JP2010118300A - Glass substrate for flat panel display, and plasma display panel using the same - Google Patents

Abstract

An alignment mark having high accuracy and good visibility can be easily formed without modifying the production line and without greatly increasing the number of man-hours, and a flat panel display can be manufactured with low cost and high productivity. .
A glass substrate for a flat panel display, in which a photosensitive film bx is formed on a glass substrate 21, and at least one of a concave portion and a convex portion is provided on the surface of the photosensitive film bx to position an exposure mask. An alignment mark 51 for alignment is formed.
[Selection] Figure 4

Description

  The present invention relates to a glass substrate for flat panel display on which an alignment mark used for a plasma display panel or the like is formed, and a plasma display panel using the same.

  In recent years, among flat panel displays, a plasma display panel (hereinafter referred to as “PDP”) that can be easily enlarged has become one of the mainstream.

  In a conventional PDP, a large number of discharge cells are formed between a front plate and a back plate arranged to face each other. The front plate has a front glass substrate, a display electrode pair formed of a pair of scan electrodes and sustain electrodes formed on the glass substrate, and a dielectric layer and a protective layer covering them. The back plate includes a glass substrate on the back side, a data electrode formed on the glass substrate, a dielectric layer covering the glass electrode, a partition wall, and a phosphor layer. Then, the front plate and the rear plate are arranged opposite to each other so that the display electrode pair and the data electrode are three-dimensionally crossed and sealed, and a discharge gas is sealed in the internal discharge space. Here, a discharge cell is formed at a portion where the display electrode pair and the data electrode face each other. A gas discharge is generated in each discharge cell of the PDP configured as described above, and red, green, and blue phosphors are excited and emitted to perform color display.

  Each of the scan electrode and the sustain electrode is formed by stacking a narrow striped bus electrode on a wide striped transparent electrode. The transparent electrode is formed by patterning an ITO thin film formed on the entire surface of the glass substrate using a sputtering method or the like into a stripe shape by a photolithography method. At this time, alignment marks for aligning the exposure mask necessary for the subsequent processes are simultaneously formed. The bus electrode is formed by printing a conductive photosensitive paste on a glass substrate on which a transparent electrode and an alignment mark are formed, aligning an exposure mask, exposing, and etching (see, for example, Patent Document 1). ).

  However, in order to form a transparent electrode, a large vacuum apparatus and an expensive ITO target material for forming an ITO thin film by sputtering or the like are necessary. Furthermore, an exposure machine and an exposure mask for etching the ITO thin film by a photolithography method are required, which causes a problem that not only the production equipment becomes large but also the productivity of the PDP is lowered.

Therefore, as a method of configuring a PDP without forming a transparent electrode, a PDP in which a scan electrode and a sustain electrode are formed with a conductive bus electrode is disclosed (for example, see Patent Document 2). However, in a PDP in which no transparent electrode is formed, it is necessary to form alignment marks by other methods. As a method of forming the alignment mark, for example, a method of forming by printing, laser engraving or the like (for example, refer to Patent Document 3), a method of forming with the same material as the bus electrode, and the like are known.
JP 2000-156158 A JP 2004-127951 A JP 2004-130789 A

  Accuracy and visibility are important for alignment marks of flat panel displays. In particular, a high-definition PDP that is becoming mainstream in recent years requires particularly high accuracy. However, in order to manufacture a PDP having an electrode configuration that does not use a transparent electrode, the alignment mark must be formed by another method, and there are problems such as remodeling of the manufacturing line and increase in the number of manufacturing steps.

  For example, although a means for forming an alignment mark using a conventional photosensitive paste or the like is disclosed, it is necessary to separately provide an exposure / development process before the display electrode pair is formed. Will increase significantly.

  When forming a display electrode pair using a conventional photosensitive conductive paste or the like, it is possible to form an alignment mark at the same time as the display electrode pair. However, when the display electrode pair is formed by performing multiple exposures. This method cannot be applied. Actually, when forming the display electrode pair, exposure is performed twice in order to suppress exposure defects due to scratches on the exposure mask and adhesion of dust. At this time, in order to prevent misalignment between the first exposure and the second exposure, an alignment mark for aligning at least the second exposure mask is indispensable.

  In addition, since the photosensitive conductive paste is normally applied as thick as 3 μm to 10 μm, there is a problem that patterning accuracy is low when exposed and developed, and it is difficult to accurately create alignment marks.

  The present invention has been made in view of the above problems, and can easily form an alignment mark having high accuracy and good visibility without remodeling the production line and without greatly increasing the number of man-hours. An object of the present invention is to provide a flat panel display glass substrate and a plasma display panel using the same, which can produce a flat panel display with high productivity.

  In order to achieve the above object, the present invention is a glass substrate for a flat panel display, wherein a photosensitive film is formed on the glass substrate, and at least one of a concave portion and a convex portion is provided on the surface of the photosensitive film. An alignment mark for aligning the exposure mask is formed. This configuration makes it easy to form alignment marks with high accuracy and good visibility without remodeling the production line or significantly increasing the number of man-hours, and manufacturing flat panel displays with low cost and high productivity. The glass substrate for flat panel displays which can be provided can be provided.

  Moreover, this invention is a glass substrate for flat panel displays, Comprising: An exposure mask is aligned by forming a photosensitive film | membrane on a glass substrate and providing a recessed part and a convex part adjacently on the surface of a photosensitive film | membrane. An alignment mark is formed. Even with this configuration, alignment marks with high accuracy and good visibility can be easily formed without modifying the production line and without significantly increasing the number of man-hours. A glass substrate for a flat panel display that can be manufactured can be provided.

  The photosensitive film of the glass substrate for flat panel display of the present invention contains a black material, and the black material preferably has an average particle size of 1 μm or less.

  Moreover, it is desirable that the fluctuation width of the step between the concave portion and the convex portion of the photosensitive film of the glass substrate for flat panel display of the present invention is 0.5 μm or more.

  Moreover, you may expose and provide the recessed part and convex part of the photosensitive film | membrane of the glass substrate for flat panel displays of this invention.

  Moreover, the plasma display panel of this invention is equipped with the glass substrate for flat panel displays in any one of Claims 1-5. This configuration makes it easy to form alignment marks with high accuracy and good visibility without remodeling the production line or significantly increasing the number of man-hours, and manufacturing flat panel displays with low cost and high productivity. A plasma display panel can be provided.

  According to the present invention, an alignment mark having high accuracy and good visibility can be easily formed without remodeling the production line and without greatly increasing the number of man-hours. It is possible to provide a glass substrate for a flat panel display and a plasma display panel that can be manufactured.

  Hereinafter, a manufacturing method of a flat panel display according to an embodiment of the present invention will be described with reference to the drawings, taking a manufacturing method of a PDP as an example.

(Embodiment 1)
FIG. 1 is an exploded perspective view of PDP 10 according to Embodiment 1 of the present invention. The PDP 10 is configured by arranging the front plate 20 and the back plate 30 so as to face each other and sealing the periphery with low-melting glass (not shown), and a large number of discharge cells are formed therein. Yes.

  The front plate 20 includes a front glass substrate 21, a display electrode pair 24 including a scanning electrode 22 and a sustain electrode 23, a dielectric layer 26, and a protective layer 27. A plurality of display electrode pairs 24 in which a discharge gap is formed between a pair of scanning electrodes 22 and sustaining electrodes 23 are formed on the glass substrate 21 in parallel with each other. A dielectric layer 26 is formed so as to cover these display electrode pairs 24, and a protective layer 27 is formed on the dielectric layer 26.

  The back plate 30 has a glass substrate 31 on the back side, a data electrode 32, a dielectric layer 33, a partition wall 34, and a phosphor layer 35. On the glass substrate 31, a plurality of data electrodes 32 are formed in parallel to each other. A dielectric layer 33 is formed so as to cover the data electrode 32, and further, a grid-like partition wall 34 including a vertical partition wall 34 a and a horizontal partition wall 34 b is formed thereon, and the surface of the dielectric layer 33 and the side surface of the partition wall 34 are formed. In addition, phosphor layers 35 of red, green and blue colors are formed.

  The front plate 20 and the back plate 30 are arranged to face each other so that the display electrode pair 24 and the data electrode 32 are three-dimensionally crossed, and a discharge cell is formed at a portion where the display electrode pair 24 and the data electrode 32 face each other. . The front plate 20 and the back plate 30 are sealed using low-melting glass at a position outside the image display area where the discharge cells are formed, and a discharge gas is sealed in the internal discharge space.

  2A and 2B are diagrams showing details of the front plate 20 of the PDP 10 according to Embodiment 1 of the present invention. FIG. 2A is an enlarged view of the front plate 20, and FIG. It is an enlarged view of a cross section.

  The scan electrode 22 includes a bus electrode 221 and a bus electrode 222. The sustain electrode 23 also has a bus electrode 231 and a bus electrode 232. A discharge gap MG is formed between the bus electrode 221 and the bus electrode 231.

  The bus electrodes 221 and 222 are composed of black layers 221b and 222b and conductive layers 221c and 222c, respectively, and the bus electrodes 231 and 232 are also composed of black layers 231b and 232b and conductive layers 231c and 232c. The black layers 221b, 222b, 231b, and 232b are provided to make the scan electrodes 22 and the sustain electrodes 23 appear black when the PDP 10 is viewed from the display surface side. For example, a black material such as ruthenium oxide is applied to the glass substrate 21. It is formed in a narrow stripe shape on top. The conductive layers 221c, 222c, 231c, and 232c are provided to increase the conductivity of the scan electrode 22 and the sustain electrode 23, and a conductive material containing silver on the black layers 221b, 222b, 231b, and 232b. Are formed by laminating.

  In the present embodiment, black paste (hereinafter abbreviated as “black photosensitive paste”), conductive photosensitive paste (hereinafter referred to as “conductive conductive paste”), particularly as various pastes used for manufacturing front plate 20. A dielectric photosensitive paste). Below, the creation method of each paste is demonstrated.

(Black photosensitive paste)
The black photosensitive paste is applied onto the glass substrate 21 and dried to form a first photosensitive film (hereinafter abbreviated as “black photosensitive film”), and then exposed to black layers 221b and 222b. 231b and 232b and a photosensitive paste for forming alignment marks. The black photosensitive paste is composed of an inorganic material component including a black material and glass powder, and an organic material component including a photosensitive polymer, a photosensitive monomer, and a photopolymerization initiator, and the particle size of the black material is 1 μm or less. It is.

  In order to create a black photosensitive paste, an inorganic material composed of a black material and glass powder, and a photosensitive polymer such as a photocurable polymer, a photosensitive monomer, a photopolymerization initiator, and various organic materials such as a solvent are used. It is prepared so as to have a predetermined composition, and is prepared by mixing and dispersing homogeneously.

  As the black material, for example, at least one of oxides such as ruthenium oxide, iron oxide, cobalt oxide, nickel oxide, copper oxide, and manganese dioxide can be used. Here, in order to increase the accuracy of the alignment mark, the average particle diameter of the black pigment is set to 1 μm or less, more desirably 0.01 μm to 0.5 μm. By including these black materials in the paste in an amount of 5 wt% to 40 wt%, good black layers 221b, 222b, 231b, 232b and alignment marks can be formed. If the black material is less than 5 wt%, the color becomes light and the contrast may be lowered. On the other hand, if it is larger than 40 wt%, the softening point of the paste increases, and it becomes difficult to match the thermal expansion coefficient with the glass substrate 21. Further, the ultraviolet rays do not reach the lower part during exposure, and there is a possibility that a black layer may be poorly formed.

  As the glass powder, glass powder containing bismuth oxide as a main component can be used. The average particle size of the glass powder is preferably 0.3 μm to 1.0 μm, and more preferably the maximum particle size is 2.0 μm or less. The composition of the glass powder is 30 wt% to 85 wt% of bismuth oxide, 5 wt% to 30 wt% of silicon oxide, 5 wt% to 20 wt% of boron oxide, 0.1 wt% to 10 wt% of zirconium oxide, and 2 wt% of zinc oxide. It is desirable to contain 20 wt% and aluminum oxide 1 wt% to 5 wt%, respectively. In order to improve the adhesion to the glass substrate, it is desirable to contain 25 wt% to 40 wt% of glass powder in the paste.

  Further, a conductive material may be further included as an inorganic material of the black photosensitive paste. As the conductive material, for example, fine metal particles such as silver, platinum, palladium, cobalt, nickel, manganese, molybdenum, and ruthenium having an average particle diameter of 1 μm or less, more preferably 0.01 μm to 0.5 μm can be used. .

  As an organic material of the black photosensitive paste, it is desirable to use an oligomer or polymer having a weight average molecular weight of 500 to 100,000 having a carboxyl group and an unsaturated double bond in the molecule as the photosensitive polymer. As the photosensitive monomer, a compound containing a carbon-carbon unsaturated bond can be used. By setting the content of these various organic material components to 20 wt% to 60 wt%, a black photosensitive paste with good printing characteristics can be created. In addition to photosensitive polymers, photosensitive monomers, photopolymerization initiators and solvents as organic materials, binders, UV light absorbers, sensitizers, sensitization aids, polymerization inhibitors, plasticizers, sensitizers can be added as necessary. Additives such as a sticking agent, an organic solvent, an antioxidant, a dispersant, a suspending agent, and a leveling agent can also be added.

  The viscosity of the black photosensitive paste is preferably adjusted in the range of 2000 cps to 20000 cps. For example, in order to obtain a black photosensitive film having a film thickness of 5 μm to 20 μm by coating once by screen printing, 50000 cps to 200000 cps is desirable. In order to obtain a black photosensitive film by using a blade coater method or a die coater method, 1500 cps to 20000 cps is desirable. The viscosity of the black photosensitive paste can be adjusted to the above value by the addition ratio of inorganic powder, thickener, organic solvent, plasticizer, suspending agent and the like.

  In this embodiment, 10 wt% of ruthenium oxide having an average particle size of 0.1 μm as a black material, 26 wt% of cobalt tetroxide, 12 wt% of a commercially available glass frit mainly composed of bismuth oxide as a glass powder, organic As a material, a total of 22 wt% of a commercially available photocurable polymer, a photosensitive monomer, and a photopolymerization initiator and 30 wt% of a solvent were mixed, and homogeneously mixed and dispersed with three rollers to prepare a black photosensitive paste.

(Conductive photosensitive paste)
The conductive photosensitive paste is coated on a black photosensitive film on which no alignment mark is formed and dried to form a second photosensitive film (hereinafter abbreviated as “conductive photosensitive film”), and then exposed. This is a material for forming the conductive layers 221c, 222c, 231c, and 232c. The conductive photosensitive paste is composed of an inorganic material component composed of a conductive material mainly composed of silver and glass powder, a photosensitive polymer such as a photocurable polymer, a photosensitive monomer, a photopolymerization initiator, a solvent, and the like. The various organic material components are prepared so as to have a predetermined composition, and then mixed and dispersed homogeneously.

  As the conductive material, in order to form the conductive layers 221c, 222c, 231c, and 232c finely, silver powder having an average particle size of 0.1 μm to 2.0 μm is desirable, and silver powder of 45 wt% or more is contained in the paste. By doing so, a preferable pattern for a conductive layer can be formed.

  As the glass powder, glass powder containing bismuth oxide as a main component can be used. The average particle size of the glass powder is preferably 0.3 μm to 1.0 μm, and more preferably the maximum particle size is 2.0 μm or less. The composition of the glass powder is 30 wt% to 85 wt% bismuth oxide, 5 wt% to 30 wt% silicon oxide, 5 wt% to 20 wt% boron oxide, 0.1 wt% to 10 wt% zirconium oxide, and 2 wt% zinc oxide. It is desirable to contain ˜20 wt% and aluminum oxide 1 wt% ˜5 wt%, respectively. Moreover, in order to improve the adhesiveness to a glass substrate, it is desirable to contain 0.5 wt%-5 wt% glass powder in a paste. In addition, when the above various organic materials are contained in the paste in an amount of 20 wt% to 45 wt%, a conductive photosensitive paste having good printing characteristics can be formed.

  In this embodiment, 69 wt% of silver powder having an average particle diameter of 0.8 μm, 3 wt% of a commercially available glass frit mainly composed of bismuth oxide, a commercially available photocurable polymer, a photosensitive monomer, and photopolymerization start A total of 13 wt% of the agent and 15 wt% of the solvent were prepared, and the mixture was uniformly mixed and dispersed with three rollers to prepare a conductive photosensitive paste.

(Dielectric paste)
The dielectric paste is a material for forming the dielectric layer 26. Dielectric paste is softening point containing some of boron oxide, silicon oxide, zinc oxide, alkaline earth oxide, alkali metal oxide, bismuth oxide, aluminum oxide, molybdenum oxide, tungsten oxide, cerium oxide, etc. It is a paste containing dielectric glass at 520 ° C to 590 ° C.

  In the dielectric layer 26 of the present embodiment, boron oxide 35 wt%, silicon oxide 1.4 wt%, zinc oxide 27.6 wt%, barium oxide 3.3 wt%, bismuth oxide 25 wt%, aluminum oxide 1.1 wt%, A dielectric paste containing dielectric glass containing molybdenum oxide 4.0 wt% and tungsten oxide 3.0 wt% was prepared. The dielectric glass thus prepared has a softening point of about 570 ° C.

  Next, a method for manufacturing the PDP 10 will be described.

  FIG. 3 is a diagram for explaining a method of manufacturing the front plate 20 of the PDP 10 according to Embodiment 1 of the present invention. The manufacturing process of the front plate 20 is divided into the following five processes, and each will be described in detail.

(First step)
In the first step, a black photosensitive paste is applied on the front glass substrate 21 and dried to form a black photosensitive film bx. First, the glass substrate 21 is alkali cleaned. If the glass substrate 21 is a 42-inch PDP, for example, it is a glass substrate having a size of 980 mm × 554 mm and a thickness of 1.8 mm.

  Next, a black photosensitive paste is applied to the entire surface of the glass substrate 21 using a known technique such as a screen printing method and dried to form a black photosensitive film bx. At this time, the black photosensitive paste is also applied to the positions where the alignment marks are formed in the region where the display electrode pair 24 is not formed on the glass substrate 21, in this embodiment, the four corner positions of the glass substrate 21. deep. However, the position where the alignment mark is formed is not limited to the above, and a region where the display electrode pair 24 on the long side of the glass substrate 21 is not formed or the display electrode pair 24 on the short side of the glass substrate 21 is not formed. It may be a region (FIG. 3A).

  Next, a conductive photosensitive film cx is formed at a position where an alignment mark is not formed on the black photosensitive film bx. The conductive photosensitive film cx is formed by applying a conductive photosensitive paste on the black photosensitive film bx of the glass substrate 21 using a known technique such as a screen printing method and drying it. At this time, the conductive photosensitive paste is applied to the positions where the display electrode pairs are not formed on the black photosensitive film bx where the alignment marks are to be formed, that is, the four corner positions of the glass substrate 21 in this embodiment. Not (FIG. 3 (b)).

(Second step)
In the second step, the black photosensitive film bx is exposed using the first exposure mask to form an alignment mark. On the first exposure mask 41, a pattern for forming the bus electrodes 221, 222, 231, 232 and a pattern for forming the alignment mark 51 are formed. Then, the first exposure is performed using the first exposure mask 41. The exposure intensity at this time is, for example, 300 mJ / cm ² . Then, an uneven pattern appears on the surface of the black photosensitive film bx, and these form the alignment mark 51. In this way, the alignment mark 51 is formed on the black photosensitive film bx applied at the four corners of the glass substrate 21, and the scanning electrode 22 and the sustain electrode 23 are formed in the image display area of the glass substrate 21. For the first time. However, since it is before development of the black photosensitive film bx, the alignment mark 51 thus formed appears as an uneven pattern that emerges on the black photosensitive film bx (FIG. 3C).

  FIG. 4 is a diagram showing the alignment mark 51 of the PDP 10 according to the first embodiment of the present invention. FIG. 4A is an enlarged schematic plan view of a portion of the glass substrate 21 where the alignment mark 51 is formed, and FIG. ) Is an enlarged cross-sectional view of a portion of the glass substrate 21 where the alignment mark 51 is formed. FIG. 5 is a diagram showing details of the alignment mark 51 of the PDP 10 according to Embodiment 1 of the present invention. FIG. 5A is a schematic diagram of an image obtained by capturing the alignment mark 51 with a camera, and FIG. Is a diagram showing the relationship between the first exposure mask 41 and the alignment mark 51 of the glass substrate 21, FIG. 5 (c) is a surface roughness meter to measure the shape of the surface along the AA line of FIG. 5 (a) It is a figure which shows the result.

  As described above, the alignment mark 51 forms the black photosensitive film bx formed by applying the black photosensitive paste on the glass substrate 21 and drying it, and at least one of the concave portion and the convex portion is formed on the surface of the black photosensitive film bx. It is formed by providing.

  In the present embodiment, as shown in FIG. 5 (c), the alignment mark 51 is formed by unevenness in which a concave portion and a convex portion are provided adjacent to each other on the surface of the black photosensitive film bx. The irregularities are formed by exposure. The shape of the alignment mark 51 is, for example, a cross shape having a vertical and horizontal length of 3 mm and a width of 160 μm. The convex portion is an exposed region, and it is considered that the photosensitive monomer contained in the black photosensitive film bx is formed by polymerization and curing by exposure to cause volume expansion. Moreover, it is thought that the adjacent convex part and recessed part which arise in the boundary of the area | region exposed and the area | region which is not exposed arise as follows. In the exposed region, the photosensitive monomer is polymerized and cured by exposure, and the concentration of the liquid monomer is lowered. Then, a large concentration gradient of the liquid monomer occurs at the boundary between the non-exposed area and the exposed area, and the liquid monomer diffuses from the non-exposed area to the exposed area. Due to this diffusion, the volume decreases on the side of the non-exposed region near the boundary to form a concave portion, while the exposed region side swells due to the diffused liquid monomer to form a convex portion. In this way, a convex portion is formed on the exposure region side of the boundary between the non-exposure region and the exposure region, and a concave portion is formed on the non-exposure region side, and the optically detectable alignment mark 51 is formed on the surface of the black photosensitive film bx. Is done.

  Immediately after the exposure, the unevenness of the surface of the black photosensitive film bx is relatively small, and the unevenness tends to increase with time. Therefore, in this embodiment, a standing time of 30 min to 60 min is provided after the first exposure.

  The inventor measured the shape of the surface in the vicinity of the alignment mark 51 after the elapse of 60 minutes after exposure with a surface roughness meter. As a result, as shown in FIG. 5C, the step width (= maximum value−minimum value) of the step between the concave and convex portions at the boundary between the exposed region and the non-exposed region is about 0.5 μm to 1.0 μm. It was confirmed that it can be used sufficiently as an alignment mark.

  Further, depending on the degree of diffusion / swelling, there may be a case where only a concave portion or only a convex portion is formed, but if the swing width of the step satisfies the above degree, it is recognized as an alignment mark.

  It is considered that when illumination light is projected onto the alignment mark, the presence of the concave portion or the convex portion causes the reflected light to be contrasted and picked up by the camera so that the shape can be detected.

  In addition to the above, it is also conceivable that the volume is reduced by drying and a step is generated at the boundary between the non-exposed area and the exposed area. Actually, the alignment mark can be formed in a short time by drying the glass substrate after the exposure.

(Third step)
In the third step, the alignment mark 51 is recognized in the state before the development of the black photosensitive film bx, and the second exposure mask 42 for forming the scan electrode 22 and the sustain electrode 23 is aligned, and black A second exposure of the photosensitive film bx is performed. At this time, the alignment mark 51 formed on the surface of the black photosensitive film bx is irradiated with light, and the alignment mark 51 is imaged with a camera to position the second exposure mask. On the second exposure mask 42, a pattern for forming bus electrodes 221, 222, 231, 232 is formed. However, the pattern formed on the second exposure mask 42 is designed to be slightly narrower than the pattern width of the first exposure mask 41. In this embodiment, the pattern is formed on the first exposure mask 41. A pattern that is about 20% narrower than the pattern width of the bus electrodes 221, 222, 231, and 232 is formed on the second exposure mask 42. At this time, if the wavelength width of the light irradiating the alignment mark 51 is too wide, the alignment mark 51 cannot be imaged with high accuracy. Therefore, it is desirable to use an LED having a narrower wavelength width than a tungsten lamp or the like as illumination. The second exposure intensity is, for example, 200 mJ / cm ² (FIG. 3D).

  By repeating the exposure for forming the bus electrodes 221, 222, 231, and 232 twice as described above, exposure defects due to scratches and dust adhesion on the exposure masks 41 and 42 can be suppressed to substantially zero. At this time, in order to prevent a positional shift between the first exposure and the second exposure, the alignment of the second exposure mask 42 is performed using the alignment mark formed by the first exposure. Furthermore, since the electrode pattern of the second exposure mask 42 is designed to be slightly narrower than the width of the electrode pattern of the first exposure mask 41, the electrode to be formed even if a slight positional deviation occurs. The shape of is not greatly damaged.

(4th process)
In the fourth step, the black photosensitive film bx is developed to form the scan electrode 22 and the sustain electrode 23. Specifically, the black photosensitive film bx is developed and the precursors 221bx, 222bx, 231bx, 232bx of the black layers 221b, 222b, 231b, 232b and the precursors 221cx, 222cx of the conductive layers 221c, 222c, 231c, 232c 231cx and 232cx are formed. Note that the alignment mark 51 does not necessarily remain on the glass substrate 21 after development. However, when the second exposure mask 42 is used for the second exposure, the alignment mark 51 is also exposed through the positioning hole of the second exposure mask 42. Therefore, the alignment mark 51 is usually on the glass substrate 21. (FIG. 3E).

  Next, the glass substrate 21 on which the precursors 221bx, 222bx, 231bx, and 232bx of the black layers 221b, 222b, 231b, and 232b and the precursors 221cx, 222cx, 231cx, and 232cx of the conductive layers 221c, 222c, 231c, and 232c are formed. And the bus electrodes 221, 222, 231, 232 are formed. The peak temperature of the firing at this time is desirably 550 ° C. to 600 ° C., and is 580 ° C. in this embodiment. The thicknesses of the bus electrodes 221, 222, 231, 232 are preferably 1 μm to 6 μm, and in this embodiment, 4 μm (FIG. 3F).

(5th process)
In the fifth step, a dielectric paste is applied onto the glass substrate 21 on which the bus electrodes 221, 222, 231, and 232 are formed by a known technique such as a screen printing method or a die coating method, and is dried to form the dielectric layer 26. To form a precursor. Then, the precursor of the dielectric layer 26 is fired to form the dielectric layer 26 having a thickness of 20 μm to 50 μm. In the present embodiment, the precursor of the dielectric layer 26 was baked at about 590 ° C. to form the dielectric layer 26 having a thickness of about 40 μm (FIG. 3G).

  A protective layer 27 containing magnesium oxide as a main component was formed on the dielectric layer 26 by a known technique such as a vacuum deposition method (FIG. 3 (h)).

  In this way, the front plate 20 is completed.

  Next, a method for manufacturing the back plate 30 will be described. FIG. 6 is a diagram for explaining a method of manufacturing the back plate 30 of the PDP 10 according to Embodiment 1 of the present invention.

  First, the glass substrate 31 on the back side is washed with alkali (FIG. 6A).

  Next, using a known technique such as a screen printing method or a photolithography method, a conductive photosensitive paste mainly composed of silver is applied in a stripe pattern on the glass substrate 31 at regular intervals, and a precursor of the data electrode 32 is obtained. Form the body. Next, the glass substrate 31 on which the precursor of the data electrode 32 is formed is baked to form the data electrode 32. The thickness of the data electrode 32 is, for example, 2 μm to 10 μm, and 3 μm in the present embodiment (FIG. 6B).

  Subsequently, a dielectric paste is applied on the glass substrate 31 on which the data electrodes 32 are formed, and then baked to form the dielectric layer 33. The thickness of the dielectric layer 33 is, for example, about 5 μm to 15 μm, and is 10 μm in the present embodiment (FIG. 6C).

  Subsequently, a photosensitive dielectric paste is applied on the glass substrate 31 on which the dielectric layer 33 is formed, and then baked to form a precursor of the partition wall 34. Thereafter, exposure is performed using an exposure mask, and development is performed to form partition walls 34. The height of the partition wall 34 formed in this way is, for example, 100 μm to 150 μm, and 120 μm in this embodiment (FIG. 6D).

  Then, a phosphor ink containing any one of a red phosphor, a green phosphor, and a blue phosphor is applied to the wall surface of the partition wall 34 and the surface of the dielectric layer 33. Thereafter, the phosphor layer 35 is formed by drying and baking (FIG. 6E).

Examples of the red phosphor include (Y, Gd) BO ₃ : Eu and (Y, V) PO ₄ : Eu, and examples of the green phosphor include Zn ₂ SiO ₄ : Mn and (Y, Gd) BO _3. : Tb, (Y, Gd) Al ₃ (BO ₃ ) ₄ : Tb, etc., and as the blue phosphor, for example, BaMgAl ₁₀ O ₁₇ : Eu, Sr ₃ MgSi ₂ O ₈ : Eu, etc. can be used, respectively.

  In this way, the back plate 30 is completed.

  Then, the front plate 20 and the back plate 30 are arranged to face each other so that the display electrode pair 24 and the data electrode 32 are three-dimensionally crossed, and low melting glass is used at a position outside the image display area where the discharge cells are formed. Seal. Thereafter, a discharge gas containing xenon is sealed in the internal discharge space, and the PDP 10 is completed.

  As described above, in the present embodiment, the alignment mark 51 can be formed simultaneously with the first exposure only by changing the pattern of the first exposure mask 41 used when forming the display electrode pair 24. Therefore, the front plate 20 can be created without modifying the production line and without greatly increasing the number of steps.

(Embodiment 2)
The structure of the PDP in the second embodiment is the same as the structure of the PDP shown in FIGS. Various pastes used are the same as those in the first embodiment. The second embodiment is different from the first embodiment in that a black photosensitive paste is applied to the glass substrate 21 and dried, and then exposure for forming alignment marks is performed, and then the conductive photosensitive paste is applied. Is a point.

  FIG. 7 is a diagram for explaining a method of manufacturing the front plate 20 of the PDP 10 in the second embodiment of the present invention. The manufacturing process of the front plate 20 is divided into the following five processes, and each will be described in detail.

(First step)
In the first step, a black photosensitive paste is applied on the front glass substrate 21 and dried to form a black photosensitive film bx.

  First, the glass substrate 21 is alkali cleaned. Next, a black photosensitive film bx is formed on the glass substrate 21. The black photosensitive film bx is formed by applying a black photosensitive paste to the entire surface of the glass substrate 21 using a known technique such as a screen printing method and drying it.

  At this time, the black photosensitive paste is also applied to the positions on the glass substrate 21 where the display electrode pairs are not formed and the positions where the alignment marks are to be formed, that is, the four corner positions of the glass substrate 21 in this embodiment. (FIG. 7A). The steps so far are the same as in the first embodiment.

(Second step)
In the second step, the black photosensitive film bx is exposed to form at least a first alignment mark and a second alignment mark.

Specifically, exposure for forming the first alignment mark 56 and the second alignment mark 57 is performed using the first exposure mask 45 dedicated to the alignment mark. At this time, two alignment marks 56 and 57 are formed for each of the four corner positions of the glass substrate 21 in response to performing exposure twice when forming the electrodes. The first alignment mark 56 and the second alignment mark 57 thus formed appear on the black photosensitive film bx. The exposure intensity at this time is, for example, 300 mJ / cm ² (FIG. 7B).

  Next, a conductive photosensitive film cx is formed at a position on the black photosensitive film bx where the first alignment mark and the second alignment mark are not formed. The conductive photosensitive film cx is formed by applying the above-described conductive photosensitive paste onto the black photosensitive film bx of the glass substrate 21 using a known technique such as a screen printing method and drying. At this time, the conductive photosensitive paste is not applied to the position where the alignment mark is formed (FIG. 7C).

  As described above, the unevenness on the surface of the black photosensitive film bx is relatively small immediately after the exposure of the alignment mark, and a certain amount of time is required until the alignment mark can be used. However, in the second embodiment, after the exposure for forming the alignment mark is performed, the glass substrate 21 is dried when the conductive photosensitive film cx is formed. Therefore, the alignment mark is formed in a short time.

(Third step)
In the third step, the first alignment mark 56 is recognized, the second exposure mask 46 is aligned, and the first exposure for forming the scan electrode 22 and the sustain electrode 23 is performed. Specifically, the first alignment mark 56 formed on the surface of the black photosensitive film bx is irradiated with light, the first alignment mark 56 is imaged with a camera, and the second exposure mask 46 is positioned. Do. At this time, it is desirable to use illumination such as LED. On the second exposure mask 46, a pattern for forming the bus electrodes 221, 222, 231, 232 is formed. The exposure intensity at this time is, for example, 200 mJ / cm ² (FIG. 7D).

Thereafter, the second alignment mark 57 is recognized, the third exposure mask 47 is aligned, and the second exposure for forming the scan electrode 22 and the sustain electrode 23 is performed. Specifically, the second alignment mark 57 formed on the surface of the black photosensitive film bx is read by a camera, and the third exposure mask 47 is positioned. At this time, it is desirable to use illumination such as LED. On the third exposure mask 47, a pattern for forming bus electrodes 221, 222, 231, 232 is formed. However, the pattern formed on the third exposure mask 47 is designed to be slightly narrower than the pattern width of the second exposure mask 46. The exposure intensity at this time is, for example, 200 mJ / cm ² (FIG. 7E).

  Thereafter, development is performed to form precursors 221bx, 222bx, 231bx, 232bx of black layers 221b, 222b, 231b, 232b and precursors 221cx, 222cx, 222cx, 232cx of conductive layers 221c, 222c, 231c, 232c ( FIG. 7 (f)).

  Next, the glass substrate 21 on which the precursors 221bx, 222bx, 231bx, and 232bx of the black layers 221b, 222b, 231b, and 232b and the precursors 221cx, 222cx, 231cx, and 232cx of the conductive layers 221c, 222c, 231c, and 232c are formed. Is fired to form bus electrodes 221, 222, 231, 232 (FIG. 7G).

(5th process)
Next, a dielectric paste is applied onto the glass substrate 21 on which the bus electrodes 221, 222, 231, and 232 are formed by a known technique such as a screen printing method or a die coating method, and dried to form a precursor of the dielectric layer 26. Form the body. And the precursor of the dielectric material layer 26 is baked, and the dielectric material layer 26 with a thickness of 20 micrometers-50 micrometers is formed (FIG.7 (h)).

  A protective layer 27 containing magnesium oxide as a main component was formed on the dielectric layer 26 by a known technique such as a vacuum deposition method (FIG. 7 (i)).

  Then, the front plate 20 produced as described above and the rear plate 30 produced in the same manner as in the first embodiment are arranged to face each other so that the display electrode pair 24 and the data electrode 32 are three-dimensionally crossed. Sealing is performed using low-melting glass at a position outside the formed image display area. Thereafter, a discharge gas containing xenon is sealed in the internal discharge space, and the PDP 10 is completed.

  As described above, the second embodiment has an advantage that the exposure can be performed without providing a standing time, although the number of steps for forming the first alignment mark 56 and the second alignment mark 57 is increased. The method for manufacturing a PDP in the second embodiment is particularly useful when manufacturing a PDP in which a black stripe is provided between adjacent display electrode pairs 24. By providing the alignment mark pattern on the exposure mask for forming the black stripe, the alignment mark can be formed simultaneously with the exposure of the black stripe, so that the front plate 20 can be formed without increasing the number of steps.

  In the first and second embodiments of the present invention, as shown in FIG. 2, scan electrode 22 includes bus electrode 221 and bus electrode 222, and sustain electrode 23 includes bus electrode 231 and bus electrode 232. It was described as being composed of However, the present invention is not limited to this.

  FIG. 8 is a diagram showing details of another shape of the display electrode pair of the PDP in the first or second embodiment of the present invention. The scan electrode 62 corresponds to one of the ladder-shaped long trees and defines the discharge gap MG, and the scan electrode 62 corresponds to the other of the ladder-shaped long trees and the bus electrode for increasing the conductivity of the scan electrode 62. 622 and a bus electrode 623 which corresponds to a ladder-shaped cross and for reducing the resistance between the bus electrode 621 and the bus electrode 622. Similarly, sustain electrode 63 corresponds to one of the ladder-shaped long vertical trees and corresponds to the other one of the ladder-shaped long vertical trees and the other of the long ladder-shaped vertical trees, and increases the conductivity of sustain electrode 63. A bus electrode 632 and a bus electrode 633 corresponding to a ladder-shaped rung for reducing the resistance between the bus electrode 631 and the bus electrode 632 are provided.

  By configuring the scan electrode 62 and the sustain electrode 63 in such a shape, the resistance between the bus electrode 621 and the bus electrode 622 and the resistance between the bus electrode 631 and the bus electrode 632 can be lowered. A more stable discharge can be generated. FIG. 8 shows an example in which one bus electrode 623 and 633 is provided for each discharge cell. However, the bus electrodes 623 and 633 may be appropriately provided as necessary, for example, one bus electrode is provided for three discharge cells.

  In the first and second embodiments of the present invention, the method of manufacturing the PDP 10 that manufactures the front plate 20 and the back plate 30 for each PDP using a glass substrate that is the size of one PDP has been described as an example. However, the present invention is not limited to this. For example, a so-called multi-chamfer PDP manufacturing method in which a plurality of front plates 20 and a back plate 30 are manufactured at a time using a glass substrate having a size corresponding to a plurality of PDPs, such as four PDPs or six PDPs. Can also be applied.

(Embodiment 3)
FIG. 9 is a diagram showing details of the alignment mark 81 of the PDP according to the third embodiment of the present invention. FIG. 9A is a schematic diagram of an image obtained by capturing the alignment mark 81 with a camera, and FIG. The figure which shows the relationship between the 1st exposure mask 71 and the alignment mark 81 of the glass substrate 21, FIG.9 (c) measured the shape of the surface along the AA line of Fig.9 (a) with the surface roughness meter. It is a figure which shows a result. The feature of the alignment mark 81 in the third embodiment is that the cross-shaped contour is an unexposed portion. When exposure is performed using the first exposure mask 71 having the cross-shaped contour as an unexposed portion as shown in FIG. 9B, the cross-shaped contour is deep as shown in FIG. 9C. It becomes a recess. Therefore, when the alignment mark 81 is imaged with a camera, a clear image of the alignment mark 81 can be obtained.

  It should be noted that the specific numerical values used in the first to third embodiments are merely examples, and are desirably set to optimal values as appropriate according to the specifications of the PDP.

  According to the glass substrate for flat panel display of the present invention and the plasma display panel using the same, the alignment mark having high accuracy and good visibility can be obtained without remodeling the production line and without greatly increasing the number of steps. Since it can be formed easily and a flat panel display can be manufactured with low cost and high productivity, it is useful as a flat panel display such as a plasma display panel.

The exploded perspective view of PDP in Embodiment 1 of this invention The figure which shows the detail of the front plate of the PDP The figure for demonstrating the manufacturing method of the front plate of the PDP The figure which shows the alignment mark of the PDP The figure which shows the detail of the alignment mark of the PDP The figure for demonstrating the manufacturing method of the backplate of the PDP The figure for demonstrating the manufacturing method of the front plate of PDP in Embodiment 2 of this invention. The figure which shows the detail of the other shape of the display electrode pair of PDP in Embodiment 1 or 2 of this invention The figure which shows the detail of the alignment mark of PDP in Embodiment 3 of this invention

Explanation of symbols

10 PDP
DESCRIPTION OF SYMBOLS 20 Front plate 21 (front side) glass substrate 22, 62 Scan electrode 23, 63 Sustain electrode 24 Display electrode pair 26 Dielectric layer 27 Protective layer 30 Back plate 31 (Back side) Glass substrate 32 Data electrode 33 Dielectric layer 34 partition wall 35 phosphor layer 41, 45, 71 (first) exposure mask 42, 46 (second) exposure mask 47 third exposure mask 51, 56, 57, 81 alignment mark 221, 222, 231, 232 , 621, 622, 623, 631, 632, 633 Bus electrodes 221b, 222b, 231b, 232b Black layers 221bx, 222bx, 231bx, 232bx Black layer precursors 221c, 222c, 231c, 232c Conductive layers 221cx, 222cx, 231cx, 232cx Precursor of conductive layer bx Black photosensitive film cx Conductive Photosensitive film MG discharge gap

Claims (6)

A glass substrate for a flat panel display,
A flat characterized in that a photosensitive film is formed on the glass substrate, and an alignment mark for aligning an exposure mask is formed by providing at least one of a concave portion and a convex portion on the surface of the photosensitive film. Glass substrate for panel display. A glass substrate for a flat panel display,
A flat characterized in that a photosensitive film is formed on the glass substrate, and an alignment mark for aligning an exposure mask is formed by providing a concave portion and a convex portion adjacent to the surface of the photosensitive film. Glass substrate for panel display. The glass substrate for a flat panel display according to claim 1, wherein the photosensitive film includes a black material, and the black material has an average particle size of 1 μm or less. The glass substrate for a flat panel display according to claim 2, wherein a swing width of a step between the concave portion and the convex portion of the photosensitive film is 0.5 µm or more. The glass substrate for a flat panel display according to claim 2, wherein the concave portion and the convex portion of the photosensitive film are provided by being exposed. The plasma display panel provided with the glass substrate for flat panel displays in any one of Claims 1-5.