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GB1082364A - Method for the preparation of linalool - Google Patents

Method for the preparation of linalool

Info

Publication number
GB1082364A
GB1082364A GB1152064A GB1152064A GB1082364A GB 1082364 A GB1082364 A GB 1082364A GB 1152064 A GB1152064 A GB 1152064A GB 1152064 A GB1152064 A GB 1152064A GB 1082364 A GB1082364 A GB 1082364A
Authority
GB
United Kingdom
Prior art keywords
linalool
epoxide
preparation
hydrazine
solution
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB1152064A
Inventor
Govindan Velayudhan Nair
Gopalkrishna Dattaram Pandit
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Unilever PLC
Original Assignee
Unilever PLC
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Unilever PLC filed Critical Unilever PLC
Priority to GB1152064A priority Critical patent/GB1082364A/en
Publication of GB1082364A publication Critical patent/GB1082364A/en
Expired legal-status Critical Current

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07DHETEROCYCLIC COMPOUNDS
    • C07D303/00Compounds containing three-membered rings having one oxygen atom as the only ring hetero atom
    • C07D303/02Compounds containing oxirane rings
    • C07D303/12Compounds containing oxirane rings with hydrocarbon radicals, substituted by singly or doubly bound oxygen atoms
    • C07D303/32Compounds containing oxirane rings with hydrocarbon radicals, substituted by singly or doubly bound oxygen atoms by aldehydo- or ketonic radicals

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Epoxy Compounds (AREA)

Abstract

Linalool is prepared by epoxidizing citral to the mono-a ,b -epoxide and reducing the epoxide with hydrazine to give linalool. Epoxidation is effected using an alkaline solution of hydrogen peroxide in the presence of an alkanol. The reduction of the epoxide may be carried out using a solution of hydrazine hydrate in an inert solvent, preferably in the presence of an acidic catalyst at temperatures below 30 DEG C. Examples are provided.
GB1152064A 1964-03-18 1964-03-18 Method for the preparation of linalool Expired GB1082364A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
GB1152064A GB1082364A (en) 1964-03-18 1964-03-18 Method for the preparation of linalool

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
GB1152064A GB1082364A (en) 1964-03-18 1964-03-18 Method for the preparation of linalool

Publications (1)

Publication Number Publication Date
GB1082364A true GB1082364A (en) 1967-09-06

Family

ID=9987748

Family Applications (1)

Application Number Title Priority Date Filing Date
GB1152064A Expired GB1082364A (en) 1964-03-18 1964-03-18 Method for the preparation of linalool

Country Status (1)

Country Link
GB (1) GB1082364A (en)

Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB2383327A (en) * 2001-12-19 2003-06-25 Flexitral Inc Improved citral derivatives
EP1705171A1 (en) * 2001-12-19 2006-09-27 Flexitral, Inc. Improved aromachemicals
US7309795B2 (en) 2001-12-19 2007-12-18 Luca Turin Citral derivatives
US7342042B2 (en) 2001-12-19 2008-03-11 Flexitral, Inc. Lily of the valley aromachemicals
CN113185401A (en) * 2021-04-20 2021-07-30 金溪华香香料有限公司 Synthesis process of linalyl acetate

Cited By (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB2383327A (en) * 2001-12-19 2003-06-25 Flexitral Inc Improved citral derivatives
WO2003053901A1 (en) * 2001-12-19 2003-07-03 Flexitral, Inc. Improved citral derivatives
WO2003053903A1 (en) * 2001-12-19 2003-07-03 Flexitral, Inc. Improved citral derivatives
WO2003053902A1 (en) * 2001-12-19 2003-07-03 Flexitral, Inc. Improved aromachemicals
GB2383327B (en) * 2001-12-19 2004-12-08 Flexitral Inc Improved citral derivatives
EP1705171A1 (en) * 2001-12-19 2006-09-27 Flexitral, Inc. Improved aromachemicals
US7309795B2 (en) 2001-12-19 2007-12-18 Luca Turin Citral derivatives
US7342042B2 (en) 2001-12-19 2008-03-11 Flexitral, Inc. Lily of the valley aromachemicals
US7704941B2 (en) 2001-12-19 2010-04-27 Flexitral, Inc. Citral derivatives
CN113185401A (en) * 2021-04-20 2021-07-30 金溪华香香料有限公司 Synthesis process of linalyl acetate

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