[go: up one dir, main page]

TW200813288A - Color-coated, fouling-resistant conductive clothes and manufacturing method thereof - Google Patents

Color-coated, fouling-resistant conductive clothes and manufacturing method thereof Download PDF

Info

Publication number
TW200813288A
TW200813288A TW95132884A TW95132884A TW200813288A TW 200813288 A TW200813288 A TW 200813288A TW 95132884 A TW95132884 A TW 95132884A TW 95132884 A TW95132884 A TW 95132884A TW 200813288 A TW200813288 A TW 200813288A
Authority
TW
Taiwan
Prior art keywords
conductive cloth
resin
coating
antifouling
fiber
Prior art date
Application number
TW95132884A
Other languages
English (en)
Other versions
TWI341889B (en
Inventor
Feng-Chang Chang
Hsin-Feng Cho
Jian-Wen Cheng
Original Assignee
Formosa Taffeta Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Formosa Taffeta Co Ltd filed Critical Formosa Taffeta Co Ltd
Priority to TW95132884A priority Critical patent/TWI341889B/zh
Priority to US11/850,728 priority patent/US8173555B2/en
Priority to JP2007231242A priority patent/JP5252863B2/ja
Publication of TW200813288A publication Critical patent/TW200813288A/zh
Application granted granted Critical
Publication of TWI341889B publication Critical patent/TWI341889B/zh

Links

Classifications

    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
    • D06N3/00—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof
    • D06N3/0056—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof characterised by the compounding ingredients of the macro-molecular coating
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
    • D06N7/00—Flexible sheet materials not otherwise provided for, e.g. textile threads, filaments, yarns or tow, glued on macromolecular material
    • D06N7/0094—Fibrous material being coated on one surface with at least one layer of an inorganic material and at least one layer of a macromolecular material
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
    • D06N2201/00—Chemical constitution of the fibres, threads or yarns
    • D06N2201/02—Synthetic macromolecular fibres
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
    • D06N2201/00—Chemical constitution of the fibres, threads or yarns
    • D06N2201/02—Synthetic macromolecular fibres
    • D06N2201/0245—Acrylic resin fibres
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
    • D06N2201/00—Chemical constitution of the fibres, threads or yarns
    • D06N2201/02—Synthetic macromolecular fibres
    • D06N2201/0263—Polyamide fibres
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
    • D06N2201/00—Chemical constitution of the fibres, threads or yarns
    • D06N2201/04—Vegetal fibres
    • D06N2201/042—Cellulose fibres, e.g. cotton
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
    • D06N2203/00—Macromolecular materials of the coating layers
    • D06N2203/04—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • D06N2203/041—Polyacrylic
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
    • D06N2203/00—Macromolecular materials of the coating layers
    • D06N2203/06—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • D06N2203/061—Polyesters
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
    • D06N2203/00—Macromolecular materials of the coating layers
    • D06N2203/06—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • D06N2203/066—Silicon polymers
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
    • D06N2203/00—Macromolecular materials of the coating layers
    • D06N2203/06—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • D06N2203/068—Polyurethanes
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
    • D06N2205/00—Condition, form or state of the materials
    • D06N2205/02—Dispersion
    • D06N2205/023—Emulsion, aqueous dispersion, latex
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
    • D06N2209/00—Properties of the materials
    • D06N2209/04—Properties of the materials having electrical or magnetic properties
    • D06N2209/041—Conductive
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
    • D06N2209/00—Properties of the materials
    • D06N2209/08—Properties of the materials having optical properties
    • D06N2209/0807—Coloured
    • D06N2209/083—Multi-coloured
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10S428/00—Stock material or miscellaneous articles
    • Y10S428/922—Static electricity metal bleed-off metallic stock
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00—Stock material or miscellaneous articles
    • Y10T428/24—Structurally defined web or sheet [e.g., overall dimension, etc.]
    • Y10T428/24355—Continuous and nonuniform or irregular surface on layer or component [e.g., roofing, etc.]
    • Y10T428/24372—Particulate matter
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00—Stock material or miscellaneous articles
    • Y10T428/24—Structurally defined web or sheet [e.g., overall dimension, etc.]
    • Y10T428/24355—Continuous and nonuniform or irregular surface on layer or component [e.g., roofing, etc.]
    • Y10T428/24372—Particulate matter
    • Y10T428/24413—Metal or metal compound
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00—Stock material or miscellaneous articles
    • Y10T428/31504—Composite [nonstructural laminate]
    • Y10T428/31511—Of epoxy ether
    • Y10T428/31529—Next to metal
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T442/00—Fabric [woven, knitted, or nonwoven textile or cloth, etc.]
    • Y10T442/20—Coated or impregnated woven, knit, or nonwoven fabric which is not [a] associated with another preformed layer or fiber layer or, [b] with respect to woven and knit, characterized, respectively, by a particular or differential weave or knit, wherein the coating or impregnation is neither a foamed material nor a free metal or alloy layer
    • Y10T442/2041—Two or more non-extruded coatings or impregnations
    • Y10T442/2049—Each major face of the fabric has at least one coating or impregnation
    • Y10T442/2057—At least two coatings or impregnations of different chemical composition
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T442/00—Fabric [woven, knitted, or nonwoven textile or cloth, etc.]
    • Y10T442/20—Coated or impregnated woven, knit, or nonwoven fabric which is not [a] associated with another preformed layer or fiber layer or, [b] with respect to woven and knit, characterized, respectively, by a particular or differential weave or knit, wherein the coating or impregnation is neither a foamed material nor a free metal or alloy layer
    • Y10T442/2418—Coating or impregnation increases electrical conductivity or anti-static quality
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T442/00—Fabric [woven, knitted, or nonwoven textile or cloth, etc.]
    • Y10T442/30—Woven fabric [i.e., woven strand or strip material]
    • Y10T442/3382—Including a free metal or alloy constituent
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T442/00—Fabric [woven, knitted, or nonwoven textile or cloth, etc.]
    • Y10T442/30—Woven fabric [i.e., woven strand or strip material]
    • Y10T442/3382—Including a free metal or alloy constituent
    • Y10T442/3407—Chemically deposited metal layer [e.g., chemical precipitation or electrochemical deposition or plating, etc.]

Landscapes

  • Engineering & Computer Science (AREA)
  • Textile Engineering (AREA)
  • Chemical & Material Sciences (AREA)
  • Inorganic Chemistry (AREA)
  • Chemical Or Physical Treatment Of Fibers (AREA)
  • Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
  • Laminated Bodies (AREA)

Description

200813288 九、發明說明： 【發明所屬之技術領域】 本發明係關於導電布的技術領域，尤指具有低表面電阻 且經顏色塗佈之防污導電布，及其製造方法。 【先前技術】 現有導電布一般係將布料進行無電解電鍍以形成金屬化 織物，當電鍍銅時導電布外觀呈金屬銅色、鍍銅鍵錄呈銀
灰鍍銀呈銀白色或鍍金呈金色。導電布柔軟、光滑且 透氣並具有重篁輕及易裁剪等優點。然而，由於導電布 之表面金屬化的結果，導電布無法使用一般布料之染色技 術染色’相較於顏色多樣化的一般布料，導電布的外觀單 調且在應用上的限制較大。 一此外’由於導電布之表面層為銅、鎳、、銀或金等金屬， 谷易受到使用環境的溫、溼度影響，且於作業時易受到手 痕或其他接觸影響，造成氧化、手痕、外觀污染或表面電 阻升高等缺陷。 習知有以聚氨酿樹脂或壓克力樹脂等添加導電碳黑㈣ 佈於v電布上’成為具有黑色導電性塗層之導電布。由方 =塗碳黑厚度厚’且碳黑導電性為約1Ω至^ 传具有m層之導電布無法保持原來導電布之低表面霉 阻。一般而言，導 分冤亭之表面電阻為約〇·〇〇7Ω /□至約1 G /□。此外，碳里夕w Α命 …、之…、色度不足以顯現亮麗的黑色度，更 甚者為只有早—之里#、按4史 _ν …、色k擇，對產品應用的選擇有極大的 限制。 il3856.doc 200813288 由於現有導電布具有顏色限制及易受舉境影響等缺失， 實有加以改良的必要。 【發明内容】 為了改善上述現有導電布的限制及缺弊，本發明之主要 目的在於提供一種可以在其上形成顏色、可防止人為或環 境影響其特性，並保持原有低表面電阻的導電布。
本發明之另一目的係提供一種經顏色塗佈之防污導電布 的製造方法’其包含下列步驟：提供m纖維或人造 纖維織成且包含-金屬層之導電布；及於該導電布之金屬 層上形成至少-有色樹脂塗層；其特徵在於該樹脂塗層表 面不超過導電布之經緯向紗線的交又凸點。 【實施方式】 隹本發明具體實 &顏色塗佈之防污導電布的 表义方法包含以下步驟：捭 成 ^、一以天然纖維或人造纖維織 成之布料，利用無電解電錢 ^ , . . a …亥布枓表面均勻鍍上一金屬 曰成為^電性之導電布；將 樹•塗佈配方;及於導電布之金屬層成-有色 次’母層塗層係塗佈於布料之 “顏色冰 經緯向紗線的交又凸點。 …域’但不超過布料之 上述方法所使用之天然纖維可 不限於棉、麻、絲戋毛. 、°然纖維，例如但 4毛，人造纖維可為 如但不限於嫘縈纖維、、 ”、、可人造纖維，例 維。”纖維、聚酯纖維或壓克力纖 iI3856.doc 200813288 熱知者，其中所 ’例如但不限於 上述無電解電鍍法係熟習此項技術者所 使用之金屬可為任何導電性良好之金屬 銅、鎳、銀、金或其合金。 上述方法所使用的顏料可為具有任何顏色之染料，如黑 色礙黑、有機黑、紅、藍、、綠、金等顏料或由任何需要^ 顏色的染料調製而得’其用量為樹脂塗佈配方之約1%至 約20%。樹脂可為溶劑型或水性樹脂，例如但不限於聚氨
酯樹脂、聚酯樹脂、懕古士扮^匕 、 ^ I克力樹脂、乳膠樹脂或矽利康樹 脂，其用量為樹脂塗佈配方之約1〇%至約7〇%。 在本發明之較佳實施態樣中，樹脂塗佈配方可視需要添 加架橋劑’例如但不限於異氰酸_(is(>ey舰⑷或三聚氛胺 (melamine)，其用量為樹脂塗佈配方之約1%至約10〇/〇 ;及 溶劑，例如但不限於甲苯（t〇luene)、丁酮（Mb以⑽ ne，MEK)、一甲基甲醯胺⑷则吻心⑽础也；DMF)， 其用量為樹脂塗佈配方之約3G%至60%，u將樹脂塗佈配 方稀釋至約1000 CPS至約20000 cps之黏度。 在上述方法中，塗佈有色樹脂之薄塗層的方法係熟習此 項技術者所热知者，例如但不限於刮刀塗佈方式、雕刻羅 k佈方式噴塗噴灑方式或浸潰壓吸搭配刮刀將多餘表 面樹脂刮除方式等以形成薄塗層。 在本t明之較佳實施態樣中，刮刀塗佈方式可以懸浮式 刮刀塗佈’以精確控制各塗層的塗佈量。在本發明方法之 車乂仏貝知恶樣中，刀具可為J型刀或U型刀，刀厚度為約 〇·5 mm至約5 mm ’刀具下壓導電布接觸面約0.5 mm至約 113856.doc 200813288 20 mm，1次塗佈量為約〇·ι g/M2至約8 ，且塗佈後以 約80。〇至約160°C，烘乾約1分鐘至約3分鐘。 本發明另提供一種經顏色塗佈之防污導電布，其包含一 以天然纖維或人造纖維織成且包含一金屬層之導電布，及 至少一有色樹脂塗層以刮刀方式塗佈於該導電布之金屬層 上，其中該樹脂塗層表面不超過導電布之經緯向紗線的交 叉凸點。該導電布於塗佈有色樹脂塗層前的表面電阻為約
0·0〇7Ω /□至約〇」Q /□，而於塗佈有色樹脂塗層後的表面 電阻為約0.007Ω/□至約〇.1Ω/[：]。 本發明係利用低塗佈量塗佈，且多次塗佈均不超過導電 布之經緯紗交又凸點的技術，以於導電布之單面或雙面塗 佈所需的顏色，使得導電布呈現具有均句顏色且色度深之 外觀，導電布之表面金屬層由於薄樹脂塗層之保護而不會 受到人為或環境影響其外觀及導電性能，且經顏色塗佈之 導電布表面仍然具有與原導電布相同之導電性能，不會因 為塗佈塗層過厚而使其表面電阻升高。 本發明導電布具有有色外觀、人為或環境污染防止及低表 面電阻等特性。本發明之導電布經由塗佈或貼合導電偷 或熱熔料，可成騎f布”、導電布泡 概 二具:防輕射、防靜電等特性，可以防止由電子2 汽漏之^磁波影響自身或其他電子機器而產生誤動作。 以下貫施例係用㈣本發明作進—步說明，唯非用 制本發明之範圍。任何熟悉此項技藝之人士可輕易達成： 修飾及改變均包括於本案說明書揭示内容及所附" 113856.doc 200813288 範圍之範圍内。 實施例1 :經顏色塗佈之防污導電布的製備 進行下列步驟以製得經顏色塗佈之防污導電布： 織布·以l s曰纖維織成具有經向5 〇丹尼6纖維數、緯 向50丹尼/72纖維數、經向密度152條/英吋及緯向密度124 條/英吋’及厚度為〇.1 mm的平織布料。 無電解電鍍：將該布料經過精練洗淨、熱定型、表面粗 化及表面凋整後，進行無電解電鍍銅及鎳以將布料金屬 化； 其中無電解電鍍係技藝人士熟知的製程，其包含以下步 驟活化·在3〇c下，將布料於包含氯化鈀100 mg/L、氣 化亞錫10 g/L及鹽酸100 ml/L之溶液中浸潰3分鐘，然後完 全洗淨；接著速化：在45t下，將布料於鹽酸1〇〇㈤^中 /又/貝3刀鐘，然後元全洗淨；之後進行無電解鑛銅：在如 c下，將布料於包含硫酸銅10 g/L、甲醛7·5瓜、氫氧 化鈉8 g/L、乙二胺四醋骏四鈉鹽（ethylene‘ tetraaceuc acid tetrasodium salt; EDTA-4Na)30 g/L及安定 劑0.25 ml/L之溶液中浸潰2〇分鐘，以於布料上均勻鍍上金 屬銅25克/M2，然後完全洗淨；接著進行無電解鍍鎳：在 40°C下，將布料於包含硫酸鎳22 5 g/L、次亞磷酸鈉18 g/L、檸檬酸鈉〇·! M/L及氨水2〇 ml/L之溶液中浸潰5分 鐘，以於布料上均勻鍍上金屬鎳5克/M2，然後完全洗淨， 最後進行烘乾，以製得銀灰色導電布。 以 JIS K-7194，Mitsubishi Loresta MCP-T600進行四點探 I13856.doc -10- 200813288 針測試法，將測試抵針放於布料的表面測試表面電阻；測 得所製得之銀灰色導電布具有約0·03 Ω /□的表面電阻。 製備樹脂塗佈配方：將二液型聚氨酯樹脂100克、異氮 酸酯9克、丁酮50克、黑色碳黑5克及黑色顏料5克（其中黑 色顏料包含32%碳黑、3%分散劑、20%壓克力樹脂及45% 載體）混合以形成底部塗佈配方，其黏度為約5〇〇〇 cpS ;及 將一液型聚氨自旨樹脂100克、異氰酸醋3克、丁酮50克、專 色碳黑10克及黑色顏料10克（其中黑色顏料包含32%碳黑、 3%分散劑、20%壓克力樹脂及45%載體）混合以形成面料塗 佈配方，其黏度為約4000 cp。 刮刀塗佈··以懸浮式機台將調製好的樹脂塗佈配方塗佈 於導電布之金屬層上，其中該機台使用刀厚度2 mm之j型 刀，刀具下壓導電布接觸面2 mm之條件。先以底部塗佈配 方於導電布上塗佈約5克/M2，覆蓋布料之凹點區域，但不 超過布料之經緯向紗線的交叉凸點，接著以約· 12(rc烘烤 約1分鐘，再以面料塗佈配方塗佈約5克/M2於布料之凹點 區域上’同樣不超過布料之經緯向紗線的交叉凸點，再以 約12 0 C烘烤約1分鐘，以形成經顏色塗佈之防污導電布。 比較例1 :經碳黑塗佈之防污導電布的製備 同實施例1之織布及無電解電鍍步驟以形成具有約0 03 Ω/□的表面電阻之銀灰色導電布，接著於導電布之金屬 層上塗佈包含導電碳黑之樹脂塗佈配方。首先，以包含二 液型聚氨酯樹脂100克、丁酮5〇克、異氰酸酯9克及導電碳 黑5克，且黏度約5000 cps之底部樹脂塗料配方，於導電布 113856.doc -11 - 200813288 上形成一底部塗層，接著以包含一液型聚氨酯樹脂100 克、丁酮50克、異氰酸酯3克及導電碳黑1 〇克，且黏度約 4000 cps之面料樹脂塗料配方，於導電布上形成一表面塗 層’底部塗層及面料塗層之乾膜總厚度為約〇 〇8 ，以 製得經碳黑塗佈之灰黑色防污導電布。 表1列出實施例1與比較例1所製得導電布及未經塗佈之 ^電布的布料顏色、布料厚度、表面電阻、防污性能及屏 蔽性能。 防污性能係以裁剪經向及緯向1〇公分χ1〇公分之導電布 料測试樣，測試手痕對於材料表面污染性及殘留痕跡，其 中〇··幾乎無污染痕跡，△:少許污染痕跡，及χ ••污染 痕跡非常嚴重）。
綜上所述，本 本發明係以低塗佈量塗佈， ，配合有色樹脂塗
實有極大之幫助。 外觀，且不會影響原有導電 氧化髒污、人為或環境污染 對於導電布的實用範圍領域 113856.doc

Claims (1)

  1. 200813288 十、申請專利範圍： 1. 一種經顏色塗佈之防污導電布的製造方法，其包含下列 步驟： 提供一以天然纖維或人造纖維織成且包含一金屬層之 導電布；及 • 於該導電布之金屬層上形成至少一有色樹脂塗層，其 中該樹脂塗層表面不超過導電布之經緯向紗線的交叉凸 點。 • 2.如請求们之製造方法，其中該天然纖維包含棉、麻、 絲、或毛。
    如明求項1之製造方法，其中該人造纖維包含嫘縈纖 維、尼龍纖維、聚酯纖維或壓克力纖維。 如請求項1之製造方法，其中該金屬層係經由無電解電 鍍銅、鎳、銀、金或其合金所形成。 如。月求項1之製造方法，其中該有色樹脂塗層包含約 至約20%顏料及约1%至約7〇%樹脂。 :明求項5之製造方法，其中該顏料包含黑色、紅色、 π色、綠色、金色或其他複合色顏料。 二、項5之製造方法，其中該樹脂包含溶 樹脂。 人 > 此 ::戈項7之製造方法，其中該樹脂包含聚氨酯樹脂、 1 1^、壓克力樹脂、乳膠樹脂或矽利康樹脂。 9·如睛求項5 1〇/〇至毛 衣以方法，其中該有色樹脂塗層另包含約 、、勺10°’。架橋劑及約3〇%至約6〇%溶劑。 113856.doc 200813288 10·如請求項9之製造方法，其中該架橋劑包含異氰酸酯或 二聚氰胺，及該溶劑包含甲苯、丁酮或二甲基甲醯胺。 月农項1之製造方法，其中形成該有色樹脂塗層之方 式包含以刮刀塗佈方式、雕刻羅拉塗佈方式'噴塗噴灑 方式或浸潰壓吸搭配刮刀將多餘表面樹脂刮除方式。 12·如請求項1之製造方法，其中該導電布於塗佈有色樹脂 塗層前的表面電阻為約〇·〇〇7Ω /□至約01 Ω /□，且塗佈 有色樹脂塗層後的表面電阻為約〇·〇〇7 Ω /□至約〇1 Ω / □。 13 ·種經顏色塗佈之防污導電布，其包含一以天然纖維或 人造纖維織成且包含一金屬層之導電布，及至少一有色 樹脂塗層以刮刀方式塗佈於該導電布之金屬層上，其中 σ亥私丨脂塗層表面不超過導電布之經緯向紗線的交叉凸 點。 14·如請求項13之防污導電布，其中該天然纖維包含棉、 麻、絲、或毛。 15·如請求項13之防污導電布，其中該人造纖維包含嫘縈纖 維、尼龍纖維、聚酯纖維或壓克力纖維。 1 6.如請求項13之防污導電布，其中該金屬層係經由無電解 電鑛鋼、鎳、銀、金或其合金所形成。 1 7·如請求項13之防污導電布，其中該有色樹脂塗層包含約 10/〇至約20%顏料及約1%至約7〇%樹脂。 18·如請求項17之防污導電布，其中該顏料包含黑色、紅 色、藍色、綠色、金色或其他複合色顏料。 113856.doc 200813288 1 9 ·如請求項i 7之防污導電布，其中該樹脂包含溶劑型或水 性樹脂。 20·如請求項19之防污導電布，其中該樹脂包含聚氨樹 脂、聚S旨樹脂、壓克力樹脂、乳膠樹脂或秒利康樹脂。 2 1 ·如晴求項1 7之防污導電布’其中該有色樹脂塗層另包含 約1%至約10%架橋劑及約30%至約60%溶劑。 22·如請求項21之防污導電布，其中該架橋劑包含異氰酸酯 或三聚氰胺，及該溶劑包含甲苯、丁酮或二曱基甲醯 23. 如請求項13之防污導電布，其中形成該有色樹脂塗層之 方式包含以刮刀塗佈方式、雕刻羅拉塗佈方式、喷塗噴 灑方式或浸潰壓吸搭配刮刀將多餘表面樹脂刮除方式。 24. 如請求項13之防污導電布，其中該防污導電布於塗佈有 色樹脂塗層前的表面電阻為約〇 〇〇7Ω 7口至約〇ι 〇 /口， 且塗佈有色樹脂塗層後的表面電阻為約〇〇〇7Ω/□至約 0·1 Ω /□。 113856.doc 200813288 七、指定代表圖： (一) 本案指定代表圖為：（無） (二) 本代表圖之元件符號簡單說明：
    八、本案若有化學式時，請揭示最能顯示發明特徵的化學式： (無）
    113856.doc
TW95132884A 2006-09-06 2006-09-06 Color-coated, fouling-resistant conductive clothes and manufacturing method thereof TWI341889B (en)

Priority Applications (3)

Application Number Priority Date Filing Date Title
TW95132884A TWI341889B (en) 2006-09-06 2006-09-06 Color-coated, fouling-resistant conductive clothes and manufacturing method thereof
US11/850,728 US8173555B2 (en) 2006-09-06 2007-09-06 Color-coated, fouling-resistant conductive cloth and manufacturing method thereof
JP2007231242A JP5252863B2 (ja) 2006-09-06 2007-09-06 カラーコートされた汚損耐性導電布及びその製造方法

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
TW95132884A TWI341889B (en) 2006-09-06 2006-09-06 Color-coated, fouling-resistant conductive clothes and manufacturing method thereof

Publications (2)

Publication Number Publication Date
TW200813288A true TW200813288A (en) 2008-03-16
TWI341889B TWI341889B (en) 2011-05-11

Family

ID=39152277

Family Applications (1)

Application Number Title Priority Date Filing Date
TW95132884A TWI341889B (en) 2006-09-06 2006-09-06 Color-coated, fouling-resistant conductive clothes and manufacturing method thereof

Country Status (3)

Country Link
US (1) US8173555B2 (zh)
JP (1) JP5252863B2 (zh)
TW (1) TWI341889B (zh)

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
TWI581758B (zh) * 2015-07-29 2017-05-11 Far Eastern New Century Corp 布膜生理感測器
CN112342695A (zh) * 2020-12-08 2021-02-09 常州科旭纺织有限公司 一种短纤长丝复合纱在织物中的应用

Families Citing this family (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101580953B (zh) * 2008-05-14 2011-08-03 深圳市迪凯鑫科技有限公司 一种化学沉铜液的组成及其制备方法
US8162728B2 (en) * 2009-09-28 2012-04-24 Rohm And Haas Electronic Materials Cmp Holdings, Inc. Dual-pore structure polishing pad
WO2014086038A1 (en) * 2012-12-07 2014-06-12 Laird Technologies, Inc. Coatings and methods for providing fabrics with faux metal platings
CN105818526B (zh) * 2016-03-31 2017-08-25 上海特安纶纤维有限公司 高寿命低收缩热转移印花毛毯及其制备方法
JP6778091B2 (ja) * 2016-11-25 2020-10-28 日本バイリーン株式会社 着色繊維シート及び自動車用内装材
CN111188111A (zh) * 2020-03-15 2020-05-22 江苏凯达纺织有限公司 一种抑菌型棉纺织面料制备工艺
CN113909011B (zh) * 2020-07-10 2023-04-18 高利科技股份有限公司 碳棒的制备方法及其结构

Family Cites Families (15)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS61245372A (ja) * 1986-04-16 1986-10-31 三菱樹脂株式会社 導電性メツシユ織物
JPH0448697A (ja) 1990-06-13 1992-02-18 Kowa Kogyosho:Kk 電磁シールド材およびその製造方法
US5822431A (en) * 1996-01-19 1998-10-13 General Instrument Corporation Of Delaware Virtual authentication network for secure processors
JPH111874A (ja) * 1997-06-09 1999-01-06 Achilles Corp 電磁波遮蔽性衣料材
US6105131A (en) * 1997-06-13 2000-08-15 International Business Machines Corporation Secure server and method of operation for a distributed information system
JP4112075B2 (ja) 1998-05-29 2008-07-02 セーレン株式会社 導電性布帛とその製造方法
CN1159654C (zh) * 1999-05-26 2004-07-28 富士通株式会社 网络元件管理系统和方法
CN1173092C (zh) * 1999-07-07 2004-10-27 刘绍芝 一种屏蔽电磁波的织物及其制作方法
US7006434B1 (en) * 2000-02-10 2006-02-28 Ciena Corporation System for non-disruptive insertion and removal of nodes in an ATM sonet ring
JP3903457B2 (ja) * 2000-03-29 2007-04-11 セーレン株式会社 導電性織物
JP4048697B2 (ja) 2000-07-10 2008-02-20 コニカミノルタビジネステクノロジーズ株式会社 画像形成装置と画像形成システム、及び外部プリント指示端末並びに画像形成装置の選択方法
JP2003129374A (ja) * 2001-10-24 2003-05-08 Teijin Ltd 導電性布帛
JP2003236996A (ja) * 2002-02-15 2003-08-26 Teijin Ltd 導電性シート及びそれからなる電磁波シールド材
JP2004211247A (ja) * 2003-01-06 2004-07-29 Teijin Ltd 難燃導電性布帛
AU2003903967A0 (en) * 2003-07-30 2003-08-14 Canon Kabushiki Kaisha Distributed data caching in hybrid peer-to-peer systems

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
TWI581758B (zh) * 2015-07-29 2017-05-11 Far Eastern New Century Corp 布膜生理感測器
CN112342695A (zh) * 2020-12-08 2021-02-09 常州科旭纺织有限公司 一种短纤长丝复合纱在织物中的应用

Also Published As

Publication number Publication date
JP5252863B2 (ja) 2013-07-31
US20080057815A1 (en) 2008-03-06
TWI341889B (en) 2011-05-11
JP2008062648A (ja) 2008-03-21
US8173555B2 (en) 2012-05-08

Similar Documents

Publication Publication Date Title
US8173555B2 (en) Color-coated, fouling-resistant conductive cloth and manufacturing method thereof
CN101287354B (zh) 一种锡镍合金电磁屏蔽材料及其制备方法
CN106592203A (zh) 石墨烯导电布、制备方法及其用途
JP2716505B2 (ja) 繊維状材料の金属化法
EP1903140B1 (en) Color-coated, fouling-resistant conductive cloth and manufacturing method thereof
KR101326266B1 (ko) 도전성 부직포의 제조방법 및 도전성 부직포를 이용한 멀티 기능 ｅｍｉ 차폐용 테이프의 제조방법
TWI338733B (en) Method for manufacturing embossed conductive clothes
US3058845A (en) Process for metallizing polyacrylonitrile shaped article by treating with a water soluble metal salt and reducing the salt to the free metal
JP4926936B2 (ja) 低発塵性導電糸及びその製造方法
KR100935185B1 (ko) 도전성 금속이 도금된 직물의 제조방법
CN101153462B (zh) 弹性导电布的制造方法
CN115506147A (zh) 一种多功能抗氧化金属导电织物及其制备方法
CN101338513B (zh) 压花导电布的制造方法
KR20210049824A (ko) 전도성 재료 및 금속 복합 전도성 잉크 조성물을 이용하는 금속화에 의한 그의 제조 방법
CN106906497B (zh) 一种深枪色电磁屏蔽材料及其制备方法
TWM663384U (zh) 具導電層之纖維
JP4560750B2 (ja) 金属被覆繊維とその用途
CN111996795B (zh) 电磁屏蔽复合膜布及制备方法
TWI337937B (en) Method of manufacturing elastic conductive clothes
CN119352288B (zh) 一种柔性芳纶纳米纤维导电膜及其制备方法和应用
JP2017052975A (ja) めっき繊維及びその製造方法
JPS6215637B2 (zh)
JP6284536B2 (ja) 無電解めっき用塗料組成物
JP2000129450A (ja) 部分メッキ基材、その製造方法及びそれを用いた電極材
JP2000256961A (ja) 金属被覆ガラスクロス及びその製造方法