- Is good at Brazilian martial art, "Capoeira". He demonstrates this in the Lazer Field scene in Doze Homens e Outro Segredo (2004).
- Learned conversational Russian in a matter of two months, for playing the Russian character "Kirill" in Senhores do Crime (2007).
- He usually does the voice-over for actor Hugh Grant in French versions.
- Travels so often to Bahia (Brazil), that he has even learned how to speak an almost flawless Portuguese.
- His nose got broken while filming a fight scene in Rios Vermelhos (2000).
- Did the voice of Diego in the French version of A Era do Gelo (2002).
- Made his English language debut in Elizabeth (1998).
- Monica Bellucci gave birth to their second daughter Léonie in Rome, Italy (21 May 2010).
- Met Maria Callas at his father's home when he was a child.
- His collaboration with writer/director/actor Mathieu Kassovitz in a handful of films turned him into a popular and versatile French "tough guy" star.
- For professional reasons, Vincent lives mostly in Paris while his Italian-born wife, Monica Bellucci, lives mostly in London. Despite this, they have appeared in the following films together: Satã (2006), Agentes Secretos (2004), Irreversível (2002), O Pacto dos Lobos (2001), Méditerranées (1999), Le plaisir (et ses petits tracas) (1998), Compromis (1998), Dobermann (1997), Come mi vuoi (1996) and O Apartamento (1996).
- Both Vincent and his former wife, Monica Bellucci, have been the Master of Ceremonies at the Cannes film festival: Vincent in 2006, Monica in 2003.
- When he was a little boy, he had a dog called Ici (French for "Here").
- Once enrolled in circus school at the age of 17 before starting up in TV and films.
- Was scheduled to appear with his father, Jean-Pierre Cassel in Inimigo Público nº 1 - Parte 2 (2008). They had previously appeared together in Rios Vermelhos (2000), Valse nocturne (1995) and Métisse (1993).
- His brother, Rockin' Squat (aka Mathias Cassel), is a founding member of the rap group "Assassin". Vincent's name is mentioned (as "Vinz") in their song "Libre".
- Vincent and Tina welcomed their first child, daughter Amazonie, on April 20, 2019.
- The films that he prefers from his own career are, "O Ódio (1995)" and "Blueberry - Desejo de Vingança (2004)".
- He decided to become an actor at fifteen years of age.
- He is a skilled martial artist who is trained in Capoeira and Wing Chun.
- French citizen. His father is actor Jean-Pierre Cassel and his mother is a journalist, Sabine Cassel (aka Sabine Litique). They divorced in 1980.
- When he saw the short film Fierrot le pou (1990) by Mathieu Kassovitz, he thought it perfectly represented the energy of their generation.
- First daughter, Deva, born 12 September 2004 in Rome, Italy.
- Older half-brother of Cécile Cassel. Vincent also had a sister named Olivia.
- Has his look-alike puppet in the French show Les Guignols de l'info (1988).
- Attended Carnival in Rio de Janeiro, Brazil with his wife, 'Monica Bellucci'. (2008)
- Became a father for the fourth time at age 58, when his girlfriend Nara Baptista gave birth to their son Caetano (b. January 7th, 2025).
- His pet dog is called "Ici" which is French for "here".
- In France, filming Satã (2006) ("Le Sheitan"). (abril de 2005)
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