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The Captains of the Thirteen Court Guard Squads are considered the strongest Soul Reapers in Bleach, and Mayuri Kurotsuchi is the Captain of Squad 12. Mayuri is the Soul Society's resident mad scientist, and he does not mind hurting or even killing his subordinates for research purposes. He may not be as skilled as other Captains, but he can defeat several powerful characters with his inventions and modified Zanpakutō.

Mayuri can defeat several of his fellow Captains, all of whom possess Shikai and Bankai releases of their own. He can also defeat a few Quincy, including one of Yhwach's elite bodyguards. Mayuri can defeat many of these characters with his Shikai, which can paralyze his opponents with a single cut. His living Bankai produces lethal poison and can eat his opponents. It can also counter virtually any ability.

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Jshir Ukitake has been the Captain of Squad 13 for more than a century, making him one of the strongest characters in Bleach. Ukitake has been dealing with a fatal illness his entire life, and it takes a significant toll on his body. This illness sometimes rears its head during important fights, leaving Ukitake immobilized for quite some time. That said, Ukitake is a powerful Soul Reaper who can defeat several notable characters.

Ukitake can defeat several Sternritter and Espada-ranked Arrancar, but he can beat a few Soul Reapers as well. His Zanpakuto is called Sogyo no Kotowari, and its Shikai can absorb energy-based attacks and redirect them back at the original user at full force. He can defeat a lot of characters with this Shikai, but he can also beat certain characters with his swordsmanship and Kido knowledge.

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