a perspective view showing a lamp substrate cut into four liquid crystal display panels. FIG. 17B is an enlarged plan view showing a liquid crystal display panel shown in FIG. 17A. Fig. 17C is a cross section cut along the line A-A in Fig. NB. Fig. 17C shows that the TF substrate 1a is superposed on another substrate, that is, the CF substrate 1b. 18A to 18C are exemplary diagrams showing the effects of a liquid crystal display panel according to a third embodiment of the present invention. FIG. 18A is an enlarged plan view showing a liquid crystal display panel shown in FIG. 17B. 18B and 18C are enlarged views showing corner portions of FIG. 18A. The substrates in which the liquid crystal is dropped are shown as substrate 1 in FIGS. In this specific embodiment, as shown in FIGS. 17A to 17C, the frame-like first fluid control wall 3a is formed inside the sealing material 7 coated around the display area 2 and outside the display area 2. The first fluid control wall 3a is preferably formed convexly. The first fluid control wall 3a is not allowed to contact the sealing material 7, but the wall 3a is placed as close to the sealing material 7 as possible. In addition, the second fluid control wall 3a is located inside the first fluid control wall 3a, and the third fluid control wall 3c is located inside the second fluid control wall 3b. Preferably, the distance between the wall and the wall, or between the wall and the wall < is about 2.5 cm. Of course, other intervals can provide the same effect. Therefore, the interval size is not limited to this value. The first fluid control wall 3a is formed in a rectangular shape without a slit. The second fluid control wall 3b includes a slit at a half position on each side. The third fluid control wall 3c includes a slit in each corner. In this specific embodiment, the width between the walls 3 & or the walls 3b and 3c is 45 microns, and the slit is 30 microns. Now, a fluid process of liquid crystal in a case where a liquid crystal display panel is manufactured using a substrate of a specific embodiment using a liquid crystal dropping filling method will be described. 87519.DOC -20- 1244565 First, the process of dropping liquid crystal 5 is performed, which corresponds to the volume defined by the inside of the two substrates and the sealing material 7. The liquid crystal 5 is dropped in several times. Then, 'under a reduced pressure, the substrate 1a into which the liquid crystal 5 is dropped overlaps the other substrate 1b. At this time, pressure can be applied to the two substrates so that the gap between the substrates can reach a predetermined interval h controlled by the spacer 4. After the substrate 丨 & weighs another substrate 113, the liquid crystal 5 dripped on the substrate ia is gradually distributed over the entire surface of the substrate. In the first stage, the distributed liquid crystals 5 reach the third fluid control wall 3 (see FIG. 18A). The liquid crystals 5 are distributed along the fluid control wall 3c and are located on the entire surface of the substrate. Then, the liquid crystals 5 overflow from the slits formed in each corner, and then are distributed to the periphery of the substrate 丄. The liquid crystal 5 overflowing from the slit formed at the corner of the third fluid control wall 3c reaches the second fluid control wall 31 ^. Then, it splits along the second fluid control wall 3b and reaches the periphery of the panel (see FIG. 18B). A slit is formed in the center of each side of the second fluid control wall 3b. Therefore, the liquid crystal 5 is controlled by the second fluid, and the slit 313 flows out, and then is further distributed to the outside of the substrate. The liquid crystal 5 overflowing from the slit of the second fluid control wall 3b reaches the first fluid control wall 3a 'and then distributes along the first fluid control wall, and is distributed on the panel. The 'sealing material 7' inside the fluid control wall h is hardened. Preferably, the sealing material used in the liquid crystal drip filling method is a UV light reaction type, or a UV light and / or a thermal reaction torture. In order to harden the sealing material 7 'at this time, it is irradiated with ultraviolet light to ::: =: to seal the contact between 5 ... This prevents the display from being broken by the display and the display failure. No slits are formed in the first fluid
87519.DOC -21 - 1244565 控制牆3a,密封材料7與第一流體控制牆3a間無液晶填入。 然而,藉由加熱組合面板,主要目的用於硬化密封材料7 ,並穩定基板la與lb間之單位間隔,液晶5將擴張,使得基 板與第一流體控制牆3a間可形成一微小狹縫。液晶5由此狹 缝溢出,且接著填入密封材料7與第一流體控制牆3a間。 預先計算滴入之液晶5,以與兩基板la與lb間之間隙,及 密封材料7所定義之間隔體積相符。因此,當冷卻液晶顯示 器面板時,液晶完全填入兩基板間之間隙,使得液晶顯示 器面板可具預先決定單位間隔。 上述具體實施例具一結構,其中作為第二流體控制牆3 之間隙,液晶所溢出之一狹缝形成於每側中心。若可獲得 液晶之流體控制效應,於每側可形成兩個或多個狹缝。此 外,此具體實施例亦具一結構,其中第二流體控制牆3b之 狹缝位於每個框架側之中心,且第三流體控制牆3c之狹缝 位於每個框架側之角落。於適當處,第二流體控制牆3b之 狹缝位於每個框架側之角落,且第三流體控制牆3c之狹缝 位於每個框架側之中心。於上述具體實施例,因此,第二 流體控制牆3b之狹缝位置上由第三流體控制牆3c之狹缝偏 移。若可獲得液晶之流體控制效應,第二流體控制牆3b之 狹缝可與第三流體控制牆3c之相符。此外,雖然於上述具 體實施例提供三種流體控制牆3,可藉由更多種牆獲得相 同效應。 圖19為與圖18相似之平面圖式,描述根據本發明第四具 體實施例之液晶顯示器面板。於此具體實施例,如圖19所 87519.DOC -22- 1244565 丁 $成與弟_及弟二流體控制牆3 b與3 c之每個狹缝,相 對且罪近之另一流體控制牆3d。流體控制牆3d用以阻止液 晶由每個狹缝溢出。此流體控制牆34,具有防止液晶流動 由形成於第二與第三流體控制牆几與3c之狹缝溢出之功能 ,尤其,以滴入點為中心之同心圓狀分佈,並使液晶5之分 佈實質上與密封材料7之位置具相同形式。此具體實施例可 如同前述具體實施例提供相同效應。 圖20A與20B為示範圖式,顯示根據本發明第五具體實施 例之液晶顯示器面板。圖20A為與圖19相同之平面圖式。 圖20A為圖2〇A沿A_A直線之截面。如圖2〇a與20B所示,另 一流體控制牆3d位於靠近由虛圓所表示之液晶滴入點。此 外,框架狀牆3a,3b與3c位於密封材料7與顯示器區域2間 。位於靠近液晶滴入點之其他流體控制牆3d,用以防止以 滴入點為中心之液晶5同心圓狀分佈。根據此具體實施例, 如上述,液晶5之分佈形式並非圓形而為方形,由方形密封 材料7所塑造。此有效地提高液晶5之填入係數,且大大地 阻止液晶5,與位於密封材料7内側,及顯示器區域外侧之 框架狀牆8接觸,直到兩基板間之間隙靠近預先決定之單元 間隔。 如上所提出,根據本發明,流體控制輪位於靠近液晶滴 入』k用以PJL止液晶之流動,從而降低液晶之流速 。根據此原理’本發明得以控制以滴入點為中心之液晶同 心圓狀分佈,使得液晶之分怖形式並非圓开”而為由:: 密封材料所塑造之方形。此有效地提高液晶之填人係數:87519.DOC -21-1244565 Control wall 3a, no liquid crystal is filled between the sealing material 7 and the first fluid control wall 3a. However, by heating the composite panel, the main purpose is to harden the sealing material 7 and stabilize the unit interval between the substrates 1a and 1b. The liquid crystal 5 will expand, so that a tiny slit can be formed between the substrate and the first fluid control wall 3a. The liquid crystal 5 overflows from this slit, and then fills the space between the sealing material 7 and the first fluid control wall 3a. The dripped liquid crystal 5 is calculated in advance to match the gap between the two substrates 1a and 1b and the interval volume defined by the sealing material 7. Therefore, when the liquid crystal display panel is cooled, the liquid crystal completely fills the gap between the two substrates, so that the liquid crystal display panel can have a predetermined unit interval. The above specific embodiment has a structure in which as a gap of the second fluid control wall 3, a slit overflowed by the liquid crystal is formed at the center of each side. If the liquid control effect of the liquid crystal is obtained, two or more slits can be formed on each side. In addition, this embodiment also has a structure in which the slit of the second fluid control wall 3b is located at the center of each frame side, and the slit of the third fluid control wall 3c is located at the corner of each frame side. Where appropriate, the slit of the second fluid control wall 3b is located at a corner of each frame side, and the slit of the third fluid control wall 3c is located at the center of each frame side. In the above specific embodiment, therefore, the slit position of the second fluid control wall 3b is shifted by the slit of the third fluid control wall 3c. If the liquid control effect of the liquid crystal is obtained, the slit of the second fluid control wall 3b can be matched with the third fluid control wall 3c. In addition, although three fluid control walls 3 are provided in the above specific embodiment, the same effect can be obtained by more types of walls. FIG. 19 is a plan view similar to FIG. 18, and illustrates a liquid crystal display panel according to a fourth specific embodiment of the present invention. In this specific embodiment, as shown in Fig. 19, 87519.DOC -22-1244565 Ding Chengcheng and brother _ and brother two fluid control wall 3 b and 3 c each slit, opposite and close to another fluid control wall 3d. The fluid control wall 3d is used to prevent liquid crystals from overflowing through each slit. The fluid control wall 34 has a function of preventing liquid crystal flow from overflowing from the slits formed in the second and third fluid control walls 3c and 3c. In particular, the fluid control wall 34 is arranged in a concentric circle centered on the drip point, and the liquid crystal 5 The distribution has substantially the same form as the position of the sealing material 7. This specific embodiment can provide the same effect as the foregoing specific embodiment. 20A and 20B are exemplary diagrams showing a liquid crystal display panel according to a fifth embodiment of the present invention. FIG. 20A is a plan view similar to FIG. 19. FIG. 20A is a cross-section of FIG. 20A along the line A_A. As shown in FIGS. 20a and 20B, another fluid control wall 3d is located near a liquid crystal dropping point indicated by a virtual circle. In addition, the frame-like walls 3a, 3b and 3c are located between the sealing material 7 and the display area 2. The other fluid control wall 3d located near the dropping point of the liquid crystal is used to prevent the liquid crystals 5 centered around the dropping point from being distributed concentrically. According to this specific embodiment, as described above, the distribution form of the liquid crystals 5 is not circular but square, and is shaped by a square sealing material 7. This effectively increases the filling factor of the liquid crystal 5, and greatly prevents the liquid crystal 5 from coming into contact with the frame-like wall 8 located inside the sealing material 7 and outside the display area until the gap between the two substrates approaches the predetermined cell interval. As mentioned above, according to the present invention, the fluid control wheel is positioned close to the liquid crystal dripping to prevent the liquid crystal flow, thereby reducing the liquid crystal flow rate. According to this principle, the present invention can control the concentric circular distribution of liquid crystals centered on the dropping point, so that the distribution form of the liquid crystals is not circular. People coefficient:
87519.DOC -23- 1244565 時間實質上固定,與密封材科 ,直到兩基板間之間隙靠近由 元間隔。此效應阻止密封材科 並使液晶與密封邵分接觸之 及液晶滴入點間之距離無關 間隔物所控制之預先決定單 之形式故障與結合強度變化 此外,藉由於—對基板切成«狀㈣㈣,及三声 或更多層框架狀流體控制牆於密封材料側,於塗覆液晶; 足黏貼基板過程,可阻止由第一 吊 粘,皿出 <〉夜晶,於流體抑 制牆與相鄰流體控制牆間 > 門 , 鈿間弋間隔一固疋時間,從而防止液 晶文仍未硬化密封材料之污婆、 了衣並防止由液晶污染造成之 顯示器故障。 此外,流體控制牆位於靠近液晶滴入點,且其他框架狀 流體控制牆亦位於密封材料與顯示器區域間。位於 晶滴^點之流體㈣牆,心_以滴人點為中心之液晶 同心圓狀分佈,於塗覆潘曰你、 曰日後·^黏貼過程,且從而使液 之分佈形式不為圓形,而基山〜上 ' 為由始、封材料塑造之矩形(方形) 。此功能得以提高液晶之填入係數,並阻止液晶與位於矣 f才料㈣’及顯示器區域外側之框架狀牆接觸,直到: 基板間4間隙接近預先決定之 _ 又早位間隔。此得以提供高品 貝液晶顯示器面板,盆絲由户 — …、二由仏於岔封材料内側之框架狀流 體控制牆,安排為改進阻止洛日、云贿 木狀,礼 ’夜日曰、机隨一固定長度時間之效 應,/從而防止液晶由未硬化密封材料所污染,並防止由 於液晶污染造成之顯示器故障。 熟知此項技藝之人士需進一 + v瞭解,雖然上述說明乃為 本4明具體實施例,本發明 十%月不限於此,且可產生未背離本87519.DOC -23- 1244565 The time is substantially fixed, with the sealing material section, until the gap between the two substrates is close to the gap. This effect prevents the sealing material branch and makes the distance between the contact between the liquid crystal and the seal and the drop point of the liquid crystal independent of the predetermined form of the spacer controlled by the spacer and the change in bonding strength. In addition, because- ㈣㈣, and three or more layers of frame-like fluid control wall on the side of the sealing material, coated with liquid crystal; the process of sticking the substrate, can prevent the first hanging from sticking out, <> night crystal, the fluid suppression wall and Between the adjacent fluid control walls & doors, the door and the door are spaced for a fixed period of time to prevent liquid crystals from being stained by the sealing material, clothing, and display failures caused by liquid crystal contamination. In addition, the fluid control wall is located near the drop point of the liquid crystal, and other frame-shaped fluid control walls are also located between the sealing material and the display area. The wall of the fluid is located at the point of the crystal drop. The center of the liquid crystal is distributed in a concentric circle centered on the point of the drop. During the coating process, the paste process is applied, and the liquid distribution form is not circular. , And Jishan ~ Shang 'is a rectangle (square) shaped by the starting and sealing materials. This function can increase the fill factor of the liquid crystal and prevent the liquid crystal from contacting the frame-shaped wall located outside the display area and the display area until: the 4 gaps between the substrates are close to the predetermined _ and the early interval. This can provide a high-quality shell LCD display panel, pot wire from the house to the frame-shaped fluid control wall erected on the inside of the chasing material, arranged to improve the prevention of Luo Ri, cloud bribery, etiquette, night and day, The effect of the machine with a fixed length of time, thereby preventing the liquid crystal from being contaminated by the unhardened sealing material, and preventing the display from malfunctioning due to the liquid crystal contamination. Those who are familiar with this technique need to know more about + v. Although the above description is a specific example of the present invention, the present invention is not limited to this, and it may produce
87519.DOC -24- 1244565 發明精神與所附申請專利範圍範疇之各種改變與修改。 【圖式簡單說明】 圖1為一截面模式圖式,解釋一液晶顯示器面板之概要 結構, 圖2A至2E為概念圖式,解釋使用液晶滴入填滿方法製 造液晶顯不為面板之方法, 圖3 A至3 D為概念圖式,解釋於液晶滴入填滿方法之液 晶流體化; 圖4A與4B為概念圖式,解釋於液晶滴入填滿方法之液 晶流體化; 圖5為一概念圖式’解釋於液晶滴入填滿方法之液晶流 體化; 圖6A至6C為示範圖式,顯示根據本發明第一具體實施 例之液晶顯示器面板; 圖7A至7D為示範圖式,顯示製造流體控制牆之過程; 圖8A至8D為示範圖式,顯示流體控制牆於本發明第一 具體實施例之效應; 圖9A與9B為示範圖式,顯示流體控制牆於本發明第二 具體實施例之效應; 圖10A至10E為用以解釋流體控制牆位置之截面; 圖11A至11D為示範圖式,顯示流體控制牆之示範形式; 圖12為一概念圖式,解釋流體控制牆之效應; 圖13為一概念圖式,解釋流體控制牆之效應; 圖14為一概念圖式,解釋流體控制牆之效應; 87519.DOC -25- 1244565 圖15為一示範圖式,顯示流體控制牆之位置; 圖16為一示範圖式,顯示流體控制牆之寬度; 圖17A至17C為示範圖式,顯示根據本發明第三具體實施 例之液晶顯TF為·面板, 圖18A至18C為示範圖式,顯示根據本發明具體實施例 之液晶顯示器面板效應; 圖1 9為一平面圖式,解釋根據本發明第四具體實施例之 液晶顯示器面板;及 圖20A與20B為示範圖式,顯示根據本發明第五具體實 施例之液晶顯示器面板。 【圖式代表符號說明】 1 :大型基板 1 a ·薄〗旲電晶體基板 lb :彩色濾光器基板 2 :顯示器區域 3,3 a,3 b,3 c,3 d,8 :流體控制牆 4 :間隔物 5 ·液晶 7,70 :密封材料 9 ·液晶顯tf益面板 11,12 :接觸部分 1 8 :紫外光燈 20 :感光樹脂 21 :光罩 22 :曝光源 87519.DOC -26-87519.DOC -24-1244565 Various changes and modifications in the spirit of the invention and the scope of the attached patent application. [Schematic description] Figure 1 is a cross-sectional schematic diagram explaining the general structure of a liquid crystal display panel, and Figures 2A to 2E are conceptual diagrams explaining a method for manufacturing a liquid crystal display panel using a liquid crystal drop-in filling method. 3A to 3D are conceptual diagrams explaining liquid crystal fluidization by the liquid crystal dropping filling method; FIGS. 4A and 4B are conceptual diagrams explaining liquid crystal fluidization by the liquid crystal dropping filling method; FIG. 5 is a The concept diagram is explained in the liquidization of liquid crystals by the liquid crystal dripping and filling method; FIGS. 6A to 6C are exemplary diagrams showing a liquid crystal display panel according to a first embodiment of the present invention; and FIGS. 7A to 7D are exemplary diagrams showing The process of manufacturing a fluid control wall; Figures 8A to 8D are exemplary diagrams showing the effects of the fluid control wall in the first embodiment of the present invention; Figures 9A and 9B are exemplary diagrams showing the fluid control wall in the second embodiment of the present invention Effect of the embodiment; Figs. 10A to 10E are cross-sections for explaining the position of the fluid control wall; Figs. 11A to 11D are exemplary diagrams showing an exemplary form of the fluid control wall; Fig. 12 is a conceptual diagram explaining the fluid control wall Fig. 13 is a conceptual diagram explaining the effect of a fluid control wall; Fig. 14 is a conceptual diagram explaining the effect of a fluid control wall; 87519.DOC -25- 1244565 Fig. 15 is an exemplary diagram showing fluid control The position of the wall; Fig. 16 is an exemplary diagram showing the width of the fluid control wall; Figs. 17A to 17C are exemplary diagrams showing the liquid crystal display TF panel according to the third embodiment of the present invention; Figs. 18A to 18C are An exemplary diagram showing a liquid crystal display panel effect according to a specific embodiment of the present invention; FIG. 19 is a plan view explaining a liquid crystal display panel according to a fourth specific embodiment of the present invention; and FIGS. 20A and 20B are exemplary diagrams showing A liquid crystal display panel according to a fifth embodiment of the present invention. [Illustration of representative symbols of the drawings] 1: Large substrate 1 a · Thin 旲 Transistor substrate lb: Color filter substrate 2: Display area 3, 3 a, 3 b, 3 c, 3 d, 8: Fluid control wall 4: Spacer 5 · Liquid crystal 7, 70: Sealing material 9 · Liquid crystal display tf panel 11, 12: Contact part 1 8: Ultraviolet light 20: Photosensitive resin 21: Photomask 22: Exposure source 87519.DOC -26-
Claims (1)
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| JP2002042503 | 2002-02-20 | ||
| JP2003037747A JP2003315810A (en) | 2002-02-20 | 2003-02-17 | LCD panel |
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| TW200417772A TW200417772A (en) | 2004-09-16 |
| TWI244565B true TWI244565B (en) | 2005-12-01 |
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| TW92122637A TWI244565B (en) | 2002-02-20 | 2003-08-18 | Liquid crystal display panel with fluid control wall |
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| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP4480443B2 (en) | 2004-03-31 | 2010-06-16 | 富士通株式会社 | Liquid crystal display device and method of manufacturing liquid crystal display device |
| KR101080401B1 (en) * | 2004-04-23 | 2011-11-04 | 삼성전자주식회사 | Bonding structure of flat panel display, method of forming the same, and flat panel display comprising the same |
| US7505108B2 (en) | 2004-09-02 | 2009-03-17 | Nano Loa, Inc. | Liquid crystal material filling method and liquid crystal material filling apparatus |
| JP4372648B2 (en) | 2004-09-13 | 2009-11-25 | シャープ株式会社 | Liquid crystal display device and manufacturing method thereof |
| KR100836332B1 (en) | 2005-03-18 | 2008-06-09 | 샤프 가부시키가이샤 | Panel and method for manufacturing the same |
| JP4828259B2 (en) | 2006-03-03 | 2011-11-30 | 株式会社 日立ディスプレイズ | Manufacturing method of liquid crystal display device |
| US8629969B2 (en) | 2007-11-08 | 2014-01-14 | Gold Charm Limited | Liquid crystal display panel and method of manufacturing the liquid crystal display panel |
| JP5115311B2 (en) * | 2008-05-01 | 2013-01-09 | 富士通株式会社 | Liquid crystal display element |
| JP2010002687A (en) * | 2008-06-20 | 2010-01-07 | Konica Minolta Holdings Inc | Method for manufacturing display element, and display element |
| JP5247546B2 (en) * | 2009-03-16 | 2013-07-24 | 株式会社ジャパンディスプレイウェスト | Liquid crystal display |
| JP5865117B2 (en) * | 2012-02-24 | 2016-02-17 | 株式会社ジャパンディスプレイ | OPTICAL ELEMENT, DISPLAY DEVICE, ELECTRONIC DEVICE, AND MANUFACTURING METHOD |
| JP5942555B2 (en) | 2012-04-11 | 2016-06-29 | 三菱電機株式会社 | Manufacturing method of liquid crystal display device |
| JP2017116656A (en) | 2015-12-22 | 2017-06-29 | 株式会社ジャパンディスプレイ | Liquid crystal display |
| JP7400382B2 (en) * | 2019-11-19 | 2023-12-19 | セイコーエプソン株式会社 | Electro-optical devices and electronic equipment |
| CN117518624B (en) * | 2023-05-31 | 2025-05-30 | 武汉华星光电技术有限公司 | Polymer liquid crystal dimming box and preparation method thereof, and display module |
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2003
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| TW200417772A (en) | 2004-09-16 |
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