- Was in an on-off relationship with Argentine actress Juana Viale from 2005 to 2014.
- Studied acting at Fernando González's school.
- His sister, Luz Francisca Valenzuela, was crowned Miss World Chile in 1996.
- His older half-brother Fernando Prado (actor) died at age 28 in a home accident on December 31, 1996.
- His parents, Gonzalo Valenzuela and Mariana Hölzel, died from cancer when Gonzalo was 23 years old (2001).
- Was romantically linked to Ángela Prieto, Carolina Ardohain, Marisela Santibáñez, Javiera Acevedo, Cecilia Bolocco, Verónica Soffia, Adriana Barrientos and Constanza Capelli.
- Owns with his best friend Benjamín Vicuña, theater in Santiago de Chile called "Mori" with rooms in Providencia, Las Condes, Vitacura and Recoleta.
- Became a father for the 1st time at age 29 when his girlfriend Juana Viale gave birth to their son Silvestre Valenzuela on January 23, 2008 in Santiago, Chile.
- Second son with Juana Viale, named Ringo was stillborn on May 25, 2011.
- Became a father for the 3rd time at age 34 when his girlfriend Juana Viale gave birth to their son Alí Valenzuela on March 16, 2012 in Buenos Aires, Argentina.
- Was in an on-off relationship with María Gracia Omegna co-star Papá a la Deriva (2015) from 2015 to 2021.
- Is an avid golfer, boxer and poker player.
- Co-owns, with Diego Muñoz, a box fit center in Santiago called Club Ringo.
- Lived between Chile and Argentina (2005-2019).
- Became a father for the 4th time at age 41 when his girlfriend María Gracia Omegna gave birth to their daughter Anka Valenzuela in September, 2019 in Santiago, Chile.
- Ex-boyfriend of Maite Orsini from 2021-2022.
- Resided in Laguna de Zapallar from 2020-2024.
- Owned a boxing school called "Ring Lagunita".
- In a relationship with Kika Silva since 2023.
- Close friends with Benjamín Vicuña, Diego Muñoz, Nicolás Torres, Nikolás Bottinelli and Pablo Larraín.
- Turned down Benjamín Vicuña's role in Prófugos (2011).
- His old nickname "Manguera" is because the name of his character in the play 'Sinvergüenzas' (adaption of The Full Monty: Le grand jeu (1997)) that rise to fame.
- Was a golfer from the 6-14 age.
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