NO303822B1 - Process and apparatus for producing monocarboxylic acids from carbohydrates, carbohydrate derivatives or primary alcohols - Google Patents
Process and apparatus for producing monocarboxylic acids from carbohydrates, carbohydrate derivatives or primary alcoholsInfo
- Publication number
- NO303822B1 NO303822B1 NO953536A NO953536A NO303822B1 NO 303822 B1 NO303822 B1 NO 303822B1 NO 953536 A NO953536 A NO 953536A NO 953536 A NO953536 A NO 953536A NO 303822 B1 NO303822 B1 NO 303822B1
- Authority
- NO
- Norway
- Prior art keywords
- carbohydrates
- monocarboxylic acids
- primary alcohols
- carbohydrate derivatives
- oxygen
- Prior art date
Links
- 150000001719 carbohydrate derivatives Chemical class 0.000 title abstract 3
- 150000001720 carbohydrates Chemical class 0.000 title abstract 3
- 235000014633 carbohydrates Nutrition 0.000 title abstract 3
- 150000002763 monocarboxylic acids Chemical class 0.000 title abstract 3
- 150000003138 primary alcohols Chemical class 0.000 title abstract 3
- 238000000034 method Methods 0.000 title abstract 2
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 abstract 2
- 239000001301 oxygen Substances 0.000 abstract 2
- 229910052760 oxygen Inorganic materials 0.000 abstract 2
- 229910001122 Mischmetal Inorganic materials 0.000 abstract 1
- 239000007864 aqueous solution Substances 0.000 abstract 1
- 239000003054 catalyst Substances 0.000 abstract 1
- 238000000909 electrodialysis Methods 0.000 abstract 1
- 239000007789 gas Substances 0.000 abstract 1
- 238000004519 manufacturing process Methods 0.000 abstract 1
- 229910000510 noble metal Inorganic materials 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07H—SUGARS; DERIVATIVES THEREOF; NUCLEOSIDES; NUCLEOTIDES; NUCLEIC ACIDS
- C07H7/00—Compounds containing non-saccharide radicals linked to saccharide radicals by a carbon-to-carbon bond
- C07H7/02—Acyclic radicals
- C07H7/033—Uronic acids
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides
- C07C51/16—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation
- C07C51/21—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen
- C07C51/23—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen of oxygen-containing groups to carboxyl groups
- C07C51/235—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen of oxygen-containing groups to carboxyl groups of —CHO groups or primary alcohol groups
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07H—SUGARS; DERIVATIVES THEREOF; NUCLEOSIDES; NUCLEOTIDES; NUCLEIC ACIDS
- C07H3/00—Compounds containing only hydrogen atoms and saccharide radicals having only carbon, hydrogen, and oxygen atoms
- C07H3/04—Disaccharides
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Molecular Biology (AREA)
- Biochemistry (AREA)
- Biotechnology (AREA)
- General Health & Medical Sciences (AREA)
- Genetics & Genomics (AREA)
- Health & Medical Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
- Separation Using Semi-Permeable Membranes (AREA)
- Saccharide Compounds (AREA)
- Catalysts (AREA)
Abstract
In the method proposed for the production of monocarboxylic acids from carbohydrates, carbohydrate derivatives or primary alcohols, the carbohydrates, carbohydrate derivatives or primary alcohols are oxidized continuously in aqueous solution at concentrations betweeen 0.1 and 60 % by oxygen or oxygen-containing gases, using noble-metal or mischmetal catalysts. The output flow of products thus formed is fed to an electrodialysis unit and the monocarboxylic acids removed and isolated.
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE4307388A DE4307388A1 (en) | 1993-03-10 | 1993-03-10 | Method and device for producing mono-oxidized products from carbohydrates, carbohydrate derivatives and primary alcohols |
| PCT/EP1994/000695 WO1994020448A1 (en) | 1993-03-10 | 1994-03-08 | Method and device for producing monocarboxylic acids from carbohydrates, carbohydrate derivatives or primary alcohols |
Publications (3)
| Publication Number | Publication Date |
|---|---|
| NO953536L NO953536L (en) | 1995-09-08 |
| NO953536D0 NO953536D0 (en) | 1995-09-08 |
| NO303822B1 true NO303822B1 (en) | 1998-09-07 |
Family
ID=6482323
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| NO953536A NO303822B1 (en) | 1993-03-10 | 1995-09-08 | Process and apparatus for producing monocarboxylic acids from carbohydrates, carbohydrate derivatives or primary alcohols |
Country Status (22)
| Country | Link |
|---|---|
| EP (1) | EP0651734B1 (en) |
| JP (1) | JPH08509701A (en) |
| AT (1) | ATE137489T1 (en) |
| AU (1) | AU689101B2 (en) |
| BG (1) | BG61999B1 (en) |
| BR (1) | BR9405896A (en) |
| CA (1) | CA2157937C (en) |
| CZ (1) | CZ288628B6 (en) |
| DE (2) | DE4307388A1 (en) |
| DK (1) | DK0651734T3 (en) |
| ES (1) | ES2086999T3 (en) |
| FI (1) | FI110685B (en) |
| GR (1) | GR3019822T3 (en) |
| HU (1) | HU218594B (en) |
| NO (1) | NO303822B1 (en) |
| NZ (1) | NZ262903A (en) |
| PL (1) | PL174620B1 (en) |
| RO (1) | RO114606B1 (en) |
| RU (1) | RU2129541C1 (en) |
| SK (1) | SK281397B6 (en) |
| UA (1) | UA43844C2 (en) |
| WO (1) | WO1994020448A1 (en) |
Families Citing this family (15)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE19505957A1 (en) * | 1995-02-21 | 1996-08-22 | Huels Chemische Werke Ag | Process for the preparation of keto compounds |
| DE19507668C2 (en) * | 1995-03-04 | 2000-01-27 | Suedzucker Ag | Detergent formulations containing an acylated disaccharide carboxylic acid |
| DE19542303C2 (en) * | 1995-11-14 | 1998-03-26 | Suedzucker Ag | Acylated sucrose monocarboxylic acids |
| DE19542287A1 (en) * | 1995-11-14 | 1997-05-15 | Suedzucker Ag | Process for the preparation of di- and higher-oxidized carboxylic acids of carbohydrates, carbohydrate derivatives or primary alcohols |
| DE19619016A1 (en) * | 1996-05-10 | 1997-11-13 | Suedzucker Ag | Method and device for the oxidation of carbohydrates, carbohydrate derivatives or primary alcohols, in which a catalyzed oxidation takes place |
| DE19748195A1 (en) | 1997-10-31 | 1999-05-06 | Suedzucker Ag | Disaccharide derivatives for the treatment of hyperglycaemia |
| US20020038051A1 (en) | 2000-02-18 | 2002-03-28 | Degussa-Huls Ag | Raney copper |
| RU2185369C1 (en) * | 2001-04-02 | 2002-07-20 | Тверской государственный технический университет РАН | Method of synthesis of 2-keto-l-gulonic acid |
| DE10227432B4 (en) * | 2002-06-20 | 2006-11-30 | Südzucker AG Mannheim/Ochsenfurt | Process for the separation of carbohydrate carboxylic acids |
| DE10319917B4 (en) * | 2003-05-05 | 2009-01-02 | Südzucker AG Mannheim/Ochsenfurt | Method for selective carbohydrate oxidation using supported gold catalysts |
| RU2242456C1 (en) * | 2003-08-13 | 2004-12-20 | Закрытое акционерное общество "Каустик" | Method for production of c4-c8-monocarboxylic acid |
| RU2245324C1 (en) * | 2003-09-08 | 2005-01-27 | Тверской государственный технический университет | Method for preparing 2-keto-l-gulonic acid |
| DE102005036890A1 (en) * | 2005-08-05 | 2007-02-08 | Südzucker AG Mannheim/Ochsenfurt | Supported gold catalyst |
| US8383837B2 (en) * | 2007-06-05 | 2013-02-26 | Dsm Ip Assets B.V. | Reaction with a gold catalyst |
| WO2019043069A1 (en) * | 2017-08-29 | 2019-03-07 | Julius-Maximilians-Universitaet Wuerzburg | A new class of sucrose esters and a method for their preparation |
Family Cites Families (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| SU109712A1 (en) * | 1949-09-30 | 1956-11-30 | С.М. Мещанинов | Method for continuous oxidation of hydrocarbons |
| DE3020104A1 (en) * | 1980-05-27 | 1981-12-03 | Merck Patent Gmbh, 6100 Darmstadt | METHOD FOR PRODUCING DIACETONE KETOGULONIC ACID |
| JPS6054338A (en) * | 1983-09-05 | 1985-03-28 | Mitsui Toatsu Chem Inc | Preparation of 2-keto-l-gulonic acid |
| DE3446695A1 (en) * | 1984-12-21 | 1986-06-26 | Basf Ag, 6700 Ludwigshafen | METHOD FOR CONCENTRATING AQUEOUS SOLUTIONS OF ORGANIC COMPOUNDS CONTAINING SALT, WITH A SIMULTANEOUS REDUCTION OF SALT |
| DE3522032A1 (en) * | 1985-06-20 | 1987-01-02 | Hoechst Ag | METHOD FOR THE PRODUCTION OF CARBONIC ACIDS |
| FR2597473B1 (en) * | 1986-01-30 | 1988-08-12 | Roquette Freres | PROCESS FOR THE OXIDATION OF DI-, TRI-, OLIGO- AND POLYSACCHARIDES TO POLYHYDROXYCARBOXYLIC ACIDS, CATALYST IMPLEMENTED AND PRODUCTS THUS OBTAINED. |
| DE3803465A1 (en) * | 1988-02-05 | 1989-08-17 | Huels Chemische Werke Ag | METHOD FOR PRODUCING OXIDIZED SUBSTITUTED SACCHARIDES |
| DE3916206A1 (en) * | 1989-05-18 | 1990-11-22 | Hoechst Ag | METHOD FOR PRODUCING 1-FLUOR-GLYCURONIC ACIDS AND THEIR SALTS, AND SUCH NEW 1-FLOUR-GLYCURONIC ACIDS AND THEIR SALTS |
-
1993
- 1993-03-10 DE DE4307388A patent/DE4307388A1/en not_active Withdrawn
-
1994
- 1994-03-08 DK DK94910390.7T patent/DK0651734T3/en active
- 1994-03-08 BR BR9405896A patent/BR9405896A/en not_active IP Right Cessation
- 1994-03-08 AU AU62835/94A patent/AU689101B2/en not_active Ceased
- 1994-03-08 AT AT94910390T patent/ATE137489T1/en not_active IP Right Cessation
- 1994-03-08 RU RU95121941A patent/RU2129541C1/en not_active IP Right Cessation
- 1994-03-08 WO PCT/EP1994/000695 patent/WO1994020448A1/en not_active Ceased
- 1994-03-08 ES ES94910390T patent/ES2086999T3/en not_active Expired - Lifetime
- 1994-03-08 DE DE59400253T patent/DE59400253D1/en not_active Expired - Lifetime
- 1994-03-08 NZ NZ262903A patent/NZ262903A/en not_active IP Right Cessation
- 1994-03-08 EP EP94910390A patent/EP0651734B1/en not_active Expired - Lifetime
- 1994-03-08 RO RO95-01572A patent/RO114606B1/en unknown
- 1994-03-08 CZ CZ19952310A patent/CZ288628B6/en not_active IP Right Cessation
- 1994-03-08 HU HU9501726A patent/HU218594B/en not_active IP Right Cessation
- 1994-03-08 JP JP6519588A patent/JPH08509701A/en active Pending
- 1994-03-08 SK SK1099-95A patent/SK281397B6/en unknown
- 1994-03-08 CA CA002157937A patent/CA2157937C/en not_active Expired - Fee Related
- 1994-03-08 PL PL94309642A patent/PL174620B1/en not_active IP Right Cessation
- 1994-08-03 UA UA95094017A patent/UA43844C2/en unknown
-
1995
- 1995-07-10 FI FI953372A patent/FI110685B/en active
- 1995-09-08 NO NO953536A patent/NO303822B1/en unknown
- 1995-09-22 BG BG100021A patent/BG61999B1/en unknown
-
1996
- 1996-05-02 GR GR960401130T patent/GR3019822T3/en unknown
Also Published As
| Publication number | Publication date |
|---|---|
| RO114606B1 (en) | 1999-06-30 |
| UA43844C2 (en) | 2002-01-15 |
| BR9405896A (en) | 1995-12-12 |
| AU689101B2 (en) | 1998-03-26 |
| DE4307388A1 (en) | 1994-09-15 |
| HUT73732A (en) | 1996-09-30 |
| CA2157937C (en) | 2003-05-06 |
| HU9501726D0 (en) | 1995-08-28 |
| FI953372A0 (en) | 1995-07-10 |
| SK281397B6 (en) | 2001-03-12 |
| ATE137489T1 (en) | 1996-05-15 |
| CZ231095A3 (en) | 1996-01-17 |
| NZ262903A (en) | 1996-11-26 |
| BG61999B1 (en) | 1998-12-30 |
| ES2086999T3 (en) | 1996-07-01 |
| FI953372L (en) | 1995-07-10 |
| EP0651734A1 (en) | 1995-05-10 |
| FI110685B (en) | 2003-03-14 |
| NO953536L (en) | 1995-09-08 |
| DE59400253D1 (en) | 1996-06-05 |
| HU218594B (en) | 2000-10-28 |
| CA2157937A1 (en) | 1994-09-15 |
| DK0651734T3 (en) | 1996-06-10 |
| GR3019822T3 (en) | 1996-08-31 |
| BG100021A (en) | 1996-05-31 |
| SK109995A3 (en) | 1995-12-06 |
| PL309642A1 (en) | 1995-10-30 |
| NO953536D0 (en) | 1995-09-08 |
| EP0651734B1 (en) | 1996-05-01 |
| CZ288628B6 (en) | 2001-08-15 |
| RU2129541C1 (en) | 1999-04-27 |
| WO1994020448A1 (en) | 1994-09-15 |
| AU6283594A (en) | 1994-09-26 |
| PL174620B1 (en) | 1998-08-31 |
| JPH08509701A (en) | 1996-10-15 |
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