- Cited American Psycho (2000) as one of his favorite films, having frequently watched it with his Gossip Girl (2007) co-star Chace Crawford.
- Was the leader singer of the British rock band The Filthy Youth.
- Modeled his Gossip Girl (2007) character (Chuck Bass)'s American accent after the character Carlton Banks from Willy, il principe di Bel Air (1990).
- During an interview with Radio 1 he said that his favorite movies are Il cavaliere oscuro (2008) and Il padrino - Parte II (1974).
- Was in a relationship with actress and former Gossip Girl (2007) co-star Jessica Szohr from December of 2008 until April of 2010. He was also in a relationship with actress and model Jessica Serfaty from May 2017 until the fall of 2018.
- Was the face of the 2011/2012 campaign for the Philippine clothing brand Penshoppe.
- The youngest of three brothers, Westwick is the son of Carole, an educational psychologist, and Peter, a lecturer in business studies.
- On January 29, 2024. Westwicks announces his engagement to British actress Amy Jackson. After two years of dating.
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