ES404875A1 - PROCEDURE FOR THE PRODUCTION OF 5-PHENYL-1, 3, 4, 4A, 5,9B-HEXAHYDRO-2H-INDENE (1,2-C) PYRIDINES. - Google Patents
PROCEDURE FOR THE PRODUCTION OF 5-PHENYL-1, 3, 4, 4A, 5,9B-HEXAHYDRO-2H-INDENE (1,2-C) PYRIDINES.Info
- Publication number
- ES404875A1 ES404875A1 ES404875A ES404875A ES404875A1 ES 404875 A1 ES404875 A1 ES 404875A1 ES 404875 A ES404875 A ES 404875A ES 404875 A ES404875 A ES 404875A ES 404875 A1 ES404875 A1 ES 404875A1
- Authority
- ES
- Spain
- Prior art keywords
- hydrogen atoms
- trans
- pyridines
- indene
- hexahydro
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 238000004519 manufacturing process Methods 0.000 title abstract 2
- 238000000034 method Methods 0.000 title abstract 2
- RQMWVVBHJMUJNZ-UHFFFAOYSA-N 4-chloropyridin-2-amine Chemical compound NC1=CC(Cl)=CC=N1 RQMWVVBHJMUJNZ-UHFFFAOYSA-N 0.000 title 1
- 125000004435 hydrogen atom Chemical class [H]* 0.000 abstract 5
- 150000001875 compounds Chemical class 0.000 abstract 2
- WKBOTKDWSSQWDR-UHFFFAOYSA-N Bromine atom Chemical compound [Br] WKBOTKDWSSQWDR-UHFFFAOYSA-N 0.000 abstract 1
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 abstract 1
- PXGOKWXKJXAPGV-UHFFFAOYSA-N Fluorine Chemical compound FF PXGOKWXKJXAPGV-UHFFFAOYSA-N 0.000 abstract 1
- 125000000217 alkyl group Chemical group 0.000 abstract 1
- GDTBXPJZTBHREO-UHFFFAOYSA-N bromine Substances BrBr GDTBXPJZTBHREO-UHFFFAOYSA-N 0.000 abstract 1
- 229910052794 bromium Inorganic materials 0.000 abstract 1
- 229910052801 chlorine Inorganic materials 0.000 abstract 1
- 239000000460 chlorine Substances 0.000 abstract 1
- 229910052731 fluorine Inorganic materials 0.000 abstract 1
- 239000011737 fluorine Substances 0.000 abstract 1
- 239000001257 hydrogen Substances 0.000 abstract 1
- 229910052739 hydrogen Inorganic materials 0.000 abstract 1
- 239000000203 mixture Substances 0.000 abstract 1
- 229920000137 polyphosphoric acid Polymers 0.000 abstract 1
- 150000003222 pyridines Chemical class 0.000 abstract 1
Landscapes
- Pyridine Compounds (AREA)
- Heterocyclic Carbon Compounds Containing A Hetero Ring Having Oxygen Or Sulfur (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
Abstract
Process for the production of 5-phenyl-1,3,4,4a, 5,9b-hexahydro-2H-indene [1,2-c] pyridines, of general formula Ic, **(See formula)** wherein R1II signifies hydrogen, a lower alkyl or alkenyl radical, and R2 signifies chlorine, bromine, fluorine, or a lower alkyl radical, characterized in that a compound of formula IIId is cyclized. **(See formula)** wherein R1II and R2 have the above meanings, with polyphosphoric acid, and, if desired, mixtures of compounds are separated where the 4a/5 hydrogen atoms are trans and the 4a/9b hydrogen atoms are trans and wherein the 4a/5 hydrogen atoms are trans and the 4a/9b hydrogen atoms are cis in order to isolate one isomer or each of the isomers. (Machine-translation by Google Translate, not legally binding)
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CH525869A CH513864A (en) | 1969-04-08 | 1969-04-08 | New heterocyclic antiphlogistic compounds |
| CH889169 | 1969-06-11 | ||
| CH1361069 | 1969-09-09 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| ES404875A1 true ES404875A1 (en) | 1976-01-01 |
Family
ID=27175150
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| ES404875A Expired ES404875A1 (en) | 1969-04-08 | 1972-07-14 | PROCEDURE FOR THE PRODUCTION OF 5-PHENYL-1, 3, 4, 4A, 5,9B-HEXAHYDRO-2H-INDENE (1,2-C) PYRIDINES. |
Country Status (1)
| Country | Link |
|---|---|
| ES (1) | ES404875A1 (en) |
-
1972
- 1972-07-14 ES ES404875A patent/ES404875A1/en not_active Expired
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