CA3038157C - Derive de benzotriazole et compositions d'huile de lubrification contenant du dithiocarbamate de molybdene pour reduire le frottement et la consommation de carburant - Google Patents
Derive de benzotriazole et compositions d'huile de lubrification contenant du dithiocarbamate de molybdene pour reduire le frottement et la consommation de carburant Download PDFInfo
- Publication number
- CA3038157C CA3038157C CA3038157A CA3038157A CA3038157C CA 3038157 C CA3038157 C CA 3038157C CA 3038157 A CA3038157 A CA 3038157A CA 3038157 A CA3038157 A CA 3038157A CA 3038157 C CA3038157 C CA 3038157C
- Authority
- CA
- Canada
- Prior art keywords
- lubricating oil
- oil composition
- automotive engine
- molybdenum
- molybdenum dithiocarbamate
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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- 239000010687 lubricating oil Substances 0.000 title claims abstract description 132
- KHYKFSXXGRUKRE-UHFFFAOYSA-J molybdenum(4+) tetracarbamodithioate Chemical compound C(N)([S-])=S.[Mo+4].C(N)([S-])=S.C(N)([S-])=S.C(N)([S-])=S KHYKFSXXGRUKRE-UHFFFAOYSA-J 0.000 title claims abstract description 15
- 125000003354 benzotriazolyl group Chemical class N1N=NC2=C1C=CC=C2* 0.000 title claims abstract 8
- 239000000203 mixture Substances 0.000 title claims description 168
- 239000000446 fuel Substances 0.000 title claims description 7
- 239000000654 additive Substances 0.000 claims abstract description 63
- 239000003112 inhibitor Substances 0.000 claims abstract description 15
- 238000005260 corrosion Methods 0.000 claims abstract description 9
- 230000007797 corrosion Effects 0.000 claims abstract description 9
- 230000001603 reducing effect Effects 0.000 claims abstract description 7
- -1 molybdenum dithiocarbamate compound Chemical class 0.000 claims description 79
- 239000003921 oil Substances 0.000 claims description 64
- 125000004432 carbon atom Chemical group C* 0.000 claims description 41
- 239000002270 dispersing agent Substances 0.000 claims description 40
- 229910052751 metal Inorganic materials 0.000 claims description 38
- 239000002184 metal Substances 0.000 claims description 38
- 230000000996 additive effect Effects 0.000 claims description 37
- 239000003599 detergent Substances 0.000 claims description 37
- ZOKXTWBITQBERF-UHFFFAOYSA-N Molybdenum Chemical compound [Mo] ZOKXTWBITQBERF-UHFFFAOYSA-N 0.000 claims description 29
- 239000011733 molybdenum Substances 0.000 claims description 28
- 229910052750 molybdenum Inorganic materials 0.000 claims description 28
- 150000001875 compounds Chemical class 0.000 claims description 27
- 125000000217 alkyl group Chemical group 0.000 claims description 24
- 239000002199 base oil Substances 0.000 claims description 23
- 125000001183 hydrocarbyl group Chemical group 0.000 claims description 23
- 239000003446 ligand Substances 0.000 claims description 23
- 230000001050 lubricating effect Effects 0.000 claims description 23
- 239000003963 antioxidant agent Substances 0.000 claims description 21
- 150000001412 amines Chemical class 0.000 claims description 17
- 238000000034 method Methods 0.000 claims description 16
- 229910052717 sulfur Inorganic materials 0.000 claims description 15
- 230000007935 neutral effect Effects 0.000 claims description 14
- 125000003118 aryl group Chemical group 0.000 claims description 12
- 125000000962 organic group Chemical group 0.000 claims description 10
- 239000011701 zinc Substances 0.000 claims description 10
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 claims description 9
- 229910052784 alkaline earth metal Inorganic materials 0.000 claims description 9
- 239000003607 modifier Substances 0.000 claims description 9
- 229910052725 zinc Inorganic materials 0.000 claims description 9
- JEIPFZHSYJVQDO-UHFFFAOYSA-N iron(III) oxide Inorganic materials O=[Fe]O[Fe]=O JEIPFZHSYJVQDO-UHFFFAOYSA-N 0.000 claims description 6
- 238000005461 lubrication Methods 0.000 claims description 6
- 150000001298 alcohols Chemical class 0.000 claims description 5
- 239000007866 anti-wear additive Substances 0.000 claims description 5
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 claims description 4
- 239000003513 alkali Substances 0.000 claims description 4
- AVVIDTZRJBSXML-UHFFFAOYSA-L calcium;2-carboxyphenolate;dihydrate Chemical compound O.O.[Ca+2].OC1=CC=CC=C1C([O-])=O.OC1=CC=CC=C1C([O-])=O AVVIDTZRJBSXML-UHFFFAOYSA-L 0.000 claims description 4
- 150000002170 ethers Chemical class 0.000 claims description 4
- 239000011777 magnesium Substances 0.000 claims description 4
- 229910052749 magnesium Inorganic materials 0.000 claims description 4
- 150000003003 phosphines Chemical class 0.000 claims description 4
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 4
- 125000004430 oxygen atom Chemical group O* 0.000 claims description 3
- 125000004434 sulfur atom Chemical group 0.000 claims description 3
- 244000126002 Ziziphus vulgaris Species 0.000 claims 1
- 125000001302 tertiary amino group Chemical group 0.000 claims 1
- 235000019198 oils Nutrition 0.000 description 63
- RRHGJUQNOFWUDK-UHFFFAOYSA-N Isoprene Chemical compound CC(=C)C=C RRHGJUQNOFWUDK-UHFFFAOYSA-N 0.000 description 30
- 229920000642 polymer Polymers 0.000 description 30
- 239000002585 base Substances 0.000 description 25
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 22
- 235000006708 antioxidants Nutrition 0.000 description 20
- 239000004034 viscosity adjusting agent Substances 0.000 description 19
- KAKZBPTYRLMSJV-UHFFFAOYSA-N Butadiene Chemical compound C=CC=C KAKZBPTYRLMSJV-UHFFFAOYSA-N 0.000 description 16
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 description 14
- 150000001565 benzotriazoles Chemical class 0.000 description 14
- 239000002253 acid Substances 0.000 description 13
- 229920001577 copolymer Polymers 0.000 description 12
- 229920000098 polyolefin Polymers 0.000 description 12
- 239000011593 sulfur Substances 0.000 description 12
- OFOBLEOULBTSOW-UHFFFAOYSA-N Propanedioic acid Natural products OC(=O)CC(O)=O OFOBLEOULBTSOW-UHFFFAOYSA-N 0.000 description 11
- 150000002148 esters Chemical class 0.000 description 11
- 239000005864 Sulphur Substances 0.000 description 10
- 239000000314 lubricant Substances 0.000 description 10
- 229910052799 carbon Inorganic materials 0.000 description 9
- 238000006243 chemical reaction Methods 0.000 description 9
- 239000000047 product Substances 0.000 description 9
- 150000003839 salts Chemical class 0.000 description 9
- 239000004480 active ingredient Substances 0.000 description 8
- 239000005078 molybdenum compound Substances 0.000 description 8
- 239000000178 monomer Substances 0.000 description 8
- VQTUBCCKSQIDNK-UHFFFAOYSA-N iso-butene Natural products CC(C)=C VQTUBCCKSQIDNK-UHFFFAOYSA-N 0.000 description 7
- 239000007788 liquid Substances 0.000 description 7
- 150000002752 molybdenum compounds Chemical class 0.000 description 7
- 229910052698 phosphorus Inorganic materials 0.000 description 7
- MYRTYDVEIRVNKP-UHFFFAOYSA-N 1,2-Divinylbenzene Chemical compound C=CC1=CC=CC=C1C=C MYRTYDVEIRVNKP-UHFFFAOYSA-N 0.000 description 6
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 6
- UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 description 6
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 description 6
- 229910052796 boron Inorganic materials 0.000 description 6
- 239000012141 concentrate Substances 0.000 description 6
- 150000001993 dienes Chemical class 0.000 description 6
- DMBHHRLKUKUOEG-UHFFFAOYSA-N diphenylamine Chemical compound C=1C=CC=CC=1NC1=CC=CC=C1 DMBHHRLKUKUOEG-UHFFFAOYSA-N 0.000 description 6
- 239000000463 material Substances 0.000 description 6
- 150000002736 metal compounds Chemical class 0.000 description 6
- 239000003208 petroleum Substances 0.000 description 6
- 239000011574 phosphorus Substances 0.000 description 6
- 229920005862 polyol Polymers 0.000 description 6
- 239000000376 reactant Substances 0.000 description 6
- 239000002904 solvent Substances 0.000 description 6
- KZNICNPSHKQLFF-UHFFFAOYSA-N succinimide Chemical compound O=C1CCC(=O)N1 KZNICNPSHKQLFF-UHFFFAOYSA-N 0.000 description 6
- ZOXJGFHDIHLPTG-UHFFFAOYSA-N Boron Chemical compound [B] ZOXJGFHDIHLPTG-UHFFFAOYSA-N 0.000 description 5
- VZCYOOQTPOCHFL-OWOJBTEDSA-N Fumaric acid Chemical compound OC(=O)\C=C\C(O)=O VZCYOOQTPOCHFL-OWOJBTEDSA-N 0.000 description 5
- ISWSIDIOOBJBQZ-UHFFFAOYSA-N Phenol Chemical compound OC1=CC=CC=C1 ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 description 5
- 150000004945 aromatic hydrocarbons Chemical class 0.000 description 5
- 150000001721 carbon Chemical group 0.000 description 5
- 238000002485 combustion reaction Methods 0.000 description 5
- 229920001519 homopolymer Polymers 0.000 description 5
- 229930195733 hydrocarbon Natural products 0.000 description 5
- 150000002430 hydrocarbons Chemical class 0.000 description 5
- 229910052757 nitrogen Inorganic materials 0.000 description 5
- 230000003647 oxidation Effects 0.000 description 5
- 238000007254 oxidation reaction Methods 0.000 description 5
- 150000002989 phenols Chemical class 0.000 description 5
- 150000003077 polyols Chemical class 0.000 description 5
- VZCYOOQTPOCHFL-UHFFFAOYSA-N trans-butenedioic acid Natural products OC(=O)C=CC(O)=O VZCYOOQTPOCHFL-UHFFFAOYSA-N 0.000 description 5
- NIXOWILDQLNWCW-UHFFFAOYSA-N 2-Propenoic acid Chemical class OC(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 4
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 4
- 229920002367 Polyisobutene Polymers 0.000 description 4
- 230000003078 antioxidant effect Effects 0.000 description 4
- 229920001400 block copolymer Polymers 0.000 description 4
- MTAZNLWOLGHBHU-UHFFFAOYSA-N butadiene-styrene rubber Chemical compound C=CC=C.C=CC1=CC=CC=C1 MTAZNLWOLGHBHU-UHFFFAOYSA-N 0.000 description 4
- 229910052802 copper Inorganic materials 0.000 description 4
- 239000010949 copper Substances 0.000 description 4
- 238000009472 formulation Methods 0.000 description 4
- 229910052739 hydrogen Inorganic materials 0.000 description 4
- 239000001257 hydrogen Substances 0.000 description 4
- FPYJFEHAWHCUMM-UHFFFAOYSA-N maleic anhydride Chemical compound O=C1OC(=O)C=C1 FPYJFEHAWHCUMM-UHFFFAOYSA-N 0.000 description 4
- 150000002762 monocarboxylic acid derivatives Chemical class 0.000 description 4
- 230000000269 nucleophilic effect Effects 0.000 description 4
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 description 4
- 229920000768 polyamine Polymers 0.000 description 4
- 150000003871 sulfonates Chemical class 0.000 description 4
- 238000010998 test method Methods 0.000 description 4
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 description 3
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 3
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 description 3
- 239000005977 Ethylene Substances 0.000 description 3
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 3
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 description 3
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 3
- MQHWFIOJQSCFNM-UHFFFAOYSA-L Magnesium salicylate Chemical compound [Mg+2].OC1=CC=CC=C1C([O-])=O.OC1=CC=CC=C1C([O-])=O MQHWFIOJQSCFNM-UHFFFAOYSA-L 0.000 description 3
- DNIAPMSPPWPWGF-UHFFFAOYSA-N Propylene glycol Chemical compound CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 description 3
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 3
- 150000007513 acids Chemical class 0.000 description 3
- 125000002015 acyclic group Chemical group 0.000 description 3
- 125000003342 alkenyl group Chemical group 0.000 description 3
- 125000003545 alkoxy group Chemical group 0.000 description 3
- 125000002947 alkylene group Chemical group 0.000 description 3
- 150000008064 anhydrides Chemical class 0.000 description 3
- 150000004982 aromatic amines Chemical class 0.000 description 3
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 3
- WPYMKLBDIGXBTP-UHFFFAOYSA-N benzoic acid Chemical compound OC(=O)C1=CC=CC=C1 WPYMKLBDIGXBTP-UHFFFAOYSA-N 0.000 description 3
- 230000015572 biosynthetic process Effects 0.000 description 3
- KGBXLFKZBHKPEV-UHFFFAOYSA-N boric acid Chemical class OB(O)O KGBXLFKZBHKPEV-UHFFFAOYSA-N 0.000 description 3
- 239000011575 calcium Substances 0.000 description 3
- 229910052791 calcium Inorganic materials 0.000 description 3
- 150000007942 carboxylates Chemical class 0.000 description 3
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- MTHSVFCYNBDYFN-UHFFFAOYSA-N diethylene glycol Chemical compound OCCOCCO MTHSVFCYNBDYFN-UHFFFAOYSA-N 0.000 description 3
- 239000003085 diluting agent Substances 0.000 description 3
- NAGJZTKCGNOGPW-UHFFFAOYSA-N dithiophosphoric acid Chemical compound OP(O)(S)=S NAGJZTKCGNOGPW-UHFFFAOYSA-N 0.000 description 3
- 230000000694 effects Effects 0.000 description 3
- 125000002573 ethenylidene group Chemical group [*]=C=C([H])[H] 0.000 description 3
- 125000000524 functional group Chemical group 0.000 description 3
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- BHEPBYXIRTUNPN-UHFFFAOYSA-N hydridophosphorus(.) (triplet) Chemical compound [PH] BHEPBYXIRTUNPN-UHFFFAOYSA-N 0.000 description 3
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- 229940072082 magnesium salicylate Drugs 0.000 description 3
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- TXBCBTDQIULDIA-UHFFFAOYSA-N 2-[[3-hydroxy-2,2-bis(hydroxymethyl)propoxy]methyl]-2-(hydroxymethyl)propane-1,3-diol Chemical compound OCC(CO)(CO)COCC(CO)(CO)CO TXBCBTDQIULDIA-UHFFFAOYSA-N 0.000 description 2
- PTJWCLYPVFJWMP-UHFFFAOYSA-N 2-[[3-hydroxy-2-[[3-hydroxy-2,2-bis(hydroxymethyl)propoxy]methyl]-2-(hydroxymethyl)propoxy]methyl]-2-(hydroxymethyl)propane-1,3-diol Chemical compound OCC(CO)(CO)COCC(CO)(CO)COCC(CO)(CO)CO PTJWCLYPVFJWMP-UHFFFAOYSA-N 0.000 description 2
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- HYZHPAXFOXQGMV-UHFFFAOYSA-N benzotriazol-1-ylmethanamine Chemical compound C1=CC=C2N(CN)N=NC2=C1 HYZHPAXFOXQGMV-UHFFFAOYSA-N 0.000 description 2
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- UHZZMRAGKVHANO-UHFFFAOYSA-M chlormequat chloride Chemical compound [Cl-].C[N+](C)(C)CCCl UHZZMRAGKVHANO-UHFFFAOYSA-M 0.000 description 2
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- QXJQHYBHAIHNGG-UHFFFAOYSA-N trimethylolethane Chemical compound OCC(C)(CO)CO QXJQHYBHAIHNGG-UHFFFAOYSA-N 0.000 description 1
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- 235000015112 vegetable and seed oil Nutrition 0.000 description 1
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Classifications
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- C10M133/38—Heterocyclic nitrogen compounds
- C10M133/44—Five-membered ring containing nitrogen and carbon only
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- C10M169/04—Mixtures of base-materials and additives
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- C10M135/16—Thio-acids; Thiocyanates; Derivatives thereof having a carbon-to-sulfur double bond thiourea type, i.e. containing the group
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- C10M137/10—Thio derivatives
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- C10M2215/223—Five-membered rings containing nitrogen and carbon only
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- C10M2215/26—Amines
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- C10M2219/068—Thiocarbamate metal salts
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- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
- C10N2030/00—Specified physical or chemical properties which is improved by the additive characterising the lubricating composition, e.g. multifunctional additives
- C10N2030/04—Detergent property or dispersant property
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
- C10N2030/00—Specified physical or chemical properties which is improved by the additive characterising the lubricating composition, e.g. multifunctional additives
- C10N2030/06—Oiliness; Film-strength; Anti-wear; Resistance to extreme pressure
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
- C10N2030/00—Specified physical or chemical properties which is improved by the additive characterising the lubricating composition, e.g. multifunctional additives
- C10N2030/10—Inhibition of oxidation, e.g. anti-oxidants
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
- C10N2030/00—Specified physical or chemical properties which is improved by the additive characterising the lubricating composition, e.g. multifunctional additives
- C10N2030/12—Inhibition of corrosion, e.g. anti-rust agents or anti-corrosives
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
- C10N2030/00—Specified physical or chemical properties which is improved by the additive characterising the lubricating composition, e.g. multifunctional additives
- C10N2030/54—Fuel economy
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
- C10N2040/00—Specified use or application for which the lubricating composition is intended
- C10N2040/25—Internal-combustion engines
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
- C10N2040/00—Specified use or application for which the lubricating composition is intended
- C10N2040/25—Internal-combustion engines
- C10N2040/255—Gasoline engines
Landscapes
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Organic Chemistry (AREA)
- Inorganic Chemistry (AREA)
- Lubricants (AREA)
Abstract
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| EP18164161 | 2018-03-27 | ||
| EP18164161.4 | 2018-03-27 |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CA3038157A1 CA3038157A1 (fr) | 2019-09-27 |
| CA3038157C true CA3038157C (fr) | 2023-11-07 |
Family
ID=61827561
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CA3038157A Active CA3038157C (fr) | 2018-03-27 | 2019-03-27 | Derive de benzotriazole et compositions d'huile de lubrification contenant du dithiocarbamate de molybdene pour reduire le frottement et la consommation de carburant |
Country Status (7)
| Country | Link |
|---|---|
| US (1) | US20190300810A1 (fr) |
| EP (1) | EP3546549B1 (fr) |
| JP (1) | JP7149887B2 (fr) |
| KR (1) | KR102706017B1 (fr) |
| CN (1) | CN110305717A (fr) |
| CA (1) | CA3038157C (fr) |
| SG (1) | SG10201902658WA (fr) |
Families Citing this family (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP7150680B2 (ja) * | 2019-09-24 | 2022-10-11 | 株式会社三共 | 遊技機 |
| CN111205910A (zh) * | 2020-01-09 | 2020-05-29 | 辽宁汽众润滑油生产有限公司 | 一种ab型复合功效发动机润滑油组合物 |
| EP4237520A1 (fr) * | 2020-10-28 | 2023-09-06 | Chevron U.S.A. Inc. | Composition d'huile lubrifiante avec une huile de base renouvelable, ayant une faible teneur en soufre et en cendres sulfatées et contenant des composés de molybdène et de bore |
| JP7104200B1 (ja) * | 2021-03-17 | 2022-07-20 | 出光興産株式会社 | 潤滑油組成物 |
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| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3087936A (en) | 1961-08-18 | 1963-04-30 | Lubrizol Corp | Reaction product of an aliphatic olefinpolymer-succinic acid producing compound with an amine and reacting the resulting product with a boron compound |
| GB989409A (en) | 1962-08-24 | 1965-04-14 | Gen Electric | Organopolysiloxane compositions |
| CA1048507A (fr) | 1974-03-27 | 1979-02-13 | Jack Ryer | Produit d'apport pour les composes oleagineux |
| US4113639A (en) | 1976-11-11 | 1978-09-12 | Exxon Research & Engineering Co. | Lubricating oil composition containing a dispersing-varnish inhibiting combination of an oxazoline compound and an acyl nitrogen compound |
| DE2702604C2 (de) | 1977-01-22 | 1984-08-30 | Basf Ag, 6700 Ludwigshafen | Polyisobutene |
| US4116876A (en) | 1977-01-28 | 1978-09-26 | Exxon Research & Engineering Co. | Borated oxazolines as varnish inhibiting dispersants in lubricating oils |
| US4234435A (en) | 1979-02-23 | 1980-11-18 | The Lubrizol Corporation | Novel carboxylic acid acylating agents, derivatives thereof, concentrate and lubricant compositions containing the same, and processes for their preparation |
| EP0608962A1 (fr) | 1985-03-14 | 1994-08-03 | The Lubrizol Corporation | Condensats à haut poids moléculaire contenant de l'azote, carburants et lubrifiants les contenant |
| CA1262721A (fr) | 1985-07-11 | 1989-11-07 | Jacob Emert | Additifs-dispersants solubles dans l'huile, utiles dans des compositions oleagineuses |
| US4963275A (en) | 1986-10-07 | 1990-10-16 | Exxon Chemical Patents Inc. | Dispersant additives derived from lactone modified amido-amine adducts |
| US4956107A (en) | 1987-11-30 | 1990-09-11 | Exxon Chemical Patents Inc. | Amide dispersant additives derived from amino-amines |
| US4857217A (en) | 1987-11-30 | 1989-08-15 | Exxon Chemical Patents Inc. | Dispersant additives derived from amido-amines |
| US4938880A (en) | 1987-05-26 | 1990-07-03 | Exxon Chemical Patents Inc. | Process for preparing stable oleaginous compositions |
| US4927551A (en) | 1987-12-30 | 1990-05-22 | Chevron Research Company | Lubricating oil compositions containing a combination of a modified succinimide and a Group II metal overbased sulfurized alkylphenol |
| IL89210A (en) | 1988-02-26 | 1992-06-21 | Exxon Chemical Patents Inc | Lubricating oil compositions containing demulsifiers |
| JPH0251591A (ja) * | 1988-06-24 | 1990-02-21 | Exxon Chem Patents Inc | パワートランスミッティング組成物において有用な添加剤の相乗的組合せ |
| DE68907288T2 (de) * | 1988-06-24 | 1993-10-21 | Exxon Chemical Patents Inc | Reibungsvermindernde Hydroxyätheramine für Kraftübertragungsflüssigkeiten und Verschleissschutzadditive, die damit verwendbar sind. |
| US4938881A (en) | 1988-08-01 | 1990-07-03 | The Lubrizol Corporation | Lubricating oil compositions and concentrates |
| US5229022A (en) | 1988-08-01 | 1993-07-20 | Exxon Chemical Patents Inc. | Ethylene alpha-olefin polymer substituted mono- and dicarboxylic acid dispersant additives (PT-920) |
| US4952739A (en) | 1988-10-26 | 1990-08-28 | Exxon Chemical Patents Inc. | Organo-Al-chloride catalyzed poly-n-butenes process |
| US5241003A (en) | 1990-05-17 | 1993-08-31 | Ethyl Petroleum Additives, Inc. | Ashless dispersants formed from substituted acylating agents and their production and use |
| US5430105A (en) | 1992-12-17 | 1995-07-04 | Exxon Chemical Patents Inc. | Low sediment process for forming borated dispersant |
| BR9508038A (pt) | 1994-06-17 | 1997-11-18 | Exxon Chemical Patents Inc | Produto contendo amida de um hidrocarboneto funcionalizado processo de produção do mesmo e composição de óleo lubrificante |
| CN1203097C (zh) | 1994-07-11 | 2005-05-25 | 埃克森美孚化学专利公司 | 重多胺衍生的润滑油用琥珀酰亚胺分散剂 |
| US5565128A (en) | 1994-10-12 | 1996-10-15 | Exxon Chemical Patents Inc | Lubricating oil mannich base dispersants derived from heavy polyamine |
| US6143701A (en) * | 1998-03-13 | 2000-11-07 | Exxon Chemical Patents Inc. | Lubricating oil having improved fuel economy retention properties |
| US6074993A (en) * | 1999-10-25 | 2000-06-13 | Infineuma Usa L.P. | Lubricating oil composition containing two molybdenum additives |
| US6207623B1 (en) * | 2000-01-14 | 2001-03-27 | Exxonmobil Research And Engineering Company | Industrial oils of enhanced resistance to oxidation |
| US6660696B1 (en) * | 2002-05-24 | 2003-12-09 | Indian Oil Corporation Limited | Thermally stable phosphorothionates as antioxidant, antiwear, friction reducing and extreme pressure lubricant additives from cashew nut shell liquid |
| JP2004051758A (ja) | 2002-07-19 | 2004-02-19 | Asahi Denka Kogyo Kk | 硫黄含量の高い鉱油を基油とする潤滑油組成物 |
| US20050124507A1 (en) * | 2003-12-09 | 2005-06-09 | Watts Raymond F. | Power transmission fluids with improved friction characteristics |
| JP5203590B2 (ja) * | 2006-10-27 | 2013-06-05 | 出光興産株式会社 | 潤滑油組成物 |
| JP5512344B2 (ja) | 2010-03-23 | 2014-06-04 | 株式会社Adeka | 内燃機関用潤滑油組成物 |
| JP2011201962A (ja) * | 2010-03-24 | 2011-10-13 | Jx Nippon Oil & Energy Corp | 省燃費型エンジン油組成物 |
| KR20130100964A (ko) * | 2010-06-25 | 2013-09-12 | 제이엑스 닛코닛세키에너지주식회사 | 연비 절약형 엔진 오일 조성물 |
| KR20120011635A (ko) * | 2010-07-29 | 2012-02-08 | 현대자동차주식회사 | 연비향상형 저점도 디젤 엔진오일 조성물 |
| US9963656B2 (en) * | 2012-04-12 | 2018-05-08 | Infineum International Limited | Lubricating oil compositions |
| JP6027170B1 (ja) | 2015-03-31 | 2016-11-16 | 出光興産株式会社 | 内燃機関用潤滑油組成物 |
| JP6711512B2 (ja) | 2016-02-24 | 2020-06-17 | 出光興産株式会社 | 潤滑油組成物、及び当該潤滑油組成物の製造方法 |
-
2019
- 2019-02-18 EP EP19157843.4A patent/EP3546549B1/fr active Active
- 2019-03-19 US US16/357,925 patent/US20190300810A1/en not_active Abandoned
- 2019-03-26 KR KR1020190033983A patent/KR102706017B1/ko active Active
- 2019-03-26 CN CN201910230614.1A patent/CN110305717A/zh active Pending
- 2019-03-26 SG SG10201902658W patent/SG10201902658WA/en unknown
- 2019-03-27 JP JP2019059804A patent/JP7149887B2/ja active Active
- 2019-03-27 CA CA3038157A patent/CA3038157C/fr active Active
Also Published As
| Publication number | Publication date |
|---|---|
| CN110305717A (zh) | 2019-10-08 |
| EP3546549B1 (fr) | 2022-11-09 |
| US20190300810A1 (en) | 2019-10-03 |
| JP2019173000A (ja) | 2019-10-10 |
| EP3546549A1 (fr) | 2019-10-02 |
| KR102706017B1 (ko) | 2024-09-19 |
| CA3038157A1 (fr) | 2019-09-27 |
| JP7149887B2 (ja) | 2022-10-07 |
| KR20190113613A (ko) | 2019-10-08 |
| SG10201902658WA (en) | 2019-10-30 |
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