- Younger brother of Diego Milito.
- Defender for C.A. Independiente (Avellaneda, 1997-2003, 2011-12), Real Zaragoza (Spain, 2003-2007) and FC Barcelona (Spain, 2007-2011); in all 421 games and 11 goals.
- 1997: Began his professional soccer career at the 17 age.
- Honours with C.A. Independiente: Argentine League (2002). Honours with Real Zaragoza: Spanish Cup (2004) and Spanish Super Cup (2004). Honours with FC Barcelona: Spanish Cup (2009), Spanish League (2009, 2010, 2011), Spanish Super Cup (2009, 2010), UEFA Champions League (2009, 2011), UEFA Super Cup (2009) and FIFA Club World Cup (2009).
- 42 appearances for Argentina National Football Team (2000-2011). Member of the Copa América 2007, 2011, Confederations Cup 2005, and the Germany '06 squads.
- Father of, with Silvina Santarelli, Santiago Milito (b. 2003) and Luca Milito (b. 2008).
- Member of the Argentina National team who finished runner-up at the 2005 FIFA Confederations Cup and 2007 Copa América.
- 2012: Retired from football player at the age 31.
- Was the youngest captain of the C.A. Independiente.
- Won the Footballer of the Year of Argentina award in 2002.
- Won the treble with FC Barcelona (La Liga, Copa del Rey and UEFA Champions League) in 2009.
- Played well over 150 games for C.A. Independiente and Real Zaragoza.
- Head coach of Estudiantes de La Plata (2015, 2019-20), C.A. Independiente (2016), O'Higgins F.C. (2017-18) and Argentinos Juniors (2021-).
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