TW200814312A - Semiconductor device with reliable high-voltage gate oxide and method of manufacture thereof - Google Patents
Semiconductor device with reliable high-voltage gate oxide and method of manufacture thereof Download PDFInfo
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- TW200814312A TW200814312A TW096127977A TW96127977A TW200814312A TW 200814312 A TW200814312 A TW 200814312A TW 096127977 A TW096127977 A TW 096127977A TW 96127977 A TW96127977 A TW 96127977A TW 200814312 A TW200814312 A TW 200814312A
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- Prior art keywords
- layer
- barrier layer
- boron
- semiconductor device
- gate
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- 239000004065 semiconductor Substances 0.000 title claims abstract description 49
- 238000000034 method Methods 0.000 title claims description 24
- 238000004519 manufacturing process Methods 0.000 title claims description 9
- ZOXJGFHDIHLPTG-UHFFFAOYSA-N Boron Chemical compound [B] ZOXJGFHDIHLPTG-UHFFFAOYSA-N 0.000 claims abstract description 30
- 229910052796 boron Inorganic materials 0.000 claims abstract description 30
- 239000000463 material Substances 0.000 claims abstract description 21
- 239000003990 capacitor Substances 0.000 claims abstract description 20
- 239000000758 substrate Substances 0.000 claims abstract description 15
- 230000004888 barrier function Effects 0.000 claims description 31
- MWUXSHHQAYIFBG-UHFFFAOYSA-N Nitric oxide Chemical compound O=[N] MWUXSHHQAYIFBG-UHFFFAOYSA-N 0.000 claims description 12
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 claims description 8
- 238000007254 oxidation reaction Methods 0.000 claims description 8
- MZLGASXMSKOWSE-UHFFFAOYSA-N tantalum nitride Chemical compound [Ta]#N MZLGASXMSKOWSE-UHFFFAOYSA-N 0.000 claims description 8
- 239000004020 conductor Substances 0.000 claims description 4
- 229910052757 nitrogen Inorganic materials 0.000 claims description 4
- 239000011701 zinc Substances 0.000 claims description 4
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 claims description 3
- 229910052732 germanium Inorganic materials 0.000 claims description 3
- GNPVGFCGXDBREM-UHFFFAOYSA-N germanium atom Chemical compound [Ge] GNPVGFCGXDBREM-UHFFFAOYSA-N 0.000 claims description 3
- 229910052725 zinc Inorganic materials 0.000 claims description 3
- 239000008267 milk Substances 0.000 claims description 2
- 210000004080 milk Anatomy 0.000 claims description 2
- 235000013336 milk Nutrition 0.000 claims description 2
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims 1
- MZUJJYPDPVMHNP-UHFFFAOYSA-N [O-][N+]#N.OS(O)(=O)=O Chemical compound [O-][N+]#N.OS(O)(=O)=O MZUJJYPDPVMHNP-UHFFFAOYSA-N 0.000 claims 1
- 239000004760 aramid Substances 0.000 claims 1
- 229920003235 aromatic polyamide Polymers 0.000 claims 1
- 229910052797 bismuth Inorganic materials 0.000 claims 1
- JCXGWMGPZLAOME-UHFFFAOYSA-N bismuth atom Chemical compound [Bi] JCXGWMGPZLAOME-UHFFFAOYSA-N 0.000 claims 1
- 229910052799 carbon Inorganic materials 0.000 claims 1
- 238000003763 carbonization Methods 0.000 claims 1
- 238000002955 isolation Methods 0.000 claims 1
- 239000010977 jade Substances 0.000 claims 1
- 230000008021 deposition Effects 0.000 abstract description 7
- 238000009792 diffusion process Methods 0.000 abstract description 5
- BOTDANWDWHJENH-UHFFFAOYSA-N Tetraethyl orthosilicate Chemical compound CCO[Si](OCC)(OCC)OCC BOTDANWDWHJENH-UHFFFAOYSA-N 0.000 abstract 1
- 230000009931 harmful effect Effects 0.000 abstract 1
- 235000012431 wafers Nutrition 0.000 description 11
- 230000015572 biosynthetic process Effects 0.000 description 9
- 238000000151 deposition Methods 0.000 description 8
- 150000002500 ions Chemical class 0.000 description 7
- 230000003647 oxidation Effects 0.000 description 7
- 229910052581 Si3N4 Inorganic materials 0.000 description 4
- 229910021420 polycrystalline silicon Inorganic materials 0.000 description 4
- IOVCWXUNBOPUCH-UHFFFAOYSA-M Nitrite anion Chemical compound [O-]N=O IOVCWXUNBOPUCH-UHFFFAOYSA-M 0.000 description 3
- 238000010586 diagram Methods 0.000 description 3
- 239000006185 dispersion Substances 0.000 description 3
- 238000001459 lithography Methods 0.000 description 3
- 229920002120 photoresistant polymer Polymers 0.000 description 3
- 229920005591 polysilicon Polymers 0.000 description 3
- KJTLSVCANCCWHF-UHFFFAOYSA-N Ruthenium Chemical compound [Ru] KJTLSVCANCCWHF-UHFFFAOYSA-N 0.000 description 2
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 2
- 238000005520 cutting process Methods 0.000 description 2
- 238000005516 engineering process Methods 0.000 description 2
- 239000001301 oxygen Substances 0.000 description 2
- 229910052760 oxygen Inorganic materials 0.000 description 2
- 238000000059 patterning Methods 0.000 description 2
- 229910052707 ruthenium Inorganic materials 0.000 description 2
- 239000002904 solvent Substances 0.000 description 2
- 241000283690 Bos taurus Species 0.000 description 1
- 235000014676 Phragmites communis Nutrition 0.000 description 1
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 1
- 229910001347 Stellite Inorganic materials 0.000 description 1
- AHICWQREWHDHHF-UHFFFAOYSA-N chromium;cobalt;iron;manganese;methane;molybdenum;nickel;silicon;tungsten Chemical compound C.[Si].[Cr].[Mn].[Fe].[Co].[Ni].[Mo].[W] AHICWQREWHDHHF-UHFFFAOYSA-N 0.000 description 1
- 238000010411 cooking Methods 0.000 description 1
- 239000013078 crystal Substances 0.000 description 1
- 238000000354 decomposition reaction Methods 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 230000005611 electricity Effects 0.000 description 1
- 230000001804 emulsifying effect Effects 0.000 description 1
- 230000003628 erosive effect Effects 0.000 description 1
- 230000005284 excitation Effects 0.000 description 1
- YBMRDBCBODYGJE-UHFFFAOYSA-N germanium oxide Inorganic materials O=[Ge]=O YBMRDBCBODYGJE-UHFFFAOYSA-N 0.000 description 1
- 239000011810 insulating material Substances 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 150000002739 metals Chemical class 0.000 description 1
- 150000004767 nitrides Chemical class 0.000 description 1
- 238000005121 nitriding Methods 0.000 description 1
- PVADDRMAFCOOPC-UHFFFAOYSA-N oxogermanium Chemical compound [Ge]=O PVADDRMAFCOOPC-UHFFFAOYSA-N 0.000 description 1
- 238000009304 pastoral farming Methods 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- 238000004544 sputter deposition Methods 0.000 description 1
- 239000004575 stone Substances 0.000 description 1
- 238000007740 vapor deposition Methods 0.000 description 1
Classifications
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- H—ELECTRICITY
- H10—SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
- H10D—INORGANIC ELECTRIC SEMICONDUCTOR DEVICES
- H10D30/00—Field-effect transistors [FET]
- H10D30/01—Manufacture or treatment
- H10D30/021—Manufacture or treatment of FETs having insulated gates [IGFET]
- H10D30/023—Manufacture or treatment of FETs having insulated gates [IGFET] having multiple independently-addressable gate electrodes influencing the same channel
-
- H—ELECTRICITY
- H10—SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
- H10D—INORGANIC ELECTRIC SEMICONDUCTOR DEVICES
- H10D64/00—Electrodes of devices having potential barriers
- H10D64/60—Electrodes characterised by their materials
- H10D64/66—Electrodes having a conductor capacitively coupled to a semiconductor by an insulator, e.g. MIS electrodes
- H10D64/68—Electrodes having a conductor capacitively coupled to a semiconductor by an insulator, e.g. MIS electrodes characterised by the insulator, e.g. by the gate insulator
- H10D64/681—Electrodes having a conductor capacitively coupled to a semiconductor by an insulator, e.g. MIS electrodes characterised by the insulator, e.g. by the gate insulator having a compositional variation, e.g. multilayered
- H10D64/685—Electrodes having a conductor capacitively coupled to a semiconductor by an insulator, e.g. MIS electrodes characterised by the insulator, e.g. by the gate insulator having a compositional variation, e.g. multilayered being perpendicular to the channel plane
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- H—ELECTRICITY
- H10—SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
- H10D—INORGANIC ELECTRIC SEMICONDUCTOR DEVICES
- H10D64/00—Electrodes of devices having potential barriers
- H10D64/60—Electrodes characterised by their materials
- H10D64/66—Electrodes having a conductor capacitively coupled to a semiconductor by an insulator, e.g. MIS electrodes
- H10D64/68—Electrodes having a conductor capacitively coupled to a semiconductor by an insulator, e.g. MIS electrodes characterised by the insulator, e.g. by the gate insulator
- H10D64/693—Electrodes having a conductor capacitively coupled to a semiconductor by an insulator, e.g. MIS electrodes characterised by the insulator, e.g. by the gate insulator the insulator comprising nitrogen, e.g. nitrides, oxynitrides or nitrogen-doped materials
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- H—ELECTRICITY
- H10—SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
- H10D—INORGANIC ELECTRIC SEMICONDUCTOR DEVICES
- H10D84/00—Integrated devices formed in or on semiconductor substrates that comprise only semiconducting layers, e.g. on Si wafers or on GaAs-on-Si wafers
- H10D84/01—Manufacture or treatment
- H10D84/0123—Integrating together multiple components covered by H10D12/00 or H10D30/00, e.g. integrating multiple IGBTs
- H10D84/0126—Integrating together multiple components covered by H10D12/00 or H10D30/00, e.g. integrating multiple IGBTs the components including insulated gates, e.g. IGFETs
- H10D84/0144—Manufacturing their gate insulating layers
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- H—ELECTRICITY
- H10—SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
- H10D—INORGANIC ELECTRIC SEMICONDUCTOR DEVICES
- H10D84/00—Integrated devices formed in or on semiconductor substrates that comprise only semiconducting layers, e.g. on Si wafers or on GaAs-on-Si wafers
- H10D84/01—Manufacture or treatment
- H10D84/02—Manufacture or treatment characterised by using material-based technologies
- H10D84/03—Manufacture or treatment characterised by using material-based technologies using Group IV technology, e.g. silicon technology or silicon-carbide [SiC] technology
- H10D84/038—Manufacture or treatment characterised by using material-based technologies using Group IV technology, e.g. silicon technology or silicon-carbide [SiC] technology using silicon technology, e.g. SiGe
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- H—ELECTRICITY
- H10—SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
- H10D—INORGANIC ELECTRIC SEMICONDUCTOR DEVICES
- H10D84/00—Integrated devices formed in or on semiconductor substrates that comprise only semiconducting layers, e.g. on Si wafers or on GaAs-on-Si wafers
- H10D84/80—Integrated devices formed in or on semiconductor substrates that comprise only semiconducting layers, e.g. on Si wafers or on GaAs-on-Si wafers characterised by the integration of at least one component covered by groups H10D12/00 or H10D30/00, e.g. integration of IGFETs
- H10D84/811—Combinations of field-effect devices and one or more diodes, capacitors or resistors
-
- H—ELECTRICITY
- H10—SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
- H10D—INORGANIC ELECTRIC SEMICONDUCTOR DEVICES
- H10D84/00—Integrated devices formed in or on semiconductor substrates that comprise only semiconducting layers, e.g. on Si wafers or on GaAs-on-Si wafers
- H10D84/80—Integrated devices formed in or on semiconductor substrates that comprise only semiconducting layers, e.g. on Si wafers or on GaAs-on-Si wafers characterised by the integration of at least one component covered by groups H10D12/00 or H10D30/00, e.g. integration of IGFETs
- H10D84/82—Integrated devices formed in or on semiconductor substrates that comprise only semiconducting layers, e.g. on Si wafers or on GaAs-on-Si wafers characterised by the integration of at least one component covered by groups H10D12/00 or H10D30/00, e.g. integration of IGFETs of only field-effect components
- H10D84/83—Integrated devices formed in or on semiconductor substrates that comprise only semiconducting layers, e.g. on Si wafers or on GaAs-on-Si wafers characterised by the integration of at least one component covered by groups H10D12/00 or H10D30/00, e.g. integration of IGFETs of only field-effect components of only insulated-gate FETs [IGFET]
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- H—ELECTRICITY
- H10—SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
- H10D—INORGANIC ELECTRIC SEMICONDUCTOR DEVICES
- H10D1/00—Resistors, capacitors or inductors
- H10D1/60—Capacitors
- H10D1/68—Capacitors having no potential barriers
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- H—ELECTRICITY
- H10—SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
- H10D—INORGANIC ELECTRIC SEMICONDUCTOR DEVICES
- H10D30/00—Field-effect transistors [FET]
- H10D30/60—Insulated-gate field-effect transistors [IGFET]
-
- H—ELECTRICITY
- H10—SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
- H10D—INORGANIC ELECTRIC SEMICONDUCTOR DEVICES
- H10D84/00—Integrated devices formed in or on semiconductor substrates that comprise only semiconducting layers, e.g. on Si wafers or on GaAs-on-Si wafers
- H10D84/80—Integrated devices formed in or on semiconductor substrates that comprise only semiconducting layers, e.g. on Si wafers or on GaAs-on-Si wafers characterised by the integration of at least one component covered by groups H10D12/00 or H10D30/00, e.g. integration of IGFETs
- H10D84/82—Integrated devices formed in or on semiconductor substrates that comprise only semiconducting layers, e.g. on Si wafers or on GaAs-on-Si wafers characterised by the integration of at least one component covered by groups H10D12/00 or H10D30/00, e.g. integration of IGFETs of only field-effect components
- H10D84/83—Integrated devices formed in or on semiconductor substrates that comprise only semiconducting layers, e.g. on Si wafers or on GaAs-on-Si wafers characterised by the integration of at least one component covered by groups H10D12/00 or H10D30/00, e.g. integration of IGFETs of only field-effect components of only insulated-gate FETs [IGFET]
- H10D84/85—Complementary IGFETs, e.g. CMOS
- H10D84/856—Complementary IGFETs, e.g. CMOS the complementary IGFETs having different architectures than each other, e.g. high-voltage and low-voltage CMOS
Landscapes
- Semiconductor Integrated Circuits (AREA)
- Metal-Oxide And Bipolar Metal-Oxide Semiconductor Integrated Circuits (AREA)
Description
200814312 九、發明說明: 【發明所屬之技術領域】 右奶2明係有關於半導體元件及其形成方法,且特別 , 、 件在成長程序時,因硼擴散至高電 堡閘極乳化層所導致的不穩定。 门电 【先前技術】 :::元件已被大量的使用在各種的應用上,且變 電二;::或缺的—部分。其中的應用包括電腦、 :為樂等。而電子元件被大量應用的理由之- 成為μH 及成本的降低。因此技術上的改良已 成為叙展丰導體元件的重要部分。 巳 以下將簡要說明用來形成半 材料,如石夕,作為„ 件的製程。將- 电卞兀件。將此材料形成—適 十里 圓的薄片。接著選擇性地以種通:疋稱為晶 需的半導體特性。最後各種二 ==可獲得所 所需的元件。 ㈢形成於日日a上以獲得 晶圓上的表面結構可 面曝露於一蝕刻劑中。—般來‘里序來完成。將晶圓表 術來進行選擇性導在微影技術;利:習:的微影技 材料平勻地沉積於晶圓表面。此 阻或其他抗蝕 —罩幕來將部份的抗㈣曝光而過 °503-A32446TWF/kai 200814312 曝光後的光阻會變得更堅硬或更脆弱,接著可利用溶劑 清除較脆弱的部份,而存留的光阻可保護晶圓表面不被 蝕刻劑所侵蝕。當晶圓蝕刻程序完成後,再將之前存留 的光阻以一適當的溶劑去除。 此外,可利用各種沉積技術將其他材料,例如金屬 或其他導電及絕緣材料等沉積於晶圓表面,例如,以化 學氣相沉積(CVD)或濺鍍法進行沉積。也可額外佈植離 子。接著,選擇性地沉積及移除各種材料,使層狀堆疊 的電子元件結構形成於晶圓表面。 早一晶圓通常含有複數個晶粒’通常各晶粒皆為相 同結構,但並非絕對。在所有製程結束後(或在中間程序 時),可對晶圓進行檢查及測試,並將損壞的部份移除或 修復。最後將分離及測試過的晶粒封裝於一硬塑膠材料 中並以外部導線連接晶粒内部。封裝完成的晶粒具有許 多的導線,又可稱為晶片。 在製程當中,電子元件可同時形成於晶圓上。當某 一材料在沉積或選擇性钱刻後,此材料可被用於許多相 同或不同的元件。因此需要小心的設計使其符合經濟效 益 例如,在高電壓混合訊號模式(high voltage mixed mode,HV-M.Μ)的應用方面,半導體元件具有一電容器結 構,置於NMOS低電壓(LV)閘極及NMOS高電壓(HV) 閘極之間,如第1A-1F圖所示。第1A-1F圖為半導體元 件10的傳統製程剖面圖,應注意的是,本文所述之“半 0503-A32446TWF/kai 6 200814312 可為一或複數個晶粒所形成的晶片,且在直 ^下’則是描述晶粒特定部份的元件或製程。 板半導體元件10的製備’首先形成基 令所幵,成 )11料2()及卩料25。在此步驟
图、。二 用來支持三個元件(請參照第1F …上所述,g!圖的半導體元件包含此 Ϊ相關結構。接著形成場氧化結構30、31、3—2:同 ΓΓΒ之^)HV閑極氧化層35形成於ρ型井15之上,二 iTEOS㈤所不。HV間極氧化層35可利用四乙氧基石夕产 w ΓΓΥ1 orth〇siiicat^^ 二成。在,料上進行崎序以產生 的圖案,又稱為“圖案化,,。 π而罟 第二_氧化層4G形成於半導體 如弟1C圖所示。接著形成一 们表面, 性關此導電層以形成導電::夕晶石夕),並選擇 闰私-,丄# 电、、、口構45、46及47,如第m 二成—電容器的下導電層,導電結構45 為HV閘極,導電結構4 苒5
圖所示。最後,第二導雷 乐1E 高溫氧化層5G之上以带成^ W積於多晶石夕間氧化層/ 件1〇的表面配置如二成圖:侧 =,由上述傳統製程所形成之hv閉極氧化芦且 1又不佳等缺點。而間極氧化層的低穩定度顯^是 〇503-A32446TWF/kai /曙 14312 在進行TEQU料由丨 果。因此,半導體業界 ,散所造成的結 極的方法。 可衣備高穩定度HV閘 【發明内容】 本發明提供-種高穩定度 成閑極氧化層之前沉積—離子阻二V體-件,其係在形 氧化層的穩定度。 ㈢,从增加HV閘極 本^明係提供一種半導體 圖案化成適當:構二:===成長多綱料並 層、纟一,,介電層ΐ:多二二^ 氮切層可為-薄膜。在-ί: 成於基板上(或—多晶 7 離子阻尸早層形 極氧化層分解所造成的離子擴散。 f在另-實施例中,離子阻障層包括= 鋅(ZnO ^ ^ (TaX〇yNz)、氮氧化錯(ΖΓ〇具)、氮氧化 立中x=聽修心及氮氧切版啊所構成, 中x為=之正整數,y及z為任何之非負整數。理想 同釭序中沉積電容器介電層及離子阻障層。 本毛月另提供一種半導體元件的形成方法,包括提 〇503-A32446TWF/kai 200814312 供 包括土p刑’單9日日圓,且在基板㈣成複數個井, 個井上’:井及及::7r:形成一⑽ 在此實施例中二弟::電結構於氧化層及n型井上。 上,且—长/μ 夕日日矽氧化層接著形成於整個元件 上且一鼠化矽層形成於多曰石々气几思L 件 佳為-薄膜。在此實氮化石夕層較 介電層的一部 石夕層可作為一臀止:層形成於ρ型井上,氮化 所造成的散:可二, 在-較佳,… ㈣沉積間極氧化層。 -容哭上二 積及圖案化最後的導電層以形成 包谷σσ上極板及Η V閘極。 ,了讓本㈣之上述和其他目的、特徵 更明峨’下文特舉較佳實施例,並配人所附s 作詳細說明如下: I配口所附圖不, 【實施方式】 本發明係提供一種刹 t (HV-顧)技術來製造半導體向^堅、混合訊號模式 體元件包括-電容器設置於_“法,本發明之半導 , BH ^ 於—问電壓閘極及一低電壓閘 極之間。本發明切應料 發明之半導體元件製 7牛"^兀件之上。本 、生士从丁自旦/鄉 和因硼擴散至HV氧化區所 響。(相較之下,鱗擴散至η型井上雜 成的影響較低)。以下第2α。^ 施例。 下乐2八至邛圖係顯示本發明之一實 0503-A32446TWF/kai 200814312 第2A至2F圖為半導體元件】〇〇之製程剖面圖,本 ,明實施例之元件與第1A_1F圖之元件類似,具有一電 容器基板與一 HV閘極。與前案類似,首先在半導體基 板上形成二個井區。在此實施例中,n型井115形成於基 板1〇5中,且介於卩型井11〇及ρ型井12〇之間,如第 2Α圖所示。接著依序形成薄間極氧化層及場氧化結 構126 127、128、129 ’如第2Β圖所示。應注意的是, 上述各結構的相對尺寸可適度的改變。 利用沉積與圖案化程序,如微影技術形成第一多晶 =,’如第=圖所示之多晶石夕結構13〇及135。應注意 疋此a序巾多晶⑦結構並未形成於ρ型井⑽上。 开> 成多晶矽氧化層13 8,例如,&# 上述結構之上。接著再=成長步驟形成於 牧有丹"匕f貝一層材料,較祛.舞 (swuo,但也可使用1乂彳土為鼠化石夕 (Ta Ο N ^ -- 八他材料,例如氮氧化鈕 及,化帥養、氮氧化鋅⑽哪、碳化 夕⑸❽及㈣切(six0yNZ)之至少 何之正整數,7及2為 /、甲X為任 ,. 非負整數,如第2D圖所示。 可叙現,Si3N4層14〇在電|哭& 極板之間,可作A 人+ 為結構16Q的上下 以阻止β 1 13 4層140可作為一硼停止層, 二且止或減緩在沉積HV閘極氧 擴散出來的。在此實施例中,=p型井110所 -閘極氧化材料,並利㈣ 咖沉積技術沉積 化材料以形成間極氧化結構;45,=广^^^ X乐圖所不。 〇5〇3-A32446TWF/kai 10 200814312 在半導體元件100上f 著圖案化此多晶石夕層以形第二多晶石夕層,接 第2E圖所示。上極板i =益' 160的上極板150,如 極155形成於間極氧化層uJT4層140上,且閘 邮4 (或其他離子 。如上所述,由於利用 避免硼擴散,使間極具極氧化層⑷以 層是用來阻止或減緩由p H於料阻障 此又稱為“硼阻障層,,。土 所擴散出來的硼,因 $發明之半導體元件的製 弟二井及第三井之間,形 ^括⑦置弟一井於 第三井上,形成第__ 魏層於第―、第二及 形成弟二導電結構於氧化及#井上以及 氮化矽(SisN4)離子阻障声 —方。接著沉積一 其中此Si3N4層形成於第S一及第—二^二、及第三井上, 二氧化層,形成第三導 —^电結構之上。形成第 導雷社Μ呈古c. 構於弟—井上,其中哕筮 W、.、口構具有&義層,且第 ,、中。亥弟- 形成第四導電結構於第三 層為一介電層,最後 -閑極,以作為—高電;間極::第:導電結構可形成 為一 Ρ型井。 在—貫施例中,第三井 在另一實施例中,叫乂層可 !旦(Tax〇yNz)、氫氧化錯降⑽括—或複數個氮氧化 化石夕(叫)及氫氧化邦叫队),=化鋅⑽yNz)、碳 數,y及z為任何之非負整數。一 X為任何之正整 此實施例之形成方法包括 夕日日矽氧化膜,例 〇503-A32446TWF/kai 11 200814312 如在沉積Si3N4層 刖刊用 (epitaXial-growth)形成。在另—f m二程序 程序形成第二氧化層。第三及第四 ^咖沉積 可在同—程序中沉積而成。 、、-構,如夕晶矽, 在另—實施例中,本發明係提供— 形成方法,包括提供-基板,形成 +¥脰凡件的 沉積-氮切層於p型井上, 卜井於絲板上, (或其他離子阻障層)及p型井^ H =氮化石夕 ::成此氧化層,以及形成-導電結構於氧^ 閉極,例如,可作為-高電厂勵J 二=::方法更包括形成—電容器鄰接至此閘 電層㈣成一第—極板,形成-介 -二於弟極板之上’此介電層包括氧化 :弟二極板於介電層之上。閑極及第二極板可以相 材料及早一的多晶矽圖案化層形成。 ° 、 在-實施例巾,較佳同時形錢 此氮切於P型井上。此方 層及4 物之介電層於第一極板上,且在 多晶條 多晶石夕氧化物。^且在切前絲成此 雖然本發明已以較佳實施例揭露如±,秋 ==明,任何熟習此技藝者,在不脫離= 圍内’當可作些許之更動與潤飾,因此本發明 ί耗圍當視後附之申請專利範圍所界定者為準。 〇503-A32446TWF/kai 12 200814312 【圖式簡單說明】 第1A圖顯示在基板上形成p型井及η型井區。 第1Β圖顯示形成場氧化結構,及一 HV閘極氧化層 形成於Ρ型井區上。 第1C圖顯示第二閘極氧化層形成於半導體元件的 整個表面。 第1D圖顯示形成導電結構。 第1Ε圖顯示多晶矽間氧化層/高溫氧化層形成於導 電結構上。 第1F圖顯示第二導電層沉積於多晶矽間氧化層/高 溫氧化層上以形成電容器的上導電層。 第2Α圖顯示半導體基板上形成ρ型井及η型井區。 第2Β圖顯示依序形成薄閘極氧化層及場氧化結構。 第2C圖顯示多晶矽結構形成於閘極氧化層上。 第2D圖顯示形成場氧化結構後沉積氮化矽材料層。 第2Ε圖顯示形成閘極氧化結構。 第2F圖顯示本發明之半導體結構。 【主要元件符號說明】 10〜半導體元件; 12〜基板; 15、25〜Ρ型井; 20〜Ν型井; 30、31、32、33〜場氧化結構; 35〜HV閘極氧化層; 40〜第二閘極氧化層; 45、46、47〜導電結構; 50〜多晶矽間氧化層/高溫氧化層; 0503-A32446TWF/kai 13 200814312 55〜第二導電層; 105〜基板; 115〜η型井; 126、127、128、129 130、135〜多晶碎結構 13 8〜多晶石夕氧化層; 145〜閘極氧化結構; 155〜閘極; 100〜半導體元件; 110、】20〜ρ型井,· 125〜薄閘極氧化層·, 場氧化結構; j 140〜氮化矽(Si3N4)層; 15 0〜上極板; 160〜電容器結構。 0503-A32446TWF/kai 14
Claims (1)
- 200814312 十、申請專利範圍·· 1· 一種半導體元件,包括·· 一電容器;包括: 一第一導電層; 第二導電層,設置於該第一導電層上方; 硼阻障層,設置於該第一及第二導電層之間作為 一介電層;以及 , 一高電壓閘極,鄰近該電容器;包括: ; 一硼阻障層;以及 一導電層,設置於該硼阻障層上。 2·如申請專利範圍第丨項所述之半導體元件,其 該硼阻障層包括氮化矽(Si3N4)。 八 3·如申請專利範圍第1項所述之半導體元件,其中 "亥硼阻障層包括氮氧化鈕(TaxOyNz)、氮氧化錯 (Zr〇yNz)、氮氧化鋅(Zn〇yNz)、碳化梦⑻❽及氮氧化石夕 (1 (SlX〇yNz)之至少一種材料,其中X為任何之正整數,y及 I Z為任何之非負整數。 ^及 ^ 4·如申請專利範圍第1項所述之半導體元件,其中 該高電壓閘極更包括—第—氧化層及—第二氧化層了且 兩者以該硼阻障層隔離。 >如申請專利範圍第丨項所述之半導體元件,其中 忒电谷态之硼阻障層及該高電壓閘極之硼阻障層由— 一程序沉積而成。 6.如申請專利範圍第5項所述之半導體元件,其中 0503-A32446TWF/kai 200814312 該硼阻障層為一薄膜。 8.如申請專利範圍第1項所述之半 括一低電壓(LV)閘極。 9·如申請專利範圍第8項所述之半 该低電閘極包括一硼阻障層。 7·如申請專利範圍第6項所述之 該硼阻障層的厚度在100至5〇〇入之間。、 /、中 導體元件,更包 導體元件,其中 」〇.如申請專利範圍第i項所述之半導體元件 该咼電壓閘極形成於一 !)型井上。 ’、 + L如申請專利範㈣1項所述之半導體元件,其中 該電容器形成於一 n型井上,且該高電壓閘極形 型井上。 、P 12.如申凊專利範圍第〗1項所述之半導體元件,更 包括一低電壓閘極形成於一 p型井上。 13 ·如申凊專利範圍第12項所述之半導體元件,其中該η型井設置於該低電壓閘極之p型井及該高電壓閘 極之p型井之間。 14· 一種半導體元件,包括: 一基板,包括一p型井;以及 一高電壓閘極結構,形成於該P型井之上,其中該 高電閘極壓結構包括一形成於一硼阻障層上之閘極。 15·如申請專利範圍第14項所述之半導體元件,其 中該硼阻障層包括氮化矽(Si3N4)。 16·如申請專利範圍第14項所述之半導體元件,其 0503-A32446TWF/kai 16 200814312 =阻障層包括氮氧化趣(TaA,Nz)、氮氧化結 =他)、氮氧化鋅(Zn〇yNz)、碳化邦抑及氮氧化石夕 h〇yNz)之至少一種材料,其中χ為任何之正整數, ζ為任何之非負整數。 ^ 二·—如申請專利範圍第14項所述之半導體元件,更 包括—氧化層’該氧化層以—氮切層與該?型井隔離。 18.如申請專利範圍帛ί4項所述之半導體元件 广電容器’該電容器包括一下極板、上極板及 電層介於上極板與下極板之間。 19 · 一種半導體元件,包括·· 一電容器,包括: 一第一導電層; ;以及 一導電層之 間 一第二導電層,設置於該第一導電層上 一氮化矽(SisN4)層,設置於該第一及第 其作為一介電層;以及 一高電壓閘極,鄰近該電容器,包括: 一第一氧化層; 一氮化矽(Si3N4)層; 一第二氧化層;以及 該氮化矽(Si3N4) 包括: 一導電層,設置於該第一氧化層 層及該第二氧化層之上。 20· 種半導體元件的製造方法 提供一基板; 其步驟包括: 形成一電容器於該基板上 0503-A32446TWF/kai 17 200814312 形成一第一導電層; 形成—硼阻障層於該第一導電層之上; π第二導電層於該硼阻障層之上,其中該硼阻 p 早層作為—介電層;以及 -厭=!:成一高電壓閑極於該電容器附近,其中該高 ::甲°匕括一硼阻障層,以及-導電層於該硼阻障層 之上。 21.如申請專利範圍第2〇項所述之半導體元件的製 化方法,其中該硼阻障層包括氮化矽(以#4)。 如申°月專利辜巳圍第20項所述之半導體元件的製 二該Λ阻障層包括氮氧化组(τ_、氮氧 化石夕(six〇yNZ、、鼠乳、化辞(Zn〇yNz)、碳化石夕(SixCy)及氮氧 y及z為任何之非負整數。 玉數 23. 如申請專利範圍第如項所述之半導體元件的製 I”卜展其中該高電壓閘極更包括-第-氧化層及-第 —羊 爿,且兩者以該硼阻障層隔離。 24. Μ請專利範圍第%項所述之半導體元件的彭 二声由其^該^器之雜障層及該高電壓閘極之· 丨且丨早層由一早一程序沉積而成。 = ·,=請專利範圍第2〇項所述之半導體元件的製 。方法其中該硼阻障層為一薄膜。 26. $申請專利範圍第2()項所述之半導體元件㈣ ^法,其中該硼阻障層的厚度在100至500A之間。 〇503-A32446TWF/kai 18 200814312 匕括形成一低電壓(LV)閘極於 造方=申請專觸第27項所述之 ^ "中°亥低電閘極包括一硼阻障層。 、生29_如申請專利範圍第20項所述之半導體元件的製 造方法,其中該高電壓閘極形成於一 P型井上。 、 30.如中請專利範圍第2()項所述之半導體元件的製 造方法,其中該電容器形成於―n型井上,且該厚 閘極形成於一 P型井上。 土 31·如申請專利範圍第3〇項所述之半導體元件的製 造方法,更包括一低電壓閘極形成於一 p型井上。衣 32·如申請專利範圍第η項所述之半導體元件的製 造方法,其中該η型井設置於該低電壓閘極之p型井及 該高電壓閘極之p型井之間。 0503-A32446TWF/kai 19
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| US9571093B2 (en) | 2014-09-16 | 2017-02-14 | Navitas Semiconductor, Inc. | Half bridge driver circuits |
| US9647476B2 (en) | 2014-09-16 | 2017-05-09 | Navitas Semiconductor Inc. | Integrated bias supply, reference and bias current circuits for GaN devices |
| US9960154B2 (en) * | 2014-09-19 | 2018-05-01 | Navitas Semiconductor, Inc. | GaN structures |
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| US10431664B2 (en) | 2017-06-30 | 2019-10-01 | Taiwan Semiconductor Manufacturing Co., Ltd. | Gate structure and methods thereof |
| CN113161230B (zh) * | 2020-12-14 | 2022-05-17 | 安徽安芯电子科技股份有限公司 | 磷硼同步一次扩散缓变结芯片的扩散工艺 |
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| US4449224A (en) * | 1980-12-29 | 1984-05-15 | Eliyahou Harari | Dynamic merged load logic (MLL) and merged load memory (MLM) |
| US4598460A (en) * | 1984-12-10 | 1986-07-08 | Solid State Scientific, Inc. | Method of making a CMOS EPROM with independently selectable thresholds |
| US4851361A (en) * | 1988-02-04 | 1989-07-25 | Atmel Corporation | Fabrication process for EEPROMS with high voltage transistors |
| JPH0491469A (ja) * | 1990-08-01 | 1992-03-24 | Sharp Corp | 不揮発性半導体メモリ |
| US5393691A (en) * | 1993-07-28 | 1995-02-28 | Taiwan Semiconductor Manufacturing Company | Fabrication of w-polycide-to-poly capacitors with high linearity |
| US5338701A (en) * | 1993-11-03 | 1994-08-16 | Taiwan Semiconductor Manufacturing Company | Method for fabrication of w-polycide-to-poly capacitors with high linearity |
| US5550072A (en) * | 1994-08-30 | 1996-08-27 | National Semiconductor Corporation | Method of fabrication of integrated circuit chip containing EEPROM and capacitor |
| JPH08125152A (ja) * | 1994-10-28 | 1996-05-17 | Canon Inc | 半導体装置、それを用いた相関演算装置、ad変換器、da変換器、信号処理システム |
| JP3415712B2 (ja) * | 1995-09-19 | 2003-06-09 | 松下電器産業株式会社 | 半導体装置及びその製造方法 |
| US6228708B1 (en) | 1998-12-10 | 2001-05-08 | United Microelectronics Corp. | Method of manufacturing high voltage mixed-mode device |
| EP1014441B1 (en) * | 1998-12-22 | 2009-08-05 | STMicroelectronics S.r.l. | Method for manufacturing EEPROM with periphery |
| JP2001085625A (ja) * | 1999-09-13 | 2001-03-30 | Hitachi Ltd | 半導体集積回路装置およびその製造方法 |
| US6407435B1 (en) * | 2000-02-11 | 2002-06-18 | Sharp Laboratories Of America, Inc. | Multilayer dielectric stack and method |
| US6466427B1 (en) * | 2000-05-31 | 2002-10-15 | Taiwan Semiconductor Manufacturing Co., Ltd. | Microelectronic capacitor structure compatible with copper containing microelectronic conductor layer processing |
| US6498377B1 (en) * | 2002-03-21 | 2002-12-24 | Macronix International, Co., Ltd. | SONOS component having high dielectric property |
| US6853052B2 (en) * | 2002-03-26 | 2005-02-08 | Semiconductor Energy Laboratory Co., Ltd. | Semiconductor device having a buffer layer against stress |
| JP4451594B2 (ja) * | 2002-12-19 | 2010-04-14 | 株式会社ルネサステクノロジ | 半導体集積回路装置及びその製造方法 |
| JP4085891B2 (ja) * | 2003-05-30 | 2008-05-14 | ソニー株式会社 | 半導体装置およびその製造方法 |
| CN100352062C (zh) | 2003-10-30 | 2007-11-28 | 上海集成电路研发中心有限公司 | 一种高介电常数材料栅结构及其制备方法 |
| US7960810B2 (en) | 2006-09-05 | 2011-06-14 | Taiwan Semiconductor Manufacturing Company, Ltd. | Semiconductor device with reliable high-voltage gate oxide and method of manufacture thereof |
-
2006
- 2006-09-05 US US11/515,961 patent/US7960810B2/en not_active Expired - Fee Related
-
2007
- 2007-07-31 TW TW096127977A patent/TWI362110B/zh not_active IP Right Cessation
- 2007-08-16 CN CN2007101410465A patent/CN101140930B/zh not_active Expired - Fee Related
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2011
- 2011-05-09 US US13/103,807 patent/US8338243B2/en not_active Expired - Fee Related
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- 2012-12-21 US US13/724,307 patent/US8669150B2/en not_active Expired - Fee Related
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|---|---|
| CN101140930A (zh) | 2008-03-12 |
| US8338243B2 (en) | 2012-12-25 |
| TWI362110B (en) | 2012-04-11 |
| US20130130451A1 (en) | 2013-05-23 |
| US7960810B2 (en) | 2011-06-14 |
| CN101140930B (zh) | 2010-06-16 |
| US20110212585A1 (en) | 2011-09-01 |
| US8669150B2 (en) | 2014-03-11 |
| US20080054399A1 (en) | 2008-03-06 |
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