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MX2017016861A - Metodo de calibracion para medicion de la dureza del agua. - Google Patents

Metodo de calibracion para medicion de la dureza del agua.

Info

Publication number
MX2017016861A
MX2017016861A MX2017016861A MX2017016861A MX2017016861A MX 2017016861 A MX2017016861 A MX 2017016861A MX 2017016861 A MX2017016861 A MX 2017016861A MX 2017016861 A MX2017016861 A MX 2017016861A MX 2017016861 A MX2017016861 A MX 2017016861A
Authority
MX
Mexico
Prior art keywords
calibration method
calibration
water hardness
hardness measurement
present
Prior art date
Application number
MX2017016861A
Other languages
English (en)
Inventor
Li Hui
Knoth Alexandra
Schwartz Joe
Brant Wilson Christopher
Kahaian Arthur
Original Assignee
Ecolab Usa Inc
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Ecolab Usa Inc filed Critical Ecolab Usa Inc
Publication of MX2017016861A publication Critical patent/MX2017016861A/es

Links

Classifications

    • G—PHYSICS
    • G01—MEASURING; TESTING
    • G01N—INVESTIGATING OR ANALYSING MATERIALS BY DETERMINING THEIR CHEMICAL OR PHYSICAL PROPERTIES
    • G01N33/00—Investigating or analysing materials by specific methods not covered by groups G01N1/00 - G01N31/00
    • G01N33/18—Water
    • G01N33/1853—Hardness of water
    • G—PHYSICS
    • G01—MEASURING; TESTING
    • G01N—INVESTIGATING OR ANALYSING MATERIALS BY DETERMINING THEIR CHEMICAL OR PHYSICAL PROPERTIES
    • G01N21/00—Investigating or analysing materials by the use of optical means, i.e. using sub-millimetre waves, infrared, visible or ultraviolet light
    • G01N21/17—Systems in which incident light is modified in accordance with the properties of the material investigated
    • G01N21/25—Colour; Spectral properties, i.e. comparison of effect of material on the light at two or more different wavelengths or wavelength bands
    • G01N21/27—Colour; Spectral properties, i.e. comparison of effect of material on the light at two or more different wavelengths or wavelength bands using photo-electric detection ; circuits for computing concentration
    • G01N21/274—Calibration, base line adjustment, drift correction
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09B—ORGANIC DYES OR CLOSELY-RELATED COMPOUNDS FOR PRODUCING DYES, e.g. PIGMENTS; MORDANTS; LAKES
    • C09B11/00—Diaryl- or thriarylmethane dyes
    • C09B11/04—Diaryl- or thriarylmethane dyes derived from triarylmethanes, i.e. central C-atom is substituted by amino, cyano, alkyl
    • C09B11/10—Amino derivatives of triarylmethanes
    • C09B11/24—Phthaleins containing amino groups ; Phthalanes; Fluoranes; Phthalides; Rhodamine dyes; Phthaleins having heterocyclic aryl rings; Lactone or lactame forms of triarylmethane dyes
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09B—ORGANIC DYES OR CLOSELY-RELATED COMPOUNDS FOR PRODUCING DYES, e.g. PIGMENTS; MORDANTS; LAKES
    • C09B67/00—Influencing the physical, e.g. the dyeing or printing properties of dyestuffs without chemical reactions, e.g. by treating with solvents grinding or grinding assistants, coating of pigments or dyes; Process features in the making of dyestuff preparations; Dyestuff preparations of a special physical nature, e.g. tablets, films
    • C09B67/0071—Process features in the making of dyestuff preparations; Dehydrating agents; Dispersing agents; Dustfree compositions
    • C09B67/0083—Solutions of dyes
    • G—PHYSICS
    • G01—MEASURING; TESTING
    • G01N—INVESTIGATING OR ANALYSING MATERIALS BY DETERMINING THEIR CHEMICAL OR PHYSICAL PROPERTIES
    • G01N21/00—Investigating or analysing materials by the use of optical means, i.e. using sub-millimetre waves, infrared, visible or ultraviolet light
    • G01N21/62—Systems in which the material investigated is excited whereby it emits light or causes a change in wavelength of the incident light
    • G01N21/63—Systems in which the material investigated is excited whereby it emits light or causes a change in wavelength of the incident light optically excited
    • G01N21/64—Fluorescence; Phosphorescence
    • G01N21/6428—Measuring fluorescence of fluorescent products of reactions or of fluorochrome labelled reactive substances, e.g. measuring quenching effects, using measuring "optrodes"
    • G—PHYSICS
    • G01—MEASURING; TESTING
    • G01N—INVESTIGATING OR ANALYSING MATERIALS BY DETERMINING THEIR CHEMICAL OR PHYSICAL PROPERTIES
    • G01N21/00—Investigating or analysing materials by the use of optical means, i.e. using sub-millimetre waves, infrared, visible or ultraviolet light
    • G01N21/62—Systems in which the material investigated is excited whereby it emits light or causes a change in wavelength of the incident light
    • G01N21/63—Systems in which the material investigated is excited whereby it emits light or causes a change in wavelength of the incident light optically excited
    • G01N21/64—Fluorescence; Phosphorescence
    • G01N21/6428—Measuring fluorescence of fluorescent products of reactions or of fluorochrome labelled reactive substances, e.g. measuring quenching effects, using measuring "optrodes"
    • G01N21/643—Measuring fluorescence of fluorescent products of reactions or of fluorochrome labelled reactive substances, e.g. measuring quenching effects, using measuring "optrodes" non-biological material
    • G—PHYSICS
    • G01—MEASURING; TESTING
    • G01N—INVESTIGATING OR ANALYSING MATERIALS BY DETERMINING THEIR CHEMICAL OR PHYSICAL PROPERTIES
    • G01N21/00—Investigating or analysing materials by the use of optical means, i.e. using sub-millimetre waves, infrared, visible or ultraviolet light
    • G01N21/62—Systems in which the material investigated is excited whereby it emits light or causes a change in wavelength of the incident light
    • G01N21/63—Systems in which the material investigated is excited whereby it emits light or causes a change in wavelength of the incident light optically excited
    • G01N21/64—Fluorescence; Phosphorescence
    • G01N21/645—Specially adapted constructive features of fluorimeters
    • G—PHYSICS
    • G01—MEASURING; TESTING
    • G01N—INVESTIGATING OR ANALYSING MATERIALS BY DETERMINING THEIR CHEMICAL OR PHYSICAL PROPERTIES
    • G01N21/00—Investigating or analysing materials by the use of optical means, i.e. using sub-millimetre waves, infrared, visible or ultraviolet light
    • G01N21/17—Systems in which incident light is modified in accordance with the properties of the material investigated
    • G01N21/25—Colour; Spectral properties, i.e. comparison of effect of material on the light at two or more different wavelengths or wavelength bands
    • G01N21/27—Colour; Spectral properties, i.e. comparison of effect of material on the light at two or more different wavelengths or wavelength bands using photo-electric detection ; circuits for computing concentration
    • G01N21/274—Calibration, base line adjustment, drift correction
    • G01N21/278—Constitution of standards
    • G—PHYSICS
    • G01—MEASURING; TESTING
    • G01N—INVESTIGATING OR ANALYSING MATERIALS BY DETERMINING THEIR CHEMICAL OR PHYSICAL PROPERTIES
    • G01N2201/00—Features of devices classified in G01N21/00
    • G01N2201/12—Circuits of general importance; Signal processing
    • G01N2201/127—Calibration; base line adjustment; drift compensation
    • G—PHYSICS
    • G01—MEASURING; TESTING
    • G01N—INVESTIGATING OR ANALYSING MATERIALS BY DETERMINING THEIR CHEMICAL OR PHYSICAL PROPERTIES
    • G01N33/00—Investigating or analysing materials by specific methods not covered by groups G01N1/00 - G01N31/00
    • G01N33/18—Water
    • G01N33/1813—Specific cations in water, e.g. heavy metals

Landscapes

  • Health & Medical Sciences (AREA)
  • Chemical & Material Sciences (AREA)
  • Physics & Mathematics (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Immunology (AREA)
  • Analytical Chemistry (AREA)
  • Biochemistry (AREA)
  • General Health & Medical Sciences (AREA)
  • General Physics & Mathematics (AREA)
  • Pathology (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Nuclear Medicine, Radiotherapy & Molecular Imaging (AREA)
  • Engineering & Computer Science (AREA)
  • Optics & Photonics (AREA)
  • Organic Chemistry (AREA)
  • Molecular Biology (AREA)
  • Mathematical Physics (AREA)
  • Theoretical Computer Science (AREA)
  • Spectroscopy & Molecular Physics (AREA)
  • Medicinal Chemistry (AREA)
  • Food Science & Technology (AREA)
  • Investigating, Analyzing Materials By Fluorescence Or Luminescence (AREA)
  • Investigating Or Analysing Materials By The Use Of Chemical Reactions (AREA)
  • Investigating Or Analyzing Non-Biological Materials By The Use Of Chemical Means (AREA)
  • Tires In General (AREA)

Abstract

La presente invención se relaciona con métodos que pueden usarse para calibrar automáticamente un instrumento de medición de fluorescencia capaz de medir continuamente la concentración de la dureza en agua de proceso. El método de calibración se usa para compensar el desplazamiento de instrumento y equipo, los cambios de condiciones operacionales y la contaminación de reactivos y estándares de calibración. La calibración del instrumento de medición de la fluorescencia usando el presente método de calibración mejora la exactitud y la capacidad de repetición para las mediciones de la concentración de dureza subsecuentes.
MX2017016861A 2015-07-01 2016-07-01 Metodo de calibracion para medicion de la dureza del agua. MX2017016861A (es)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US201562187559P 2015-07-01 2015-07-01
PCT/US2016/040751 WO2017004553A1 (en) 2015-07-01 2016-07-01 Calibration method for water hardness measurement

Publications (1)

Publication Number Publication Date
MX2017016861A true MX2017016861A (es) 2018-04-10

Family

ID=56611558

Family Applications (1)

Application Number Title Priority Date Filing Date
MX2017016861A MX2017016861A (es) 2015-07-01 2016-07-01 Metodo de calibracion para medicion de la dureza del agua.

Country Status (10)

Country Link
US (1) US10317385B2 (es)
EP (2) EP4224144B1 (es)
JP (1) JP6773692B2 (es)
CN (1) CN107771279B (es)
AU (1) AU2016288252B2 (es)
BR (1) BR112017026865B1 (es)
CA (1) CA2989956C (es)
ES (2) ES3052582T3 (es)
MX (1) MX2017016861A (es)
WO (1) WO2017004553A1 (es)

Families Citing this family (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
AU2019226561B2 (en) * 2018-03-02 2024-09-19 Ecolab Usa Inc. Ultralow range fluorometer calibration
CN113242760B (zh) 2018-12-21 2023-10-03 埃科莱布美国股份有限公司 用于监测渗透膜完整性的快速示踪剂注射
JP7148136B2 (ja) * 2019-01-17 2022-10-05 国立大学法人大阪大学 水の硬度の測定
US11162933B2 (en) * 2019-09-11 2021-11-02 Haier Us Appliance Solutions, Inc. System and method for detecting heavy metals in a fluid
CA3182200A1 (en) 2020-06-30 2022-01-06 Hui Li Linearized optical sensor calibration for measuring calcium
CN119044430A (zh) * 2024-08-22 2024-11-29 厦门市吉龙德环境工程有限公司 一种适用于水质硬度在线分析仪的硬度测定方法

Family Cites Families (50)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3960497A (en) 1975-08-19 1976-06-01 Beckman Instruments, Inc. Chemical analyzer with automatic calibration
US4355072A (en) 1980-02-12 1982-10-19 U.S. Philips Corporation Magnetic hexagonal ferrite layer on a nonmagnetic hexagonal mixed crystal substrate
US4383043A (en) 1981-07-13 1983-05-10 American Monitor Corporation Magnesium assay with calmagite or eriochrome black T reagents
US4457847B2 (en) 1981-11-05 1996-12-31 Nalco Chemical Co Carboxylate polymers for internal scale control agents in boiler systems
US4545920A (en) 1982-05-28 1985-10-08 Nalco Chemical Company Boiler water treating compositions
US4999305A (en) 1985-07-10 1991-03-12 Wolcott Duane K Apparatus for titration flow injection analysis
US4711726A (en) 1986-12-29 1987-12-08 Nalco Chemical Company Carboxylate N-vinylamide copolymers for internal scale control and passivation in high pressure boiler systems
US5173434A (en) 1990-11-05 1992-12-22 Baxter Diagnostics Inc. Measurement of color reactions by monitoring a change of fluorescence
US5041386A (en) 1988-12-19 1991-08-20 Nalco Chemical Company Concentration cycles, percent life holding time and continuous treatment concentration monitoring in boiler systems by inert tracers
DE69032422T2 (de) 1989-12-15 1999-02-04 F. Hoffmann-La Roche Ag, Basel Reagenzzusammensetzung, Verfahren und Kits zur Quantifizierung von Magnesium oder Calcium und Magnesium
US5094958A (en) 1990-08-30 1992-03-10 Fiberchem Inc. Method of self-compensating a fiber optic chemical sensor
JP3024301B2 (ja) * 1991-09-18 2000-03-21 栗田工業株式会社 アゾール類の濃度管理方法
US5302253A (en) 1992-04-13 1994-04-12 Nalco Chemical Company On-line acid monitor and neutralizer feed control of the overhead water in oil refineries
US5324665A (en) 1992-11-18 1994-06-28 Nalco Chemical Company On-line method for monitoring chloride levels in a fluid stream
US5425267A (en) 1993-08-31 1995-06-20 Nalco Chemical Company Corrosion simulator and method for simulating corrosion activity of a process stream
US5462880A (en) 1993-09-13 1995-10-31 Optical Sensors Incorporated Ratiometric fluorescence method to measure oxygen
US5384050A (en) 1993-11-04 1995-01-24 Nalco Chemical Company Hydrazones as oxygen scavengers in boiler water systems
US5411889A (en) * 1994-02-14 1995-05-02 Nalco Chemical Company Regulating water treatment agent dosage based on operational system stresses
US5672515A (en) 1995-09-12 1997-09-30 Optical Sensors Incorporated Simultaneous dual excitation/single emission fluorescent sensing method for PH and pCO2
US5736405A (en) * 1996-03-21 1998-04-07 Nalco Chemical Company Monitoring boiler internal treatment with fluorescent-tagged polymers
US5734098A (en) 1996-03-25 1998-03-31 Nalco/Exxon Energy Chemicals, L.P. Method to monitor and control chemical treatment of petroleum, petrochemical and processes with on-line quartz crystal microbalance sensors
JP3545928B2 (ja) * 1997-12-26 2004-07-21 富士電機ホールディングス株式会社 マグネシウムイオン濃度測定装置
US6336058B1 (en) 2000-05-01 2002-01-01 Nalco Chemical Company Use of control matrix for boiler control
US6587753B2 (en) 2000-05-01 2003-07-01 Ondeo Nalco Company Use of control matrix for boiler control
US6735535B1 (en) 2000-05-05 2004-05-11 Electro Industries/Gauge Tech. Power meter having an auto-calibration feature and data acquisition capabilities
US6436711B1 (en) 2000-12-13 2002-08-20 Nalco Chemical Company Fluorometric control of aromatic oxygen scavengers in a boiler system
US6790666B2 (en) 2001-12-28 2004-09-14 Nalco Company Method to ascertain whether soluble hardness is calcium or magnesium based
US6790664B2 (en) 2001-12-28 2004-09-14 Nalco Company Fluorometric monitoring and control of soluble hardness of water used in industrial water systems
US7220382B2 (en) 2003-07-31 2007-05-22 Nalco Company Use of disulfonated anthracenes as inert fluorescent tracers
JP5103015B2 (ja) * 2004-08-11 2012-12-19 ミズ株式会社 電解機能水生成装置における性能維持方法
CA2577340A1 (en) 2004-08-19 2006-03-02 Blood Cell Storage, Inc. Fluorescent ph detector system and related methods
US20060246595A1 (en) 2005-05-02 2006-11-02 Banks Rodney H Method for using an all solid-state fluorometer in monitoring and controlling chemicals in water
MY152491A (en) 2005-10-26 2014-10-15 Gen Electric Methods and systems for delivery of fluidic samples to sensor arrays
US7402424B2 (en) 2006-02-01 2008-07-22 Schlumberger Technology Corporation Spectroscopic pH measurement at high-temperature and/or high-pressure
US8147758B2 (en) * 2006-06-23 2012-04-03 General Electric Company Water hardness sensor system
US7448255B2 (en) 2006-06-29 2008-11-11 Nalco Company Very high-temperature fluorescent tracer and automation for boiler water applications
CN101210930A (zh) * 2006-12-27 2008-07-02 中国科学院沈阳应用生态研究所 一种测定血清中镁含量的方法
US8658094B2 (en) 2007-01-29 2014-02-25 Nalco Company High temperature and pressure oxidation-reduction potential measuring and monitoring device for hot water systems
US8658095B2 (en) 2007-01-29 2014-02-25 Nalco Company High temperature and pressure oxidation-reduction potential measuring and monitoring device for hot water systems
US7951298B2 (en) 2007-09-10 2011-05-31 Nalco Company Method and device for preventing corrosion in hot water systems undergoing intermittent operations
US7955853B2 (en) 2007-07-24 2011-06-07 Nalco Company Method and device for creating and analyzing an at temerature and pressure oxidation-reduction potential signature in hot water systems for preventing corrosion
JP5631215B2 (ja) 2007-11-21 2014-11-26 メドトロニック ミニメド インコーポレイテッド 血糖管理維持システム
US8068033B2 (en) 2008-10-31 2011-11-29 Nalco Company Method of detecting contamination in industrial process boiler systems
US9150793B2 (en) 2008-11-03 2015-10-06 Nalco Company Method of reducing corrosion and corrosion byproduct deposition in a crude unit
US8352207B2 (en) * 2010-03-31 2013-01-08 Ecolab Usa Inc. Methods for calibrating a fluorometer
US8951472B2 (en) * 2010-07-19 2015-02-10 Andalyze, Inc. Portable fluorimetric apparatus, method and system
US9134238B2 (en) 2010-12-01 2015-09-15 Nalco Company Method for determination of system parameters for reducing crude unit corrosion
EP2657681A1 (en) * 2012-04-26 2013-10-30 Roche Diagnostics GmbH Improvement of the sensitivity and the dynamic range of photometric assays by generating multiple calibration curves
US8956875B2 (en) 2013-03-14 2015-02-17 Ecolab USA, Inc. Water hardness monitoring via fluorescence
CA2923839C (en) 2013-09-13 2021-12-07 Ecolab Usa Inc. Multi-compartment package

Also Published As

Publication number Publication date
AU2016288252A1 (en) 2017-12-21
AU2016288252B2 (en) 2021-08-12
JP6773692B2 (ja) 2020-10-21
CA2989956C (en) 2024-05-14
ES2953378T3 (es) 2023-11-10
US10317385B2 (en) 2019-06-11
CN107771279B (zh) 2022-03-22
JP2018519513A (ja) 2018-07-19
EP4224144A1 (en) 2023-08-09
ES3052582T3 (en) 2026-01-12
CA2989956A1 (en) 2017-01-05
WO2017004553A1 (en) 2017-01-05
EP3317644A1 (en) 2018-05-09
CN107771279A (zh) 2018-03-06
BR112017026865A2 (pt) 2020-06-30
EP3317644C0 (en) 2023-07-19
EP3317644B1 (en) 2023-07-19
EP4224144C0 (en) 2025-10-08
EP4224144B1 (en) 2025-10-08
US20170003261A1 (en) 2017-01-05
BR112017026865B1 (pt) 2021-08-31

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