CN106009203A - Creep-resistant antistatic palm fiber-reinforced polyethylene composite material and preparation method thereof - Google Patents
Creep-resistant antistatic palm fiber-reinforced polyethylene composite material and preparation method thereof Download PDFInfo
- Publication number
- CN106009203A CN106009203A CN201610643074.6A CN201610643074A CN106009203A CN 106009203 A CN106009203 A CN 106009203A CN 201610643074 A CN201610643074 A CN 201610643074A CN 106009203 A CN106009203 A CN 106009203A
- Authority
- CN
- China
- Prior art keywords
- polyethylene
- weight
- parts
- temperature
- creep
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- -1 polyethylene Polymers 0.000 title claims abstract description 88
- 229920000573 polyethylene Polymers 0.000 title claims abstract description 47
- 239000004698 Polyethylene Substances 0.000 title claims abstract description 46
- 239000002131 composite material Substances 0.000 title claims abstract description 21
- 238000002360 preparation method Methods 0.000 title claims abstract description 15
- TWRXJAOTZQYOKJ-UHFFFAOYSA-L Magnesium chloride Chemical compound [Mg+2].[Cl-].[Cl-] TWRXJAOTZQYOKJ-UHFFFAOYSA-L 0.000 claims abstract description 18
- 239000000463 material Substances 0.000 claims abstract description 14
- 238000002156 mixing Methods 0.000 claims abstract description 13
- 239000004695 Polyether sulfone Substances 0.000 claims abstract description 11
- 229920006393 polyether sulfone Polymers 0.000 claims abstract description 11
- 239000000843 powder Substances 0.000 claims abstract description 11
- 239000010425 asbestos Substances 0.000 claims abstract description 10
- 239000010445 mica Substances 0.000 claims abstract description 10
- 229910052618 mica group Inorganic materials 0.000 claims abstract description 10
- 239000002994 raw material Substances 0.000 claims abstract description 10
- 229910052895 riebeckite Inorganic materials 0.000 claims abstract description 10
- 239000004205 dimethyl polysiloxane Substances 0.000 claims abstract description 9
- 229910001629 magnesium chloride Inorganic materials 0.000 claims abstract description 9
- 229920000435 poly(dimethylsiloxane) Polymers 0.000 claims abstract description 9
- 239000000835 fiber Substances 0.000 claims abstract description 6
- 240000000961 Setaria parviflora Species 0.000 claims description 18
- 239000004812 Fluorinated ethylene propylene Substances 0.000 claims description 12
- HQQADJVZYDDRJT-UHFFFAOYSA-N ethene;prop-1-ene Chemical group C=C.CC=C HQQADJVZYDDRJT-UHFFFAOYSA-N 0.000 claims description 12
- 229920009441 perflouroethylene propylene Polymers 0.000 claims description 12
- LYRFLYHAGKPMFH-UHFFFAOYSA-N Amide-Octadecanoic acid Natural products CCCCCCCCCCCCCCCCCC(N)=O LYRFLYHAGKPMFH-UHFFFAOYSA-N 0.000 claims description 8
- FMRHJJZUHUTGKE-UHFFFAOYSA-N Ethylhexyl salicylate Chemical compound CCCCC(CC)COC(=O)C1=CC=CC=C1O FMRHJJZUHUTGKE-UHFFFAOYSA-N 0.000 claims description 8
- VZCYOOQTPOCHFL-OWOJBTEDSA-N Fumaric acid Natural products OC(=O)\C=C\C(O)=O VZCYOOQTPOCHFL-OWOJBTEDSA-N 0.000 claims description 8
- 235000021355 Stearic acid Nutrition 0.000 claims description 8
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 claims description 8
- 229910052782 aluminium Inorganic materials 0.000 claims description 8
- 239000004411 aluminium Substances 0.000 claims description 8
- FYIBPWZEZWVDQB-UHFFFAOYSA-N dicyclohexyl carbonate Chemical compound C1CCCCC1OC(=O)OC1CCCCC1 FYIBPWZEZWVDQB-UHFFFAOYSA-N 0.000 claims description 8
- 229940068171 ethyl hexyl salicylate Drugs 0.000 claims description 8
- 239000001530 fumaric acid Substances 0.000 claims description 8
- 229940057995 liquid paraffin Drugs 0.000 claims description 8
- QIQXTHQIDYTFRH-UHFFFAOYSA-N octadecanoic acid Chemical compound CCCCCCCCCCCCCCCCCC(O)=O QIQXTHQIDYTFRH-UHFFFAOYSA-N 0.000 claims description 8
- OQCDKBAXFALNLD-UHFFFAOYSA-N octadecanoic acid Natural products CCCCCCCC(C)CCCCCCCCC(O)=O OQCDKBAXFALNLD-UHFFFAOYSA-N 0.000 claims description 8
- 229940037312 stearamide Drugs 0.000 claims description 8
- 239000008117 stearic acid Substances 0.000 claims description 8
- VZCYOOQTPOCHFL-UHFFFAOYSA-N trans-butenedioic acid Natural products OC(=O)C=CC(O)=O VZCYOOQTPOCHFL-UHFFFAOYSA-N 0.000 claims description 8
- 239000005543 nano-size silicon particle Substances 0.000 claims description 7
- 239000000203 mixture Substances 0.000 claims description 6
- 229920005989 resin Polymers 0.000 claims description 6
- 239000011347 resin Substances 0.000 claims description 6
- UDFARPRXWMDFQU-UHFFFAOYSA-N 2,6-ditert-butyl-4-[(3,5-ditert-butyl-4-hydroxyphenyl)methylsulfanylmethyl]phenol Chemical compound CC(C)(C)C1=C(O)C(C(C)(C)C)=CC(CSCC=2C=C(C(O)=C(C=2)C(C)(C)C)C(C)(C)C)=C1 UDFARPRXWMDFQU-UHFFFAOYSA-N 0.000 claims description 5
- SSKNCQWPZQCABD-UHFFFAOYSA-N 2-[2-[2-(2-heptanoyloxyethoxy)ethoxy]ethoxy]ethyl heptanoate Chemical compound CCCCCCC(=O)OCCOCCOCCOCCOC(=O)CCCCCC SSKNCQWPZQCABD-UHFFFAOYSA-N 0.000 claims description 5
- 150000001412 amines Chemical class 0.000 claims description 4
- 150000001875 compounds Chemical class 0.000 claims description 3
- 238000007599 discharging Methods 0.000 claims description 3
- 238000002347 injection Methods 0.000 claims description 3
- 239000007924 injection Substances 0.000 claims description 3
- 238000001746 injection moulding Methods 0.000 claims description 3
- 238000012986 modification Methods 0.000 claims description 3
- 230000004048 modification Effects 0.000 claims description 3
- 238000000465 moulding Methods 0.000 claims description 3
- 238000005453 pelletization Methods 0.000 claims description 3
- 238000003756 stirring Methods 0.000 claims description 3
- 238000010792 warming Methods 0.000 claims description 3
- 238000009833 condensation Methods 0.000 claims description 2
- 230000005494 condensation Effects 0.000 claims description 2
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims 2
- 240000007594 Oryza sativa Species 0.000 claims 1
- 235000007164 Oryza sativa Nutrition 0.000 claims 1
- 235000009566 rice Nutrition 0.000 claims 1
- 239000000377 silicon dioxide Substances 0.000 claims 1
- 235000012239 silicon dioxide Nutrition 0.000 claims 1
- 239000000945 filler Substances 0.000 abstract description 2
- 229920006172 Tetrafluoroethylene propylene Polymers 0.000 abstract 2
- 229920001223 polyethylene glycol Polymers 0.000 abstract 2
- UWHCKJMYHZGTIT-UHFFFAOYSA-N tetraethylene glycol Chemical compound OCCOCCOCCOCCO UWHCKJMYHZGTIT-UHFFFAOYSA-N 0.000 abstract 2
- RSWGJHLUYNHPMX-UHFFFAOYSA-N Abietic-Saeure Natural products C12CCC(C(C)C)=CC2=CCC2C1(C)CCCC2(C)C(O)=O RSWGJHLUYNHPMX-UHFFFAOYSA-N 0.000 abstract 1
- KHPCPRHQVVSZAH-HUOMCSJISA-N Rosin Natural products O(C/C=C/c1ccccc1)[C@H]1[C@H](O)[C@@H](O)[C@@H](O)[C@@H](CO)O1 KHPCPRHQVVSZAH-HUOMCSJISA-N 0.000 abstract 1
- BLCKNMAZFRMCJJ-UHFFFAOYSA-N cyclohexyl cyclohexyloxycarbonyloxy carbonate Chemical compound C1CCCCC1OC(=O)OOC(=O)OC1CCCCC1 BLCKNMAZFRMCJJ-UHFFFAOYSA-N 0.000 abstract 1
- 229940008099 dimethicone Drugs 0.000 abstract 1
- 235000013870 dimethyl polysiloxane Nutrition 0.000 abstract 1
- UYPSRNLGLSAOPV-UHFFFAOYSA-N n,n-dimethyl-3-octadecanoyloxypropan-1-amine oxide Chemical compound CCCCCCCCCCCCCCCCCC(=O)OCCC[N+](C)(C)[O-] UYPSRNLGLSAOPV-UHFFFAOYSA-N 0.000 abstract 1
- KHPCPRHQVVSZAH-UHFFFAOYSA-N trans-cinnamyl beta-D-glucopyranoside Natural products OC1C(O)C(O)C(CO)OC1OCC=CC1=CC=CC=C1 KHPCPRHQVVSZAH-UHFFFAOYSA-N 0.000 abstract 1
- IPCSVZSSVZVIGE-UHFFFAOYSA-N hexadecanoic acid Chemical compound CCCCCCCCCCCCCCCC(O)=O IPCSVZSSVZVIGE-UHFFFAOYSA-N 0.000 description 4
- 229910000831 Steel Inorganic materials 0.000 description 3
- 238000010438 heat treatment Methods 0.000 description 3
- 239000010959 steel Substances 0.000 description 3
- 150000003568 thioethers Chemical class 0.000 description 3
- LSDPWZHWYPCBBB-UHFFFAOYSA-N Methanethiol Chemical compound SC LSDPWZHWYPCBBB-UHFFFAOYSA-N 0.000 description 2
- IMNFDUFMRHMDMM-UHFFFAOYSA-N N-Heptane Chemical compound CCCCCCC IMNFDUFMRHMDMM-UHFFFAOYSA-N 0.000 description 2
- 235000021314 Palmitic acid Nutrition 0.000 description 2
- 239000002253 acid Substances 0.000 description 2
- 230000007797 corrosion Effects 0.000 description 2
- 238000005260 corrosion Methods 0.000 description 2
- 150000002148 esters Chemical class 0.000 description 2
- MNWFXJYAOYHMED-UHFFFAOYSA-N heptanoic acid Chemical compound CCCCCCC(O)=O MNWFXJYAOYHMED-UHFFFAOYSA-N 0.000 description 2
- 238000000034 method Methods 0.000 description 2
- WQEPLUUGTLDZJY-UHFFFAOYSA-N n-Pentadecanoic acid Natural products CCCCCCCCCCCCCCC(O)=O WQEPLUUGTLDZJY-UHFFFAOYSA-N 0.000 description 2
- 238000011056 performance test Methods 0.000 description 2
- 230000005855 radiation Effects 0.000 description 2
- ATJFFYVFTNAWJD-UHFFFAOYSA-N Tin Chemical compound [Sn] ATJFFYVFTNAWJD-UHFFFAOYSA-N 0.000 description 1
- 206010048222 Xerosis Diseases 0.000 description 1
- 238000004378 air conditioning Methods 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 238000001354 calcination Methods 0.000 description 1
- 238000003763 carbonization Methods 0.000 description 1
- 239000004927 clay Substances 0.000 description 1
- 229920001577 copolymer Polymers 0.000 description 1
- 230000007547 defect Effects 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 238000012423 maintenance Methods 0.000 description 1
- 230000003647 oxidation Effects 0.000 description 1
- 238000007254 oxidation reaction Methods 0.000 description 1
- 239000012744 reinforcing agent Substances 0.000 description 1
- 230000035939 shock Effects 0.000 description 1
- 239000000243 solution Substances 0.000 description 1
- 230000006641 stabilisation Effects 0.000 description 1
- 238000011105 stabilization Methods 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
- C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
- C08L23/04—Homopolymers or copolymers of ethene
- C08L23/06—Polyethene
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C45/00—Injection moulding, i.e. forcing the required volume of moulding material through a nozzle into a closed mould; Apparatus therefor
- B29C45/17—Component parts, details or accessories; Auxiliary operations
- B29C45/76—Measuring, controlling or regulating
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C45/00—Injection moulding, i.e. forcing the required volume of moulding material through a nozzle into a closed mould; Apparatus therefor
- B29C45/17—Component parts, details or accessories; Auxiliary operations
- B29C45/76—Measuring, controlling or regulating
- B29C45/77—Measuring, controlling or regulating of velocity or pressure of moulding material
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C45/00—Injection moulding, i.e. forcing the required volume of moulding material through a nozzle into a closed mould; Apparatus therefor
- B29C45/17—Component parts, details or accessories; Auxiliary operations
- B29C45/76—Measuring, controlling or regulating
- B29C45/78—Measuring, controlling or regulating of temperature
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/001—Conductive additives
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/011—Nanostructured additives
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/017—Additives being an antistatic agent
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2201/00—Properties
- C08L2201/04—Antistatic
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
- C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/14—Polymer mixtures characterised by other features containing polymeric additives characterised by shape
- C08L2205/16—Fibres; Fibrils
Landscapes
- Engineering & Computer Science (AREA)
- Manufacturing & Machinery (AREA)
- Mechanical Engineering (AREA)
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Abstract
The invention discloses a creep-resistant antistatic palm fiber-reinforced polyethylene composite material and a preparation method thereof. The creep-resistant antistatic palm fiber-reinforced polyethylene composite material is prepared from 130-140 parts by weight of polyethylene, 20-30 parts by weight of a tetrafluoroethylene-propylene copolymer, 10-15 parts by weight of polyethersulfone, 6-8 parts by weight of fumaric acid-modified rosin pentaerythritol ester, 5-7 parts by weight of tetraethylene glycol diheptylate, 3-5 parts by weight of dicyclohexyl peroxydicarbonate and 7-9 parts by weight of bis-aminopropyl/ethoxy aminopropyl dimethicone. Through mixing treatment on the tetrafluoroethylene-propylene copolymer, polyethersulfone and polyethylene and use of palm fibers, basic magnesium chloride whiskers and asbestos powder as fillers, material mechanical properties are improved, material creep resistance is improved and the problem of poor polyethylene material creep resistance is solved. Through use of stearamidopropyl amine oxide, conductive mica powder and tetraethylene glycol diheptylate as raw materials, polyethylene material antistatic performances are improved.
Description
Technical field
The present invention relates to a kind of composite, concretely relate to a kind of creep resistant antistatic monkey grass enhanced polyethylene multiple
Condensation material and preparation method thereof.
Background technology
Along with the raising of China's economic level, people are more and more higher to the requirement of quality of life.Living environment and working environment
Most in living as everybody, people are more and more higher to its requirement, and temperature is exactly a portion.In the face of cold
Winter, heating has become indispensable part, and the use of air-conditioning the most all can make xerosis cutis, is not the head of people
Choosing.Ground radiation heating is uniform because of temperature stabilization, does not interferes with ambient humidity and receives an acclaim and pursue.Terrestrial surface radiation supplied in the past
Heating coil road generally uses steel pipe, but steel pipe has a lot of defect, as weight is big, is difficult to install；Poor corrosion resistance, often needs
Maintenance replacing etc..Typically now use polyethylene tube, solve steel pipe weight greatly, the most corrosion-resistant and problem of poor toughness, it tool
Flexible is good, anticorrosive, shock resistance, the series of advantages such as wear-resistant, but polyethylene tube also exists, and tube wall is the thickest, cost mistake
Height, when overpressure reach a certain height, easily there is the series of problems such as creep in tube wall.Fluorinated ethylene propylene copolymer has
High intensity and high rigidity, if forming composite with polyethylene, it is possible to the strength and stiffness increasing pipe solve creep problem,
Reduce wall thickness simultaneously.The present invention is contemplated to develop a kind of creep resistant antistatic monkey grass enhanced polyethylene composite.
Summary of the invention
It is an object of the invention to provide a kind of creep resistant antistatic monkey grass enhanced polyethylene composite and preparation method thereof.
For reaching above-mentioned purpose, the technical solution used in the present invention is:
A kind of creep resistant antistatic monkey grass enhanced polyethylene composite, is formed by the preparation of raw material of following weight portion: polyethylene
130-140, fluorinated ethylene propylene copolymer 20-30, polyether sulfone 10-15, fumaric acid colophonium pentaerythritol ester 6-8, TEG
Two heptanoate 5-7, peroxidating dicyclohexyl carbonate 3-5, ethyoxyl aminopropyl polydimethylsiloxane 7-9, double (3,5-di-t-butyl
-4-hydroxybenzyl) thioether 5-7, ethylhexyl salicylate 6-9, double stearic acid aluminium 4-6, liquid paraffin 4-5, stearamide propyl group oxidation
Amine 3-5, Methyl stannum mercaptide 3-5, hexamethylene-1,2-dioctyl phthalate di-isooctyl 8-9, monkey grass 14-16, nano silicon 8-10,
Conductive mica powder 10-12, calcinated argil 7-9, basic magnesium chloride whisker 7-9, flake asbestos 4-6.
The preparation method of a kind of creep resistant antistatic monkey grass enhanced polyethylene composite, comprises the following steps:
(1) by polyethylene, fluorinated ethylene propylene copolymer dried 50-60min under conditions of temperature is 110-115 DEG C, so
After ethyoxyl aminopropyl polydimethylsiloxane is sprayed at stirring at low speed on the mixture of polyethylene and fluorinated ethylene propylene copolymer
30-40min, is then incubated 2-3h at a temperature of 70-75 DEG C, obtains modified mixed resin；
(2) modification mixed resin, polyether sulfone are placed in mixing roll the 2-3min that plasticates at a temperature of 80-90 DEG C, are subsequently adding palm fibre
Palmitic acid fiber, nano silicon, conductive mica powder, calcinated argil, basic magnesium chloride whisker, flake asbestos, after being warming up to 130 DEG C
Continue mixing 8-10min, obtain the mixing thing of polyethylene；
(3) by mixing for polyethylene thing and fumaric acid colophonium pentaerythritol ester, tetraethylene glycol bis-enanthate, peroxidating dicyclohexyl carbonate,
Double (3,5-di-tert-butyl-4-hydroxyl benzyl) thioether, ethylhexyl salicylate, double stearic acid aluminium, liquid paraffin, stearamide propyl group aoxidize
Amine, Methyl stannum mercaptide, hexamethylene-1, the raw material such as 2-dioctyl phthalate di-isooctyl joins in kneader, together at 150-160 DEG C
At a temperature of mediate reduce the temperature to less than 40 DEG C after 20-30min after dischargings, prepared compound；
(4) adding mixture into extruding pelletization in double screw extruder, arranging parameter is: mold temperature is 100 DEG C, injection molding machine
Barrel temperature is 420 DEG C, molding injection pressure 130MPa, pressurize are 100MPa, back pressure is 0.5MPa, obtains described polyethylene
Composite.
Beneficial effects of the present invention:
The composite polyethylene material of the present invention uses fluorinated ethylene propylene copolymer, polyether sulfone are blended together with polyethylene to process, and add
Add the fillers such as monkey grass, basic magnesium chloride whisker, flake asbestos as reinforcing agent, enhanced the mechanical property of material, improve
The creep-resistant property of material, solves the problem that polythene material creep resisting ability is not enough；Add stearamide propyl group amine oxide,
The raw material such as conductive mica powder, tetraethylene glycol bis-enanthate improves the antistatic property of polythene material.
Detailed description of the invention
Below in conjunction with specific embodiment, technical scheme of the present invention is further described.
Embodiment 1:
A kind of creep resistant antistatic monkey grass enhanced polyethylene composite, is formed by the preparation of raw material of following weight portion (kg):
Polyethylene 130, fluorinated ethylene propylene copolymer 20, polyether sulfone 10, fumaric acid colophonium pentaerythritol ester 6, TEG two heptan
Acid esters 5, peroxidating dicyclohexyl carbonate 3, ethyoxyl aminopropyl polydimethylsiloxane 7, double (3,5-di-t-butyl-4-hydroxyl benzyl
Base) thioether 5, ethylhexyl salicylate 6, double stearic acid aluminium 4, liquid paraffin 4, stearamide propyl group amine oxide 3, Methyl stannum mercaptide
3, hexamethylene-1,2-dioctyl phthalate di-isooctyl 8, monkey grass 14, nano silicon 8, conductive mica powder 10, calcinated argil
7, basic magnesium chloride whisker 7, flake asbestos 4.
The preparation method of a kind of creep resistant antistatic monkey grass enhanced polyethylene composite, comprises the following steps:
(1) by polyethylene, fluorinated ethylene propylene copolymer dried 50-60min under conditions of temperature is 110-115 DEG C, so
After ethyoxyl aminopropyl polydimethylsiloxane is sprayed at stirring at low speed on the mixture of polyethylene and fluorinated ethylene propylene copolymer
30-40min, is then incubated 2-3h at a temperature of 70-75 DEG C, obtains modified mixed resin；
(2) modification mixed resin, polyether sulfone are placed in mixing roll the 2-3min that plasticates at a temperature of 80-90 DEG C, are subsequently adding palm fibre
Palmitic acid fiber, nano silicon, conductive mica powder, calcinated argil, basic magnesium chloride whisker, flake asbestos, after being warming up to 130 DEG C
Continue mixing 8-10min, obtain the mixing thing of polyethylene；
(3) by mixing for polyethylene thing and fumaric acid colophonium pentaerythritol ester, tetraethylene glycol bis-enanthate, peroxidating dicyclohexyl carbonate,
Double (3,5-di-tert-butyl-4-hydroxyl benzyl) thioether, ethylhexyl salicylate, double stearic acid aluminium, liquid paraffin, stearamide propyl group aoxidize
Amine, Methyl stannum mercaptide, hexamethylene-1, the raw material such as 2-dioctyl phthalate di-isooctyl joins in kneader, together at 150-160 DEG C
At a temperature of mediate reduce the temperature to less than 40 DEG C after 20-30min after dischargings, prepared compound；
(4) adding mixture into extruding pelletization in double screw extruder, arranging parameter is: mold temperature is 100 DEG C, injection molding machine
Barrel temperature is 420 DEG C, molding injection pressure 130MPa, pressurize are 100MPa, back pressure is 0.5MPa, obtains described polyethylene
Composite.
Embodiment 2:
A kind of creep resistant antistatic monkey grass enhanced polyethylene composite, is formed by the preparation of raw material of following weight portion (kg):
Polyethylene 135, fluorinated ethylene propylene copolymer 25, polyether sulfone 12.5, fumaric acid colophonium pentaerythritol ester 7, TEG two heptan
Acid esters 6, peroxidating dicyclohexyl carbonate 4, ethyoxyl aminopropyl polydimethylsiloxane 8, double (3,5-di-t-butyl-4-hydroxyl benzyl
Base) thioether 6, ethylhexyl salicylate 7.5, double stearic acid aluminium 5, liquid paraffin 4.5, stearamide propyl group amine oxide 4, methyl mercaptan
Stannum 4, hexamethylene-1,2-dioctyl phthalate di-isooctyl 8.5, monkey grass 15, nano silicon 9, conductive mica powder 11, calcining
Potter's clay 8, carbonization 8, asbestos 5.
Preparation method is with embodiment 1.
Embodiment 3:
A kind of creep resistant antistatic monkey grass enhanced polyethylene composite, is formed by the preparation of raw material of following weight portion (kg): poly-
Ethylene 140, fluorinated ethylene propylene copolymer 30, polyether sulfone 15, fumaric acid colophonium pentaerythritol ester 8, TEG two enanthic acid
Ester 7, peroxidating dicyclohexyl carbonate 5, ethyoxyl aminopropyl polydimethylsiloxane 9, double (3,5-di-tert-butyl-4-hydroxyl benzyls)
Thioether 7, ethylhexyl salicylate 9, double stearic acid aluminium 6, liquid paraffin 5, stearamide propyl group amine oxide 5, Methyl stannum mercaptide 5,
Hexamethylene-1,2-dioctyl phthalate di-isooctyl 9, monkey grass 16, nano silicon 10, conductive mica powder 12, calcinated argil 9,
Basic magnesium chloride whisker 9, flake asbestos 6.
Preparation method is with embodiment 1.
The performance test results of the composite polyethylene material that above-described embodiment 1-3 prepares is as shown in the table:
The performance test results of the composite polyethylene material that table 1 embodiment 1-3 prepares
Claims (2)
1. a creep resistant antistatic monkey grass enhanced polyethylene composite, it is characterised in that by the preparation of raw material of following weight portion
Form: polyethylene 130-140, fluorinated ethylene propylene copolymer 20-30, polyether sulfone 10-15, fumaric acid colophonium pentaerythritol ester
6-8, tetraethylene glycol bis-enanthate 5-7, peroxidating dicyclohexyl carbonate 3-5, ethyoxyl aminopropyl polydimethylsiloxane 7-9,
Double (3,5-di-tert-butyl-4-hydroxyl benzyl) thioether 5-7, ethylhexyl salicylate 6-9, double stearic acid aluminium 4-6, liquid paraffin 4-5,18
LAO 3-5, Methyl stannum mercaptide 3-5, hexamethylene-1,2-dioctyl phthalate di-isooctyl 8-9, monkey grass 14-16, receive
Rice silicon dioxide 8-10, conductive mica powder 10-12, calcinated argil 7-9, basic magnesium chloride whisker 7-9, flake asbestos 4-6.
The preparation method of a kind of creep resistant antistatic monkey grass enhanced polyethylene composite the most according to claim 1, it is special
Levy and be, comprise the following steps:
(1) by polyethylene, fluorinated ethylene propylene copolymer dried 50-60min under conditions of temperature is 110-115 DEG C, then
Ethyoxyl aminopropyl polydimethylsiloxane is sprayed at stirring at low speed on the mixture of polyethylene and fluorinated ethylene propylene copolymer
30-40min, is then incubated 2-3h at a temperature of 70-75 DEG C, obtains modified mixed resin；
(2) modification mixed resin, polyether sulfone are placed in mixing roll the 2-3min that plasticates at a temperature of 80-90 DEG C, are subsequently adding Petiolus Trachycarpi
Fiber, nano silicon, conductive mica powder, calcinated argil, basic magnesium chloride whisker, flake asbestos, be warming up to 130 DEG C follow-up
Continuous mixing 8-10min, obtains the mixing thing of polyethylene；
(3) by mixing for polyethylene thing and fumaric acid colophonium pentaerythritol ester, tetraethylene glycol bis-enanthate, peroxidating dicyclohexyl carbonate,
Double (3,5-di-tert-butyl-4-hydroxyl benzyl) thioether, ethylhexyl salicylate, double stearic acid aluminium, liquid paraffin, stearamide propyl group aoxidize
Amine, Methyl stannum mercaptide, hexamethylene-1, the raw material such as 2-dioctyl phthalate di-isooctyl joins in kneader, together at 150-160 DEG C
At a temperature of mediate reduce the temperature to less than 40 DEG C after 20-30min after dischargings, prepared compound；
(4) adding mixture into extruding pelletization in double screw extruder, arranging parameter is: mold temperature is 100 DEG C, injection molding machine material
Cylinder temperature is 420 DEG C, molding injection pressure 130MPa, pressurize are 100MPa, back pressure is 0.5MPa, obtains described polyethylene multiple
Condensation material.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610643074.6A CN106009203A (en) | 2016-08-08 | 2016-08-08 | Creep-resistant antistatic palm fiber-reinforced polyethylene composite material and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610643074.6A CN106009203A (en) | 2016-08-08 | 2016-08-08 | Creep-resistant antistatic palm fiber-reinforced polyethylene composite material and preparation method thereof |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN106009203A true CN106009203A (en) | 2016-10-12 |
Family
ID=57135367
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201610643074.6A Pending CN106009203A (en) | 2016-08-08 | 2016-08-08 | Creep-resistant antistatic palm fiber-reinforced polyethylene composite material and preparation method thereof |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN106009203A (en) |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106867074A (en) * | 2017-01-13 | 2017-06-20 | 长兴天晟能源科技有限公司 | A kind of functional agglomerate for strengthening polyethylene creep resisting ability |
| CN110511562A (en) * | 2018-05-22 | 2019-11-29 | 上海杰事杰新材料(集团)股份有限公司 | A kind of antistatic flame retardant nylon composite material and preparation method thereof |
Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102417650A (en) * | 2011-11-28 | 2012-04-18 | 浙江伟星新型建材股份有限公司 | Wear-resistant cross-linked PE composite pipe and preparation method thereof |
| CN105001482A (en) * | 2015-06-10 | 2015-10-28 | 苏州宏恒化工有限公司 | HDPE composite material for snowboard and preparation method thereof |
-
2016
- 2016-08-08 CN CN201610643074.6A patent/CN106009203A/en active Pending
Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102417650A (en) * | 2011-11-28 | 2012-04-18 | 浙江伟星新型建材股份有限公司 | Wear-resistant cross-linked PE composite pipe and preparation method thereof |
| CN105001482A (en) * | 2015-06-10 | 2015-10-28 | 苏州宏恒化工有限公司 | HDPE composite material for snowboard and preparation method thereof |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106867074A (en) * | 2017-01-13 | 2017-06-20 | 长兴天晟能源科技有限公司 | A kind of functional agglomerate for strengthening polyethylene creep resisting ability |
| CN110511562A (en) * | 2018-05-22 | 2019-11-29 | 上海杰事杰新材料(集团)股份有限公司 | A kind of antistatic flame retardant nylon composite material and preparation method thereof |
| CN110511562B (en) * | 2018-05-22 | 2022-10-04 | 上海杰事杰新材料(集团)股份有限公司 | A kind of antistatic flame retardant nylon composite material and preparation method thereof |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN104448813B (en) | Glass fiber reinforced polyamide 66 composite material, and preparation method and application thereof | |
| CN103613886B (en) | Fluoroelastomer glue stock of a kind of high temperature high voltage resistant and preparation method thereof and application | |
| RU2635136C1 (en) | Glass-filled composition based on polyphenylenesulphide | |
| CN107446346A (en) | A kind of wear-resisting high-temperature nylon composite of fibre reinforced and preparation method thereof | |
| CN106751777B (en) | High-intensitive PA6 composite material and preparation method based on basalt fibre enhancing | |
| CN103613902B (en) | A kind of heat conduction friction-resistant polyformaldehyde composite material and preparation method thereof | |
| CN112961420B (en) | Graphene modified high-density polyethylene composite material for carrier roller and preparation method thereof | |
| CN104530695A (en) | Wear-resistant nylon composite material and preparation method thereof | |
| CN101250300B (en) | A kind of ultra-high molecular weight polyethylene composite liner | |
| CN103613883A (en) | Wear-resistant hard composite material using graphene as filler and preparation method thereof | |
| EP3670578A1 (en) | Polyamide moulding material for extrusion blow molding | |
| CN107759964A (en) | A kind of polyformaldehyde composite material and its production and use | |
| CN101831172A (en) | Carbon fiber reinforced nylon 66 composite material and preparation method thereof | |
| EP2998354A1 (en) | Ptfe resin composition | |
| CN109306179A (en) | Use of polyamide 5X as apparent quality improver for reinforced thermoplastic compositions | |
| CN106009203A (en) | Creep-resistant antistatic palm fiber-reinforced polyethylene composite material and preparation method thereof | |
| CN104072901B (en) | Underground modified PVC non-excavation special communication pipe and preparation method thereof | |
| CN107057154A (en) | Wear resistant polyethylene composite pipe | |
| CN105949763A (en) | Environment-friendly polyamide composition with good appearance and hot water stability and preparation method of polyamide composition | |
| US20160145432A1 (en) | Resin composition and sealing member | |
| CN105264018B (en) | Resin composition and sealing element using same | |
| CN108912673A (en) | A kind of polyamide moulding composition of high-strength, high-anti-friction | |
| CN103613903A (en) | Friction-resistant composite material and preparation method thereof | |
| Guptaa et al. | Thermal and moisture absorption property of hybrid sisal and jute epoxy composite | |
| CN106398111A (en) | PEEK/glass fiber/kaolin composite material and preparation method thereof |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| RJ01 | Rejection of invention patent application after publication | ||
| RJ01 | Rejection of invention patent application after publication |
Application publication date: 20161012 |